A simple set searching optimization method for Er3+-Yb3+ co-doped fiber lasers

A simple set searching optimization algorithm is proposed for Er³⁺-Yb³⁺ co-doped fiber lasers in this paper. This method enables fiber lasers to acquire the optimum fiber length and Yb³⁺-Er³⁺ concentration ratio for a given accuracy. The numerical results illustrate that the optimum Yb³⁺-Er³⁺ concentration ratio changes very little, the optimum fiber length shortens and the corresponding output power is increased with erbium ions concentration increasing. The total Yb³⁺ and Er³⁺ contents are nearly constant under certain pump power, while the optimum total erbium ions and ytterbium ions are decreased with pump power decreasing.     

High power cladding-pumped Er3+/Yb3+ fiber amplifiers: technologies, performances and impact of nonlinear effects

Yb³⁺-sensitized Er³⁺-doped fibers are attracting increasing interest because of the high achievable performances, such as high gain and pump efficiency. High output power can be obtained from a double clad (dc) Er³⁺/Yb³⁺ co-doped fiber pumped with broad area high power pump laser diodes. The principle of amplification in this kind of co-doped fibers is presented in this paper. Different solutions for the injection of pump power in the 1^st-cladding have been described. The energy transfer mechanism in a Er³⁺/Yb³⁺ co-doped system including cooperative-upconversion process is explained. Gain and absorption properties ofdc fibers have been determined experimentally and inserted in a theoretical amplifier model. Good agreement between measurements and modelling has been obtained. Hybrid Er³⁺-Er³⁺/Yb³⁺ amplifier architectures are suitable to obtain + 30 dBm output power. The gain bandwidth is in the 1535–1565 nm range for single wavelength operation. A spectral gain flatness is observed in a reduced C-bandWDM operation (i.e. 1545–1565 nm) without gain-flattening filter. Nonlinear effects such as the optical Kerr effect or the stimulated Brillouin scattering can be observed in high power amplifiers due to the high output peak power confined in the fiber core. These two nonlinear phenomena have been investigated for different high power amplifier configurations. Numerical modelling have also confirmed the observed signal distortions.     

Electrospinning Preparation and Drug‐Delivery Properties of an Up‐conversion Luminescent Porous NaYF4:Yb3+, Er3+@Silica Fiber Nanocomposite

Up‐conversion (UC) luminescent porous silica fibers decorated with NaYF₄:Yb³⁺, Er³⁺ nanocrystals (NCs) (denoted as NaYF₄:Yb³⁺, Er³⁺@silica fiber) are prepared by the electrospinning process using cationic surfactant P123 as a template. Monodisperse and hydrophobic oleic acid capped β‐NaYF₄: Yb³⁺, Er³⁺ NCs are prepared by thermal decomposition methodology. Then, these NCs are transferred into aqueous solution by employing cetyltrimethylammonium bromide (CTAB) as secondary surfactant. The water‐dispersible β‐NaYF₄:Yb³⁺, Er³⁺ NCs are dispersed into precursor electrospinning solution containing P123 and tetraethyl orthosilicate (TEOS), followed by preparation of precursor fibers via electrospinning. Finally, porous α‐NaYF₄:Yb³⁺, Er³⁺@silica fiber nanocomposites are obtained after annealing the precursor fibers containing β‐NaYF₄:Yb³⁺, Er³⁺ at 550 °C. The as‐prepared α‐NaYF₄:Yb³⁺, Er³⁺@silica fiber possesses porous structure and UC luminescence properties simultaneously. Furthermore, the obtained nanocomposites can be used as a drug delivery host carrier and drug storage/release properties are investigated, using ibuprofen (IBU) as a model drug. The results indicate that the IBU–loaded α‐NaYF₄:Yb³⁺, Er³⁺@silica fiber nanocomposites show UC emission of Er³⁺ under 980 nm NIR laser excitation and a controlled release property for IBU. Meanwhile, the UC emission intensity of IBU–α‐NaYF₄:Yb³⁺, Er³⁺@silica fiber system varies with the released amount of IBU.     

