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1.
A laboratory investigation of the interface transmissivity is reported for five different geosynthetic clay liners (GCLs) and a range of different geomembranes (GMBs) for a range of stresses from 10 to 150?kPa. The GCLs were prehydrated under normal stress before permeation. The GCLs examined comprised three multicomponent (a smooth coated, a smooth laminated, and textured coated) and two conventional (one with granular and one with powdered sodium bentonite) GCLs. The effect of a 4?mm circular defect in the coating of a multicomponent GCL directly below the 10?mm diameter hole in the GMB is investigated. The effect of GMB stiffness and texture is examined. Additionally, the effect of hydration and permeation of smooth coated GCL with highly saline solution and synthetic landfill leachate (SL3) is presented. It is shown that the 2-week interface transmissivity (θ2-week) can be one to two orders of magnitude higher than steady-state interface transmissivity (θ steady-state) at low stresses (10?kPa–50?kPa), whereas at high stresses (150?kPa) the variation is substantially less. For a smooth coated GCL hydrated and permeated with reverse osmosis (RO) water, GMB stiffness and texture has a limited effect on interface transmissivity when the coating is placed in contact with GMB at normal stresses of 10?kPa–150?kPa, whereas coating indentations result in much high interface transmissivity when placed in contact with GMB. GCL prehydration and permeation with highly saline solutions leads to higher interface transmissivity compared to RO water. With a 4.0?mm defect in the coating, the interface transmissivity between the coating and woven geotextile is higher than that between the coating and GMB for the stress levels and GCL examined.  相似文献   

2.
The interface transmissivity (θ) of two multicomponent geosynthetic clay liners (GCLs) is investigated upon hydration and permeation with a highly saline solution (TDS ≈ 260,000 mg/l; Na+ ~ 95,000 mg/l; K+~12,000 mg/l) at two stress levels (10 kPa and 150 kPa). One GCL had a smooth 0.2 mm-thick coating whereas the second GCL had a textured 1 mm-thick coating. For both GCLs, the interface transmissivity after 2-weeks is shown to be higher than at steady-state. The lower the geomembrane's (GMB) stiffness, the lower interface transmissivity. However, the effect is generally diminished at steady state and higher stress. The effect of GMB stiffness at 10 kPa is shown to be 1.6-times that at 150 kPa. Similarly, the 2-week and steady state interface transmissivity for the textured GMB was higher at 10 kPa than at 150 kPa. Coating texture and coating orientation are shown to have a significant effect on GMB/multicomponent GCL interface transmissivity. A hole in the coating aligned with GMB hole creates an additional flow path at the coating/GCL interface (θGeofilm/GCL), however most of the flow occurs at the coating/GMB interface (θGeofilm/GMB).  相似文献   

3.
In composite liners made of geomembrane (GMB)-geosynthetics clay liners (GCLs), maintaining bentonite in the GCL in a suitably hydrated state is critical for their performance. Hydration of GCL from subsoil, following industry best practice, is time consuming and conditional on suitable water chemistry in subsoil. In addition, under thermal gradients, dehydration occurs, with moisture migrating downwards to the subsoil, leading to the development of cracks in the bentonite and hence loss of performance.Two novel ideas are proposed in this paper, namely hydration of GCLs by artificial irrigation and hydraulic separation of the liner system from the underlying subsoil. Three new composite liner designs allowing for actively irrigating a geosynthetic clay liner (GCL) through a geocomposite layer were investigated. In two of the three designs, the hydraulic connection between the GCL and the subsoil was broken by placing an additional GMB between them. The new designs were tested in column experiments under 20 kPa overburden pressure and temperatures of up to 78 °C applied to the top of the liner. The performances of the new designs were compared to that of a standard GCL-GMB design where GCL was allowed to hydrate from a well-graded sandy subsoil. Three scenarios for the staging of hydration and thermal load application were investigated.Under active hydration of the composite liners, it took less than 14 days for the GCLs to reach a gravimetric water content ω of 110–130%, compared to 49 days taken to reach ω~95% under hydration from the subsoil. GCLs in the new designs in which the hydraulic connection with the subsoil was broken, remained well-hydrated (ω>100%) after 14 days of heating and no cracks appeared in the bentonite. On the other hand, the GCL in the conventional design experienced severe desiccation under the same conditions. The new designs hence offer a viable solution to the problem of slow hydration and/or thermal desiccation of GCLs.  相似文献   

