Integrated hydrogen production options based on renewable and nuclear energy sources

Due to varied global challenges, potential energy solutions are needed to reduce environmental impact and improve sustainability. Many of the renewable energy resources are of limited applicability due to their reliability, quality, quantity, and density. Thus, the need remains for additional sustainable and reliable energy sources that are sufficient for large-scale energy supply to complement and/or back up renewable energy sources. Nuclear energy has the potential to contribute a significant share of energy supply with very limited impacts to global climate change. Hydrogen production via thermochemical water decomposition is a potential process for direct utilization of nuclear thermal energy. Nuclear hydrogen and power systems can complement renewable energy sources by enabling them to meet a larger extent of global energy demand by providing energy when the wind does not blow, the sun does not shine, and geothermal and hydropower energies are not available. Thermochemical water splitting with a copper–chlorine (Cu–Cl) cycle could be linked with nuclear and selected renewable energy sources to decompose water into its constituents, oxygen and hydrogen, through intermediate copper and chlorine compounds. In this study, we present an integrated system approach to couple nuclear and renewable energy systems for hydrogen production. In this regard, nuclear and renewable energy systems are reviewed to establish some appropriate integrated system options for hydrogen production by a thermochemical cycle such as Cu–Cl cycle. Several possible applications involving nuclear independent and nuclear assisted renewable hydrogen production are proposed and discussed. Some of the considered options include storage of hydrogen and its conversion to electricity by fuel cells when needed.     

Rational design and fabrication of surface tailored low dimensional Indium Gallium Nitride for photoelectrochemical water cleavage

Currently several type of energy sources exist in the modern world. The energy makes people's life more comfortable, easy, time savings, fast transformation of information and various modes of transmission. Because of large demand of energy, efforts on production of energy increases day by day which subsequently increase serious environmental concerns such as pollution and lack of existing natural resources. In this respect, several attempts have been proposed for new type of renewable and chemical energy systems to overcome the economic burden, global warming and environmental problems caused by the use of conventional fossil fuels. Hydrogen production via water splitting is a promising and ideal route for renewable energy using the most abundant resources of solar light and water. Cost effective photocatalyst for Photoelectrochemical (PEC) water splitting using semiconductor materials as light absorbers have been extensively studied due to their stability and simplicity. Over the past few decades, various metal oxide photocatalysts for water splitting have been developed and their photocatalytic application was studied under UV irradiation. Alternative semiconductor photocatalyst should harness solar energy in the visible light, one such semiconductor material is indium gallium nitride (InGaN), owing to its suitable and tunable energy band-gap, chemical resistance and notable photoelectrocatalytic activity. This review article is initiated with the brief introduction about the origin and methods of production of hydrogen gas from both renewable and nonrenewable energy sources. Multi-functional properties and applications of InGaN are described along with past and recent efforts of InGaN materials for hydrogen evolution by several investigators are provided in detail. In addition, future prospects and ways to improve the PEC performance of InGaN are presented at the end of this review.     

Electrolyser-based energy management: a means for optimising the exploitation of variable renewable-energy resources in stand-alone applications

Electrolyser-based energy management (EBM) offers a versatile means for optimising the process of harnessing energy supplies derived from variable and/or intermittent renewable resources, e.g. solar (photo-voltaic), wind, wave and tidal. In general, EBM systems consist of an electrolyser, water and gas (hydrogen and, optimally, oxygen) storage and management systems and a means of (re-) generating electricity, e.g. a fuel cell. Such systems achieve their management via energy conversion and storage, this operational principle being referred to as electricity supply-and-demand management (ESDM). Implementation of this principle offers significant advantages in the utilisation of variable and/or intermittent renewable resources, as it permits electricity generated during periods of high-availability/low-demand to be “time-shifted” for subsequent re-supply during periods of low-availability/high-demand. Furthermore, EBM systems have the important advantage over other ESDM systems that the stored form of energy is readily utilisable as a pollution-free gas supply for thermal end-uses. This reconversion route significantly enhances the overall energy-conversion efficiency. Electrolyser and fuel cells based upon proton-exchange membrane technologies are preferred because these afford considerable operational advantages over any alternatives. In this paper these advantages are expanded upon and preliminary data based on these ideas are presented.     

Tidal current turbines glance at the past and look into future prospects in Malaysia

Periodic changes of water levels, and associated tidal currents, are due to the gravitational attraction forces between the Earth, the Sun and the Moon. These changes can be transformed to a renewable energy resource called Tidal Current Energy. A number of resource quantization and demonstration studies have been performed throughout the world and it is believed that offshore ocean energy sector will benefit from this emerging technology. In this study, a set of basic definitions which are relevant to this technology are presented with an overview on the main tidal turbine schemes and the mooring methods that in use. A review of the current development and their fields of applications are outlined. The Blade Element Momentum BEM method and the Computational Fluid Dynamics CFD are discussed. The last section highlights the importance of this technology and its applicability in Malaysia. Other renewable energy resources in Malaysia are highlighted and discussed as well.     

