Effect of feed pressure on the performance of the photovoltaic powered reverse osmosis seawater desalination system

This paper describes the potential of the development of a seawater desalination system that combines the technologies of reverse osmosis (RO) and photovoltaic (PV) to deliver 100 m³/day of sweet water. Silicon cells are chosen for the PV array and the polyamide thin-film composite seawater Filmtec membranes are selected for the RO system. The software ROSA is adopted to study the influences of the feed pressure on the performance of the system. It is found that as the feed pressure increases, the specific energy of the plant decreases but the percentage of recovery increases.     

Dynamic and multiphysic PEM electrolysis system modelling: A bond graph approach

Proton exchange membrane (PEM) electrolysis technology appears as a key technology in the development of hydrogen-energy market applications such as energy storage or fuel for mobility. Its coupling with renewable electrical sources involves some issues related to the intermittent operation of PEM electrolysis systems. Within this framework, modelling is an essential tool to understand these issues, provide a thorough analysis and suggest some design optimization. A bibliographic analysis was carried out to identify existing models. State of the art highlighted that, although it is critical for the conception of such systems, only a few models take into account the dynamic of the whole system including balance of plant. Therefore, in this paper a new dynamic and multiphysic model of a proton exchange membrane electrolysis system is presented. It was first developed under a graphical modelling formalism: the bond graphs (BG). Regarding dynamic and multiphysic modelling of complex systems, the BG have many advantages: it involves four levels of modelling using only one tool; it is a unified multiphysic approach; the parameters used have a physical meaning; the BG model can be refined very easily by adding new elements without having to start again the modelling process. Finally, because of its causal and structural properties, BG is suitable for modelling but also for control, sizing and diagnosis analysis. The model was then transcribed systematically into block diagrams in modular fashion for reutilisability of model libraries components. After a validation process, the model was proved to describe accurately the dynamic behaviour of a semi-industrial PEM electrolysis system (25 kW). The dynamic model can now be used to achieve some analyses through BG structural properties and simulations. Thus, it is a powerful tool to improve the design of PEM electrolysis systems powered by intermittent electrical sources.     

Robust diagnosis of PEM electrolysers using LFT bond graph

A model based diagnosis for Proton Exchange Membrane (PEM) water electrolyser has been presented in this paper using Linear Fractional Transformation (LFT) bond graph technique. LFT helps in calculating the adaptive thresholds in order to make the diagnosis robust against parameters and measurement uncertainties, hence avoiding false alarms. A modular approach has been followed that allows the model to be adapted to different configurations of PEM electrolyser. The developed diagnosis has been first tested offline by injecting the faults into behavioural model of the PEM electrolyser and then implemented online for a single cell PEM electrolyser.     

Analysis of solar desalination system using heat pump

This paper investigates a pilot desalination system which consists of a direct expansion solar assisted heat pump (DXSAHP) coupled to a single-effect evaporator unit. The working fluid used is R134a and distillate is obtained via falling film evaporation and flashing in the unit. Experiments have been conducted in both day and night meteorological conditions in Singapore and the effects of solar irradiation and compressor speed have been studied against the system performance. From the experiments, the Performance Ratio (PR) obtained ranges from 0.43 to 0.88, the average Coefficient of Performance (COP) was 8 and the highest distillate production recorded was 1.38 kg/h.     

Bond graph modeling,design and experimental validation of a photovoltaic/fuel cell/ electrolyzer/battery hybrid power system