Temperature-dependent fluorescence characteristics of an ytterbium-sensitized erbium-doped silica fiber for sensor applications

The characteristics of temperature-dependent fluorescence of an ytterbium (Yb³⁺)-sensitized erbium (Er³⁺)-doped silica fiber are presented. A 10-cm long double-clad Yb³⁺/Er³⁺-codoped fiber is diode-pumped at 915 nm and the individual fluorescence intensities from Yb³⁺ and Er³⁺ ions are measured with varying the fiber temperature. The ratio of the dual fluorescence intensities varies exponentially with temperature in the range of room temperature to ∼300 °C. This dual-dopant system has dual emission bands that emit comparable fluorescence powers. Particularly, the self-referencing fluorescence intensity ratio is insensitive to external perturbations in the fiber, which is useful for sensors that are used in a harsh environment without any use of additional referencing techniques. This scheme allows a compact, long-life, and low-cost temperature sensor and can also be combined with a wide range of existing fiber-optic multiplexing schemes that can simultaneously detect multiple physical parameters.     

Effect of Yb^3＋ concentration on Er^3＋ luminescence properties of sol-gelderived silica-alumina xerogels

Er~(3 )-activated silicate glasses are recognized of tech-nological interest in several areas and,in particular ,it iswell known for their successful application in opticalamplification at the C band (1530 -1565 nm) of tele-communications[1].Inside this l…     

高平均波长稳定性超荧光光纤光源

光纤陀螺要求其光源具有高功率、宽谱输出,同时在大温度范围内仍具有好的平均波长稳定性。为了满足-45℃~70℃大温度范围的应用需求,采用双程后向抽运、法拉第旋转反射、带通滤波等技术手段,对光纤材料和器件进行大温区全局优化,以改善超荧光光纤光源的平均波长稳定性。理论分析了不同中心波长和带宽的带通滤波器以及光纤长度等参量对平均波长稳定性的改善效果,以及和光谱带宽的关系。按照设计结果选择滤波、光纤长度等参量,通过对-45℃~70℃全温区范围进行系统全局优化设计,得到输出功率为32mW,功率稳定性为0.65%,光谱带宽为12.5nm,光源平均波长变化量为23.5×10-6。结果表明,平均波长稳定性在0.5×10-6/℃以下的高稳定性超荧光光纤光源中,32mW输出功率非常高;所得的0.2×10-6/℃是115℃大温差范围、30mW以上超荧光光纤光源中非常优异的平均波长稳定性指标,满足光纤陀螺对光纤光源的要求。     

Er3+/Yb3+双掺光纤放大器理论模型

本文在分析一些文献的基础上,仿照掺Er3+光纤放大器的理论模型,尝试建立了一个Er3+/Yb3+双掺光纤放大器的理论模型。利用本模型,可以模拟双掺光纤中信号、泵浦及放大的自发辐射(ASE)的变化情形,并得到一些有意义的数值结果。     

Luminescence properties of light-emitting diodes based on GaAs with the up-conversion Y<Subscript>2</Subscript>O<Subscript>2</Subscript>S:Er,Yb luminophor

Y₂O₂S luminophors doped with Er³⁺ and Yb³⁺ ions are produced by means of solid-phase synthesis and deposited onto standard AL123A infrared light-emitting diodes. When excited with 940 nm radiation from a light-emitting diode, the structures exhibit intense visible up-conversion luminescence. A maximal brightness of 2340 cd/m² of green and red up-conversion luminescence at corresponding wavelengths around 550 and 600 nm is observed for the Y₂O₂S compound doped with 2 at % Er³⁺ ions and 6 at % Yb³⁺ ions. The ratio of the intensity of green (or red) up-conversion luminescence to the intensity of infrared Stokes luminescence increases with increasing applied voltage. The efficiency of visible emission of the light-emitting diode structures is η = 1.2 lm/W at an applied voltage of 1.5 V.     