4.
The effects of the silt aggregation, compaction density, and water content of the subgrade on the hydration of five different geosynthetic clay liner (GCL) products is reported based on a series of laboratory column experiments conducted over a six-year period. GCLs meeting typical specifications in terms of minimum hydraulic conductivity and swell index are hydrated to equilibrium from the same subgrade soil with sufficient cations to cause cation exchange during hydration. It is then shown that the GCL bentonite granularity and GCL structure can have a significant (~four orders of magnitude) effect on hydraulic conductivity under the same test conditions (from 8 × 10−12 m/s for one GCL to 6 × 10−8 m/s for another GCL product). The effect of subgrade water content on the hydraulic performance of GCLs are not self-evident and quite dependent on the bentonite granularity, GCL structure, and permeant. Varying the subgrade water content from 5 to 16% and allowing the GCL to hydrate to equilibrium before permeation led to up to 5-fold difference in hydraulic conductivity when permeated with tap water and up to 60-fold difference when the same product is permeated with synthetic municipal solid waste leachate. When permeated with synthetic leachate, increasing stress from 70 kPa to 150 kPa led to a slight (average 37%; maximum 2.7-fold) decrease in hydraulic conductivity due to a decrease in bulk void ratio. It is shown that hydraulic conductivity is lower for GCLs with a scrim-reinforced geotextile, and/or with finer bentonite. It is shown that selecting a GCL based on the initial hydraulic conductivity and swell index in a manufacturers product sheet provides no assurance of good performance in field applications and it is recommended that designers pay more attention to selection of a GCL and preparation of the subgrade for important projects.  相似文献   

5.
A study was conducted to investigate (1) physicochemical factors that influence polymer elution from GCLs containing a blend of bentonite and linear (water-soluble) polymer (LPB GCLs) and (2) the mechanism that controls the chemical compatibility of LPB GCLs when polymer elutes. A series of hydraulic conductivity (k), free swell and viscosity tests were performed on a commercial LPB GCL using DI water, varying concentrations of NaCl and CaCl?. Comparable tests were also performed on a conventional bentonite (CB) GCL containing the same untreated bentonite and the same physical properties as the LPB GCL. The LPB GCL showed improved swelling and hydraulic performance compared to the CB GCL when permeated with salt solutions. Total organic carbon analysis of the effluents showed that polymer eluted from the LPB GCL regardless of the permeant solution. However, the rate at which polymer eluted increased as the concentration and valence of the dominant cation increased. The rate at which polymer eluted also increased with hydraulic gradient. The mass of polymer retained inside the GCL matrix did not correlate with the k of the LPB GCL. Free swell tests coupled with chemical analysis suggest that, the improved chemical compatibility of the LPB GCL was due to the ability of the polymer to scavenge cations from the solution which allows the bentonite to undergo adequate swelling during the initial hydration period. Analogous to water-prehydrated CB GCLs, the dispersed structure of the bentonite fabric and increased adsorbed water molecules attained during initial swelling controls the k of the LPB GCL when polymer elutes.  相似文献   

6.
This paper explores the influence of polymer enhancement on water uptake and retention by geosynthetic clay liners (GCLs) across a wide suction range (up to 106 kPa), including the low suction regime (0.1–10 kPa) typically omitted in past studies. The suction measurement methods used enabled elucidation of water uptake and retention behaviour through the framework of GCL pore structures and their corresponding suction regimes. Polymer enhanced GCLs (PE-GCLs) have high maximum water uptake, and both the water entry and air expulsion values tend to be high. Due to high swelling, the onset of geotextile confinement for PE-GCLs was observed at high suctions. The impact of polymer becomes more apparent when the bentonite achieves a pseudo-two-layer interlayer hydration state at a suction of about 40 MPa (RH = 75%). The hydration mechanism for the polymer fraction in bentonite is unique to the specific polymer type, polymer dosage, and manufacturing process. The water retention behaviour at the low suction range is caused by the in-filling of geotextile pores, bentonite swelling and extrusion, and polymer water adsorption. Insights from this study can form the basis for developing a more suitable bimodal generalised model for fitting the water retention curves of GCLs.  相似文献   

