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以金氏菌Kingella H为菌种,在填充活性炭的玻璃柱中挂膜建立固定化生物膜反应器.分析和考察了碳源浓度、氮源浓度、染料浓度、处理时间、初始pH值、进水温度和曝气量等因素对生物膜反应器处理结晶紫(CV)模拟废水的影响.结果表明,较低浓度的碳源和氮源即可维持反应器的正常运行,达到理想的脱色效果;CV对生物膜的活性有一定的抑制作用,但反应器仍可使浓度高达500 mg·L-1的CV模拟废水在30 min内的脱色率达97%以上;反应器的最佳运行条件是:进水的pH值为7,温度为35℃,处理过程中的曝气量为180 L·min-1. 相似文献
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研究了硝酸改性活性炭(AC)催化微波(MW)照射降解水中结晶紫的方法。探讨了改性液浓度、改性时间、MW照射时间、催化剂用量和结晶紫溶液初始浓度等因素对降解的影响。结果表明,改性AC催化活性高于未改性AC。对于25.0 mL 100 mg/L结晶紫溶液,当改性AC质量浓度为2.0 g/L,MW照射3.0 min时,降解率为94.6%。通过提高催化剂用量至2.4 g/L或延长照射时间至4.0 min,降解率分别可达98.2%和100%。此法适合于染料废水的处理。 相似文献
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新型光电化学协同催化降解结晶紫 总被引:1,自引:0,他引:1
以TiO2/Ti薄膜电极为阳极、石墨电极为阴极,设计了一种新型的双槽光电化学协同催化反应器,用该反应器对结晶紫溶液进行了降解研究。考察了结晶紫溶液的浓度、pH值、阴极电位等因素对结晶紫降解脱色效率的影响,对结晶紫的脱色与矿化过程进行了初步讨论,并根据结晶紫在降解反应前后GC-MS中间产物分析和紫外-可见光谱的变化,探讨了其催化降解过程。结果表明,在光电化学协同催化反应器中,当结晶紫溶液初始浓度为30mg/L和溶液初始pH值为3时,经过120min的催化降解,其降解脱色率高达98.3%,而矿化率相对较低,约在20%~30%,相对于结晶紫的脱色反应速率而言,其矿化过程相对缓慢。 相似文献
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天然泥炭对水中结晶紫的吸附行为 总被引:1,自引:0,他引:1
通过静态实验探讨了天然泥炭吸附水中结晶紫时的影响因素、动力学、等温式和热力学。结果表明,在研究条件下吸附90min后天然泥炭对结晶紫的吸附量为31.77~70.49mg.g-1,吸附量随着结晶紫初始浓度或温度的增加而增加,但随着天然泥炭用量的增加而减小。在pH为5~8时随着pH的增加而增加。此外,天然泥炭吸附结晶紫的速度较快,吸附90min后基本达到平衡。吸附动力学规律符合Lagergren准二级反应模型,不同温度下的吸附等温式都与Langmuir方程符合很好。热力学分析表明,吸附过程吸热,吸附焓变ΔH和熵变ΔS都为正值,吸附自由能变ΔG为负值。 相似文献
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用毛细管电泳(CE)-紫外可见(UV-Vis)检测法测定鲫鱼中结晶紫残留量的新方法。样品中的结晶紫用硼氢化钾还原为其代谢产物隐色结晶紫;鲫鱼样品用乙腈提取,二氯甲烷萃取,浓缩净化后用毛细管电泳进样检测,外标法定量。结果表明:该方法能有效用于鲫鱼中结晶紫的分析检测。其最佳测定条件为:流动相,100 mmol/L磷酸-磷酸二氢钠缓冲溶液(pH4.0);紫外检测波长267 nm;分离电压为12 kV。结晶紫标准工作液浓度范围为1~32μg/mL时线性关系良好,相关系数为0.9942。方法检出限和定量检出限均为2.9μg/kg。空白样品结晶紫添加水平为5、10、20μg/mL时平均回收率分别为83.97%、109.55%和88.45%,相对标准偏差分别为3.22%、5.05%和2.09%。 相似文献
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采用新型的喷射环流三相生物反应器,以牛粪浆作活性污泥源,粉煤灰为生物载体,研究了活性污泥法处理甲基紫染料废水过程。确定出该过程的最佳降解操作条件为:p H= 6.5~7.5,温度为 28 ℃,通气流量为 1.5 m 3·h- 1;降解过程的脱色率超过 94 % ,连续运行时 C O Dcr的去除率在 62 % 左右。实验得出甲基紫降解动力学方程式为: - d Sedt = 0.0936 X Se219+ Se (m g· L- 1·h- 1) 相似文献
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鼠李糖脂促进含油餐饮废水的生物降解 总被引:3,自引:1,他引:2
研究生物表面活性剂鼠李糖脂发酵液在含废油餐饮废水的好氧处理过程中的降解性能.结果表明,作为一种高效、绿色环保的生物表面活性剂,鼠李糖脂发酵液能非常迅速地促进废水中餐饮废油的生物降解.在采用活性污泥法处理实际废水的曝气池中的试验进一步表明,对油脂的生物降解能力而言,添加鼠李糖脂发酵液比未添加的处理效果要显著得多;同时,温度和糖脂发酵液的添加量对降解能力有较明显的影响.在27℃和糖脂加量为1倍CMC的最优条件下,废水中废油24 h的生物降解率高达89%. 相似文献
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Angelo Chianese Reinhard G. Sangl Alfons B. Mersmann 《Chemical Engineering Communications》1996,146(1):1-12
The present work reports the results of so called “impact experiments” on nine different kinds of crystals, five inorganic salts and four organic acids, performed by letting ten crystals fall through an evacuated tube onto a glass plate. The ratio between the abraded volume of a crystal and the volume of the crystal itself is inversely proportional to the plasticity index of the material. The size distribution of the fragments, in terms of number density function vs. size, is well fitted for all the systems by a power law equation with an order equal to - 2.82
For one of the system examined, potassium sulphate, the size distributions of fragments obtained by the impact experiments have been successfully compared with those of the fines produced during batch seeded crystallizations carried out at low supersaturations. It therefore appears that the size distribution of the fragments generated by crystal attrition in a crystallizer may be generally predicted by means of the proposed power law equation. 相似文献