Improvement of 1.53 μm emission and energy transfer of Yb3+/Er3+ co-doped tellurite glass and fiber

To improve the 1.53 μm band emission of Er³⁺, the trivalent Yb³⁺ ions were introduced into the Er³⁺ single-doped tellurite glass with composition of TeO₂–ZnO–La₂O₃, a potential gain medium for Er³⁺-doped fiber amplifier (EDFA). The improved effects were investigated from the measured 1.53 μm band and visible band spontaneous emission spectra together with the calculated 1.53 μm band stimulated emission (signal gain) spectra under the excitation of 975 nm laser diode (LD). It was found that Yb³⁺/Er³⁺ co-doping scheme can remarkably improve the visible band up-conversion and the 1.53 μm band fluorescence emission intensity, and meanwhile improves the 1.53 μm band signal gain to some extent, which were attributed to the result of the effective energy transfer of Yb³⁺:²F_5/2 + Er³⁺:⁴I_15/2 → Yb³⁺:²F_7/2 + Er³⁺:⁴I_11/2. The quantitative study of energy transfer mechanism was performed and microscopic energy transfer parameters between the doped rare-earth ions were determined. In addition, the spectroscopic properties of Er³⁺ were also investigated from the measured absorption spectrum according to the Judd–Ofelt theory, and the structure behavior and thermal stability of the prepared tellurite glass were analyzed based on the X-ray diffraction (XRD) and differential scanning calorimeter (DSC) measurements, respectively.     

Atomic‐Level Passivation of Individual Upconversion Nanocrystal for Single Particle Microscopic Imaging

Lanthanide‐doped upconversion nanoparticles (UCNPs) have significant applications for single‐molecule probes and high‐resolution display. However, one of their major hurdles is the weak luminescence, and this remains a grand challenge to achieve at the single‐particle level. Here, 484‐fold luminescence enhancement in LuF₃:Yb³⁺, Er³⁺ rhombic flake UCNPs is achieved, thanks to the Yb³⁺‐mediated local photothermal effect, and their original morphology, size, and good dispersibility are well preserved. These data show that the surface atomic structure of UCNPs as well as transfer from amorphous to ordered crystal structure is modulated by making use of the local photothermal conversion that is generated by the directional absorption of 980 nm light by Yb³⁺ ions. The confocal luminescence images obtained by super‐resolution stimulated emission depletion also show the great enhancement of individual LuF₃:Yb³⁺, Er³⁺ nanoparticles; the high signal‐to‐noise ratio images indicate that the laser treatment technology opens the door for single particle imaging and practical application.     

Performance of Er3+-doped chalcogenide glass MOF amplifier applied for 1.53 μm band

A model of Er3＋-doped chalcogenide glass （GasGe20Sb10S65） microstructured optical fiber （MOF） amplifier under the excitation of 980 nm is presented to demonstrate the feasibility of it applied for 1.53 μm band optical communications. By solving the Er3＋ population rate equations and light power propagation equations, the amplifying performance of 1.53 μm band signals for Er3＋-doped chalcogenide glass MOF amplifier is investigated theoretically. The results show that the Er6＋-doped chalcogenide glass MOF exhibits a high signal gain and broad gain spectrum, and its maximum gain for small-signal input （-40 dBm） exceeds 22 dB on the 300 cm MOF under the excitation of 200 mW pump power Moreover, the relations of 1.53 μm signal gain with fiber length, input signal power and pump power are analyzed. The results indicate that the Er3＋-doped Ga5Ge20Sb10S65 MOF is a promising gain medium which can be applied to broadband amplifiers operating in the third communication window.     

Monovalent Charge Compensation Enables Efficient Lanthanide-Based Near-Infrared Perovskite LEDs

Lanthanide ions (Yb³⁺ or Er³⁺) alloying of CsPb(Cl_1-xBr_x)₃ quantum dots (QDs) to emit approaching 1000 nm show promise in near-infrared light-emitting diodes (NIR-LEDs). High Yb³⁺ alloying ratio increases the electroluminance efficiency of emission at 990 nm and enables high external quantum efficiency (EQE) of NIR-LEDs, however, the high alloying ratio also results in inferior material stability and PLQY drop because of Yb³⁺-induced nanocrystal precipitation. This study finds that the heavy alloying of Yb³⁺ ions causes lattice distortion and coherent energy reduction of Yb³⁺: CsPb(Cl_1-xBr_x)₃ QDs, induced by two Yb³⁺ ions replacing three Pb²⁺, which leads to the collapse of the octahedral structure in ambient conditions. It posits that spontaneous monovalent ion (Na⁺) alloying can address the trade-off between material stability and emission intensity. The Na⁺ occupies the vacancy of Pb²⁺ ions, relaxing the distortion in the lattice and improving the phase stability of octahedral structure, and this optimized structure in turn allows a higher Yb³⁺ alloying ratio. Stability measurements show that the Na⁺/Yb³⁺ co-alloyed films show ten-fold higher material stability and 2.0-fold emission efficiency related to controls. It reports that as a result Na⁺/Yb³⁺ co-alloyed NIR-LEDs have an EQE of 6.4% at 990 nm, which is among the highest perovskite NIR-LEDs beyond 950 nm.     