7.
The desiccation and subsequent hydraulic conductivity of both a standard (GCL_A) and polymer-enhanced (GCL_B) Na-bentonite GCL hydrated from a well-graded sandy subsoil under 20 kPa, then subjected to a thermal gradient, and finally rehydrated and permeated with distilled water or 0.325 mol/L Na+ synthetic brine are reported.With moderate temperature of 40 °C applied to the top of the liner, GCL_B experienced less cracking than GCL_A, but this advantage disappeared when temperatures increased. Both desiccated specimens of GCL_A and B showed significant self-healing when permeated with distilled water and their hydraulic conductivities quickly reduced to around 10−11 m/s at 20 kPa upon rehydration. However, when GCL_B desiccated specimens were permeated with the synthetic brine, their hydraulic conductivities were found to be one to two orders of magnitude higher than corresponding values obtained with distilled water. On the other hand, GCL_A (with no polymer treatment) maintained its hydraulic conductivities at the same level obtained with distilled water. It is concluded that caution should be exercised in using polymer-bentonite in applications in which GCLs are subjected to significant thermal gradients unless there is data to show they are resistant to thermal effects.  相似文献   

8.
《Soils and Foundations》2007,47(1):79-96
To investigate systematically the effects of electrolytic solutions on the barrier performance of geosynthetic clay liners (GCLs), a long-term hydraulic conductivity test for 3 years at longest was conducted on a nonprehydrated GCL permeated with inorganic chemical solutions. The hydraulic conductivity test for waste leachates was also conducted. The results of the test show that the hydraulic conductivity of GCLs significantly correlates with the swelling capacity of bentonite contained in GCLs. GCLs have excellent barrier performance of k<1.0×10-8 cm/s when the free swell is larger than 15 mL/2 g-solid regardless of the type and concentration of the permeant solution. In addition, when the results of the hydraulic conductivity test with chemical inorganic solutions were compared to those with waste leachates, the hydraulic conductivity of GCL permeated with chemical solution was almost the same within the electric conductivity of 0-25 S/m as that permeated with waste leachate having similar electric conductivity. The hydraulic conductivity of GCLs to be used in landfill bottom liners can be estimated by the hydraulic conductivity values obtained from the experiment using chemical solutions having the similar electric conductivity values, if the chemical solution had the electric conductivity within=25 S/m.  相似文献   

9.
The hydraulic conductivity of geosynthetic clay liners (GCLs) permeated with deionized water (S0) and NH4+ solutions, with concentrations of 100 mg/L (S100) and 1000 mg/L (S1000), was examined under six dry-wet cycles. The internal properties of virgin, desiccated, and healed GCLs were analyzed and quantified using X-ray computed tomography images. The hydraulic conductivity of the GCLs permeated with S0 and S100 underwent a negligible change during the six dry-wet cycles, whereas that of S1000 increased by almost three orders of magnitude after two desiccations. Each desiccation, after permeating with S0 and S100, generated a completely different macro-crack pattern; however, generation of macro-cracks at the same locations from dry cycles 2 to 6 and an abundance of micro-cracks were typical for S1000. This implies the severe deterioration of bentonite due to multi-desiccations and chemical compatibility with S1000. Moreover, the swell index of bentonite exposed to S1000 was reduced by approximately half, after six dry-wet cycles. Despite the lower volume percentage of macro-cracks for S1000 compared to S0 and S100, the swelling capacity of this bentonite was insufficient to fully heal these cracks. Hence, the swelling properties of bentonite dominate crack volume with regard to determining the hydraulic conductivity of GCLs.  相似文献   

10.
Flow in an idealized geosynthetic clay liner (GCL) containing bentonite comprised of equisized and equispaced square granules was simulated using a hydrodynamic model to quantitatively evaluate the premise that the hydraulic conductivity of GCLs diminishes as the bentonite granules hydrate and swell into adjacent intergranular pores, creating smaller and tortuous intergranular flow paths. Predictions with the model indicate that hydraulic conductivity decreases as granules swell and intergranular pores become smaller, and that greater granule swelling during hydration is required to achieve low hydraulic conductivity when the bentonite is comprised of larger granules, or the bentonite density is lower (lower bentonite mass per unit area). Predictions made with the model indicate that intergranular pores become extremely small (<1 μm) as the hydraulic conductivity approaches 10−11 m/s. These outcomes are consistent with experimental data showing that GCLs are more permeable when hydrated and permeated with solutions that suppress swelling of the bentonite granules, and that the hydraulic conductivity of GCLs with bentonite having smaller intergranular pores (e.g., GCLs with smaller bentonite granules, more broadly graded particles, or higher bentonite density) is less sensitive to solutions that suppress swelling.  相似文献   