Seawater desalination using renewable energy sources

The origin and continuation of mankind is based on water. Water is one of the most abundant resources on earth, covering three-fourths of the planet's surface. However, about 97% of the earth's water is salt water in the oceans, and a tiny 3% is fresh water. This small percentage of the earth's water—which supplies most of human and animal needs—exists in ground water, lakes and rivers. The only nearly inexhaustible sources of water are the oceans, which, however, are of high salinity. It would be feasible to address the water-shortage problem with seawater desalination; however, the separation of salts from seawater requires large amounts of energy which, when produced from fossil fuels, can cause harm to the environment. Therefore, there is a need to employ environmentally-friendly energy sources in order to desalinate seawater.After a historical introduction into desalination, this paper covers a large variety of systems used to convert seawater into fresh water suitable for human use. It also covers a variety of systems, which can be used to harness renewable energy sources; these include solar collectors, photovoltaics, solar ponds and geothermal energy. Both direct and indirect collection systems are included. The representative example of direct collection systems is the solar still. Indirect collection systems employ two sub-systems; one for the collection of renewable energy and one for desalination. For this purpose, standard renewable energy and desalination systems are most often employed. Only industrially-tested desalination systems are included in this paper and they comprise the phase change processes, which include the multistage flash, multiple effect boiling and vapour compression and membrane processes, which include reverse osmosis and electrodialysis. The paper also includes a review of various systems that use renewable energy sources for desalination. Finally, some general guidelines are given for selection of desalination and renewable energy systems and the parameters that need to be considered.     

Hydrogen-based systems for integration of renewable energy in power systems: Achievements and perspectives

This paper is a critical review of selected real-world energy storage systems based on hydrogen, ranging from lab-scale systems to full-scale systems in continuous operation. 15 projects are presented with a critical overview of their concept and performance. A review of research related to power electronics, control systems and energy management strategies has been added to integrate the findings with outlooks usually described in separate literature. Results show that while hydrogen energy storage systems are technically feasible, they still require large cost reductions to become commercially attractive. A challenge that affects the cost per unit of energy is the low energy efficiency of some of the system components in real-world operating conditions. Due to losses in the conversion and storage processes, hydrogen energy storage systems lose anywhere between 60 and 85% of the incoming electricity with current technology. However, there are currently very few alternatives for long-term storage of electricity in power systems so the interest in hydrogen for this application remains high from both industry and academia. Additionally, it is expected that the share of intermittent renewable energy in power systems will increase in the coming decades. This could lead to technology development and cost reductions within hydrogen technology if this technology is needed to store excess renewable energy. Results from the reviewed projects indicate that the best solution from a technical viewpoint consists in hybrid systems where hydrogen is combined with short-term energy storage technologies like batteries and supercapacitors. In these hybrid systems the advantages with each storage technology can be fully exploited to maximize efficiency if the system is specifically tailored to the given situation. The disadvantage is that this will obviously increase the complexity and total cost of the energy system. Therefore, control systems and energy management strategies are important factors to achieve optimal results, both in terms of efficiency and cost. By considering the reviewed projects and evaluating operation modes and control systems, new hybrid energy systems could be tailored to fit each situation and to reduce energy losses.     

Energy sprawl,land taking and distributed generation: towards a multi-layered density

The transition from fossil fuels to renewable resources is highly desirable to reduce air pollution, and improve energy efficiency and security. Many observers are concerned, however, that the diffusion of systems based on renewable resources may give rise to energy sprawl, i.e. an increasing occupation of available land to build new energy facilities of this kind. These critics foresee a transition from the traditional fossil-fuel systems, towards a renewable resource system likewise based on large power stations and extensive energy grids. A different approach can be taken to reduce the risk of energy sprawl, and this will happen if the focus is as much on renewable sources as on the introduction of distributed renewable energy systems based on micro plants (photovoltaic panels on the roofs of buildings, micro wind turbines, etc.) and on multiple micro-grids. Policy makers could foster local energy enterprises by: introducing new enabling rules; making more room for contractual communities; simplifying the compliance process; proposing monetary incentives and tax cuts. We conclude that the diffusion of innovation in this field will lead not to an energy sprawl but to a new energy system characterized by a multi-layered density: a combination of technology, organization, and physical development.     

