共查询到20条相似文献,搜索用时 15 毫秒
1.
Pengcheng Liu Yixian Wang Qilin Gu Jagjit Nanda John Watt David Mitlin 《Advanced materials (Deerfield Beach, Fla.)》2020,32(7):1906735
Potassium (K) metal anodes suffer from a challenging problem of dendrite growth. Here, it is demonstrated that a tailored current collector will stabilize the metal plating–stripping behavior even with a conventional KPF6-carbonate electrolyte. A 3D copper current collector is functionalized with partially reduced graphene oxide to create a potassiophilic surface, the electrode being denoted as rGO@3D-Cu. Potassiophilic versus potassiophobic experiments demonstrate that molten K fully wets rGO@3D-Cu after 6 s, but does not wet unfunctionalized 3D-Cu. Electrochemically, a unique synergy is achieved that is driven by interfacial tension and geometry: the adherent rGO underlayer promotes 2D layer-by-layer (Frank–van der Merwe) metal film growth at early stages of plating, while the tortuous 3D-Cu electrode reduces the current density and geometrically frustrates dendrites. The rGO@3D-Cu symmetric cells and half-cells achieve state-of-the-art plating and stripping performance. The symmetric rGO@3D-Cu cells exhibit stable cycling at 0.1–2 mA cm−2, while baseline Cu prematurely fails when the current reaches 0.5 mA cm−2. The half-cells cells of rGO@3D-Cu (no K reservoir) are stable at 0.5 mA cm−2 for 10 000 min (100 cycles), and at 1 mA cm−2 for 5000 min. The baseline 3D-Cu, planar rGO@Cu, and planar Cu foil fails after 5110, 3012, and 1410 min, respectively. 相似文献
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Xiao Tang Dong Zhou Peng Li Xin Guo Bing Sun Hao Liu Kang Yan Yury Gogotsi Guoxiu Wang 《Advanced materials (Deerfield Beach, Fla.)》2020,32(4):1906739
Potassium metal batteries are considered as attractive alternatives beyond lithium-ion batteries. However, uncontrollable dendrite growth on the potassium metal anode has restrained their practical applications. A high-performance potassium anode achieved by confining potassium metal into a titanium-deficient nitrogen-containing MXene/carbon nanotube freestanding scaffold is reported. The high electronic transport and fast potassium diffusion in this scaffold enable reduced local current density and homogeneous ionic flux during plating/stripping processes. Furthermore, as verified by theoretical calculations and experimental investigations, such “potassium-philic” MXene sheets can induce the nucleation of potassium, and guide potassium to uniformly distribute in the scaffold upon cycling. Consequently, the as-developed potassium metal anodes exhibit a dendrite-free morphology with high Coulombic efficiency and long cycle life during plating/stripping processes. Such anodes also deliver significantly improved electrochemical performances in potassium–sulfur batteries compared with bare potassium metal anodes. This work can provide a new avenue for developing potassium metal-based batteries. 相似文献
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Jiaheng Zhang Dan Cai Liping Zhu Xiuli Wang Jiangping Tu 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(34):2301119
K metal battery is a kind of high-energy-density storage device with economic advantages. However, due to the dendrite growth and difficult processing characteristics, it is difficult to prepare stable K metal anode with thin thickness and fixed area capacity, which severely limits its development. In this work, a multi-functional 3D skeleton (rGCA) is synthesized by simple vacuum filtration and thermal reduction, and K metal anodes with controllable thickness and area capacity (K content) can be fabricated by changing the raw material mass and graphene layer spacing of rGCA. Moreover, the graphene sheet layer of rGCA can relax stress and relieve volume expansion; carbon nanotubes can serve as the fast transport channel of electrons, reducing internal impedance and local current density; Ag nanoparticles can induce the uniform nucleation and deposition of K+. The K metal composite anodes (rGCA-K) based on the conductive skeleton can effectively suppress dendrites and exhibit excellent electrochemical performance in symmetric and full cells. The controllable fabrication process of stable K metal anode is expected to help K metal batteries move toward the stage of commercial production. 相似文献
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In Situ Formed Gradient Composite Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes
Cai Hong Zhang Tong Jin Jiandong Liu Jianmin Ma Nian Wu Li Le Yu 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(38):2301523