This work presents a complete bond graph modeling of a hybrid photovoltaic-fuel cell-electrolyzer-battery system. These are multi-physics models that will take into account the influence of temperature on the electrochemical parameters. A bond graph modeling of the electrical dynamics of each source will be introduced. The bond graph models were developed to highlight the multi-physics aspect describing the interaction between hydraulic, thermal, electrochemical, thermodynamic, and electrical fields. This will involve using the most generic modeling approach possible for managing the energy flows of the system while taking into account the viability of the system. Another point treated in this work is to propose. In this work, a new strategy for the power flow management of the studied system has been proposed. This strategy aims to improve the overall efficiency of the studied system by optimizing the decisions made when starting and stopping the fuel cell and the electrolyzer. It was verified that the simulation results of the proposed system, when compared to simulation results presented in the literature, that the hydrogen demand is increased by an average of 8%. The developed management algorithm allows reducing the fuel cell degradation by 87% and the electrolyzer degradation by 65%. As for the operating time of the electrolyzer, an increment of 65% was achieved, thus improving the quality of the produced hydrogen. The Fuel Cell's running time has been decreased by 59%. With the ambition to validate the models proposed and the associated commands, the development of this study gave rise to the creation of an experimental platform. Using this high-performance experimental platform, experimental tests were carried out and the results obtained are compared with those obtained by simulation under the same metrological conditions.     

Second law analysis of reverse osmosis desalination plants: An alternative design using pressure retarded osmosis

A second law analysis of a reverse osmosis desalination plant is carried out using reliable seawater exergy formulation instead of a common model in literature that represents seawater as an ideal mixture of liquid water and solid sodium chloride. The analysis is performed using reverse osmosis desalination plant data and compared with results previously published using the ideal mixture model. It is demonstrated that the previous model has serious shortcomings, particularly with regard to calculation of the seawater flow exergy, the minimum work of separation, and the second law efficiency. The most up-to-date thermodynamic properties of seawater, as needed to conduct an exergy analysis, are given as correlations in this paper. From this new analysis, it is found that the studied reverse osmosis desalination plant has very low second law efficiency (<2%) even when using the available energy recovery systems. Therefore, an energy recovery system is proposed using the (PRO) pressure retarded osmotic method. The proposed alternative design has a second law efficiency of 20%, and the input power is reduced by 38% relative to original reverse osmosis system.     

Bond graph modeling approach development for fuel cell PEMFC systems

This paper addresses the problem of bond graph methodology as a graphical approach for modeling fuel cell systems. The system consists of a Proton Exchange Membrane Fuel Cell (PEMFC) stack, an interleaved boost converter, battery pack connected via a buck converter.     

Proof-of-concept study of an integrated solar desalination system

This paper describes the performance of a directly heated solar desalination system. The design concept is based on using a direct solar energy collection unit, integrated with flash evaporation and low temperature multi-effect distillation (LT-MED) equipment. Key parameters affecting desalination rate include flashing evaporation pressure, first effect distillation pressure and seawater temperature. The experimental results indicate that at flash evaporation pressure of 0.01 MPa, first effect distillation pressure of 0.004 MPa, and the temperature of solar-heated seawater of 78 °C, the system can reach steady state operation in 17 min. At steady state, desalination rate of 0.204 × 10⁻³ m³/min is obtained. On raising temperature from 70 to 78 °C, net increase in desalination rate of 0.165 × 10⁻³ m³/min is achieved. In contrast, the change of first effect distillation pressure only had minimum effect on desalination rate. Experimental results are in agreement with the theoretical analysis. If temperature continues to increase beyond 78 °C, scaling due to precipitation of CaSO₄ takes place. In this study, the techniques that prevent the system from scaling deposits are discussed.     

Application of a multi-criteria analysis for the selection of the most suitable energy source and water desalination system in Mauritania

Water deficits and their associated shortages are serious problems in many areas of the world. The paper presents a multi-criteria analysis for selection of the most suitable system in Mauritania. Six scenarios, different energy sources, technologies of water desalination processes and water use and five criteria are analyzed. The multi-criteria analysis shows that the optimal solution is different for each scenario; in some cases the photovoltaic-reverse osmosis option is preferable; in others, the best option is reverse-osmosis powered by wind energy or concentrating solar parabolic.     