Renewable energy in the South Pacific—options and constraints

Over the last fifteen years the small island nations in the South Pacific have seen the introduction of various forms of renewable energy technologies. In spite of high expectations from the development of indigenous renewable energy resources using nonconventional approaches (wind power, wave power, ocean thermal energy conversion, biogas digestors, biomass gasifiers), these technologies have largely failed to develop into viable alternatives to conventional approaches (based on imported petroleum, biomass and hydroelectric power). Among the few exceptions are solar photovoltaic power for remote islands, especially when provided through a utility type institution, solar water heaters, and the use of biomass wastes by agroindustries. As a result, all the island countries are still heavily dependent on fossil fuels for their energy requirements. Some of them to such an extent that their petroleum imports are up to 500% of their total exports.As far as acceptance of new renewable energy technologies by the Pacific communities goes hasty decisions and introductions have done more harm than good.     

A comparative study of critical factors influencing the renewable energy systems use in the Indian context

The use of renewable energy technologies in developing countries has steadily increased over the past few decades. The widespread use of renewable sources requires a greater understanding of the available options. In order to ascertain the quantum of acceptance of renewable energy sources in the context of possible deterioration of the environment, on account of the increased use of fossil fuels, a Delphi study had been conducted. The feedback from the study was collected and analysed, so as to arrive at a general consensus. By the year 2020, the renewable energy contribution is expected to be 25% of the total energy use in India. At that time, the main resources utilised would be biomass, wind and solar in the order of their quantum of use. Using skewness and rank correlation analysis the results of the Delphi study were studied. It is identified that price, equipment efficiency and technology are the critical factors for commercialising renewable energy sources as denoted by skewness coefficients of 11.6, 5.55 and 0.68, respectively. Rank correlation indicates that the correlation between biomass gasifier electric conversion and biogas electric conversion for lighting is positive, denoting the possibility of integration of the two systems. Similarly, it has been analysed for integrated systems in the area of cooking, pumping, heating, cooling and transportation. This study will help in the formation of strategies which will ensure the development of the optimal integrated energy systems for continuous power supply.     

Recent progresses in porphyrin assisted hydrogen evolution

The indiscriminate exploitation of fossil fuels over a period of two centuries has eventually led us to a juncture where search for alternate energy sources and sustainable development has become inevitable. Solar energy remains the most reliable renewable energy source, efficient harnessing of which can serve to meet the future energy demands. Photo-assisted water splitting to generate hydrogen, a potential clean fuel has been the focus of current research in this field. Design and development of suitable materials for efficient solar energy conversion remains the major challenge to be tackled in this aspect. A cost-effective technology for conversion of solar energy is still a distant dream. The present paper attempts a general overview of the basic principles of water splitting with special focus on porphyrin-based systems as promising water splitting systems.     

Energy demand and greenhouse gas emissions from urban passenger transportation versus availability of renewable energy: The example of the Canadian Lower Fraser Valley

The energy consumption and greenhouse gas emissions of all private and transit vehicles from the Lower Fraser Valley, British Columbia, Canada are analysed for the year 2000. The energy figures are then compared with the Province's renewable energy potential. Results indicate that electric trolley buses and the automated rapid transit SkyTrain were eight times as energy efficient as private vehicles. These two modes were also 100 times as emission efficient as private vehicles in terms of greenhouse gas emitted per passenger-kilometer. Analysis of a minimal greenhouse gas emissions scenario, based on local renewable energy resources, electrolytic hydrogen production, and conversion of all private vehicles to fuel-cell technology indicates that such a strategy would utilize between 40% and 60% of the Province's renewable energy resources. We conclude that, if the use of renewable energy resources is chosen to reduce emissions from urban passenger transportation, probability of success will be increased by reducing the sector's energy demand through a transfer of ridership to the most energy efficient modes.     

Low-grade heat conversion into power using organic Rankine cycles – A review of various applications

An organic Rankine cycle (ORC) machine is similar to a conventional steam cycle energy conversion system, but uses an organic fluid such as refrigerants and hydrocarbons instead of water. In recent years, research was intensified on this device as it is being progressively adopted as premier technology to convert low-temperature heat resources into power. Available heat resources are: solar energy, geothermal energy, biomass products, surface seawater, and waste heat from various thermal processes. This paper presents existing applications and analyzes their maturity. Binary geothermal and binary biomass CHP are already mature. Provided the interest to recover waste heat rejected by thermal devices and industrial processes continue to grow, and favorable legislative conditions are adopted, waste heat recovery organic Rankine cycle systems in the near future will experience a rapid growth. Solar modular power plants are being intensely investigated at smaller scale for cogeneration applications in buildings but larger plants are also expected in tropical or Sahel regions with constant and low solar radiation intensity. OTEC power plants operating mainly on offshore installations at very low temperature have been advertised as total resource systems and interest on this technology is growing in large isolated islands.     