Lithium (Li) metal anode (LMA) is highly considered as a desirable anode material for next-generation rechargeable batteries because of its high specific capacity and the lowest reduction potential. However, uncontrollable growth of Li dendrites, large volume change, and unstable interfaces between LMA and electrolyte hinder its practical application. Herein, a novel in situ formed artificial gradient composite solid electrolyte interphase (GCSEI) layer for highly stable LMAs is proposed. The inner rigid inorganics (Li2S and LiF) with high Li+ ion affinity and high electron tunneling barrier are beneficial to achieve homogeneous Li plating, while the flexible polymers (poly(ethylene oxide) and poly(vinylidene fluoride)) on the surface of GCSEI layer can accommodate the volume change. Furthermore, the GCSEI layer demonstrates fast Li+ ion transport capability and increased Li+ ion diffusion kinetics. Accordingly, the modified LMA enables excellent cycling stability (over 1000 h at 3 mA cm−2) in the symmetric cell using carbonate electrolyte, and the corresponding Li-GCSEI||LiNi0.8Co0.1Mn0.1O2 full cell demonstrates 83.4% capacity retention after 500 cycles. This work offers a new strategy for the design of dendrite-free LMAs for practical applications. 相似文献
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Yang Zhao Lyudmila V. Goncharova Andrew Lushington Qian Sun Hossein Yadegari Biqiong Wang Wei Xiao Ruying Li Xueliang Sun 《Advanced materials (Deerfield Beach, Fla.)》2017,29(18)
Na‐metal batteries are considered as the promising alternative candidate for Li‐ion battery beneficial from the wide availability and low cost of sodium, high theoretical specific capacity, and high energy density based on the plating/stripping processes and lowest electrochemical potential. For Na‐metal batteries, the crucial problem on metallic Na is one of the biggest challenges. Mossy or dendritic growth of Na occurs in the repetitive Na stripping/plating process with an unstable solid electrolyte interphase layer of nonuniform ionic flux, which can not only lead to the low Coulombic efficiency, but also can create short circuit risks, resulting in possible burning or explosion. In this communication, the atomic layer deposition of Al2O3 coating is first demonstrated for the protection of metallic Na anode for Na‐metal batteries. By protecting Na foil with ultrathin Al2O3 layer, the dendrites and mossy Na formation have been effectively suppressed and lifetime has been significantly improved. Furthermore, the thickness of protective layer has been further optimized with 25 cycles of Al2O3 layer presenting the best performance over 500 cycles. The novel design of atomic layer deposition protected metal Na anode may bring in new opportunities to the realization of the next‐generation high energy‐density Na metal batteries. 相似文献
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Hao Sun Guanzhou Zhu Yuanmin Zhu Meng-Chang Lin Hui Chen Yuan-Yao Li Wei Hsuan Hung Bo Zhou Xi Wang Yunxiang Bai Meng Gu Cheng-Liang Huang Hung-Chun Tai Xintong Xu Michael Angell Jing-Jong Shyue Hongjie Dai 《Advanced materials (Deerfield Beach, Fla.)》2020,32(26):2001741
Rechargeable lithium metal batteries are next generation energy storage devices with high energy density, but face challenges in achieving high energy density, high safety, and long cycle life. Here, lithium metal batteries in a novel nonflammable ionic-liquid (IL) electrolyte composed of 1-ethyl-3-methylimidazolium (EMIm) cations and high-concentration bis(fluorosulfonyl)imide (FSI) anions, with sodium bis(trifluoromethanesulfonyl)imide (NaTFSI) as a key additive are reported. The Na ion participates in the formation of hybrid passivation interphases and contributes to dendrite-free Li deposition and reversible cathode electrochemistry. The electrolyte of low viscosity allows practically useful cathode mass loading up to ≈16 mg cm−2. Li anodes paired with lithium cobalt oxide (LiCoO2) and lithium nickel cobalt manganese oxide (LiNi0.8Co0.1Mn0.1O2, NCM 811) cathodes exhibit 99.6–99.9% Coulombic efficiencies, high discharge voltages up to 4.4 V, high specific capacity and energy density up to ≈199 mAh g−1 and ≈765 Wh kg−1 respectively, with impressive cycling performances over up to 1200 cycles. Highly stable passivation interphases formed on both electrodes in the novel IL electrolyte are the key to highly reversible lithium metal batteries, especially for Li–NMC 811 full batteries. 相似文献
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Lithiophilic Cu‐CuO‐Ni Hybrid Structure: Advanced Current Collectors Toward Stable Lithium Metal Anodes 下载免费PDF全文
Shuilin Wu Zhenyu Zhang Minhuan Lan Shaoran Yang Junye Cheng Junjie Cai Jianhua Shen Ying Zhu Kaili Zhang Wenjun Zhang 《Advanced materials (Deerfield Beach, Fla.)》2018,30(9)
