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几种聚酯超细纤维染色用分散染料染色性能的研究 总被引:1,自引:0,他引:1
选用4只分散染料对聚酯超细纤维进行染色,并对其移染性、皂洗牢度及染料的高温分散性进行了研究。结果表明:染料的移染性与染料分子结构有关,分子量小,移染性好;皂洗牢度与染浴浓度有关,在相同条件下,染色浓度为4%时比12%高1级。碱性染色结果表明:BlueUP—GF在碱性条件下酯基水解严重,不适合碱性染色。 相似文献
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超细涤纶织物碱性浴染色工艺研究 总被引:1,自引:0,他引:1
用分散染料在碱性浴条件下对超细涤纶织物的染色进行了研究,分别对酸、碱性染浴条件下的上染百分率、染色牢度进行了测试,结果表明:超细涤纶在碱性条件下进行染色是可行的。 相似文献
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涤纶织物通过丝胶处理后,吸湿性、抗静电性和回潮率有了明显的提高,改善了涤纶织物的服用性能。用酸性染料对处理后的涤纶织物进行染色,染色均匀。经固色后,取得了较高的染色牢度。 相似文献
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根据Shell公司和Dystar公司的研究,用Optidye系统从分散染料吸附与上染率、染色温度、pH值、匀染性及染色牢度等方面解析了聚对苯二甲酸丙二酯(PTT)纤维的染色性能。PTT纤维在100℃就可染到深色,在60~80℃和90~100℃有两个吸附速度较快区域;PTT纤维属易染型纤维,在最高温度染保持30~40min即可。高温型分散染料在120℃染色,常压100℃染色无需pH值调节。分散染料染色牢度(洗涤、摩擦及耐光)非常好。 相似文献
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《合成纤维》2016,(10):44-49
以有机碱三乙醇胺为催化剂,邻苯二甲酸酐(简称苯酐)与自制阳离子改性剂WLS反应,制备苯酯助剂,并将其作为涤纶分散黑ECT染料常压染色的促染剂。通过系统研究,优化出苯酯合成工艺,并探讨苯酯助剂与N-正丁基邻苯二甲酰亚胺(简称亚胺)复配对分散黑ECT常压染色性能的影响。结果表明:苯酯与亚胺有很好的协同效应,二者质量比按2∶1复配时,可获得最佳染色效果。该复配促染剂应用于涤纶常压染色中,染色后织物先进行195℃焙烘2.5 min,再还原清洗,织物的染色深度K/S值和上染百分率较常压无助剂、同条件染色工艺显著提高,而且基本达到传统高温高压的染色效果。 相似文献
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以壳聚糖为原料,通过邻苯二甲酸酐封闭2位氨基,利用三聚氰氯将壳聚糖的6位羟基引入聚乙二醇(PEG2000)链上,得到水溶性较好的壳聚糖衍生物(TCSO-PEG2000)。用TCSO-PEG2000整理剂对涤纶织物进行处理,采用红外光谱和扫描电镜对整理剂及涤纶织物进行表征分析,研究整理剂的用量、焙烘时间、焙烘温度等对涤纶织物的强力、透气性、亲水性、抗静电等性能的影响。结果表明:在整理剂质量浓度为8 g/L、焙烘时间为5 min、焙烘温度为120℃时,涤纶织物具有较好的力学性能、亲水性能及抗静电性能。 相似文献
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A series of monoazo disperse dyes derived from naphthalimide containing butyric acid has been applied on polyamide fabrics. The build up and dyeing properties of these dyes such as leveling property, wash, light, perspiration for alkaline and acidic conditions, and rubbing fastnesses on polyamide fabrics have been investigated. The results showed that the applied dyes are capable of producing red to bluish red hues on polyamide fabrics. Because of the presence of both carboxylic acid and hydroxyl groups on the molecular structure of Dye 3, it showed desired and more strength in respect to other used dyes. Comparing the build up of these dyes to commercial dyes such as disperse red 60 and disperse red 73 revealed that most of the used dyes have higher build up in comparison to the commercial ones. Measurement of fastness properties of dyed samples indicated that they have good wash (4–5), rubbing (4), perspiration (4–5), and heat fastnesses (4–5) and they possess less than moderate light fastness (3–4) on polyamide fabrics. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011. 相似文献
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The heterocyclic amines 2‐amino‐6‐methoxy‐ and 2‐amino‐6‐nitrobenzothiazole, 3‐amino‐5‐nitro‐[2,1]‐benzisothiazole, and 2‐amino‐3,5‐dinitrothiophene were diazotized and coupled to substituted N‐β‐acetoxyethylanilines to give dyes which colored cellulose acetate in red to deep blue hues. The color of the dyes is discussed with respect to the nature of the heterocyclic ring and to the substituents in the diazo and coupling component. Dyeing and fastness properties of the dyes on cellulose acetate are also reported. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 3479–3483, 2004 相似文献
