共查询到20条相似文献，搜索用时 15 毫秒
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Yingying Dong Yan Zou Jianyu Yuan Hang Yang Yue Wu Chaohua Cui Yongfang Li 《Advanced materials (Deerfield Beach, Fla.)》2019,31(52)
The use of a ternary active layer offers a promising approach to enhance the power conversion efficiency (PCE) of polymer solar cells (PSCs) via simply incorporating a third component. Here, a ternary PSC with improved efficiency and stability facilitated by a new small molecule IBC‐F is demonstrated. Even though the PBDB‐T:IBC‐F‐based device gives an extremely low PCE of only 0.21%, a remarkable PCE of 15.06% can be realized in the ternary device based on PBDB‐T:IE4F‐S:IBC‐F with 20% IBC‐F, which is ≈10% greater than that (PCE = 13.70%) of the control binary device based on PBDB‐T:IE4F‐S. The improvement in the device performance of the ternary PSC is mainly attributed to the enhancement of fill factor, which is due to the improved charge dissociation and extraction, suppressed bimolecular and trap‐assisted recombination, longer charge‐carrier lifetime, and enhanced intermolecular interactions for preferential face‐on orientation. Additionally, the ternary device with 20% IBC‐F shows better thermal and photoinduced stability over the control binary device. This work provides a new angle to develop the third components for building ternary PSCs with enhanced photovoltaic performance and stability for practical applications. 相似文献
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Hong Wei Qiao Shuang Yang Yun Wang Xiao Chen Tian Yu Wen Li Juan Tang Qilin Cheng Yu Hou Huijun Zhao Hua Gui Yang 《Advanced materials (Deerfield Beach, Fla.)》2019,31(5)
A gradient heterosturcture is one of the basic methods to control the charge flow in perovskite solar cells (PSCs). However, a classical route for gradient heterosturctures is based on the diffusion technique, in which the guest ions gradually diffuse into the films from a concentrated source of dopants. The gradient heterosturcture is only accessible to the top side, and may be time consuming and costly. Here, the “intolerant” n‐type heteroatoms (Sb3+, In3+) with mismatched cation sizes and charge states can spontaneously enrich two sides of perovskite thin films. The dopants at specific sides can be extracted by a typical hole‐transport layer. Theoretical calculations and experimental observations both indicate that the optimized charge management can be attributed to the tailored band structure and interfacial electronic hybridization, which promote charge separation and collection. The strategy enables the fabrication of PSCs with a spontaneous graded heterojunction showing high efficiency. A champion device based on Sb3+ doped film shows a stabilized power‐conversion efficiency of 21.04% with a high fill factor of 0.84 and small hysteresis. 相似文献
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倒置钙钛矿太阳能电池(PSCs)具有器件结构简单、吸光系数高、迟滞效应小、良好的缺陷容忍性等优点,受到了广泛的关注。但倒置器件光电转换效率(PCE)尚有待提高,究其原因是空穴传输层(HTL)和钙钛矿层界面处的能量损失表现出相对较小的开路电压。文章综述了包括有机聚合物、无机物、尖晶石氧化物等作为空穴传输材料的相关研究进展,进一步分析了通过调节电极/空穴传输层能级使之与钙钛矿价带匹配,及通过界面修饰促进器件对载流子的注入与收集,从而提高光电转换效率的研究现状。对提高倒置钙钛矿太阳能电池性能的研究具有一定的指导意义,最后对倒置器件的应用前景进行了展望。 相似文献
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Xiaopeng Xu Zhaozhao Bi Wei Ma Zishuai Wang Wallace C. H. Choy Wenlin Wu Guangjun Zhang Ying Li Qiang Peng 《Advanced materials (Deerfield Beach, Fla.)》2017,29(46)
In this work, highly efficient ternary‐blend organic solar cells (TB‐OSCs) are reported based on a low‐bandgap copolymer of PTB7‐Th, a medium‐bandgap copolymer of PBDB‐T, and a wide‐bandgap small molecule of SFBRCN. The ternary‐blend layer exhibits a good complementary absorption in the range of 300–800 nm, in which PTB7‐Th and PBDB‐T have excellent miscibility with each other and a desirable phase separation with SFBRCN. In such devices, there exist multiple energy transfer pathways from PBDB‐T to PTB7‐Th, and from SFBRCN to the above two polymer donors. The hole‐back transfer from PTB7‐Th to PBDB‐T and multiple electron transfers between the acceptor and the donor materials are also observed for elevating the whole device performance. After systematically optimizing the weight ratio of PBDB‐T:PTB7‐Th:SFBRCN, a champion power conversion efficiency (PCE) of 12.27% is finally achieved with an open‐circuit voltage (V oc) of 0.93 V, a short‐circuit current density (J sc) of 17.86 mA cm?2, and a fill factor of 73.9%, which is the highest value for the ternary OSCs reported so far. Importantly, the TB‐OSCs exhibit a broad composition tolerance with a high PCE over 10% throughout the whole blend ratios. 相似文献