A theoretical model of thulium-doped silica fiber＇s ASE in the 1900 nm waveband

A theoretical model in the 1900 nm waveband for amplified spontaneous emission (ASE) of thulium-doped silica fiber is presented. The ASE spectral power as functions of the fiber length and the pump power is investigated by solving the rate and propagation equations. By calculation, when the concentration of thulium in fiber is 2.25×1025 m-3, the fiber core diameter is 2.6 μm, and the pump power is 200 mW at 808 nm, the optimal fiber length is 8.1 m, and the output power of ASE can reach 60 mW in...     

Spectral properties and energy transfer in Er3+/Yb3+ co-doped LiYF4 crystal

Laser crystals of LiYF4 (LYF) singly doped with Er3+ in 2.0% and co-doped with Er3+/Yb3+ in about 2.0%/1.0% molar fraction in the raw composition are grown by a vertical Bridgman method. X-ray diffraction (XRD), absorption spectra, fluorescence spectra and decay curves are measured to investigate the structural and luminescent properties of the crystals. Compared with the Er3+ singly doped sample, obviously enhanced emission at 1.5 μm wavelength and green and red up-conversion emissions from Er3+/Yb3+ co-doped crystal are observed under the excitation of 980 nm laser diode. Meanwhile, the emission at 2.7 μm wavelength from Er3+ singly doped crystal is reduced. The fluorescence decay time ranging from 18.60 ms for Er3+ singly doped crystal to 23.01 ms for Er3+/Yb3+ co-doped crystal depends on the ionic concentration. The luminescent mechanisms for the Er3+/Yb3+ co-doped crystals are analyzed, and the possible energy transfer processes from Yb3+ to Er3+ are proposed.     

基于单泵浦源结构的高平坦C+L波段掺Er3＋光纤宽带光源

为了实现高平坦的C+L波段放大的自发辐射光(AS E)光输出,提出并设计了一种 基于LD单泵浦源,并且采用两段掺杂浓度完全相同的掺Er3＋光纤(EDF)作为增 益介质的宽 带光源。对光源的基本原理及实现方案进行了理论分析和实验验证。首先,根据Er3＋ 能级 结构介绍C+L波段宽带光源 的产生原理。然后,设计系统结构,在结构中采用976nm LD作泵 浦源,通过耦合器将泵浦光按照一定比 例分为两路对EDF泵浦;采用两支波分复用器(WDM)将泵浦光耦合进入EDF,并通过 熔接环形镜(FLM)提高转换效率;输出端熔 接隔离器(ISO)防止端面回波对输出造成影响。最后,根据EDF的ASE增益 数学模型对EDF长度进行了分析和优 化。实验结果表明,用于调整C波段ASE光输出的EDF1长选用2m,用于调整L波段ASE光输出 EDF2长选为16m, 获得平坦C+L波段ASE光输出,在不使用任何滤波器的条件下,在1540～1610nm波段范围内光谱平坦度为±0.525dB,在 1520～1610nm范围内光 谱平坦度为±1.119dB。本文方法使用1支976nm LD实现了C+L波段的高平坦输出,简化了系统结构,并降低了系统成本。     

L-band tunable erbium doped fiber ring laser using fiber loop mirror filters

We present a novel and efficient L-band wavelength-tunable Er^3＋ doped fiber laser of ring structure. In the cavity two segments of Er^3＋ doped fiber and a fiber Bragg grating are used to improve pump efficiency. Tunable filters based on fiber loop mirrors are also applied inside the cavity to act as both a wavelength selector and a line-width compressor. Using these techniques, a tunable laser with tuning range up to 42 nm, output power larger than 1 mW, power uniformity controlled within 1.75 dB and side mode suppression ratio about 40 dB is achieved.     