Modeling and design of a solar thermal system for hybrid cooking application

This paper proposes a hybrid solar cooking system where the solar energy is brought to the kitchen. The energy source is a combination of the solar thermal energy and the Liquefied Petroleum Gas (LPG) that is in common use in kitchens. The solar thermal energy is transferred to the kitchen by means of a circulating fluid. The transfer of solar heat is a twofold process wherein the energy from the collector is transferred first to an intermediate energy storage buffer and the energy is subsequently transferred from the buffer to the cooking load. There are three parameters that are controlled in order to maximize the energy transfer from the collector to the load viz. the fluid flow rate from collector to buffer, fluid flow rate from buffer to load and the diameter of the pipes. This is a complex multi energy domain system comprising energy flow across several domains such as thermal, electrical and hydraulic. The entire system is modeled using the bond graph approach with seamless integration of the power flow in these domains. A method to estimate different parameters of the practical cooking system is also explained. Design and life cycle costing of the system is also discussed. The modeled system is simulated and the results are validated experimentally.     

Exergy analysis of micro-organic Rankine power cycles for a small scale solar driven reverse osmosis desalination system

Exergy analysis of micro-organic Rankine heat engines is performed to identify the most suitable engine for driving a small scale reverse osmosis desalination system. Three modified engines derived from simple Rankine engine using regeneration (incorporation of regenerator or feedliquid heaters) are analyzed through a novel approach, called exergy-topological method based on the combination of exergy flow graphs, exergy loss graphs, and thermoeconomic graphs. For the investigations, three working fluids are considered: R134a, R245fa and R600. The incorporated devices produce different results with different fluids. Exergy destruction throughout the systems operating with R134a was quantified and illustrated using exergy diagrams. The sites with greater exergy destruction include turbine, evaporator and feedliquid heaters. The most critical components include evaporator, turbine and mixing units. A regenerative heat exchanger has positive effects only when the engine operates with dry fluids; feedliquid heaters improve the degree of thermodynamic perfection of the system but lead to loss in exergetic efficiency. Although, different modifications produce better energy conversion and less exergy destroyed, the improvements are not significant enough and subsequent modifications of the simple Rankine engine cannot be considered as economically profitable for heat source temperature below 100 °C. As illustration, a regenerator increases the system’s energy efficiency by 7%, the degree of thermodynamic perfection by 3.5% while the exergetic efficiency is unchanged in comparison with the simple Rankine cycle, with R600 as working fluid. The impacts of heat source temperature and pinch point temperature difference on engine’s performance are also examined. Finally, results demonstrate that energy analysis combined with the mathematical graph theory is a powerful tool in performance assessments of Rankine based power systems and permits meaningful comparison of different regenerative effects based on their contribution to systems improvements.     

Feasibilty study of renewable energy powered seawater desalination technology using natural vacuum technique

With an ever-increasing population and rapid growth of industrialization, there is great demand for fresh water. Desalination has been a key proponent to meet the future challenges due to decreasing availability of fresh water. However, desalination uses significant amount of energy, today mostly from fossil fuels. It is, therefore, reasonable to rely on renewable energy sources such as solar energy, wind energy, ocean thermal energy, waste heat from the industry and other renewable sources. The present study deals with the energy-efficient seawater desalination system utilizing renewable energy sources and natural vacuum technique. A new desalination technology named Natural Vacuum Desalination is proposed. The novel desalination technique achieve remarkable energy efficiency through the evaporation of seawater under vacuum and will be described in sufficient detail to demonstrate that it requires much less electric energy compared to any conventional desalination plant of fresh water production of similar capacity. The discussion will highlight the main operative and maintenance features of the proposed natural vacuum seawater desalination technology which seems to have promising techno-economic potential providing also advantageous coupling with renewable energy sources.     