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The recently emerged integrated perovskite/bulk-heterojunction (BHJ) organic solar cells (IPOSCs) without any recombination layers have generated wide attention. This type of device structure can take the advantages of tandem cells using both perovskite solar and near-infrared (NIR) BHJ organic solar materials for wide-range sunlight absorption and the simple fabrication of single junction cells, as the low bandgap BHJ layer can provide additional light harvesting in the NIR region and the high open-circuit voltage can be maintained at the same time. This progress report highlights the recent developments in such IPOSCs and the possible challenges ahead. In addition, the recent development of perovskite solar cells and NIR organic solar cells is also covered to fully underline the importance and potential of IPOSCs. 相似文献
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Lijun Huo Tao Liu Xiaobo Sun Yunhao Cai Alan J. Heeger Yanming Sun 《Advanced materials (Deerfield Beach, Fla.)》2015,27(18):2938-2944
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Tingting Yan Wei Song Jiaming Huang Ruixiang Peng Like Huang Ziyi Ge 《Advanced materials (Deerfield Beach, Fla.)》2019,31(39)
Ternary heterojunction strategies appear to be an efficient approach to improve the efficiency of organic solar cells (OSCs) through harvesting more sunlight. Ternary OSCs are fabricated by employing wide bandgap polymer donor (PM6), narrow bandgap nonfullerene acceptor (Y6), and PC71BM as the third component to tune the light absorption and morphologies of the blend films. A record power conversion efficiency (PCE) of 16.67% (certified as 16.0%) on rigid substrate is achieved in an optimized PM6:Y6:PC71BM blend ratio of 1:1:0.2. The introduction of PC71BM endows the blend with enhanced absorption in the range of 300–500 nm and optimises interpenetrating morphologies to promote photogenerated charge dissociation and extraction. More importantly, a PCE of 14.06% for flexible ITO‐free ternary OSCs is obtained based on this ternary heterojunction system, which is the highest PCE reported for flexible state‐of‐the‐art OSCs. A very promising ternary heterojunction strategy to develop highly efficient rigid and flexible OSCs is presented. 相似文献
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Ke Gao Zonglong Zhu Bo Xu Sae Byeok Jo Yuanyuan Kan Xiaobin Peng Alex K.‐Y. Jen 《Advanced materials (Deerfield Beach, Fla.)》2017,29(47)
Employing a layer of bulk‐heterojunction (BHJ) organic semiconductors on top of perovskite to further extend its photoresponse is considered as a simple and promising way to enhance the efficiency of perovskite‐based solar cells, instead of using tandem devices or near infrared (NIR)‐absorbing Sn‐containing perovskites. However, the progress made from this approach is quite limited because very few such hybrid solar cells can simultaneously show high short‐circuit current (JSC) and fill factor (FF). To find an appropriate NIR‐absorbing BHJ is essential for highly efficient, organic, photovoltaics (OPV)/perovskite hybrid solar cells. The materials involved in the BHJ layer not only need to have broad photoresponse to increase JSC, but also possess suitable energy levels and high mobility to afford high VOC and FF. In this work, a new porphyrin is synthesized and blended with [6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM) to function as an efficient BHJ for OPV/perovskite hybrid solar cells. The extended photoresponse, well‐matched energy levels, and high hole mobility from optimized BHJ morphology afford a very high power conversion efficiency (PCE) (19.02%) with high Voc, JSC, and FF achieved simultaneously. This is the highest value reported so far for such hybrid devices, which demonstrates the feasibility of further improving the efficiency of perovskite devices. 相似文献
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Le Liu Yuanyuan Kan Ke Gao Jianxiao Wang Min Zhao Hao Chen Chengjie Zhao Tonggang Jiu Alex-K.-Y. Jen Yuliang Li 《Advanced materials (Deerfield Beach, Fla.)》2020,32(11):1907604
