Performance investigation in modified and improved augmented power generation Kalina cycle using Python

In the generation of electricity and cogeneration, Kalina cycle is considered as one of the competitors to organic Rankine cycle. With the simplicity and identical components of the binary mixture, Kalina system makes it more prominent to get developed and implemented as well with its environmental friendly associate. This work proposes a new improved Kalina cycle system to convert the natural source from sun to useful work. The proposed system utilizes heat source suitable to medium temperature heat applications. The proposed cycle have 2 units of solar collector, favoring an additional heat recovery and higher performance. Solar hot source temperature and pressure are 190°C and 45 bar with additional flow to the turbine of 1.15 kg/s. Energy and second law analysis have considered in evaluating the performance of the proposed plant. The energy analysis shows minimum value of net power, energy efficiency and plant efficiency as 241 kW, 15.5% and 5.7. The exergy analysis defines that, to the proposed cycle, the exergy efficiency initializes at 77% with more exergy destruction at turbine with 31%. With the parametric analysis, the system is amended to have the maximum values of energy and exergy performances as 18.5%, 7.1% and 85%. The parametric study identifies the optimum value of the inlet temperature and pressure of the pump and turbine.     

Exergy analysis of a cogeneration plant using coal gasification and solid oxide fuel cell

This paper presents exergy analysis of a conceptualized combined cogeneration plant that employs pressurized oxygen blown coal gasifier and high‐temperature, high‐pressure solid oxide fuel cell (SOFC) in the topping cycle and a bottoming steam cogeneration cycle. Useful heat is supplied by the pass‐out steam from the steam turbine and also by the steam raised separately in an evaporator placed in the heat recovery steam generator (HRSG). Exergy analysis shows that major part of plant exergy destruction takes place in gasifier and SOFC while considerable losses are also attributed to gas cooler, combustion chamber and HRSG. Exergy losses are found to decrease with increasing pressure ratio across the gas turbine for all of these components except the gas cooler. The fuel cell operating temperature influences the performance of the equipment placed downstream of SOFC. Copyright © 2005 John Wiley & Sons, Ltd.     

Thermo-environ study of a concentrated photovoltaic thermal system integrated with Kalina cycle for multigeneration and hydrogen production

Unlike steam and gas cycles, the Kalina cycle system can utilize low-grade heat to produce electricity with water-ammonia solution and other mixed working fluids with similar thermal properties. Concentrated photovoltaic thermal systems have proven to be a technology that can be used to maximize solar energy conversion and utilization. In this study, the integration of Kalina cycle with a concentrated photovoltaic thermal system for multigeneration and hydrogen production is investigated. The purpose of this research is to develop a system that can generate more electricity from a solar photovoltaic thermal/Kalina system hybridization while multigeneration and producing hydrogen. With this aim, two different system configurations are modeled and presented in this study to compare the performance of a concentrated photovoltaic thermal integrated multigeneration system with and without a Kalina system. The modeled systems will generate hot water, hydrogen, hot air, electricity, and cooling effect with photovoltaic cells, a Kalina cycle, a hot water tank, a proton exchange membrane electrolyzer, a single effect absorption system, and a hot air tank. The environmental benefit of two multigeneration systems modeled in terms of carbon emission reduction and fossil fuel savings is also studied. The energy and exergy efficiencies of the heliostat used in concentrating solar radiation onto the photovoltaic thermal system are 90% and 89.5% respectively, while the hydrogen production from the two multigeneration system configurations is 10.6 L/s. The concentrated photovoltaic thermal system has a 74% energy efficiency and 45.75% exergy efficiency, while the hot air production chamber has an 85% and 62.3% energy and exergy efficiencies, respectively. Results from this study showed that the overall energy efficiency of the multigeneration system increases from 68.73% to 70.08% with the integration of the Kalina system. Also, an additional 417 kW of electricity is produced with the integration of the Kalina system and this justifies the importance of the configuration. The production of hot air at the condensing stage of the photovoltaic thermal/Kalina hybrid system is integral to the overall performance of the system.     

