共查询到20条相似文献,搜索用时 31 毫秒
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XING Feng JIANG Chao HE Wenwang Department of Physics Peking University Beijing China Originally published in ACTA METALL SIN 《金属学报(英文版)》1989,2(8):122-126
The magnetic properties of Nd_2(Fe_(1-x)M_x)_(14)B(M=C and Si) compounds have been investi-gated.Substituting Fe by small amount of metalloid C and Si atoms,the compounds are intetragonal structure and have uniaxial anisotropy.The substitution of C for part of Fe de-creases the Curie temperature of the compounds and the intrinsic coercivity of bond samples atlow temperature.The replacement of Fe by Si makes the Curie temperature increase with amaximum at the vicinity of x=0.15.When the range of the content of Si is 0≤x≤0.10,thecoercivity distinctly increases at room temperature.from 62.7 kA/m at x=0 to138.7kA/m at x=0.06,where the residual magnetization has a maximum:in the mean timethe saturation magnetization decreases only by a small amount. 相似文献
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采用铜模吸铸工艺成功制备了一系列的(Fe_(1-x-y)Co_yNi_x)_(68.4)B_(23)Y_(4.6)Nb_4块体非晶合金,并采用X射线衍射仪(XRD)、差热分析仪(DTA)、振动样品磁强计(VSM)测试块体非晶合金的结构、热稳定性和磁性能.探讨了不同Co、Ni含量对(Fe_(1-x-y)Co_yNi_x)_(68.4)B_(23)Y_(4.6)Nb>.4>系合金玻璃形成能力(GFA)及磁性能的影响.结果表明:合金(Fe_(0.5)Co_(0.5))_(68.4)B_(23)Y_(4.6)Nb_4、(Fe_xNi_(1-x)_(68.4)B_(23.6)Nb_4(x=0.05、0.1、0.15、0.2)、(Fe_(1-x-y)Co_yNi_x)_(68.4)B_(23)Y_(4.6)Nb_4(x=0.15、0.3、0.45,y=0.1、0.2)均可制得直径为3 mm的非晶棒.该系列合金均具有良好的软磁性能,但随着Co、Ni含最的增加,其饱和磁化强度均下降. 相似文献
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Md Anisur Rahman Yun-Zhuo Lu Qiang Luo Shou-Jiang Qu Feng-Xia Ye Yi-Xuan Wu Jun Shen 《金属学报(英文版)》2016,29(9):834
Fe_(43)M_5Cr_(15)Mo_(14)C_(15)B_6Y_2 (M=Mn,Co,Ni,and Cu in at.%)bulk metallic glasses(BMGs)are synthesized using the suction casting technique,and the glass-forming ability(GFA),microstructure,and thermal and magnetic properties of these glasses are extensively examined using X-ray diffraction,differential scanning calorimeter,and vibrating sample magnetometer techniques.Among the four BMG alloys,Fe_(43)Ni_5Cr_(15)Mo_(14)C_(15)B_6Y_2 exhibits the lowest coercivity and the highest saturation magnetization,Curie temperature,effective magnetic moment,and GFA.By contrast,Fe_(43)Mn_5Cr_(15)Mo_(14)C_(15)B_6Y_2 presents the poorest magnetic properties,such as the highest coercivity and the lowest saturation magnetization,Curie temperature,and effective magnetic moment.Fe_(43)Cu_5Cr_(15)Mo_(14)C_(15)B_6Y_2 demonstrates the lowest thermal stability and GFA.The observed thermal,structural,and magnetic properties of these BMG alloys are discussed in terms of the kinetics of BMG synthesization and the formation of different ferromagnetic,ferrimagnetic,and antiferromagnetic phases. 相似文献
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研究了Cr部分取代Fe对Sm_2(Fe_(1-x)Cr_x)_17N_(~2.7)磁粉磁特性的影响.添加少量Cr(x=0-0.1),该化合物的结构不变化。随Cr含量的增加,它的Curie温度、各向异性场、饱和磁化强度、平均Fe原子磁矩和平均超精细场均有所降低.材料的单相性显著改善,矫顽力提高.Sm_2(Fe_(0.95)Cr_(0.05))_17N_(~2.7)磁粉的矫顽力_iH_c达到1592kA/m. 相似文献