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本文研究了染色助剂对涤纶超细纤维染色热力学的影响,研究发现:1、染色助剂的存在并未改变分散染料在涤纶纤维中的分配机理,即服从Nest定律;2、阴离子表面活性剂存在时,分散染料对涤纶超细纤维的亲合力降低,其中在110℃时降低的幅度比较大;染色热比不加阴离子表面活性剂时低得多,染色熵的绝对值也低得多;3、非离子表面活性剂在降低了分散染料对涤纶超细纤维的亲合力的同时,也降低了分散染料在染色过程中的染色热和染色熵的绝对值;4、载体的存在使得染色等温吸附曲线的斜率和亲和力均比较高,但是染色饱和值却较低;5、匀染剂SL的存在使得染色热和染色墒的绝对值均较高。 相似文献
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In this study chitosan samples of different nature, prepared by hydrolysis with HCL and modification by reaction with dimethylaminobenzaldehyde in methanol were applied to acrylic and polyester fabrics by pad‐dry‐cure method in presence and absence of binder (acrylate based copolymer). The pretreated samples were printed with acid dye. The effect of acid hydrolysis, modification, and concentration of chitosan on the color strength of the prints was investigated. The printed fabrics were evaluated for color yield and fastness properties. The color strength of the prints in presence of binder was three times higher than in its absence. The enhancment in color strength was relies mainly on N% of chitosan. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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采用高温高压的染色方法,通过分散染料上染生物能纤维针织面料,对影响其染色性能的助剂用量、染液pH值、升温速率、固色时间这4个主要因素进行单因素分析,并采用正交试验的方法对其染色工艺进行优化,最后通过对染色色牢度进行评定,得出上染生物能纤维针织面料的最佳染色工艺。 相似文献
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结合生产实际讨论了影响涤纶FDY长丝网络度的因素,着重讨论了网络压力、网络张力、产品的规格、原料的品种、喷嘴的类型等几个方面对FDY网络数量和网络牢度的影响,阐述了不同条件下如何保证产品的网络度,同时兼顾到能耗、生产运行以及产品质量等方面的因素。 相似文献
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本文重点讨论了涤/棉针织物一浴法染色新工艺,包括精炼染涤一浴法、练漂染涤一浴一步法、先染涤后棉氧漂一浴两步法、分散/活性一浴一步法、分散/活性一浴两步法。对分散/活性两浴法染色节能工艺也进行了考察。实验结果表明:合理的染色工艺和适当的染化料能很好的保障染色质量,而且对提高生产效率、降低染色成本、减小环境污染都有很大帮助。 相似文献
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将自制载体SY应用于聚砜酰胺织物阳离子染色过程中,研究了SY用量对织物上染率、表观颜色深度、耐日晒色牢度等性能的影响.结果 表明,新型载体SY在聚砜酰胺染色过程中能起到很好的载体作用,能够大幅度提高阳离子染料对聚砜酰胺织物的上染率.此外,固着于织物表面的SY还能够产泛吸收紫外光,从而避免了太阳光对聚砜酰胺织物上染料的破... 相似文献
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A series of water-soluble colored polyesters (polymeric dyes) were synthesized by interfacial polycondensation reaction of terephthaloyl chloride and various bisazodiols (monomeric dyes) that were derived from diarylidene cyclopentanone and diarylidene cyclohexanone by coupling with various diazonium salts of anthraquinone dyes containing the sodium salts of the sulfonic acid group. All the colored polyesters were characterized by their elemental analysis, IR and UV-visible spectroscopy, viscometry, solubility, and TGA. Color and dyeability of the polymeric dyes are discussed by comparing them with those of the corresponding monomeric dyes. The color fastness of the polymeric dyes show fair to very good fastness to light and very good to excellent fastness to washing, rubbing, perspiration, and sublimation. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 68: 2041–2048, 1998 相似文献