11.
The performance of five different GCLs (two GCLs with standard sodium bentonite and three GCLs with polymer enhanced bentonite) subjected to three different climatic modes of wet-dry cycles simulating conditions to which a GCL might expose in cover systems over a prolonged time is reported. The wetting cycles lasted for 8 h, while the drying cycles varied between 16 h, seven days, and 14 days. It is shown that after around a year of accelerated aging, the hydraulic conductivity of the aged GCLs increased notably when permeated with tap water at an applied effective stress of 15 kPa for a range of heads (0.07, 0.14, 0.21, 0.49, and 1.2 m). The combined effects of the number and the duration of the wet-dry cycles, the GCL's mass per unit area, the carrier geotextile, the size and the number of the needle punch bundles, and the thermal treatment to bond the needle-punch bundles to the carrier geotextile are discussed. The poor hydraulic performance of the polymer-amended/modified bentonite GCLs is discussed.  相似文献   

12.
Geosynthetic clay liners (GCLs) are used in landfill liner applications due primarily to their low hydraulic conductivity to water. The low hydraulic conductivity of GCLs comes from the structure of the clay in the bentonite. However, the interaction between clay and aggressive liquids may alter the structure of the clay and, thus, result in an increase in the hydraulic conductivity of the GCL. This paper presents the results of a project aimed at evaluating the impact of a synthetic leachate on the structure of four different bentonites used in the manufacturing of GCLs. The preparation of bentonite dispersions increased the interaction between the bentonites and the various liquids. The hydraulic properties of the dispersions also were tested using filter press tests to obtain flow curves. Results of these tests were correlated with the cationic concentration, electrical conductivity and pH of the dispersions, swell indexes of the bentonite extracted from the GCLs, and permittivities of the intact GCLs determined in oedopermeameter tests. The results showed that one bentonite was more sensitive to the synthetic leachate than the other bentonites. For example, the permittivities of the more sensitive bentonite based on the oedopermeameter tests and filter press tests were respectively 2.11 × 10−8 s−1 and 5.6 × 10−8 s−1, whereas the permittivities for other bentonites, including a natural sodium bentonite and two sodium-activated calcium bentonites, were respectively 5.7 to 6.5 × 10−9 s−1 and 3.2 to 3.5 × 10−8 s−1. The filter press test served as a quick and easy-to-use test to compare the performance of the various bentonites in containing a given liquid. However, the oedopermeameter test or direct permeation test is preferable to filter press tests or fluid loss tests for evaluating the long-term impact of a liquid on a bentonite.  相似文献   

13.
The results of a comprehensive testing program conducted to evaluate the hydraulic conductivity (k) of two geosynthetic clay liners (GCLs) considered as a liner component for a tailings impoundment at a proposed zinc and copper mine are reported. The two GCLs were permeated with a relatively low ionic-strength ground water (GW) from the mine site and two electrolyte solutions, a process water (PW) and a simulated leachate (SL), with chemical compositions consistent with those expected during operation of the impoundment. A total of 22 flexible-wall tests were performed to determine the effects of prehydration with the GW, type of GCL, type of permeant liquid, and duration of the back-pressure stage of the test. The k values for both GCLs permeated with the GW were 1.7 × 10−9 cm/s, which is within the range 1–3 × 10−9 cm/s typically reported for GCLs permeated with low ionic-strength liquids, such as deionized water. However, the mean values of k based on permeation of duplicate specimens of both types of GCL with either PW or SL relative to the values of k based on permeation with GW, or k/kw, ranged from a factor of 200 (2.3 orders of magnitude) to a factor of 7600 (3.9 orders of magnitude). Thus, both tailings impoundment solutions had significant adverse impacts on the hydraulic performance of both GCLs. Given the overall range of k/kw values, factors such as prehydration, type of GCL, type of permeant liquid, and duration of back pressure, were relatively insignificant. The results of this study serve to emphasize the need to perform hydraulic conductivity testing using site specific materials.  相似文献   

