共查询到18条相似文献,搜索用时 78 毫秒
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以棕榈酸和单乙醇胺为原料,采用两步法合成棕榈酸单乙醇酰胺,考察了合成反应中第二步胺解工艺反应时间、投料比、催化剂用量等因素对反应纯度的影响,并通过正交实验优化工艺条件.得到最佳工艺条件为:反应时间4h,n(单乙醇胺):n(棕榈酸)=1.05∶1,催化剂KOH用量为0.3%.验证实验胺值(KOH)仅为3.98 mg/g.研究表明,随着表面活性剂棕榈酸单乙醇酰胺质量分数的增大,其泡沫性能显著增强,ω>0.15%时,显示出较强的起泡性与稳泡性;30℃时,ω=0.10%的溶液起泡高度可达180 mm,50℃时两种质量分数(ω =0.10%,ω=0.25%)溶液稳泡性仍保持良好;本产品与同类表面活性剂FAS、AES相比具有较好的泡沫性能. 相似文献
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大豆油脂肪酸单乙醇酰胺的合成 总被引:1,自引:0,他引:1
在碱性催化剂作用下以大豆油和单乙醇胺为原料合成大豆油脂肪酸单乙醇酰胺.考察了反应温度、反应时间、催化剂用量等因素对反应的影响,并通过正交实验优化了反应条件,得到的较佳反应条件为:反应温度130℃,反应时间3 h,催化剂甲醇钠用量0.2%(基于总反应物的质量).当大豆油与单乙醇胺的质量比分别为100:10、100:15、100:20,在优化条件下反应时,单乙醇胺转化率分别为96.56%、94.88%和91.51%. 相似文献
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羧甲基化法合成油酸单乙醇酰胺醚羧酸盐 总被引:5,自引:0,他引:5
以油酸为起始原料,经酰胺化和羧甲基化反应制得了油酸单乙醇酰胺醚羧酸盐(OAEC).正交实验考察了投料比、催化剂用量、反应温度、反应时间等对羧甲基化反应的影响.最佳工艺条件为:n(油酸单乙醇酰胺)∶n(氯乙酸钠)∶n(NaOH)=1∶1.55∶3.5,65℃反应4 h.在此条件下,油酸单乙醇酰胺的平均转化率达95.94%.IR分析表明合成产物为目的产物,HPLC分析表明产物纯度较高.产物OAEC的表面张力为29.06 mN/m,发泡力为64 mm,去污力为16.90,属低泡温和型表面活性剂. 相似文献
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在传统铬鞣工序中应用加脂剂不仅有助鞣作用,而且能赋予蓝坯革一定的加脂效果。我们在实验中合成了两种烷醇酰胺琥珀酸单酯磺酸二钠盐──N—2—羟乙基烷基酰胺琥珀酸单酯磺酸二钠[简称HEAASS]和N,N—二(2—羟乙基)烷基酰胺二(琥珀酸单酯磺酸二钠)[简称DHEAADSS],将其试用于浸酸铬鞣,发现二者均有良好的助鞣效果,但DHEAADSS的助鞣性能要优于HEAASS。 相似文献
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In ovo administration of copper nanoparticles and copper sulfate positively influences chicken performance 下载免费PDF全文
Natalia Mroczek‐Sosnowska Monika Łukasiewicz Agnieszka Wnuk Ewa Sawosz Jan Niemiec Abdullah Skot Sławomir Jaworski André Chwalibog 《Journal of the science of food and agriculture》2016,96(9):3058-3062
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目的建立一种快速、简便测定保健食品中硫酸软骨素的液相色谱方法,并进行方法学研究。方法样品经过前处理,以乙腈和0.005 mol/L戊烷磺酸钠溶液为流动相,等度洗脱,经Diamonsil C18柱分离,于192 nm波长检测。结果用本方法进行检测,能很好地分离硫酸软骨素,在浓度0.008 mg/m L~0.04 mg/m L之间呈现良好的线性关系,方法的相关系数可达1.000,平均回收率在98.5%~100.0%之间,相对标准偏差为0.6%。结论采用该方法能测定保健食品中硫酸软骨素,耗时短、操作简便、准确、重现性好,分离效果明显,可在实验室推广。 相似文献
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Guray Erener Nuh Ocak Ali Vaiz Garipoglu 《Journal of the science of food and agriculture》2007,87(4):689-693
A total of 360 one‐day‐old broilers (Ross 308) were allocated to three treatment groups with four replicates each of 30 chicks to evaluate the effects of the dietary hazelnut kernel oil (HKO) inclusion on the performance and the composition of fatty acid of meat in broilers. Treatments were diets with (1) soybean oil (SO), (2) HKO, or (3) HKO + SO (in equal amount, HKSO) added to the basal diets. There were no significant differences in weight gain, feed per gain, dressing percentage, abdominal fat weight, and mortality among the different dietary oil sources. Dietary HKO decreased (P < 0.01) linoleic and linolenic acids contents and the ratio of SFA:MUFA (saturated fatty acids:unsaturated fatty acids) of breast meats in broiler, and increased oleic acid content compared to SO. The result indicates that meat from broiler chickens fed diets containing HKO, singly or combined with SO could be an important source of oleic acid for human diets. Copyright © 2007 Society of Chemical Industry 相似文献
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在纯生啤酒中添加微量的PGA,可有效地提高纯生啤酒的泡沫稳定性。实验发现,在初过滤之后,终过滤之前,向纯生啤酒中添加35mgPGA/L啤酒,静置5min后,泡持值可从294s平均增加到402s,即泡持值提高了36.7%。经过60d贮藏后,测得其泡持值为390s。 相似文献
