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1.
In this work, hydroxyapatite (HA) powders were synthesized using calcium hydroxide Ca(OH)2 and orthophosphoric acid H3PO4 via wet chemical precipitation method in aqueous medium. Calcium‐to‐phosphorus (Ca/P) ratio was set to 1.57, 1.67, 1.87 that yield calcium‐deficient HA, stoichiometric HA, and calcium‐rich HA, respectively. These synthesized HA powders (having different Ca/P ratio) were characterized in terms of particle size and microstructural examination. Then, the densification and mechanical properties of the calcium‐deficient HA, stoichiometric HA, and calcium‐rich HA were evaluated from 1000 to 1350°C. Experimental results have shown that no decomposition of hydroxyapatite phase was observed for stoichiometric HA (Ca/P = 1.67) and calcium‐deficient HA (Ca/P = 1.57) despite sintered at high temperature of 1300°C. However, calcium oxide (CaO) was detected for calcium‐rich HA (Ca/P = 1.87) when samples sintered at the same temperature. The study revealed that the highest mechanical properties were found in stoichiometric HA samples sintered at 1100–1150°C, having relative density of ~99.8%, Young's modulus of ~120 GPa, Vickers hardness of ~7.23 GPa, and fracture toughness of ~1.22 MPam1/2.  相似文献   

2.
Using a conventional solid‐state reaction Ca5A4(VO4)6 (A2+ = Mg, Zn) ceramics were prepared and their microwave dielectric properties were investigated for the first time. X‐ray diffraction revealed the formation of pure‐phase ceramics with a cubic garnet structure for both samples. Two promising ceramics Ca5Zn4(VO4)6 and Ca5Mg4(VO4)6 sintered at 725°C and 800°C were found to possess good microwave dielectric properties: εr = 11.7 and 9.2, Q × f = 49 400 GHz (at 9.7 GHz) and 53 300 GHz (at 10.6 GHz), and τf = ?83 and ?50 ppm/°C, respectively.  相似文献   

3.
Ceramics in the system 0.45Ba0.8Ca0.2TiO3–(0.55?x)Bi(Mg0.5Ti0.5)O3xNaNbO3, x = 0–0.02 were fabricated by a conventional solid‐state reaction route. X‐ray powder diffraction indicated cubic or pseudocubic symmetry for all samples. The parent 0.45Ba0.8Ca0.2TiO3–0.55Bi(Mg0.5Ti0.5)O3 composition is a relaxor dielectric with a near‐stable temperature coefficient of relative permittivity, εr = 950 ± 10% across the temperature range 80°C–600°C. Incorporation of NaNbO3 at x = 0.2 extends the lower working temperature to ≤25°C, with εr = 575% ± 15% from temperatures ≤25°C to >400°C, and tan δ < 0.025 from 25°C to 400°C. Values of dc resistivity ranged from ~109 Ω·m at 250°C to ~106 Ω·m at 500°C. The properties suggest that this material may be of interest for high‐temperature capacitor applications.  相似文献   

4.
0.9(Mg0.95Zn0.05)2(Ti0.8Sn0.2)O4–0.1(Ca0.8Sr0.2)TiO3 (MZTS–CST) ceramics were prepared by a conventional solid‐state route. The MZTS–CST ceramics sintered at 1325°C exhibited εr = 18.2, Q × f = 49 120 GHz (at 8.1 GHz), and τf = 15 ppm/°C. The effects of LiF–Fe2O3–V2O5 (LFV) addition on the sinterability, phase composition, microstructure, and microwave dielectric properties of MZTS–CST were investigated. Eutectic liquid phases 0.12CaF2/0.28MgF2/0.6LiF and MgV2O6 were developed, which lowered the sintering temperature of MZTS–CST ceramics from 1325°C to 950°C. X‐ray powder diffraction (XRPD) and energy dispersive spectroscopy (EDS) analysis revealed that MZTS and CST coexisted in the sintered ceramics. Secondary phase Ca5Mg4(VO4)6 as well as residual liquid phase affected the microwave dielectric properties of MZTS–CST composite ceramics. Typically, the MZTS–CST–5.3LFV composite ceramics sintered at 950°C showed excellent microwave dielectric properties: εr = 16.3, Q × f = 30 790 GHz (at 8.3 GHz), and τf = ?10 ppm/°C.  相似文献   