Performance review of a novel combined thermoelectric power generation and water desalination system

A novel combined thermoelectric power generation and water desalination system is described with a system schematic. The proposed system utilises low grade thermal energy to heat thermoelectric generators for power generation and water desalination. A theoretical analysis presents the governing equations to estimate the systems performance characteristics combined with experimental validation. Experimental set-up consists of an electric heat source, thermoelectric modules, heat pipes, a heat sink and an evaporator vessel. Four heat pipes are embedded in a heat spreader block to passively cool the bottom side of the thermoelectric cells. The condenser of these four heat pipes is immersed in a pool of saline water stored in an evaporation vessel which is maintained at sub-atmospheric pressure. The liquid to vapour phase change cooling method achieve low saturation temperature and offers a high heat transfer coefficient for the cooling of the thermoelectric generators. At the same time this method utilises the low temperature heat extracted from the cold side of the thermoelectric generator for water desalination. It was observed that at low saturation temperatures greater heat flux could be supplied to the thermoelectric generators with less heat losses to the atmosphere.     

Experimental investigation of an adsorption desalination plant using low-temperature waste heat

Adsorption cycle is a practical and inexpensive method of desalinating the saline and brackish water to produce potable water for both industrial and residential applications. As compared with the commercial desalination methods, the adsorption technology has the unique advantages such as (i) the utilization of the low-temperature waste heat, (ii) low corrosion and fouling rates on the tube materials due to the low-temperature evaporation of saline water, (iii) and it has almost no major moving parts which renders inherently low maintenance cost. In addition, the adsorption cycle offers two important benefits that are not available to the existing desalination technologies; namely, (i) a two-prong phenomenal barrier to any “bio-contamination” during the water generation process as compared with existing methods and (ii) the reduction in global warming due to the utilization of low-temperature waste heat which otherwise would have been purged to the atmosphere. This paper describes an experimental investigation and the specific water yields from a four-bed adsorption desalination plant is presented with respect to major assorted coolant and feed conditions.     

Feasibility study of brackish water desalination in the Egyptian deserts and rural regions using PV systems

Fresh water is the most important source for life on the earth. In the Egyptian deserts and rural areas, there is a shortage of fresh water in spite of the presence of large sources of brackish water. Solar energy is abundant in these remote areas of Egypt, where the amount of sunshine hours is around 3500 h/year. This paper introduces a feasibility study of water desalination in these areas using photovoltaic energy as the primary source of energy. The availability of water resources and solar energy in these areas has been investigated. Also, a design of a PV powered small scale reverse osmosis water desalination system is studied and economically estimated. It is found that the cost of producing 1 m³ of fresh water using the small PV powered RO water desalination systems is 3.73$. This cost is based on using a small system that is operating during the daylight only. If the system size and the daily period of operation are increased, the price of producing fresh water will be decreased in these regions. Also, it is important to mention that using renewable energy sources in feeding different systems in these rural areas with their energy demands will maintain their environment clean and healthy for people.     

Application of gas-turbine exhaust gases for brackish water desalination: a techno-economic evaluation

During the last 20 years, the electricity generation system of Crete Island has been actually based on the operation of several gas-turbines, presenting an annual utilization factor higher than 50%. Despite the undeniable advantages of modern gas-turbines, one cannot disregard the huge quantities of hot exhausted gases produced, containing almost two thirds of the chemical energy of fuel consumed. On the other hand, the island faces serious water resources insufficiency problems, especially during hot periods of the year. In this context, the island electricity generation utility (Public Power Corporation (PPC)) is planning to allocate the so far unexploited exhausted gases of a recently installed gas-turbine (LM-6000) at the Linoperamata–Heraklion power station to the neighboring municipality of Gaziou. The main idea elaborated in the present study is the techno-economic evaluation of a new desalination plant, utilizing a thermal desalination process and taking advantage of the heat content of the above-mentioned gas-turbine. According to the results obtained, it is almost certain that the proposed desalination plant is able to produce an amount of clean water adequate to cover the local habitants' needs at a moderate cost, not only saving almost 15,000 tones of imported oil per year but also alleviating the local environment from several flue gases.     

