导电高聚物PPV及其掺杂后结构的电镜研究

本文应用电子衍射、衍衬及低剂量高分辨成像等方法研究了导电高聚物ＰＰＶ及其ＦｅＣｌ３掺杂后的形态、结构与取向分布函数。     

轻质宽频导电高分子微波吸收材料研究

导电高分子材料(PA、PAn、PPy、PTh、PPV等)具有分子结构可设计、成本低、易合成、加工方便,同时又具有对不同频率的微波产生吸收,且吸收频段宽、比重轻(密度:1.0～2.0g/cm3)、热稳定性好等特点,有望发展成为新型宽频有机吸波材料[1].文章对导电高分子微波吸收材料的吸波原理、分类和制备方法及近期国内外研究进展进行了介绍.     

导电聚苯胺／羰基铁粉复合吸收效能的研究

利用软磁金属粉末羰基铁粉的良好电磁吸收特性,加入不等量的导电聚苯胺,制备成导电聚苯胺／羰基铁粉复合材料。在1．8mm厚的涂层中,随导电聚苯胺含量的增加,其吸波效能得到显著改善。分析表明,导电聚苯胺／羰基铁粉有利于发展成为轻质、宽频、强吸收的优良吸波材料。     

ZnSe纳米晶材料的超快吸收谱

通过改进的溶剂热方法,以KBH4作为还原剂,在三乙胺溶液介质中制备了ZnSe纳米晶材料.与ZnSe体材料相比,其纳米材料的稳态吸收边发生了蓝移,而且纳米颗粒的尺寸越小,蓝移量越大,这是由于随着尺度减少而引起的量子限制效应增强造成的.对在溶液中的ZnSe纳米颗粒的超快吸收谱的研究表明,当纳米颗粒的平均尺寸为75nm时,电子-声子散射时间为8.74ps;当平均尺寸为45nm时,散射时间为2.77ps.随着纳米颗粒尺寸的减小,载流子与颗粒表面的非弹性碰撞几率增加,从而使载流子-声子耦合的强度增强,导致载流子-声子散射时间缩短.     

极化高聚物薄膜复电光系数的测量方法研究

本文基于Mach-Zehnder干涉仪,采用电场调制法测量极化高聚物薄膜复数电光系数和膜厚变化方法,用该方法同时测定了上有对称三明治结构,极化的掺染料红1号（DR1）有机玻璃（PMMA）膜在波长632．8nm处复数电光系数的实部和虚部,给出了考虑到膜厚变化（因调制电场力作用引起）时电光调制信号表达式,观察到其实,虚部对电光效应的不同贡献,结果表明,样品厚度对高聚物薄膜复数电光系数的测量在样品的固有共振频率处有较大影响,该共振频率大小与玻璃衬底厚度有关,并可用受迫振动模型来解释。     

半导体纳米材料光学吸收谱的温度效应

观测了半导体纳米薄膜材料,在室温下的紫外-可见吸收光谱及随测量温度变化至液氦温区的光谱变化,考察光吸收边随温度降低发生蓝移的情况,进而分析温度效应对晶格参数及电子-声子相互作用的影响,造成其能带漂移.     

半导陶瓷的红外吸收谱和喇曼散射谱

ＺｒＯ２·ＳｉＯ２·Ｐ２Ｏ５半导陶瓷是由ＺｒＯ２、ＳｉＯ２和Ｈ３ＰＯ４用高温固相反应制成．它的傅里叶红外吸收谱是由ＺｒＯ２和ＳｉＯ２的标准谱叠加而成．根据标准峰的位置分别计算出两种氧化物的四个基本声子能量．这些声子按照不同组合方式形成ＺｒＯ２·ＳｉＯ２·Ｐ２Ｏ５半导陶瓷的全部傅里叶红外吸收峰．半导陶瓷的喇曼背向散射峰也是由这些基本声子组合而成．对比四角和单斜ＺｒＯ２的喇曼特征谱线看出，在未掺杂和用Ｙ２Ｏ３或Ｎｂ２Ｏ５掺杂的半导陶瓷样品中，ＺｒＯ２的晶粒微结构分别属于单斜和四角对称晶系．     