14.
The self-healing of a GCL with artificial defects (circular holes and rectangular slits, both with and without the carrier geotextile preserved below the holes) upon hydration on a Godfrey silty sand (GSS) subgrade with wfdn = 5, 10 and 16% under 2–100 kPa is examined. Circular holes with the carrier geotextile missing below holes with diameters up to 25.4 mm self-healed on the wfdn = 5% and 10% GSS but not on 16% GSS, while none self-healed when carrier geotextile was preserved below the holes. When DI water was introduced to the surface under 100 kPa, circular holes with diameter up to 38.1 mm self-healed. Neither the single 15 mm-wide slit nor double 15 mm-wide parallel slits with 20 mm-wide strip of undamaged GCL between them resting on wfdn = 10% GSS under 20 kPa fully self-healed. The introduction of simulated synthetic landfill leachate (SSL) to the GCL surface under 70 kPa did not result in self-healing. Post-hydration k tests found that GCL without a carrier geotextile below a hole up to 25.4 mm in diameter would not have a significant adverse effect on the hydraulic conductivity compared with an intact GCL provided the permeant was tap water rather than SSL.  相似文献   

15.
Hydraulic conductivity of seven geosynthetic clay liners (GCLs) to synthetic coal combustion product (CCP) leachates were evaluated in this study. The leachates are chemically representative of typical and worst scenarios observed in CCP landfills. The ionic strength (I) of the synthetic CCP leachates ranged from 50 mM to 4676 mM (TCCP-50, LRMD-96, TFGDS-473, LR-2577, HI-3179 and HR-4676). One of the GCLs contained conventional sodium bentonite (Na–B) and the other six contained bentonite-polymer (B–P) mixture with polymer loadings ranging from 0.5% to 12.7%. Hydraulic conductivity tests were conducted at an effective confining stress of 20 kPa. The hydraulic conductivity of the Na–B GCLs were >1 × 10−10 m/s when permeated with all six CCP leachates, whereas the B–P GCLs with sufficient polymer loading maintained low hydraulic conductivity to synthetic CCP leachates. All the B–P GCLs showed low hydraulic conductivity (<1 × 10−10 m/s) to low ionic strength leachates (TCCP-50, I = 50 mM and LRMD-96, I = 96 mM). B–P GCLs with P > 5% showed low hydraulic conductivity (<1 × 10−10 m/s) up to HI-3179 leachates. These results suggest that B–P GCLs with sufficient polymer loading can be used to manage aggressive CCP leachates.  相似文献   

16.
This paper presents a novel suction-controlled chamber that permits the determination of the full water retention curves of geosynthetic clay liners (GCLs) under non-uniform temperature-stress paths. It investigates field conditions encountered in brine ponds (low confining stress settings) and heap leach pads (high confining stress settings) during construction and operation stages. Consequently, the analysis of the moisture dynamics in a GCL was defined under the wetting path (construction) and drying path (operation). High vertical stresses were found to facilitate a more rapid water uptake as capillarity is established faster than at low, confined stresses. In general, the drying curves increase the water desorption over the suction range investigated due to the low water viscosity caused by high temperatures. The wetting of the GCL at 20 °C and drying at 70 °C under either low, confined stress (2 kPa) or high confining stress (130 kPa) shows a reduction in the volumetric water contents. Furthermore, on the drying path, the coupled effect of elevated temperature and high confining stress accelerates water desorption leading possibly to potential desiccation.  相似文献   