Thermodynamic analysis of an integrated power generation system driven by solid oxide fuel cell

A new integrated power generation system driven by the solid oxide fuel cell (SOFC) is proposed to improve the conversion efficiency of conventional energy by using a Kalina cycle to recover the waste heat of exhaust from the SOFC-GT. The system using methane as main fuel consists an internal reforming SOFC, an after-burner, a gas turbine, preheaters, compressors and a Kalina cycle. The proposed system is simulated based on the developed mathematical models, and the overall system performance has been evaluated by the first and second law of thermodynamics. Exergy analysis is conducted to indicate the thermodynamic losses in each components. A parametric analysis is also carried out to examine the effects of some key thermodynamic parameters on the system performance. Results indicate that as compressor pressure ratio increases, SOFC electrical efficiency increases and there is an optimal compressor pressure ratio to reach the maximum overall electrical efficiency and exergy efficiency. It is also found that SOFC electrical efficiency, overall electrical efficiency and exergy efficiency can be improved by increasing air flow rate. Also, the largest exergy destruction occurs in the SOFC followed by the after-burner, the waste heat boiler, the gas turbine. The compressor pressure ratio and air flow rate have significant effects on the exergy destruction in some main components of system.     

联产制冷的能效性能探讨

利用汽轮机抽汽作为吸收式制冷驱动热源的联产制冷，将供电、制冷有机结合在一起，不仅满足制冷要求也改善联产机组效率。通过引入抽汽yong增益概念，揭示了汽轮机抽汽特性规律，在此基础上从联产制冷目的yong效率角度比较了几种制冷方式，分析了汽轮机抽汽参数和相对内效率等因素对联产制冷能效性能影响规律，抽汽的yong增益比是联产制冷yong效率影响起决定作用的因素，所得结论对联产制冷吸收机的合理选用匹配提供有益的指导。     

Thermodynamic evaluation of hydrogen and electricity cogeneration coupled with very high temperature gas-cooled reactors

Hydrogen production using thermal energy, derived from nuclear reactor, can achieve large-scale hydrogen production and solve various energy problems. The concept of hydrogen and electricity cogeneration can realize the cascade and efficient utilization of high-temperature heat derive for very high temperature gas-cooled reactors (VHTRs). High-quality heat is used for the high-temperature processes of hydrogen production, and low-quality heat is used for the low-temperature processes of hydrogen production and power generation. In this study, two hydrogen and electricity cogeneration schemes (S1 and S2), based on the iodine-sulfur process, were proposed for a VHTR with the reactor outlet temperature of 950 °C. The thermodynamic analysis model was established for the hydrogen and electricity cogeneration. The energy and exergy analysis were conducted on two cogeneration systems. The energy analysis can reflect the overall performance of the systems, and the exergy analysis can reveal the weak parts of the systems. The analysis results show that the overall hydrogen and electricity efficiency of S1 is higher than that of S2, which are 43.6% and 39.2% at the hydrogen production rate of 100 mol/s, respectively. The steam generators is the components with the highest exergy loss coefficient, which are the key components for improving the system performance. This study presents a theoretical foundation for the subsequent optimization of hydrogen and electricity cogeneration coupled with VHTRs.     

Energetic and exergetic performance analyses of a combined heat and power plant with absorption inlet cooling and evaporative aftercooling

In this paper, exergy method is applied to analyze the gas turbine cycle cogeneration with inlet air cooling and evaporative aftercooling of the compressor discharge. The exergy destruction rate in each component of cogeneration is evaluated in detail. The effects of some main parameters on the exergy destruction and exergy efficiency of the cycle are investigated. The most significant exergy destruction rates in the cycle are in combustion chamber, heat recovery steam generator and regenerative heat exchanger. The overall pressure ratio and turbine inlet temperature have significant effect on exergy destruction in most of the components of cogeneration. The results obtained from the analysis show that inlet air cooling along with evaporative aftercooling has an obvious increase in the energy and exergy efficiency compared to the basic gas turbine cycle cogeneration. It is further shown that the first-law efficiency, power to heat ratio and exergy efficiency of the cogeneration cycle significantly vary with the change in overall pressure ratio and turbine inlet temperature but the change in process heat pressure shows small variation in these parameters.     