Theoretical approach for a pressure drop in two-phase particle-laden flows

The purpose of this research is to develop an analytical model for a pressure drop per unit pipe length due to the turbulence modulations of a carrier phase which results from the presence of a dispersed phase in various types of diluted two-phase flows. The wake behind a particle, a particle size, the loading ratio and the density difference between two phases of a particle-laden flow were considered as significant parameters, which have an influence on the turbulence of a particle-laden flow, and the relative velocity of the laden particles was calculated by using a terminal velocity. The frictional pressure drop was formulated by using the force balance in the control volume by considering the shear stresses due to the presence of particles and an analogy of the shear stresses in the solid surfaces. The numerical results show a good agreement with the available experimental data and the model successfully predicted the mechanism of the pressure drop in the particle-laden flows.     

An optimization model for a mechanical vapor compression desalination plant driven by a wind/PV hybrid system

A renewable hybrid system to produce domestic water is presented. It consists of a photovoltaic module, a wind turbine, a mechanical vapor compression desalination plant and a storage unit. An optimization model based on a mathematical programming is developed to control the energy flows exchanged among the system components in order to satisfy the domestic water demand. The model has been solved for three specific case studies in Morocco, where two of them are located in Rabat which aim to satisfy the hourly and monthly water demand of 20 households, whereas, the last one is in Essaouira, which aims to ensure the monthly water demand of 40 households. The main motivations behind selecting these specific case studies are the evaluation of the efficiency and feasibility of such system in two coastal sites having different characteristics of renewable energy sources. The obtained results show that the domestic water demands are satisfied in each time interval at a reasonable economic cost comparable to the current average cost of water in Morocco which is about 0.7 € m⁻³.     

Modeling and optimization of a solar driven membrane distillation desalination system

The desalination technology using membrane distillation driven by solar energy is a feasible solution for reducing the energy cost. A dynamic simulation model for a solar driven membrane distillation desalination system (SMDDS) is developed on the Aspen Custom Modeler^® (ACM) platform for the system performance and optimization study. The rigorous model for the spiral-wound air gap membrane distillation (SP-AGMD) module takes into account the heat and mass transfer resistances associated with each composing layer. The effects of adopting different objective functions, solar radiation conditions, thermal storage tank configurations, as well as the flowrates of the membrane distillation module and the thermal storage tank on the optimized performance are reported. Simple thermal storage tank and lower flowrate of the membrane distillation module are advantageous to higher water production rate. A control system using conventional PI (Proportional/Integral) controllers is proposed and the water production rate can reach about 87% of the optimal result for clear sky operation.     

Desalinated water and hydrogen generation from seawater via a desalination unit and a low temperature electrolysis using a novel solar-based setup

This study investigates the proficiency of employing solar energy in a novel setup geared towards simultaneous production of desalinated water and hydrogen wielding parabolic trough solar collectors (prime mover) in three solar radiation approaches; low radiation, high irradiation and no radiation. Targeted for coastal areas, this setup generates electricity using an organic Rankine cycle; utilizing its waste heat, a desalination unit applying humidification and dehumidification processes, yields desalinated water. Subsequently, hydrogen is produced through exploiting a proton exchange membrane electrolyser as a low temperature electrolyser fed by electricity and water. One of the cardinal points of this system is the production of hydrogen by means of electricity and desalinated water obtained from previous stages. With the purpose of determining the efficiency of this setup, a parametric study has been conducted grounded on the effect of important parameters on production rates and different efficiencies. Ensuing, multi-objective optimization is set forth by implementing a genetic algorithm in order to effectuate the optimal design state. The results indicated that the desalination rate in the three solar radiation approaches mentioned are 1.76 kg/s, 1.07 kg/s and 1.36 kg/s, respectively, and the hydrogen production rate are 4.33 g/s, 2.62 g/s and 3.54 g/s, correspondingly.