Modeling of hydrogen production with a stand-alone renewable hybrid power system

Hydrocarbon resources adequately meet today’s energy demands. Due to the environmental impacts, renewable energy sources are high in the agenda. As an energy carrier, hydrogen is considered one of the most promising fuels for its high energy density as compared to hydrocarbon fuels. Therefore, hydrogen has a significant and future use as a sustainable energy system. Conventional methods of hydrogen extraction require heat or electrical energy. The main source of hydrogen is water, but hydrogen extraction from water requires electrical energy. Electricity produced from renewable energy sources has a potential for hydrogen production systems. In this study, an electrolyzer using the electrical energy from the renewable energy system is used to describe a model, which is based on fundamental thermodynamics and empirical electrochemical relationships. In this study, hydrogen production capacity of a stand-alone renewable hybrid power system is evaluated. Results of the proposed model are calculated and compared with experimental data. The MATLAB/Simscape^® model is applied to a stand-alone photovoltaic-wind power system sited in Istanbul, Turkey.     

A modeling approach for investigating climate change impacts on renewable energy utilization

In this study, an integrated community‐scale energy model (ICEM) was developed for supporting renewable energy management (REM) systems planning with the consideration of changing climatic conditions. Through quantitatively reflecting interactive relationships among various renewable energy resources under climate change, not only the impacts of climate change on each individual renewable energy but also the combined effects on power‐generation sector from renewable energy resources could be incorporated within a general modeling framework. Also, discrete probability levels associated with various climate change impacts on the REM system could be generated. Moreover, the ICEM could facilitate capacity–expansion planning for energy‐production facilities within a multi‐period and multi‐option context in order to reduce energy‐shortage risks under a number of climate change scenarios. The generated solutions can be used for examining various decision options that are associated with different probability levels when availabilities of renewable energy resources are affected by the changing climatic conditions. A series of probability levels of hydropower‐, wind‐ and solar‐energy availabilities can be integrated into the optimization process. The developed method has been applied to a case of long‐term REM planning for three communities. The generated solutions can provide desired energy resource/service allocation and capacity–expansion plans with a minimized system cost, a maximized system reliability and a maximized energy security. Tradeoffs between system costs, renewable energy availabilities and energy‐shortage risks can also be tackled with the consideration of climate change, which would have both positive and negative impacts on the system cost, energy supply and greenhouse‐gas emission. Copyright © 2011 John Wiley & Sons, Ltd.     

Technical–economical analysis of the Saveh biogas power plant

The resource limitation of fossil fuels and the problems arising from their combustion has led to widespread research on the accessibility of new and renewable energy resources. Solar, wind, thermal and hydro sources, and finally biogas are among these renewable energy resources. But what makes biogas distinct from other renewable energies is its importance in controlling and collecting organic waste material and at the same time producing fertilizer and water for use in agricultural irrigation. Unlike other forms of renewable energy, biogas neither has any geographical limitations and required technology for producing energy and nor is it complex or monopolistic. Considering the ever increasing amount of different types of organic waste materials (about 15 million tonnes) in Iran, working on the control of waste material and biogas production becomes inevitable.In this paper, biogas and the benefits from its production are discussed, as is the technical-economic analysis of the Saveh biogas power plant as a case study.     

Economical evaluation of electricity generation considering externalities

The economics of renewable energy are the largest barrier to renewable penetration. Nevertheless, the strong desire to reduce environmental emissions is considered a great support for renewable energy sources. In this paper, a full analysis for the cost of the kWh of electricity generated from different systems actually used in Egypt is presented. Also renewable energy systems are proposed and their costs are analyzed. The analysis considers the external cost of emissions from different generating systems. A proposed large scale PV plant of 3.3 MW, and a wind farm 11.25 MW grid connected at different sites are investigated. A life cycle cost analysis for each system was performed using the present value criterion. The comparison results showed that wind energy generation has the lowest cost, followed by a combined cycle–natural gas fired system. A photovoltaic system still uses comparatively expensive technology for electricity generation; even when external costs are considered the capital cost of photovoltaic needs to be reduced by about 60% in order to be economically competitive.     