二维强耦合磁双极化子的自旋极化基态性质

基于Lee-Low-Pines变分法研究了抛物量子点中二维强耦合磁双极化子的自旋极化基态性质,推导出磁双极化子的基态能量E0和声子平均数珡N随量子点受限强度ω0、介电常数比η、电子-声子耦合强度α和磁场的回旋频率ωc的变化规律。结果表明,磁双极化子的声子平均数珡N随α、ω0和ωc的增加而增大;磁双极化子的基态能量由两电子的单粒子能量Ee、两电子间库伦相互作用能Ec、电子自旋与磁场相互作用能ES、电子-声子相互作用能Ee-ph四部分组成;电子-声子相互作用能Ee-ph总是小于零,其绝对值随α、ω0和ωc的增加而增大,它是束缚态磁双极化子形成的有力因素;限定势和电子之间的库伦排斥能的存在不利于束缚态磁双极化子的形成;电子自旋-磁场相互作用的效应ES导致基态能级的"精细结构"。     

非导电样品荷电效应的吸收电流评价方法

在扫描电镜(SEM)中,通过记录和实时处理电子束辐照样品过程中产生的吸收电流Iα,评价非导电样品的荷电效应。对于非导电样品,Iα的绝对值很小,且变化幅度很大,这是电荷在非导电样品表面被捕获、积累和释放过程的直接反映。此外,Iα还可用来评价荷电补偿(改变环境压力、改变成像参数及对样品表面进行导电处理)的效果。     

皮秒激光辐照下半导体表面结构变化的研究

研究了皮钞激光辐照下，半导体吸收和反射特性与材料性质、激光能量密度及激光产生电子-空穴等离子体的关系。实验测量了硅材料与掺杂硅材料表面反射率与Nd:YAG锁模激光器能量密度的关系曲线，给出了分析靶面结构的方法。     

非线性吸收对聚合物PMMA/DR1光漂白的影响

研究了在1064nm处非线性吸收对有机聚合物材料PMMA/DR1光漂白的影响。实验结果表明,在较强的入射光作用下,由于双光子吸收的作用,使得PMMA/DR1发生光漂白,其折射率产生微小的变化,且随光漂白时间的增加而产生饱和。     

五甲氧基红的吸收光谱和皮秒激光光谱研究

进行了五甲氧基红(2、4、2′、4′、2″—五甲氧基三苯甲醇)吸收光谱和皮秒激光荧光光谱研究。发现在酸性低粘度醇类溶剂中,五甲氧基三苯甲基正离子的褪色现象。对其褪色机理及溶剂粘度对于五甲氧基红皮秒激光光谱的影响进行了讨论。     

蓝宝石片的皮秒激光划片工艺研究

由于具有硬度高、热导低及脆性大的特点,蓝宝石材料的精细加工较为困难。对皮秒脉冲激光用于蓝宝石片划片的特点进行了分析和讨论。在此基础上,对用于红外焦平面组件封装的蓝宝石片的皮秒激光划片参数进行了研究,并得到了一系列优化参数。对于红外焦平面阵列封装中常用的厚度为0.4 mm的蓝宝石过渡电极板,在组合划片参数为P(100) X(0.01/20) Y&Z(12) Z(0.1/3)时达到了最佳划片效果。分析了激光功率参数变化对划片的影响,并对实际划片操作中的一些问题进行了探讨。     

可调谐二极管激光吸收光谱技术在探测灵敏度上的探讨

可调谐二极管激光吸收光谱(TDLAS)技术是利用二极管激光器波长调谐特性,获得被测气体在特征吸收光谱范围内的吸收光谱,从而对污染气体进行定性或定量的分析的一种技术方法.在对痕量气体的监测时一般会采取一定的措施去克服直接吸收型气体传感器的缺陷,提高检测精度.文中概述了TDLAS技术的研究现状,针对近年来国内外出现的基于可调谐二极管激光吸收光谱技术在减小系统干扰,提高探测灵敏度的技术措施,从系统结构处理,调制解调技术,检测装置的处理,检测信号的处理等多个方面作了深入的研讨.     

