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Transformations in In-MoO3 nanosystems have been studied by optical spectroscopy, micros-copy, and gravimetry in relation to the thickness of the In and MoO3 layers and heat-treatment temperature and time. We have measured the contact potential difference across the In and MoO3 films and the photo-voltage in the In-MoO3 system and constructed the energy band diagram of the In-MoO3 system. A model has been proposed for the thermal transformation of the MoO3 films in In-MoO3 bilayers, which involves a redistribution of equilibrium charge carriers at the contact, the formation of a [(V a)++e] center during the preparation of the MoO3 film, transformation of the center into a [e(V a)++e] center during the fabrication of the In-MoO3 bilayer, and thermal ionization of the [e(V a)++e] center. 相似文献
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A discussion of the general properties of three systems of dielectric films i.e. MoO3 and the mixed oxide systems MoO3-In2O3 and MoO3-SiO is presented. Composition, film thickness, substrate deposition temperature and annealing all have a substantial effect on the structure and various properties of the films. The general properties of these three systems of dielectric films include analysis by X-ray photoelectron spectroscopy, UV-visible and infrared spectroscopy including the Fourier transform technique, electrical properties both d.c. and a.c. at both low and high fields and electron spin resonance. An attempt is made to show how the variations of properties depend on many disposable parameters. In particular the use of X-ray photoelectron spectroscopy shows how the local atomic and molecular bonding changes as a result of varying preparation parameters and this feature is a recent facility in the field of thin dielectric-semiconducting films. It is expected that the general discussion in this paper may help in the interpretation of results on other thin dielectric and semiconducting films. 相似文献
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Marina Tyunina Dagmar Chvostova Oliva Pacherova Tomas Kocourek Miroslav Jelinek Lubomir Jastrabik 《Science and Technology of Advanced Materials》2014,15(4)
Optical index of refraction n is studied by spectroscopic ellipsometry in epitaxial nanofilms of NaNbO3 with thickness ~10 nm grown on different single-crystal substrates. The index n in the transparency spectral range (n ≈ 2.1 – 2.2) exhibits a strong sensitivity to atmospheric-pressure gas ambience. The index n in air exceeds that in an oxygen ambience by δn ≈ 0.05 – 0.2. The thermo-optical behaviour n(T) indicates ferroelectric state in the nanofilms. The ambience-sensitive optical refraction is discussed in terms of fundamental connection between refraction and ferroelectric polarization in perovskites, screening of depolarizing field on surfaces of the nanofilms, and thermodynamically stable surface reconstructions of NaNbO3. 相似文献
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The van der Waals forces across a very thin liquid layer (nanofilm) in contact with a plane solid wall make the liquid nonhomogeneous. The dynamics of such flat liquid nanofilms is studied in isothermal case.The Navier–Stokes equations are unable to describe fluid motions in very thin films. The notion of surface free energy of a sharp interface separating gas and liquid layer is disqualified. The concept of disjoining pressure replaces the model of surface energy. In the nanofilm a supplementary free energy must be considered as a functional of the density.The equation of fluid motions along the nanofilm is obtained through the Hamilton variational principle by adding, to the conservative forces, the forces of viscosity in lubrication approximation. The evolution equation of the film thickness is deduced and takes into account the variation of the disjoining pressure along the layer. 相似文献