Island breezes

What does 40% renewable energy look like on a small island grid? As with most things in life, the answer is, "It depends." It depends on the characteristics of the thermal generation mix, the diversity of the variable renewable resources, the capabilities and characteristics of the renewable generation technology, and the characteristics of the transmission grid. Island systems face challenges in these areas not experienced by large, integrated systems. In spite of this, Hawaiian grids are targeting--and on one island have recently reached--40% of electrical energy from the islands' abundant renewable resources. The steps to reach this goal are outlined in a recent agreement between the Hawaiian Electric utility; the governor of Hawaii; the Hawaii Department of Business, Economic Development, and Tourism; and the State of Hawaii Office of the Consumer Advocate. The U.S. Department of Energy (DOE) also participated. Information on this energy agreement, part of the Hawaii Clean Energy Initiative, can be found at hawaiicleanenergy.com or www.heco.com.     

Appropriate technologies for large-scale production of electricity and hydrogen fuel

Appropriate technology for energy supply requires the use of the most effective energy resources and conversion technologies that will also result in the minimum acceptable impact upon the environment. A useful parameter for evaluation of energy resources for large-scale production of electricity and hydrogen fuel is the specific energy of the appropriate energy resources. Available resources for such large-scale applications must come from some mixture of renewable, fossil, and nuclear energy. Analysis is made of the appropriate use of solar energy, chemical combustion fuels, and nuclear energy on the basis of their specific energy. The results show that the most appropriate resources for large-scale production of electricity and hydrogen are low-specific solar photovoltaic and wind turbine energy for large numbers of distributed small-scale applications and high-specific nuclear energy for smaller numbers of large-scale applications.     

Negative carbon intensity of renewable energy technologies involving biomass or carbon dioxide as inputs

Conventional fossil fuel-based energy technologies can achieve efficiency in energy conversion but they are usually completely inefficient in carbon conversion because they generate significant CO₂ emissions to the atmosphere per unit energy converted. In contrast, some renewable energy technologies characterized by negative carbon intensity can simultaneously achieve efficiency in the conversion of energy and in the conversion of carbon. These carbon negative renewable energy technologies can generate useful energy and remove CO₂ from the atmosphere, either by direct capture and recycling of atmospheric CO₂ or indirectly, by involving biofuels. Interestingly, the deployment of carbon negative renewable energy technologies can offset carbon emissions from conventional fossil fuel-based energy technologies and thus reduce the overall carbon intensity of energy systems.The current review analyzes two groups of renewable energy technologies involving biomass or CO₂ as inputs. The discussions focus on useful techniques which enable to achieve negative carbon intensity of energy while being technologically promising in near-term as well as cost-effective. These analyzes include advanced carbon sequestration concepts such as soil carbon sequestration and CO₂ recycling to useful C-rich products such as fuels and fertilizers. The 'drop-in' of renewable energy is achieved by allowing bioenergy and renewable energies in the form of renewable electricity, renewable thermal energy, solar energy, renewable hydrogen, etc. The carbon negative renewable energy technologies are analyzed and perspectives and constraints of each technology are expounded.     

Biomass-derived aviation fuels: Challenges and perspective

The worldwide utilization of fossil energy, including its specific application as transportation fuel, significantly contributes to the continuous increase of the atmospheric CO₂ concentration. Several solutions have been promoted or scheduled to reduce CO₂ emissions. Among these solutions, the development of renewable energy resources, such as bio-fuels, offers important advantages as promoted by several countries and institutions who disclosed their plans to partly or totally use alternative renewable energy sources in the future. For the rapidly growing aviation sector, aviation fuel derived from fossil resources is still the major available energy source. The development of renewable aviation fuel is considered to be a promising future strategy to reduce related CO₂ emissions. The worldwide total aviation fuel consumption by commercial airlines increased from about 260 million m³/year in 2005 to over 340 million m³/year in 2018, and a further annual increase of about 5% is expected till 2050.Worldwide actions have hence been undertaken with respect to bio-aviation fuel production, distribution, and demonstration flying. As a relatively new topic, there are a lot of remaining challenges in technology development, fuel certification and distribution. The production technology, policy and environmental impact of bio-aviation fuel were comprehensively reviewed, including its production by the catalytic conversion of lipids, by the conversion of carbohydrates or lignocellulosic biomass, and by developing bio-refinery concepts for bio-aviation fuel production. The future reduction of CO₂ emissions in the aviation sector requires an improvement of the biomass to aviation fuel production technology through the correct integration of biology, chemical engineering, and energy crops. The paper illustrates this potential integration through reviewing the current research in the production of aviation fuels from biomass, including the complete industrial chain from airplane manufacturer, aviation fuel producer and provider, airline strategies, and ongoing R&D, bearing in mind that major efforts are required to foster the development of the cost-effective production of renewable aviation fuel. The different topics of the Table of contents will be subsequently dealt with.