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YANG Hongying SHEN Baogen YANG Linyuan GUO Huiqun Laboratory of Magnetics Institute of Physics Academia Sinica Beijing China 《金属学报(英文版)》1992,5(11):396-400
The Curie temperature increases but crystallization temperature decreases with the in-crease of Ga content,x,of amorphous(Fe_(1-x)Ga_x)_(77.5)Nd_4B_(18.5) alloys.The averagemagnetic moment of Fe atoms is almost a constant.By X-ray diffraction and ther-momagnetic measurements,the crystalline phases of the alloys,an unknown phase andα-(Fe,Ga)besides Fe_3 B as major one,were identified.The relationship between roomtemperature coercive field and Ga.content was also studied. 相似文献
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YANG Jilian ZHANG Baisheng JIN Lan DING Yongfan YE Chuntang Institute of Atomic Energy Beijing ChinaYANG Yingchang SUN Hong KONG Linshu Peking University Beijing China YANG Jilian Associate Professor P.O.Box Sub Beijing China 《金属学报(英文版)》1990,3(8):145-148
The site occupancies in permanent magnetic alloy Y_2(Fe_(0.95)Al_(0.05))_(14)B has been studied bymeans of neutron diffraction.The results from profile refinement show that Al enters thetetragonal structure of Nd_2Fe_(14)B and occupies the 4c and 8j_2 sites of the space groupP4_2/mnm preferably.The relation between the site occupancies and the magnetic proper-ties is discussed preliminarily. 相似文献
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STRUCTURAL AND MAGNETIC PROPERTIES OF Y (Mn_(1—x)Fe_x)_(12) 总被引:1,自引:0,他引:1
<正> 稀土金属R和3d过渡族金属M形成一系列金属间化合物,如RM_5,RM_2,R_2M_(17)等已作为新型磁性材料应用,而RM_(12)型化合物,可能由于除Mn以外,像Fe,Co,Ni等都不能建立RM_(12)相,并且RM_(12)是反铁磁的,以前研究较少。我们用Fe代Mn,研究三元金属间化合物R(Mn,Fe)_(12)单相存在的条件以及通过原子代换的方法,改变合金的电子组态和磁性离子间的相互作用,从而影响和改变物体的磁性。 相似文献
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MAGNETIC MOMENT,CURIE TEMPERATURE AND SPIN WAVE EXCITATION FOR AMORPHOUS Fe_(90-x)Si_xZr_(10) ALLOYS
SHEN Baogen ZHANG Zhiying GUO Huiqun ZHAO Jiangao Institute of Physics Academia Sinica Beijing ChinaGU Benxi Nanjing University Nanjing China 《金属学报(英文版)》1991,4(7):31-36
The magnetization curves at 1.5 K and thermomagnetic curves for amorphous Fe_(90-x)Si_xZr_(10)(x=0,4,7 and 10)alloys prepared by the drum spinning technique have been measured with an extracting sample magnetometer.It is obtained that the average magnetic moment,,per magnetic atom and Curie temperature,T_c,in the amorphous FeSiZr alloys increase with increasing Si content.The and T_c are found to be quite small,compared with amorphous FeSiB alloys.This unusual behavior is suggested to be due to the presence of the Fe—Fe antiferromagnetic interactions.The temperature dependence of magnetization at lower temperature is in accordance with Bloch's T~(3/2) law.Calculation shows that the spin wave stiffness constant,D,increases with increasing Si content from 0.37 meV·nm~2 for x=0 to 0.538 meV·nm~2 for x=10.The values ofindicate that the range of the exchange interaction is roughly the mean atomic distance of nearest neighbours. 相似文献