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MoO3 and MoO3-x nanostructures were grown in a simple one-step process by direct evaporation of MoO3 pellets from a tungsten resistive source in presence of helium or hydrogen at pressures from 100 to 1200 Pa. This method uses no templates, catalysts or oxidizing agents. It leads to one dimensional (1-D) crystalline nanostructures mixed with amorphous material in variable ratios. Amorphous structures grew preferentially when hydrogen was used as carrier gas while crystalline material predominated when helium was used. In fact, only crystalline structures were found when the evaporation was carried out under a helium pressure of 600 Pa with source temperatures between 763 and 910 degrees C. Hydrated MoO3 phases with different water concentrations were preferentially formed using hydrogen. X-ray photoelectron spectroscopy detected only molybdenum in its +6 oxidation state in the samples grown under helium, exhibiting the same chemical composition of the source material. Molybdenum in its +6 as well as its +5 oxidation states was detected in the samples obtained under hydrogen at 600 Pa. Hydroxyl groups were identified in samples grown using both gases. The effect of the helium pressure on the growth kinetics and crystallinity of the samples is discussed according to the kinetics conditions (supersaturation, evaporation, cooling and convection rates) driving to the formation of nanostructures in the inert-gas condensation. Finally, the effect of hydrogen on the growth of MoO3 is discussed. 相似文献
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MoO3-modified porous glasses are prepared via impregnation with aqueous ammonium molybdate, followed by thermal decomposition of the salt. With increasing MoO3 content, the edge of the charge-transfer band shifts to longer wavelengths. The photochromic properties of the modified glass are well defined at an MoO3 content of about 14 mol/g. 相似文献
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《Materials Letters》2005,59(24-25):3112-3114
One-dimensional microstructures of orthorhombic molybdenum trioxide (α-MoO3) have been synthesized via acidification of ammonium heptamolybdate tetrahydrate. A solution of precursor compound, ammonium heptamolybdate tetrahydrate, is acidified to pH 3.5 using diluted glacial acetic acid. Then the intermediate compound is sintered at 300 and 600 °C to give the final α-MoO3, and the SEM shows that it still keeps its micrometer fibers structure. 相似文献
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采用简单热氧化蒸发沉积法在ITO玻璃基片上制备了大面积MoO3微纳米片。制备出的微纳米片具有良好晶体结构,其长度、宽度和片层厚度分别可达100,1~5μm和约100nm;微纳米片沿[001]方向生长,这是因为晶体各方向键合能的不同而具有不同的生长速度,其形成过程遵循气-固生长机制。光致发光谱显示室温下MoO3微纳米片同时具有紫光发射峰、蓝光发射峰和绿光发光带,发射光强度随氧化沉积温度升高而增大,这是由于温度升高,微纳米片缺陷增加导致的。 相似文献
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V. G. Grossman B. G. Bazarov L. A. Glinskaya Zh. G. Bazarova 《Inorganic Materials》2013,49(12):1224-1226
Subsolidus (450–480°C) phase relations in the Tl2MoO4-Pr2(MoO4)3-Hf(MoO4)2 system have been studied by X-ray diffraction. The system has been shown to contain molybdates with the compositions Tl5PrHf(MoO4)6 (5: 1: 2), TlPrHf0.5(MoO4)3 (1: 1: 1), and Tl2PrHf2(MoO4)6.5 (2: 1: 4). Single crystals of the double molybdate TlPr(MoO4)2 have been grown for the first time from high-temperature solutions through spontaneous nucleation, and their crystal structure has been determined: tetragonal symmetry, sp. gr. P4/nnc, a = 6.3170(1) Å, c = 9.5529(2) Å, V = 381.204(12) Å3, Z = 2. 相似文献
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MoO3在介孔分子筛MCM-41上分散和存在状态的研究 总被引:2,自引:0,他引:2
在773K加热MoO3和MCM-41的机械混合物,可以实现 MoO3分散在介孔分子筛MCM-41表面,用透射电镜和选区电子衍射,配合XRD和液氮温度下氮吸附-脱附曲线和BJH孔径分布,研究了活性组分MoO3在有序介孔材料MCM-41上的存在状态,以及MoO3分散到MCM-41表面后MCM-41的结构变化情况.结果表明:当MoO3的含量小于单层分散阈值,加热后MoO3的XRD衍射峰彻底消失;用HRTEM观察不到分散在MCM-41表面或孔道中的MoO3颗粒,而EDS能谱证明在MCM-41的孔道中有呈分散态的MoO3存在.MoO3的含量大于单层分散阈值,通过加热不能使MoO3完全分散在MCM-41表面,而且XRD、HRTEM、氮吸附-脱附等温线和孔径分布都表明由于MoO3的分散量较大,载体MCM-41的有序介孔结构遭到破坏. 相似文献
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塑料基MoO3电致变色薄膜性能 总被引:1,自引:0,他引:1
采用溶胶-凝胶工艺,在镀有ITO透明电极的聚对苯二甲酸乙二酯(PET)基体上制备了MoO3电致变色薄膜.用FT-IR和TG-DTA分析了薄膜的成分和热稳定性,用分光光度计、电化学工作站研究了其在1 mol/L的LiClO4碳酸丙烯酯(PC)液体电解质中的电致变色性能.结果表明:薄膜主要成分是含有水合过氧化氢的无定形MoO3;着、退色前后可见光透过率变化△T为40%,在550 nm时的致色效率为44.8 cm^2/C,经1000次循环,电色性能变化很小;着色速度和对比度随着色电压的增加而增加,Li^0的扩散和Li+的迁移分别控制着着色速度和退色速度. 相似文献