Metallic lithium (Li) is a promising anode material for next‐generation rechargeable batteries. However, the dendrite growth of Li and repeated formation of solid electrolyte interface during Li plating and stripping result in low Coulombic efficiency, internal short circuits, and capacity decay, hampering its practical application. In the development of stable Li metal anode, the current collector is recognized as a critical component to regulate Li plating. In this work, a lithiophilic Cu‐CuO‐Ni hybrid structure is synthesized as a current collector for Li metal anodes. The low overpotential of CuO for Li nucleation and the uniform Li+ ion flux induced by the formation of Cu nanowire arrays enable effective suppression of the growth of Li dendrites. Moreover, the surface Cu layer can act as a protective layer to enhance structural durability of the hybrid structure in long‐term running. As a result, the Cu‐CuO‐Ni hybrid structure achieves a Coulombic efficiency above 95% for more than 250 cycles at a current density of 1 mA cm?2 and 580 h (290 cycles) stable repeated Li plating and stripping in a symmetric cell. 相似文献
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Chengzhao Luo Tong Shen Haoqing Ji Dong Huang Jie Liu Bingyu Ke Yihan Wu Yu Chen Chenglin Yan 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(2)
Sodium dendrite growth is responsible for short circuiting and fire hazard of metal batteries, which limits the potential application of sodium metal anode. Sodium dendrite can be effectively suppressed by applying mechanically robust electrolyte in battery systems. Herein, a composite gel polymer electrolyte (GPE) is designed and fabricated, mainly consisting of graphene oxide (GO) and polyvinylidene fluoride‐hexafluoropropylene (PVDF‐HFP). With the addition of an appropriate amount of GO content, the compressive Young's modulus of 2 wt% GO+PVDF‐HFP (2‐GPH) composite GPE is greatly enhanced by a factor of 10, reaching 2.5 GPa, which is crucial in the suppression of sodium dendrite growth. As a result, uniform sodium deposition and ultralong reversible sodium plating/stripping (over 400 h) at high current density (5 mA cm?2) are achieved. Furthermore, as evidenced by molecular dynamics simulation, the GO content facilitates the sodium ion transportation, giving a high ionic conductivity of 2.3 × 10?3 S cm?1. When coupled with Na3V2(PO4)3 cathode in a full sodium metal battery, a high initial capacity of 107 mA h g?1 at 1 C (1 C = 117 mA g?1) is recorded, with an excellent capacity retention rate of 93.5% and high coulombic efficiency of 99.8% after 1100 cycles. 相似文献
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Lithium‐metal batteries (LMBs), as one of the most promising next‐generation high‐energy‐density storage devices, are able to meet the rigid demands of new industries. However, the direct utilization of metallic lithium can induce harsh safety issues, inferior rate and cycle performance, or anode pulverization inside the cells. These drawbacks severely hinder the commercialization of LMBs. Here, an up‐to‐date review of the behavior of lithium ions upon deposition/dissolution, and the failure mechanisms of lithium‐metal anodes is presented. It has been shown that the primary causes consist of the growth of lithium dendrites due to large polarization and a strong electric field at the vicinity of the anode, the hyperactivity of metallic lithium, and hostless infinite volume changes upon cycling. The recent advances in liquid organic electrolyte (LOE) systems through modulating the local current density, anion depletion, lithium flux, the anode–electrolyte interface, or the mechanical strength of the interlayers are highlighted. Concrete strategies including tailoring the anode structures, optimizing the electrolytes, building artificial anode–electrolyte interfaces, and functionalizing the protective interlayers are summarized in detail. Furthermore, the challenges remaining in LOE systems are outlined, and the future perspectives of introducing solid‐state electrolytes to radically address safety issues are presented. 相似文献
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Xuze Guan Aoxuan Wang Shan Liu Guojie Li Feng Liang Ying‐Wei Yang Xingjiang Liu Jiayan Luo 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(37)