Er3+ Sensitized Photon Upconversion Nanocrystals

Lanthanide doped upconversion nanocrystals, showing bright future in diverse fields, are typically excited by ≈700–1000 nm light when Nd³⁺ and Yb³⁺ are used as sensitizers. Thus far, extending the excitation range of upconversion nanocrystals is still a formidable challenge. Herein, a new type of upconversion nanocrystals is reported, using Er³⁺ ions as sensitizers, which can be excited by 1532 nm light located in the second near‐infrared biological window. Through Er³⁺ sensitization, upconversion emission from a series of activators, including Nd³⁺, Ho³⁺, Eu³⁺, and Tm³⁺, is obtained and can be modulated by Yb³⁺ codoping. In addition, Er³⁺ sensitized photon upconversion of Ho³⁺ and Tm³⁺ can be further enhanced by shell coating. It is found that Er³⁺ sensitized upconversion processes are mainly dependent on the energy transfer between Er³⁺ ions and activators. Considering the demonstration of anticounterfeiting by using this newly designed nanocrystal, it is anticipated that these results can bring more opportunities to upconversion nanomaterials in other aspects, ranging from lasing to super resolution imaging.     

Combined Optical and MR Bioimaging Using Rare Earth Ion Doped NaYF4 Nanocrystals

Here, novel nanoprobes for combined optical and magnetic resonance (MR) bioimaging are reported. Fluoride (NaYF₄) nanocrystals (20–30 nm size) co‐doped with the rare earth ions Gd³⁺ and Er³⁺/Yb³⁺/Eu³⁺ are synthesized and dispersed in water. An efficient up‐ and downconverted photoluminescence from the rare‐earth ions (Er³⁺ and Yb³⁺ or Eu³⁺) doped into fluoride nanomatrix allows optical imaging modality for the nanoprobes. Upconversion nanophosphors (UCNPs) show nearly quadratic dependence of the photoluminescence intensity on the excitation light power, confirming a two‐photon induced process and allowing two‐photon imaging with UCNPs with low power continuous wave laser diodes due to the sequential nature of the two‐photon process. Furthermore, both UCNPs and downconversion nanophosphors (DCNPs) are modified with biorecognition biomolecules such as anti‐claudin‐4 and anti‐mesothelin, and show in vitro targeted delivery to cancer cells using confocal microscopy. The possibility of using nanoprobes for optical imaging in vivo is also demonstrated. It is also shown that Gd³⁺ co‐doped within the nanophosphors imparts strong T1 (Spin‐lattice relaxation time) and T2 (spin‐spin relaxation time) for high contrast MR imaging. Thus, nanoprobes based on fluoride nanophosphors doped with rare earth ions are shown to provide the dual modality of optical and magnetic resonance imaging.     

Operating regimes of an optical coupler combined fiber laser system

Rate equations have been used to study an optical coupler combined Er³⁺-doped fiber laser system, in which a common mirror attached at one of the coupler output ports is shared by two constituent lasers. Three regimes may be identified for the system depending on the relative magnitude of the wavelength difference δλ between the two constituent laser fields to the reflection band of the fiber gratings. Taking into consideration the transmission features of the coupler-mirror combination, appropriate boundary conditions have been established according to the operation regimes of the compound system. After neglecting the backgrounds losses of the fiber, rate equations have been simplified to a set of algebra equations. Based on the algebra equations, we discussed in detail the case where the laser field generated by the first laser with a wavelength slightly different from that of the field oscillating inside the second laser, is injected into the other laser by the common mirror, leading to a decreased gain for the oscillating field.     

Down/Up Conversion in Ln3+‐Doped YF3 Nanocrystals

Nanocrystalline Ln³⁺‐doped YF₃ phosphors have been synthesized via a facile sonochemistry‐assisted hydrothermal route. YF₃ nanoparticles are demonstrated to be a good host material for different lanthanides. Varying the dopants leads to different optical properties. In particular, the feasibility of inducing red, green, and especially blue emission in the Yb³⁺/Er³⁺ co‐doped YF₃ sample by up‐conversion excitation in the near‐infrared region is demonstrated. Such unusually strong 411 nm blue up‐conversion emission has seldom been reported in other Yb³⁺/Er³⁺‐doped systems. The up‐conversion mechanisms have been analyzed.