High-performance,transparent conducting oxides based on cadmium stannate

We discuss the modeling of thin films of transparent conducting oxides and we compare the predictions with the observed properties of cadmium stannate. Thin films of this material were deposited using radio-frequency magnetron sputtering. The Drude free-carrier model is used to model the optical and electrical properties. The model demonstrates the need for high mobilities. The free-carrier absorbance in the visible spectrum is used as a comparative figure-of-merit for cadmium stannate and tin oxide. This shows that free-carrier absorbance is much less in cadmium stannate than in tin oxide. X-ray diffraction shows that annealed films consist of a single-phase spinel structure. The post-deposition annealing sequence is shown to be crucial to forming a single phase, which is vital for optimal optical and electrical properties. The films are typically high mobility (up to 65 cm² V^?1 s^?1) and have carrier concentrations as high as 10²¹ cm^?3. Resistivities are as low as 1.3 10^?4 Ω. cm, the lowest values reported for cadmium stannate. Atomic force microscopy indicates that the root-mean-square surface roughness is approximately ±15Å. Cadmium stannate etches readily in both hydrofluoric and hydrochloric acid, which is a commanding advantage over tin oxide.     

Scattering performance of a plane wave by conducting finite helix

The scattering of a plane wave with a linear polarization by a conducting finite helix is presented. The analytical expresses of scattering field are obtained based on the boundary condition of a sheath helix model. Effects of a pitch angle and electrical size of the helix on the resonant behavior are investigated. The analysis shows that resonant behavior of the forward/backward scattering far field is only depended on the pitch electrical size and the radial electrical size, but it is independent of the turn of the helix.     

金属银导电油墨的研究进展

金属银导电油墨是印制电子技术中的关键材料,随着电子产品向小型化、柔性化方向发展,传统的微米级金属银导电油墨已不能满足低加工温度和更小特征尺寸的要求,在此情况下,纳米银油墨和有机银油墨被开发出来。综述了纳米银导电油墨、有机银导电油墨各自的特点以及最新研究进展,并介绍了导电油墨新品种——银杂化油墨。     

Photo-induced absorption spectra of a poly(p-phenylenevinylene) polymer with fluorinated double bonds

We report on the optical and photo-physical properties of a fluorinated poly(p-phenylenevinylene) derivative, namely poly(2-methoxy-5-[(2-ethylhexyl)oxy]-1,4-phenylenedifluorovinylene) (MEH-PPDFV) and we compare them with those of the well-known non fluorinated reference system, poly(2-methoxy-5-[(2-ethylhexyl)oxy]-1,4-phenylenevinylene) (MEH-PPV) synthesized with the same procedure.Remarkable blue-shifts of absorption and emission spectra of MEH-PPDFV with respect to MEH-PPV are observed, due to the larger distortion from planarity of the fluorinated species. In addition, the blue-shift for optical transitions in absorption spectra is more pronounced than in emission ones, since the molecule conformation in the excited states is more planar than in the ground one.Microsecond photo-induced absorption spectra of MEH-PPDFV reveal three bands possessing spectral properties and/or kinetics different from those observed for MEH-PPV. The assignment of these transitions is provided in terms of free and trapped polarons as well of triplet excitons. Free-polarons have an intrinsic decay constant of 3 μs, while the trapping dynamics has a longer kinetics of 40 μs. The triplet exciton, instead, shows a monoexponetial decay behavior of constant about 10 μs.     

A Review of infrared spectroscopic studies of vapor-deposited dielectric glass films on silicon

Vibrational studies of a variety of thin dielectric glass films relevant to the silicon technology are reviewed. Attention is focused on those results and structural infor-mation obtained by direct transmission of materials vapor-deposited on single-crystal silicon substrates in the infra-red region 250 to 4000 cm^-1. In particular, the structure and bonding in some simple CVD binary silicate films are discussed in some detail in light of the recent vibrational analyses performed on the borosilicate and phosphosilicate systems.