17.
Geosynthetic clay liners (GCLs) are widely used in landfill and heap-leach facility cover system for mitigating rainfall infiltration and gas migration into atmosphere. Laboratory tests were conducted to investigate methane diffusion and advection through GCLs. Gas permeability coefficient of GCL for the case with moisture content = 47.5% is one and two orders of magnitude greater than the cases with moisture content = 68.5% and 80.9%, respectively, when 20 kPa vertical stress was applied. The batch adsorption tests indicated that adsorption of methane onto bentonite is negligible. The concentration variation for the adsorption of methane onto bentonite can be neglected. However, methane concentration decreased by 14.2% for the test of methane adsorption onto GCL during the first 2–3 days. This is because methane was adsorbed by the geotextiles rather than by the bentonite in GCL. The large porosity and surface area of geotextiles provide lots of micropores for methane adsorption. Analytical model was then developed to analyze the performance of GCL-based liners system with respect to methane transport. The results indicate that methane emission fluxes for the case with SL + GCL are 7.8 and 5.1 times less than the cases with SL + CCL when the moisture contents were 25.9% and 35.1%, respectively. The methane emission fluxes for both of the SL + GCL and SL + CCL can be neglected when they are fully saturated. GCL is recommended to be used in arid and semi-arid regions rather than CCL. GCL is recommended to be used in arid and semi-arid areas rather than CCL. Advection plays a more important role in methane migration through SL + GCL and SL + CCL than that of diffusion. With moisture contents = 25.9% and 32%, methane emission flux attributed to advection accounts for more than 90% of the total emission flux for both cases of SL + GCL and SL + CCL. With the increase of moisture content of SL, the effectiveness of SL in reducing methane emission increases. The saved space for using GCL + SL composite cover compared with using a single SL cover is 0.7 m when the moisture content equals 25.9%, which is 0.5 m greater than the case when moisture content equals 32%. GMB plays a dominant role in inhibiting methane migration and reducing methane emission flux. When moisture content equals 25.9%, the methane emission fluxes for SL + GMB + GCL and SL + GMB + CCL are 343 times and 2643 times less than the cases with SL + GCL and SL + CCL, respectively.  相似文献   

18.
The potential for desiccation of GCLs in double composite liner systems under thermal gradients is experimentally investigated. The effects of key initial and boundary conditions such as the GCL mass per unit area, initial GCL and subsoil water content, time lag between waste placement and temperature increase, the applied temperature gradient and the foundation layer thickness are investigated and discussed. The results suggest that surface temperatures of 39-45 °C, corresponding to thermal gradients of 59-67 °C/m, can induce sufficient thermally driven moisture redistribution to cause desiccation of GCLs. For surface temperatures of 29-37 °C and thermal gradients of 20-29 °C/m there was occasional slight cracking observed in about a quarter of the cases examined. Results of laboratory permeability tests on the virgin and exhumed samples are used to assess the self-healing capacity of GCLs.  相似文献   

19.
Experiments quantifying GCL permittivity and the ultimate water head the GCLs can sustain before the initiation of internal erosion when underlain by a 50 mm angular to subangular gravel subgrade are conducted. The influence of different geotextiles over the subgrade, water heads, hydration periods before testing, masses per unit area of bentonite within the GCL, and ionic strengths of the solution (cation exchange) are considered. Test results show that GCL with the scrim-reinforced nonwoven geotextile over the subgrade has the best hydraulic performance against internal erosion, followed by the woven geotextile coated with a 110 g/m2 polypropylene film. A woven or nonwoven is the least useful for preventing internal erosion, with the corresponding threshold water head initiating internal erosion >39 m for scrim-reinforced nonwoven, 21 m for lightly coated woven, 4–5 m for woven and nonwoven alone, respectively. Cation exchange, length of hydration, and mass per unit area of bentonite do not notably affect the threshold water head for the subgrade examined. Once internal erosion occurs, there is a 3-order of magnitude increase in permittivity. The practical implications are discussed.  相似文献   

20.
Semipermeable membrane behavior in clays refers to the ability of clays to restrict the migration of solutes. Thus, membrane behavior represents a potential benefit to the containment function of clay barriers used for hydraulic containment applications. In this regard, the potential influence of consolidation effective stress, σ′, on the membrane behavior of a geosynthetic clay liner (GCL) containing sodium bentonite was evaluated in the laboratory by establishing differences in salt (KCl) concentrations ranging from 3.9 to 47 mM across specimens of the GCL in a flexible-wall cell under closed-system boundary conditions. The membrane behavior exhibited by the GCL was enhanced via consolidation such that an increase in σ′ from 34.5 kPa (5 psi) to 241 kPa (35 psi) correlated with an increase in membrane efficiency from 0.015 (1.5%) to 0.784 (78.4%), respectively. The membrane efficiencies measured in this study at σ′ of 172 kPa (25 psi) and 241 kPa (35 psi) were similar to those previously reported for the same GCL using a rigid-wall cell but at unknown states of stress. The practical significance of the results is illustrated in the form of an analysis showing a reduction in liquid flux across the GCL with increasing membrane efficiency.  相似文献   

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