Morphology tuning of the blend film in organic solar cells (OSCs) is a key approach to improve device efficiencies. Among various strategies, solid additive is proposed as a simple and new way to enable morphology tuning. However, there exist few solid additives reported to meet such expectations. Herein, chlorine-functionalized graphdiyne (GCl) is successfully applied as a multifunctional solid additive to fine-tune the morphology and improve device efficiency as well as reproductivity for the first time. Compared with 15.6% efficiency for control devices, a record high efficiency of 17.3% with the certified one of 17.1% is obtained along with the simultaneous increase of short-circuit current (Jsc) and fill factor (FF), displaying the state-of-the-art binary organic solar cells at present. The redshift of the film absorption, enhanced crystallinity, prominent phase separation, improved mobility, and decreased charge recombination synergistically account for the increase of Jsc and FF after introducing GCl into the blend film. Moreover, the addition of GCl dramatically reduces batch-to-batch variations benefiting mass production owing to the nonvolatile property of GCl. All these results confirm the efficacy of GCl to enhance device performance, demonstrating a promising application of GCl as a multifunctional solid additive in the field of OSCs. 相似文献
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Organic–inorganic hybrid perovskite solar cells (HPSCs) have achieved an impressive power conversion efficiency (PCE) of 25.2% in 2019. At this stage, it is of paramount importance to understand in detail the working mechanism of these devices and which physical and chemical processes govern not only their power conversion efficiency but also their long‐term stability. The interfaces between the perovskite film and the charge transport layers are among the most important factors in determining both the PCE and stability of HPSCs. Herein, an overview is provided on the recent advances in the fundamental understanding of how these interfaces influence the performance of HPSCs. Firstly, it is discussed how the surface energy of the charge transport layer, the energy level alignment at the interfaces, the charge transport in interfacial layers, defects and mobile ions in the perovskite film, and interfacial layers or at the interfaces affect the charge recombination as well as hysteresis and light soaking phenomenon. Then it is discussed how the interfaces and interfacial materials influence the stability of HPSCs. At the same time, an overview is also provided on the various design strategies for the interfaces and the interfacial materials. At the end, the outlook for the development of highly efficient and stable HPSCs is provided. 相似文献
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Tao Luo Yalan Zhang Zhuo Xu Tianqi Niu Jialun Wen Jing Lu Shengye Jin Shengzhong Liu Kui Zhao 《Advanced materials (Deerfield Beach, Fla.)》2019,31(44)
2D perovskites stabilized by alternating cations in the interlayer space (ACI) represent a very new entry as highly efficient semiconductors for solar cells approaching 15% power conversion efficiency (PCE). However, further improvements will require understanding of the nature of the films, e.g., the thickness distribution and charge‐transfer characteristics of ACI quantum wells (QWs), which are currently unknown. Here, efficient control of the film quality of ACI 2D perovskite (GA)(MA)nPbnI3n+1 (〈n〉 = 3) QWs via incorporation of methylammonium chloride as an additive is demonstrated. The morphological and optoelectronic characterizations unambiguously demonstrate that the additive enables a larger grain size, a smoother surface, and a gradient distribution of QW thickness, which lead to enhanced photocurrent transport/extraction through efficient charge transfer between low‐n and high‐n QWs and suppressed nonradiative charge recombination. Therefore, the additive‐treated ACI perovskite film delivers a champion PCE of 18.48%, far higher than the pristine one (15.79%) due to significant improvements in open‐circuit voltage and fill factor. This PCE also stands as the highest value for all reported 2D perovskite solar cells based on the ACI, Ruddlesden–Popper, and Dion–Jacobson families. These findings establish the fundamental guidelines for the compositional control of 2D perovskites for efficient photovoltaics. 相似文献
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Oskar J. Sandberg Jona Kurpiers Martin Stolterfoht Dieter Neher Paul Meredith Safa Shoaee Ardalan Armin 《Advanced Materials Interfaces》2020,7(10)