5.
The present work reports an investigation of the interactions of Al 7075 alloy and anorthite at 850°C (150 h) and 1150°C (24 h). Transmission electron microscopy, electron probe microanalysis, X‐ray diffraction, and scanning electron microscopy coupled with energy‐dispersive spectroscopy were used to identify the mineralogical and microstructural changes at the metal–ceramic interface. At 850°C, the phase formation mechanisms were (a) Si4+–Al3+ interdiffusion between the Al alloy and anorthite to form calcium dialuminate (CA2) and Ca2+–Mg2+ interdiffusion between the Al alloy and calcium dialuminate to form spinel. At 1150°C, spinel + Al2O3 and calcium hexaluminate (CA6) + CA2 were the major and minor phase mixtures, respectively in the corroded area. A thin layer of calcium monoaluminate (CA), gehlenite, and Si was present in the immediate vicinity of anorthite. The early stages of corrosion at 1150°C and 850°C were identical. However, due to thickening of the corroded region (viz., spinel formation) and enhanced evaporation of Mg at the higher temperature, the interdiffusion path evolves from Si4+–Al3+ + Ca2+–Mg2+ to Si4+–Al3+ + Ca2+–Al3+, thus establishing the following phase evolution path at the interface:   相似文献   

6.
Two intermediate compounds of the system Ca2SiO4Ca3(PO4)2CaNaPO4 were synthesized by reaction sintering at 1600°C and analyzed structurally, chemically, and optically. The structure of Ca7(PO4)2(SiO4)2 nagelschmidtite (space group P61, a = 10.7754(1) Å, c = 21.4166(3) Å) was determined by single crystal X‐ray analysis. Its unit cell can be interpreted as a supercell (≈ × a, 3 × c) of the high‐temperature polymorph α‐Ca2SiO4. Evidence for pseudo‐hexagonal symmetry is shown. Using electron microprobe, the solid solution Ca7?xNax(PO4)2+x(SiO4)2?x, (x ≤ 2), of nagelschmidtite was confirmed. Volume thermal expansion coefficients of Ca6.8Na0.2(PO4)2.2(SiO4)1.8 and Ca5.4Na1.5(PO4)3.7(SiO4)0.3 were determined using high‐temperature X‐ray powder diffraction, yielding mean αV = 3.95 and 5.21 [×10?5/°C], respectively. Ca15(PO4)2(SiO4)6 is a distinct phase in the binary section Ca2SiO4Ca3(PO4)2 and was found to extend into the ternary space according to Ca15?xNax(PO4)2+x(SiO4)6?x, (x ≤ 0.1). Quenching experiments of the latter allowed for structural analysis of a strongly disordered, defective high‐temperature polymorph of the α‐Ca2SiO4α‐Ca3(PO4)2 solid solution. Structural relations between nagelschmidtite, Ca15(PO4)2(SiO4)6 and the end‐member compounds of the system are discussed.  相似文献   

7.
Ceramics in the solid solution system, (1 ? x)Ba0.8Ca0.2TiO3xBi(Mg0.5Ti0.5)O3, were prepared by a conventional mixed oxide route. Single‐phase perovskite‐type X‐ray diffraction patterns were observed for compositions x < 0.6. A change from tetragonal to single‐phase cubic X‐ray patterns occurred at x ≥ 0.1. Dielectric measurements indicated relaxor behavior for x ≥ 0.1. Increasing the Bi(Mg0.5Ti0.5)O3 content improved the temperature sensitivity of relative permittivity ?r at high temperatures. At x = 0.5, a near‐plateau relative permittivity, 835 ± 40, extended across the temperature range, 65°C–550°C; the permittivity increased at x = 0.6 to 2170 ± 100 for temperatures 160°C–400°C (1 kHz). The corresponding loss tangent, tanδ, was ≤0.025 for temperatures between 100°C and 430°C for composition x = 0.5; at x = 0.6, losses increased sharply at >300°C. Comparisons of dielectric properties with other materials proposed for high‐temperature capacitor applications suggest that (1 ? x)Ba0.8Ca0.2TiO3xBi(Mg0.5Ti0.5)O3 ceramics are a promising base material for further development.  相似文献   