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《Journal of dairy science》2023,106(4):2395-2407
The form of a lipid supplement, its degree of saturation, and its fatty acid (FA) profile greatly influence digestibility and cow productive response. The objective in this study was to examine the effect of fat supplements that differ in their form or FA profile on nutrient digestibility and cow performance. Forty-two mid-lactation cows (128 ± 53 d) were assigned to 3 treatment groups according to milk yield, days in milk, and body weight. For 13 wk, the cows were fed rations that contained (on a dry matter basis) (1) 2.4% of calcium salts of fatty acids (CSFA) consisting of 45% palmitic acid (PA) and 35% oleic acid (OA; CS45:35); (2) 2.4% of CSFA consisting of 80% PA and 10% OA (CS80:10); or (3) 2.0% of free FA consisting of 80% PA and 10% OA (FF80:10). Rumen samples were taken to measure the ammonia and volatile FA concentrations, and fecal samples were taken to measure the digestibility. Preplanned comparisons were CS45:35 versus CS80:10 to assess 2 CSFA supplements with different FA profiles, and CS80:10 versus FF80:10 to assess similar FA profiles in different forms. Compared with CS45:35, CS80:10 decreased the milk yields, increased the fat percentage, and tended to increase the energy-corrected milk (ECM) yields. The fat percentage of milk was highest in the FF80:10 cows (4.02%), intermediate in the CS80:10 cows (3.89%), and lowest in the CS45:35 cows (3.75%). Compared with CS80:10, FF80:10 increased milk yields (50.1 vs. 49.4 kg/d, respectively), tended to increase fat percentage, and increased 4% fat-corrected milk (4% FCM; 49.1 vs. 47.7 kg/d, respectively) and ECM yields (49.5 vs. 48.2 kg/d, respectively). Treatment had no effect on dry matter intake (DMI), and compared with CS80:10 cows, the calculated energy balance was lower in the FF80:10 cows. The 4% FCM/DMI and ECM/DMI ratios were higher in the FF80:10 group compared with the CS80:10 group. Compared with the CS80:10 cows, the FF80:10 cows had a lower rumen pH, higher propionate, lower acetate/propionate ratio, and higher total VFA. Compared with CS45:35 cows, the apparent total-tract digestibilities of neutral detergent fiber and acid detergent fiber were higher in CS80:10 cows; whereas, the apparent total-tract digestibilities of dry matter, organic matter, protein, neutral detergent fiber, and acid detergent fiber were higher in the CS80:10 cows compared with the FF80:10 cows. Compared with the CS80:10 group, the apparent digestibility of total FA was 13.0 percentage points lower in the FF80:10 cows (79.1 vs. 66.1%, respectively), and similarly, the digestibilities of 16-carbon and 18-carbon FA were lower in the FF80:10 cows than in the CS80:10 cows. In conclusion, the form, more than the FA profile of fat supplements, influenced digestibility. Further, the CSFA supplements were more digestible than the free fatty acids, regardless of the FA profile. However, energy partitioning toward production appeared to be higher in the FF80:10 cows, although the digestibility of nutrients was lower than in the CSFA product with a similar FA profile. 相似文献