Rechargeable batteries are regarded as the most promising candidates for practical applications in portable electronic devices and electric vehicles. In recent decades, lithium metal batteries (LMBs) have been extensively studied due to their ultrahigh energy densities. However, short lifespan and poor safety caused by uncontrollable dendrite growth hinder their commercial applications. Besides, a clear understanding of Li nucleation and growth has not yet been obtained. In this Review, the failure mechanisms of Li metal anodes are ascribed to high reactivity of lithium, virtually infinite volume changes, and notorious dendrite growth. The principles of Li deposition nucleation and early dendrite growth are discussed and summarized. Correspondingly, four rational strategies of controlling nucleation are proposed to guide Li nucleation and growth. Finally, perspectives for understanding the Li metal deposition process and realizing safe and high‐energy rechargeable LMBs are given. 相似文献
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An Huang Haodong Liu Ofer Manor Ping Liu James Friend 《Advanced materials (Deerfield Beach, Fla.)》2020,32(14):1907516
Both powerful and unstable, practical lithium metal batteries have remained a difficult challenge for over 50 years. With severe ion depletion gradients in the electrolyte during charging, they rapidly develop porosity, dendrites, and dead Li that cause poor performance and, all too often, spectacular failure. Remarkably, incorporating a small, 100 MHz surface acoustic wave device (SAW) solves this problem. Providing acoustic streaming electrolyte flow during charging, the device enables dense Li plating and avoids porosity and dendrites. SAW-integrated Li cells can operate up to 6 mA cm−2 in a commercial carbonate-based electrolyte; omitting the SAW leads to short circuiting at 2 mA cm−2. The Li deposition is morphologically dendrite-free and close to theoretical density when cycling with the SAW. With a 245 µm thick Li anode in a full Li||LFP (LiFePO4) cell, introducing the SAW increases the uncycled Li from 145 to 225 µm, decreasing Li consumption from 41% to only 8%. A closed-form model is provided to explain the phenomena and serve as a design tool for integrating this chemistry-agnostic approach into batteries whatever the chemistry within. 相似文献
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Kun Tang Aobing Du Shanmu Dong Zili Cui Xin Liu Chenglong Lu Jingwen Zhao Xinhong Zhou Guanglei Cui 《Advanced materials (Deerfield Beach, Fla.)》2020,32(6):1904987
Rechargeable magnesium (Mg) metal batteries are a promising candidate for “post-Li-ion batteries” due to their high capacity, high abundance, and most importantly, highly reversible and dendrite-free Mg metal anode. However, the formation of passivating surface film rather than Mg2+-conducting solid electrolyte interphase (SEI) on Mg anode surface has always restricted the development of rechargeable Mg batteries. A stable SEI is constructed on the surface of Mg metal anode by the partial decomposition of a pristine Li electrolyte in the electrochemical process. This Li electrolyte is easily prepared by dissolving lithium tetrakis(hexafluoroisopropyloxy)borate (Li[B(hfip)4]) in dimethoxyethane. It is noteworthy that Mg2+ can be directly introduced into this Li electrolyte during the initial electrochemical cycles for in situ forming a hybrid Mg2+/Li+ electrolyte, and then the cycled electrolyte can conduct Mg-ion smoothly. The existence of this as-formed SEI blocks the further parasitic reaction of Mg metal anode with electrolyte and enables this electrolyte enduring long-term electrochemical cycles stably. This approach of constructing superior SEI on Mg anode surface and exploiting novel Mg electrolyte provides a new avenue for practical application of high-performance rechargeable Mg batteries. 相似文献
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Zhaojie Li Xueying Zheng Siyang Ye Chuan Ou Yong Xie Zhenbang Li Fei Tian Danni Lei Chengxin Wang 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(39):2301005
Electrolyte engineering is a feasible strategy to realize high energy density lithium metal batteries. However, stabilizing both lithium metal anodes and nickel-rich layered cathodes is extremely challenging. To break through this bottleneck, a dual-additives electrolyte containing fluoroethylene carbonate (10 vol.%) and 1-methoxy-2-propylamine (1 vol.%) in conventional LiPF6-containing carbonate-based electrolyte is reported. The two additives can polymerize and thus generate dense and uniform LiF and Li3N-containing interphases on both electrodes’ surfaces. Such robust ionic conductive interphases not only prevent lithium dendrite formation in lithium metal anode but also suppress stress-corrosion cracking and phase transformation in nickel-rich layered cathode. The advanced electrolyte enables Li||LiNi0.8Co0.1Mn0.1O2 stably cycle for 80 cycles at 60 mA g−1 with a specific discharge capacity retention of 91.2% under harsh conditions. 相似文献