Perovskite semiconductors as the active materials in efficient solar cells exhibit free carrier diffusion lengths on the order of microns at low illumination fluxes and many hundreds of nanometers under 1 sun conditions. These lengthscales are significantly larger than typical junction thicknesses, and thus the carrier transport and charge collection should be expected to be diffusion controlled. A consensus along these lines is emerging in the field. However, the question as to whether the built‐in potential plays any role is still of matter of some conjecture. This important question using phase‐sensitive photocurrent measurements and theoretical device simulations based upon the drift‐diffusion framework is addressed. In particular, the role of the built‐in electric field and charge‐selective transport layers in state‐of‐the‐art p–i–n perovskite solar cells comparing experimental findings and simulation predictions is probed. It is found that while charge collection in the junction does not require a drift field per se, a built‐in potential is still needed to avoid the formation of reverse electric fields inside the active layer, and to ensure efficient extraction through the charge transport layers. 相似文献
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Yanan Wei Yunhao Cai Xiaobin Gu Guo Yao Zhen Fu Yuxuan Zhu Junfang Yang Junpeng Dai Jianqi Zhang Xin Zhang Xiaotao Hao Guanghao Lu Zheng Tang Qian Peng Chunfeng Zhang Hui Huang 《Advanced materials (Deerfield Beach, Fla.)》2024,36(2):2304225
The development of high-efficiency thickness-insensitive organic solar cells (OSCs) is crucially important for the mass production of solar panels. However, increasing the active layer thickness usually induces a substantial loss in efficiency. Herein, a ternary strategy in which an oligomer DY-TF is incorporated into PM6:L8-BO system as a guest component is adopted to break this dilemma. The S···F intramolecular noncovalent interactions in the backbone endow DY-TF with a high planarity. Upon the addition of DY-TF, the crystallinity of the blend is effectively improved, leading to increased charge carrier mobility, which is highly desirable in the fabrication of thick-film devices. As a result, thin-film PM6:L8-BO:DY-TF-based device (110 nm) shows a power conversion efficiency (PCE) of 19.13%. Impressively, when the active layer thickness increases to 300 nm, an efficiency of 18.23% (certified as 17.8%) is achieved, representing the highest efficiency reported for 300 nm thick OSCs thus far. Additionally, blade-coated thick device (300 nm) delivers a promising PCE of 17.38%. This work brings new insights into the construction of efficient OSCs with high thickness tolerance, showing great potential for roll-to-roll printing of large-area solar cells. 相似文献
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Ming Ren Lingyi Fang Yuyan Zhang Felix T. Eickemeyer Yi Yuan Shaik M. Zakeeruddin Michael Grätzel Peng Wang 《Advanced materials (Deerfield Beach, Fla.)》2024,36(27):2403403
Efficient and robust n-i-p perovskite solar cells necessitate superior organic hole-transport materials with both mechanical and electronic prowess. Deciphering the structure–property relationship of these materials is crucial for practical perovskite solar cell applications. Through direct arylation, two high glass transition temperature molecular semiconductors, DBC-ETPA (202 °C) and TPE-ETPA (180 °C) are synthesized, using dibenzo[g,p]chrysene (DBC) and 1,1,2,2-tetraphenylethene (TPE) tetrabromides with triphenylene–ethylenedioxythiophene-dimethoxytriphenylamine (ETPA). In comparison to spiro-OMeTAD, both semiconductors exhibit shallower HOMO energy levels, resulting in increased hole densities (generated by air oxidation doping) and accelerated hole extraction from photoexcited perovskite. Experimental and theoretical studies highlight the more rigid DBC core, enhancing hole mobility due to reduced reorganization energy and lower energy disorder. Importantly, DBC-ETPA possesses a higher cohesive energy density, leading to lower ion diffusion coefficients and higher Young's moduli. Leveraging these attributes, DBC-ETPA is employed as the primary hole-transport layer component, yielding perovskite solar cells with an average efficiency of 24.5%, surpassing spiro-OMeTAD reference cells (24.0%). Furthermore, DBC-ETPA-based cells exhibit superior operational stability and 85 °C thermal storage stability. 相似文献
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Khalid Mahmood Bhabani Sankar Swain Aram Amassian 《Advanced materials (Deerfield Beach, Fla.)》2015,27(18):2859-2865