Engineering design and exergy analyses for combustion gas turbine based power generation system

This paper presents the engineering design and theoretical exergetic analyses of the plant for combustion gas turbine based power generation systems. Exergy analysis is performed based on the first and second laws of thermodynamics for power generation systems. The results show the exergy analyses for a steam cycle system predict the plant efficiency more precisely. The plant efficiency for partial load operation is lower than full load operation. Increasing the pinch points will decrease the combined cycle plant efficiency. The engineering design is based on inlet air-cooling and natural gas preheating for increasing the net power output and efficiency. To evaluate the energy utilization, one combined cycle unit and one cogeneration system, consisting of gas turbine generators, heat recovery steam generators, one steam turbine generator with steam extracted for process have been analyzed. The analytical results are used for engineering design and component selection.     

A new integrated renewable energy system for clean electricity and hydrogen fuel production

In this paper, a new renewable energy-based cogeneration system for hydrogen and electricity production is developed. Three different methods for hydrogen production are integrated with Rankine cycle for electricity production using solar energy as an energy source. In addition, a simple Rankine cycle is utilized for producing electricity. This integrated system consists of solar steam reforming cycle using molten salt as a heat carrier, solar steam reforming cycle using a volumetric receiver reactor, and electrolysis of water combined with the Rankine cycle. These cycles are simulated numerically using the Engineering Equation Solver (EES) based on the thermodynamic analyses. The overall energetic and exergetic efficiencies of the proposed system are determined, and the exergy destruction and entropy generation rates of all subcomponents are evaluated. A comprehensive parametric study for evaluating various critical parameters on the overall performance of the system is performed. The study results show that both energetic and exergetic efficiencies of the system reach 28.9% and 31.1%, respectively. The highest exergy destruction rates are found for the steam reforming furnace and the volumetric receiver reforming reactor (each with about 20%). Furthermore, the highest entropy generation rates are obtained for the steam reforming furnace and the volumetric receiver reforming reactor, with values of 174.1 kW/K and 169.3 kW/K, respectively. Additional parametric studies are undertaken to investigate how operating conditions affect the overall system performance. The results report that 60.25% and 56.14% appear to be the highest exergy and energy efficiencies at the best operating conditions.     

Energetic,exergetic and thermoeconomic analysis of Bilkent combined cycle cogeneration plant

This paper is a case study of thermodynamics and economics related analyses applied to an existing gas/steam combined cycle cogeneration plant. Basic thermodynamic properties of the plant are determined by energy analysis utilizing main operation conditions. Exergy destructions within the plant and exergy losses to environment are investigated to determine thermodynamic inefficiencies and to assist for guiding future improvements in the plant. Cost balances and auxiliary equations are applied to several subsystems in the plant, hence, cost formation in the plant is observed. Additionally, cost rate of each product of the plant is calculated. Copyright © 2005 John Wiley & Sons, Ltd.     

Energy and exergy analyses of a solar driven Mg–Cl hybrid thermochemical cycle for co-production of power and hydrogen

Analysis and performance assessment of a solar driven hydrogen production plant running on an Mg–Cl cycle, are conducted through energy and exergy methods. The proposed system consists of (a) a concentrating solar power cycle with thermal energy storage, (b) a steam power plant with reheating and regeneration, and (c) a hybrid thermochemical Mg–Cl hydrogen production cycle. The results show that higher steam to magnesium molar ratios are required for full yield of reactants at the hydrolysis step. This ratio even increases at low temperatures, although lowering the highest temperatures appears to be more favorable for linking such a cycle to lower temperature energy sources. Reducing the maximum cycle temperature decreases the plant energy and exergy efficiencies and may cause some undesirable reactions and effects. The overall system energy and exergy efficiencies are found to be 18.8% and 19.9%, respectively, by considering a solar heat input. These efficiencies are improved to 26.9% and 40.7% when the heat absorbed by the molten salt is considered and used as a main energy input to the system. The highest exergy destruction rate occurs in the solar field which accounts for 79% of total exergy destruction of the integrated system.     

