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用中子衍射法测定了R_2Fe_(17)N_x(R=Y,Dy,Nd)中N的占位及磁结构,初步讨论了N的占位对磁性能的影响 相似文献
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钛在自贡鸿鹤化工总厂联碱生产中的应用 总被引:7,自引:1,他引:7
简述了Sm2Fe(17)Nx化合物的结构与内禀磁性能,着重回顾了Sm2Fe(17)Nx永磁合金粉及其磁体的制备工艺发展现状,并展望了Sm2Fe(17)Nx永磁体的发展前景。 相似文献
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采用提拉法生长出了掺钕钨酸铋钠(分子式Nd:NaBi(WO4)2,简称Nd:NBW)和掺钕钨酸钇钠(分子式Nd:NaY(WO4)2,简称Nd:NYW)晶体。通过TG-DTA分析得到Nd:NBW的熔点为936.2℃,Nd:NYW的熔点为1209.07℃。由吸收光谱可以看出,Nd:NBW在802nm有较强的吸收峰,Nd:NYW在804nm,752nm,586nm附近有较强、较宽的吸收峰,二者均适合于LD泵浦;并计算了晶体中Nd^+3+的吸收截面积。通过比较Nd:NBW和Nd:NYW的红外光谱和拉曼光谱结果,认为二者结构基本相同,为四方晶系、白钨矿结构、141/a空间群。 相似文献
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YANG Jilian ZHANG Baisheng JIN Lan DING Yongfan YE Chuntar Institute of Atomic Energy Beijing China YANG Yingchang KONG Linshu Associate Professor P.O.Box - Beijing China 《金属学报(英文版)》1990,3(4):297-299
Neutron diffraction measurements on Nd2(Fe0,Si0 ,)14B at room temperature and 77 K were performed. Data analysis using profile refinement was carried out. The results show that at room temperature Si atoms occupy preferentially 4c, 8j, and I6k2 sites, and the magnetic moments of bath Nd and Fe are parallel to C—axis. At 77 K, the site occupations remain unchanged as in room temperature, while the calculated Nd magnetic moment direction has an angular deviation of 37.8 ° from C—axis. 相似文献
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SONG Xiaoping WANG Xiaotian HUANG Qihua LIU Junhai YAO Yinliang Xi''''an Jiaotong University Xi''''an China 《金属学报(英文版)》1992,5(8):123-127
An addition of Nb up to 2 at.-% into(Nd,Dy)-(Fe,Co)-B alloy causes the formation ofdendrite Fe_2Nb and the precipitates in hard magnetic grains.Both increases withincreasing Nb content.During sintering,part of Fe_2Nb dissolves within the 2:14:1 grains,and the Fe_2Nb along grain boundaries hinders the growth of 2:14:1 grains.During an-nealing,the dissolved Nb in(?)-phase precipitates out,and this nearby the grain boundarydiffuses into Nd-rich phase to form new granular Fe_2Nb and to increase the Nb contentin Nd-rich phase,this results in a precipitate-free zone in the(?)-grain near Nd-rich phase. 相似文献
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Y.M.Hao C.X.Cui Y.Gao W.P.Zhao J.S.MengDepartment of Physics Tianjin Normal University Tianjin China School of Materials Science Engineering Hebei University of Technology Tianjin China Manuscript received September in 《金属学报(英文版)》2002,15(4):401-404
An approximate calculation of the exchange interaction constant JRT between the rare-earth sublattice and the transition metal sublattice in R2Fe17-xAlx (R=Tb, Gd, and Dy) compounds is given by the molecular-field model and the results of neutron diffraction. The calculated values, -JR,T/k, for Dy2Fe17-xAlx (x=5, 6, 7 and 8), Tb2Fe10Al7, Gd2Fe17-xAlx (x = 7, 8) compounds are 8.62K, 8.64K, 9.52K, 10.34K and 10.66K, 10.65K, and 9.85K, respectively, they are in agreement with the experimental values, -JR,T/k, of Dy2Fe17-xAlx (x=5, 6, 7 and 8), Tb2Fe10Al7 and Gd2Fe17-xAlx (x=7, 8) compounds, which are 8.77K, 9.25K, 10.1K, 10.9K and 10.35K, 10.1K, and 10.3K, respectively. The origins of the difference between the calculated and the experimental results are discussed. 相似文献
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YANG Jilian ZHANG Baisheng JIN Lan DING Yongfan YE Chuntang Institute of Atomic Energy Beijing ChinaYANG Yingchang SUN Hong KONG Linshu Peking University Beijing China YANG Jilian Associate Professor P.O.Box Sub Beijing China 《金属学报(英文版)》1990,3(8):145-148
The site occupancies in permanent magnetic alloy Y_2(Fe_(0.95)Al_(0.05))_(14)B has been studied bymeans of neutron diffraction.The results from profile refinement show that Al enters thetetragonal structure of Nd_2Fe_(14)B and occupies the 4c and 8j_2 sites of the space groupP4_2/mnm preferably.The relation between the site occupancies and the magnetic proper-ties is discussed preliminarily. 相似文献
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Xu Rengen Wang Xinhua Wu Jianmin Pan Hongge Chen Changpin Wang Qidong Dai Lichi Department of Materials Science Engineering Zhejiang University Hangzhou P. R. China Department Central Iron Steel Research Institute 《中国有色金属学会会刊》1999,9(1)
INTRODUCTIONItiswelknownthatSm2Fe17Nycompoundshavegoodintrinsicmagneticproperties[1].BecauseofthepoorstabilityofSm2Fe17Nyat... 相似文献
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The creep fracture behavior of intermetallic compound(Fe_(60)Ni_(40))_3(V_(98)Ti_2)has been studied.The variation of dislocation substructure was observed with TEM in the process ofsteady-state creep.It is found that there exists a large amount of stacking faults,dislocationpairs and also high density dislocation networks.SEM analysis of section near fracture sur-face points out that the intergranular crack due to coalescence of small cavities is the maincreep fracture mechanism of(Fe_(60)Ni_(40))_3(V_(98)Ti_2). 相似文献
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The crystal structures of the R2Pd2Pb (R=Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, and Lu) compounds were determined using X-ray powder diffraction. The investigated compounds crystallize with Mo2FeB2 structure type (space group P4/mbm, Pearson code tP10). The importance of stabilization by polar intermetallic R–Pd bonding is underscored by a bonding analysis derived from electronic band structure calculations. 相似文献