For one of the system examined, potassium sulphate, the size distributions of fragments obtained by the impact experiments have been successfully compared with those of the fines produced during batch seeded crystallizations carried out at low supersaturations. It therefore appears that the size distribution of the fragments generated by crystal attrition in a crystallizer may be generally predicted by means of the proposed power law equation. 相似文献
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在对材料的微/纳米级表层压痕硬度测试中,压痕周围出现的凸起对硬度的计算结果有很大的影响.采用压痕功法,通过载荷-压深曲线直接得到压痕过程中所作的功,利用原子力显微镜和Matlab软件,精确得到压痕中产生的塑性变形体积,并计算得到材料的硬度值.用压痕功法对单晶硅的压痕硬度进行了实验研究,并与其它方法进行了比较分析.结果表明:压痕功法得到的结果更稳定,凸起对结果影响较小. 相似文献
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Emeka E. Oguzie 《Chemical Engineering Communications》2013,200(5):591-601
Crystal violet dye (CV) was studied as a corrosion inhibitor for aluminum in hydrochloric acid (1 mol dm?3) and potassium hydroxide (0.5 mol dm?3) solutions in the temperature range 30°–60°C using the gravimetric technique. The effect of iodide ions on the inhibiting efficacy of CV was also assessed. CV was found to inhibit Al corrosion in both aggressive media, exhibiting greater inhibition efficiency in 1 M HCl (83.6%) than in 0.5 M KOH (23.0%). Inhibition efficiency in 0.5 M KOH was, however, synergistically increased in the presence of iodide ions to attain values up to 85.3%. Inhibition efficiency in the acidic and alkaline solutions increased with CV concentration but decreased with rise in temperature, suggesting physical adsorption of CV on the Al surface. The calculated values of activation energy (Ea), free energy of adsorption (ΔGads), and heat of adsorption (Qads) confirm the physisorption mechanism. The inhibitor adsorption characteristics were approximated by the Freundlich adsorption isotherm. 相似文献
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《Polymer-Plastics Technology and Engineering》2013,52(4):683-697
This investigation involves the chemical modification of gelatin, a biomaterial which has been widely studied because of its environmental friendliness, its ready availability from waste products, and its biodegradability. The focus was on cross-linking because it has been shown that the mechanical properties of gelatin can be improved by a sequence of processing steps involving cross-linking, swelling, orientation, and, finally, drying in the oriented state. Because cross-linking is required in this technique, the present study characterizes its possible effects on gelatin biodegradability, as gauged by the time required to solubilize the material. A series of cross-linking agents having various alkylene sequence lengths was used. The resulting cross-linked gelatins were relatively insoluble in phosphate buffer (pH = 8.2) at room temperature, but at higher temperatures, they became partially soluble. Full solubilization of cross-linked gelatins was successfully obtained, however, by the action of an alkaline proteinase, specifically subtilisin. Both the rate of the partial solubilization in buffer and the full solubilization with alkaline proteinase showed dependences on the type, concentration, and chain lengths of the cross-linking agent. 相似文献
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本文从Ba(ZrxTi1-x)O3的x取值和介质碱度的变化研究BZT固溶晶体的形成.结果表明:在水热过程中同时形成以BaZrO3为主体、部分Zr被Ti取代和以BaTiO3为主体、部分Ti被Zr所取代的两种固溶晶体是BZT合成的实质,只有在特定的x值和相应的介质碱度下,才能合成单质的BZT固溶晶体. 相似文献
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Detailed analysis of biological processes for hazardous waste-water treatment presents extreme difficulty. Complexity of organic and inorganic solute mixtures in solution prohibits GC-MS analysis. Gross parameters must be used to monitor treatment process performance. Ultrafiltration, coupled with gross parameter estimation, provides enhanced definition of treatment. Results, employed to monitor in-situ biodegradation of a hazardous landfill leachate, are discussed. 相似文献