On the thermodynamics of cogeneration

Cogeneration of various energy forms in a single piece of equipment has the potential of saving primary energy in comparison to separate generation. The amount of energy saving depends on the thermodynamic parameters of the systems to be compared and can be presented in a closed formula. For the particular case of cogeneration in a steam turbine a thorough thermodynamic analysis on the basis of exergy losses reveals the reasons for the higher efficiency. It is due to the facts that on producing the useful heat a transfer of this heat over the temperature difference between the heat intake of the cycle and the temperature of the heat demand is replaced by a power cycle and that separate power production is avoided altogether. This leads to a rational allocation of primary energy and in turn of emissions to the coupled energy forms.     

Multiobjective optimization for exergoeconomic analysis of an integrated cogeneration system

In this paper, a novel cogeneration system integrating Kalina cycle, CO₂ chemical absorption, process, and flash‐binary cycle is proposed to remove acid gases in the exhaust gas of solid oxide fuel cell (SOFC) system, improve the waste heat utilization, and reduce the cold energy consumed during CO₂ capture. In the CO₂ chemical absorption process, the methyldiethanolamine (MDEA) aqueous solution is utilized as a solvent, and feed temperature and absorber pressure are optimized via Aspen Plus software. The single‐objective and multiobjective optimization are carried out for the flash‐binary cycle subsystem. Results show that when the multiobjective optimization is applied to identify the exergoeconomic condition, the cogeneration system can simultaneously satisfy the high thermodynamic cycle efficiency and also the low product unit cost. The optimal results of the exergy efficiency, product unit cost, and normalized CO₂ emissions obtained by Pareto chart were 75.84%, 3.248 $/GJ, and 13.14 kg/MWhr, respectively.     

A district heating system based on absorption heat exchange with CHP systems

In order to decrease the energy consumption of large-scale district heating systems with cogeneration, a district heating system is presented in this paper based on absorption heat exchange in the cogeneration system named Co-ah cycle, which means that the cogeneration system is based on absorption heat exchange. In substations of the heating system, the temperature of return water of primary heat network is reduced to about 25°C through the absorption heat-exchange units. In the thermal station of the cogeneration plant, return water is heated orderly by the exhaust steam in the condenser, the absorption heat pumps, and the peak load heater. Compared with traditional heating systems, this system runs with a greater circuit temperature drop so that the delivery capacity of the heat network increases dramatically. Moreover, by recovering the exhausted heat from the condensers, the capacity of the district heating system and the energy efficiency of the combined heat and power system (CHP system) are highly developed. Therefore, high energy and economic efficiency can be obtained.     

Exergy analysis of cogeneration power plants in sugar industries

In this paper, exergy analysis of a heat-matched bagasse-based cogeneration plant of a typical 2500 tcd sugar factory, using backpressure and extraction condensing steam turbine is presented. In the analysis, exergy methods in addition to the more conventional energy analyses, are employed to evaluate overall and component efficiencies and to identify and assess the thermodynamic losses. The analysis is carried out for a wide range of steam inlet conditions selected around the sugar industry’s export cogeneration plant. The results show that, at optimal steam inlet conditions of 61 bar and 475 °C, the backpressure steam turbine cogeneration plant perform with energy and exergy efficiency of 0.863 and 0.307 and condensing steam turbine plant perform with energy and exergy efficiency of 0.682 and 0.260, respectively. Boiler is the least efficient component and turbine is the most efficient component of the plant.     

Exergetic and thermoeconomic analyses of diesel engine powered cogeneration: Part 1 – Formulations

This paper is part 1 of the study on the energy, exergy, and exergoeconomic analysis of diesel engine powered cogeneration (DEPC). Part 1 presents the formulation developed for such a comprehensive analysis while part 2 is an application of the developed formulation that considers an actual cogeneration power plant. Compression ignition engine powered cogeneration application is among the most efficient simple cycle power generation plants where the efficiencies are around 50%. The DEPC is mostly preferred in regions where natural gas is not available or not preferable because of high unit prices. In this paper, a DEPC plant is considered with all associated components. Mass, energy, and exergy balances are applied to each system component and subsystem. Exergy balance formulations are aimed to yield exergy destructions. Various efficiencies based on both energy and exergy methods and the performance assessment parameters are defined for both the system components and the entire cogeneration plant. The formulations for the cost of products, and cost formation and allocation within the system are developed based on both energy and exergy (i.e., exergoeconomic analysis). The cost analyses formulated here have significant importance to obtain the optimum marketing price of the product of thermal systems to maximize the benefit and/or minimize the cost.     