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MAGNETOSTRICTIVEBEHAVIOUROFR(Fe_(1-x)Al_x)_yALLOYS(R=Dy_(0.65)Tb_(0.25)Pr_(0.1))¥WANGBowen;WUChangheng;ZHUANGYuzhi;JINXimei;LIJi... 相似文献
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WANG Bowen YAN Rongge HAO Yanming CAO Shuying and WENG LingSchool of Electrical Engineering Hebei University of Technology Tianjin ChinaInternational Center for Materials Physics the Academy of Sciences Shenyang China 《稀有金属(英文版)》2003,22(1)
The structure, magnetization, and magnetocrystalline anisotropy were investigated using X-ray diffraction, vibrating sample magnetometer, and AC susceptibility-meter. It is found that the microstructure of (Sm0.5Nd0.5)2(Fe1-xCox)17 alloys is an (Sm,Nd)2(Fe,Co)17 phase with the rhombohedral Th2Zn17-type structure. The Curie temperature Tc increases with the Co concentration increasing, and the magnetization first increases as the Co content increases in (Sm0.5Nd0.5)2(Fe1-xCox)17 alloys and then decreases slowly. The easy magnetization direction (EMD) of (Sm0.5Nd0.5)2(Fe0.25Co0.75)17 is along the c-axis and a strong enhancement of the crystalline anisotropy energy constant K is produced by the addition of some Co atoms. The anisotropy energy constant reaches the maximum when x = 0.75 and then decreases slowly with the Co content further increasing. The (Sm0.5Nd0.5)2(Fe0.25Co0.75)17compound is an optical candidate for the new permanent magnet, which possesses a high magnetization, a high Curie temperature, 相似文献
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采用水冷铜模吸铸工艺制备了一系列的(Fe0.5Co1-xNix)72B19.2Si4.8Nb4(x=0,0.05,0.1,0.15,0.2,0.25,0.3,0.4)块体非晶合金.并采用X射线衍射仪(XRD)、差热分析仪(DTA)、振动样品磁强计(VSM)测试了块体非晶合金的结构、热稳定性和软磁性能.探讨了不同Ni/Co比例及添加稀土元素Dy对FeCoNiBSiNb系合金玻璃形成能力(GFA)、热稳定性及磁性能的影响.结果表明:当x=0.05,0.1,0.15,0.2时可制备出直径2mm的非品合金棒,但不能获得3mm非晶合金棒,x=0.25,0.3,0.4均不能获得直径2mm的非晶合金棒,且随Ni/Co比例的增大,即随Ni含量的增加,热稳定性先增加,后逐渐减小,过冷液相区△Tx逐渐减小,非晶合金的玻璃形成能力呈下降趋势,非晶合金的饱和磁化强度(Ms)下降.添加1 at%Dy后,提高了合金的非晶形成能力,可制备出直径3mm的[(Fe0.5Co0.4Ni0.1)72B19.2Si4.8Nb4]99Dy1非晶合金棒,但合金的Ms下降. 相似文献
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HU Fengxia State Key Laboratory of Magnetism Institute of Physics Academia Sinica Beijing ChinaCHEN Jinchang Beijing Teacher''''s College Beijing ChinaSHEN Baogen GUO Huiqun State Key Laboratory of Magnetism Institute of Physics Academia Sinica Beijing China 《金属学报(英文版)》1992,5(10):300-305
Curie temperature of amorphous alloys Co_(90-x)Cr_x Zr_(10) decreases linearly with increas-ing x.Average magnetic moment per magnetic atom Co or Cr is 1.51 μB or -3.62 μBrespectively.The temperature dependence of spontaneous magnetization at low temper-atures is in agreement with Bloch's T~(3/2) law.The spin wave stiffness constant decreaseswith increasing x from 4 to 20.The range of interaction is 2—3 atoms for x=4 andnearest neighbour atom for x=20.The crystallization temperature increases mono-tonically with increasing x.It may relate to the average number of outer electrons peratom.The crystalline phase components of heat-treated alloys were analyzed by X-raydiffration and thermomagnetic measurement. 相似文献