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Dongsoo Lee Seho Sun Jiseok Kwon Hyunjung Park Minchul Jang Eunkyung Park Byoungkuk Son Yeongil Jung Taeseup Song Ungyu Paik 《Advanced materials (Deerfield Beach, Fla.)》2020,32(7):1905573
The practical implementation of the lithium metal anode is hindered by obstacles such as Li dendrite growth, large volume changes, and poor lifespan. Here, copper nitride nanowires (Cu3N NWs) printed Li by a facile and low-cost roll-press method is reported, to operate in carbonate electrolytes for high-voltage cathode materials. Through one-step roll pressing, Cu3N NWs can be conformally printed onto the Li metal surface, and form a Li3N@Cu NWs layer on the Li metal. The Li3N@Cu NWs layer can assist homogeneous Li-ion flux with the 3D channel structure, as well as the high Li-ion conductivity of the Li3N. With those beneficial effects, the Li3N@Cu NWs layer can guide Li to deposit into a dense and planar structure without Li-dendrite growth. Li metal with Li3N@Cu NWs protection layer exhibits outstanding cycling performances even at a high current density of 5.0 mA cm−2 with low overpotentials in Li symmetric cells. Furthermore, the stable cyclability and improved rate capability can be realized in a full cell using LiCoO2 over 300 cycles. When decoupling the irreversible reactions of the cathode using Li4Ti5O12, stable cycling performance over 1000 cycles can be achieved at a practical current density of ≈2 mA cm−2. 相似文献
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Yanpeng Guo Ping Niu Yayuan Liu Yan Ouyang Dian Li Tianyou Zhai Huiqiao Li Yi Cui 《Advanced materials (Deerfield Beach, Fla.)》2019,31(27)
Commercial deployment of lithium anodes has been severely impeded by the poor battery safety, unsatisfying cycling lifespan, and efficiency. Recently, building artificial interfacial layers over a lithium anode was regarded as an effective strategy to stabilize the electrode. However, the fabrications reported so far have mostly been conducted directly upon lithium foil, often requiring stringent reaction conditions with indispensable inert environment protection and highly specialized reagents due to the high reactivity of metallic lithium. Besides, the uneven lithium‐ion flux across the lithium surface should be more powerfully tailored via mighty interfacial layer materials. Herein, g‐C3N4 is employed as a Li+‐modulating material and a brand‐new autotransferable strategy to fabricate this interfacial layer for Li anodes without any inert atmosphere protection and limitation of chemical regents is developed. The g‐C3N4 film is filtrated on the separator in air using a common alcohol solution and then perfectly autotransferred to the lithium surface by electrolyte wetting during normal cell assembly. The abundant nitrogen species within g‐C3N4 nanosheets can form transient Li? N bonds to powerfully stabilize the lithium‐ion flux and thus enable a CE over 99% for 900 cycles and smooth deposition at high current densities and capacities, surpassing most previous works. 相似文献
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Yong Jiang Shangying Lu Jinlong Jiang Meng Li Yalan Liao Yi Xu Shoushuang Huang Bing Zhao Jiujun Zhang 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(29):2300411
The introduction of electrolyte additives is one of the most potential strategies to improve the performance of potassium metal batteries (PMBs). However, designing an additive that can alter the K+ solvation shell and essentially inhibit K dendrite remains a challenge. Herein, the amyl-triphenyl-phosphonium bromide was introduced as an additive to build a stable solid electrolyte interphase layer. The amyl-TPP cations can form a cation shielding layer on the metal surface during the nucleation stage, preventing K+ from gathering at the tip to form K dendrites. Besides, the cations can be preferentially reduced to form KxPy with fast K+ transport kinetics. The Br− anions, as Lewis bases with strong electronegativity, can not only coordinate the Lewis acid pentafluoride to inhibit the formation of HF, but also change the K+ solvation structure to reduce solvent molecules in the first solvation structure. Therefore, the symmetrical battery exhibits a low deposition overpotential of 123 mV at 0.1 mA cm−2 over 4200 h cycle life. The full battery, paried with a perylene-tetracarboxylic dianhydride (PTCDA) cathode, possesses a cycle life of 250 cycles at 2 C and 81.9% capacity retention. This work offers a reasonable electrolyte design to obtain PMBs with long-term stablity and safety. 相似文献