A modern injected steam gas turbine cogeneration system based on exergy concept

Factors such as low capital cost, good match of power and heat requirements and proven reliability can sometimes lead an end user into purchasing gas turbines for use in a modern cogeneration plant. The steam‐injected gas turbine is an attractive electrical generating technology for mitigating the impacts of rising energy prices. According to such mentioned above this paper is to provide results of an optimization study on cogeneration power cycle, which works by gas turbine with recuperator and injection steam added to the combustor of the gas turbine. The performance characteristics of the cycle based on energy and exergy concepts and based upon practical performance constraints were investigated. The effect of the recuperator on the cycle was greatly clarified. Results also show that the output power of a gas turbine increases when steam is injected. When extra steam has to be generated in order to be able to inject steam and at the same time to provide for a given heat demand, power generating efficiency increases but cogeneration efficiency decreases with the increasing of injected steam. Copyright © 2004 John Wiley & Sons, Ltd.     

Typical off-design analytical performances of internal combustion engine cogeneration

Based on experimental data, typical off-design characteristic curves with corresponding formulas of internal combustion engine (ICE) are summarized and investigated. In combination with analytical solution of single-pressure heat recovery steam generator (HRSG) and influence of ambient pressure on combined heat and power (CHP) system, off-design operation regularities of ICE cogeneration are analyzed. The approach temperature difference ΔT _a, relative steam production and superheated steam temperature decrease with the decrease in engine load. The total energy efficiency, equivalent exergy efficiency and economic exergy efficiency first increase and then decrease. Therefore, there exists an optimum value, corresponding to ICE best efficiency operating condition. It is worth emphasizing that ΔT _a is likely to be negative in low load condition with high design steam parameter and low ICE design exhaust gas temperature. Compared with single shaft gas turbine cogeneration, ΔT _a in ICE cogeneration is more likely to be negative. The main reason for this is that the gas turbine has an increased exhaust gas flow with the decrease in load; while ICE is on the contrary. Moreover, ICE power output and efficiency decrease with the decrease in ambient pressure. Hence, approach temperature difference, relative steam production and superheated steam temperature decrease rapidly while the cogeneration efficiencies decrease slightly. It is necessary to consider the influence of ambient conditions, especially the optimization of ICE performances at different places, on cogeneration performances.     

A district heating system based on absorption heat exchange with CHP systems

In order to decrease the energy consumption of large-scale district heating systems with cogeneration, a district heating system is presented in this paper based on absorption heat exchange in the cogeneration system named Co-ah cycle, which means that the cogeneration system is based on absorption heat exchange. In substations of the heating system, the temperature of return water of primary heat network is reduced to about 25°C through the absorption heat-exchange units. In the thermal station of the cogeneration plant, return water is heated orderly by the exhaust steam in the condenser, the absorption heat pumps, and the peak load heater. Compared with traditional heating systems, this system runs with a greater circuit temperature drop so that the delivery capacity of the heat network increases dramatically. Moreover, by recovering the exhausted heat from the condensers, the capacity of the district heating system and the energy efficiency of the combined heat and power system (CHP system) are highly developed. Therefore, high energy and economic efficiency can be obtained.     

Thermoeconomic analysis method for optimization of combined heat and power systems—part II

In this paper, a thermoeconomic functional analysis method based on the Second Law of Thermodynamics and applied to analyze four cogeneration systems is presented. The objective of the developed technique is to minimize the operating costs of the cogeneration plant, namely exergetic production cost (EPC), assuming fixed rates of electricity production and process steam in exergy base. In this study a comparison is made between the same four configurations of part I. The cogeneration system consisting of a gas turbine with a heat recovery steam generator, without supplementary firing, has the lowest EPC.