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含Fe和Mn的Ni_(30)Cu_(70)固溶体团簇模型与耐蚀性研究 总被引:2,自引:0,他引:2
提出了一个极限田溶体合金的团簇模型,在此基础上优化设计了添加Fe和Mn的Ni_(30)Cu_(70)(原子分数,%)固溶体合金成分.在该模型中,固溶的Fe和Mn以Ni为第一近邻形成12配位立方八面体原子团簇(Fe_(1-x)Mn_x)Ni_(12)而分散到Cu基体中,因此极限固溶体合金成分为[M_1/_(13)Ni_(12)/_(13)]30Cu_(70)=[(Fe_(1-x)Mn_xNi_(12)]Cua_(30.3),M=(Fe_(1-x)Mn_x).采用X射线衍射和电化学腐蚀测试等方法,研究了[(Fe_(1-x)Mn_x)Ni_(12)]Cu_(30.3)合金的微观组织与耐腐蚀性能的关系.实验结果表明,对应于极限同溶体状念的[(Fe_(0.75)Mn_(0.25))Ni_(12)]Cua_(30.3)合金,在3.5%NaCl溶液中具有相对好的耐腐蚀性能. 相似文献
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DUO Liang XU Zuxiong MA Ruzhang Beijing University of Science Technology Beijing.China Institute of High Energy Physics Academia Sinica P.O.Box Beijing China 《金属学报(英文版)》1989,2(7):55-60
The amorphous Fe_(90-x)V_xZr_(10) alloy after electolytic hydrogenation procedure was studied bymeans of Mossbauer effect,magnetic measurement.X-ray diffaction and secondary ionmass spectroscopy(SIMS)techniques.The experimental results show that the magneticproperties of amorphous Fe_(90-x)V_xZr_(10) alloy are highly sensitive to the presence of hydrogen.The isomer shift(IS)has a small positive change and the magnetic properties transfer fromparamagnetic to ferromagnetic State by hydrogenation,and the effect of hydrogen absorptionis to raise Fe magnetic moment(from the increase of saturation maguetization)and Curietemperature T_c from 257 to 384 K.Finally.the considerable increase of magnetic properttesof amorphous Fe_(90-x)V_xZr_(10) alloy by hydrogenation is attributable to the change ofhybridization effect between outer electrons of Zr atoms and 3d electrons of Fe atoms.Fromthe results of SIMS experiment,it is concluded that the hydrogen atoms is localized aroundZr atoms wheh hydrogen atoms enter into the allor. 相似文献
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利用Mossbauer谱、磁测量技术,X射线衍射以及二次离子质谱分析(SIMS)技术,对三元非晶合金Fe_(90-x)V_xZr_(10)吸氢现象及磁性变化进行了研究.实验结果表明:随充氢时间(相同的充氢电流密度)的增加,非晶态合金同质异能移位增加,表明充氢后Fe核处电子密度发生变化.随充氢量增加,室温下合金由顺磁状态转变为铁磁状态,超精细分布逐渐展宽,其最大值也向高场方向移动.吸氢后合金原子磁矩及Curie温度T_C有大幅度增加.0K时饱和磁化强度从未充氢合金的120emu/g增加到174emu/g.Curie温度T_C从257K增加到384K.吸氢导致磁性变化的机理,利用杂化理论模型能够给出很好的解释. 相似文献
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Y.M.Hao) Y.Gao) )Department of Physics Tianjin Normal University Tianjin China )Library Tianjin Normal University Tianjin China 《金属学报(英文版)》1999,12(4):474-476
Inpreviouswork〔1〕,wereportedthattherhombohedralorhexagonal2:17phasestructurecanbestabilizedbyreplacingFewithAl.ThesinglephasecompoundsofR2AlFe16xMnx(R=rareearthelement)fromwithMnconcentrationuptox=8forTh2Ni17phaseandx=16forTh2Zn17phase.Inthiswor… 相似文献