8.
This research examines the chemical activation of blast‐furnace slag pastes with alkaline solutions by means of various characterization techniques. Pastes were activated using sodium silicate solutions with modulus (Ms) of 0, 1, 1.5, 2, and Na2O at 5%, 10%, and 15%. Compressive strengths of up to 108 MPa were achieved for Ms = 1–1.5 after 720 d of curing at 20°C. The addition of Na2O > 10% resulted in the formation of hydrotalcite and carbonated pastes with low compressive strength. X‐ray diffraction, microanalysis of outer products (OP), and nuclear magnetic resonance (NMR) results showed that the main reaction products in the activated cements with Ms = 1 and 5%Na2O had an average ratio Ca/Si = 0.71–0.9 and consisted of a mixture of two kinds of C–S–H; one similar to a 9 Å tobermorite‐type calcium silicate hydrate (Ca5Si6O16(OH)2 and other amorphous related to a cross‐linked structure of C–N–(A)–S–H gel. Both were intermixed with hydrotalcite and cross‐linked structures of silica gel.  相似文献   

9.
The Pechini based liquid-mix technique has been applied to prepare either single phases of hydroxyapatite –Ca10(PO4)6OH2– (OHAp), α and β-tricalcium phosphate –Ca3(PO4)2–, (α-TCP, β-TCP) or biphasic calcium phosphates (BCP). Compositions with a Ca/P molar ratio between 1.5 and 1.667 were synthesized and subjected to a thermal treatment up to 1400 °C. α and β-TCP were both prepared from a Ca/P ratio of 1.5, but while β-TCP is isolated at 900 °C and remains stable up to 1100 °C, it is necessary to anneal at 1400 °C for 72 h to obtain pure α-TCP. OHAp is obtained as a single phase from a 1.667 Ca/P ratio after annealing at 1000 °C for 24 h and starts to decompose at 1400 °C. Between these two extremes a whole range of biphasic calcium phosphates can be prepared by using this technique with an accurate control of the starting reactants. These materials have been characterized by FTIR, XRF, BET, XRD and, based on this technique, a phase quantification determination (QXRD). The solubility of these products was tested in a buffered solution at 37 °C and pH=7.4.  相似文献   

10.
Polycrystalline calcium phosphate ((Cl/OH)Ap = Ca5(PO4)3(OH/Cl); TCP = Ca3(PO4)2) fibres were prepared from aqueous solutions of calcium chloride and phosphoric acid using poly(ethylene oxide) (PEO) as spinning aid. Generation of nonwoven materials was accomplished via rotary jet spinning. Polycrystalline (Cl/OH)Ap fibres 10–25 μm in diameter were obtained with 37% ceramic yield by pyrolysis of the green fibres followed by sintering at 1150 °C in air. X-ray diffraction (XRD) analysis provided evidence for apatite formation starting at 650 °C while (Cl/OH)Ap ceramic fibres were obtained at 1100 °C via transformation through intermediate dicalcium dichloride hydrogen phosphate (Ca2Cl2(HPO4)) and calcium pyrophosphate (Ca2P2O7) phases. A glass-forming Al-based additive was applied to enhance the mechanical properties of the Cl/OH)Ap ceramic fibres and indeed resulted in the formation of (Cl/OH)Ap/Al2O3 fibres with improved mechanical stability. Finally, TCP, (Cl/OH)Ap and (Cl/OH)Ap/Al2O3 fibres were subjected to seeding with mesenchymal stem cells. Negligible cytotoxicity is observed.  相似文献   

11.
Temperature‐stable relaxor dielectrics have been developed in the solid solution system: 0.45Ba0.8Ca0.2TiO3–(0.55 ? x)Bi(Mg0.5Ti0.5)O3xNaNbO3. Ceramics of composition x = 0 have a relative permittivity ?r = 950 ± 15% over a wide temperature range from +70°C to 600°C. Modification with NaNbO3 at x = 0.2 decreases the lower limiting temperature to ?70°C, but also decreases relative permittivity such that ?r ~ 600 ± 15% over the temperature range ?70°C to 500°C. For composition x = 0.3, the low‐temperature dispersion in loss tangent, tan δ, (at 1 kHz) shifts to lower temperature, giving tan δ values ≤0.02 across the temperature range ?60°C to 300°C in combination with ?r ~ 550 ± 15%. Values of dc resistivity for all samples are of the order of 1010 Ω m at 250°C and 107 Ω m at 400°C.  相似文献   

12.
《Ceramics International》2022,48(8):11056-11063
Ce2[Zr1?x(Ca1/3Sb2/3)x]3(MoO4)9 (CZ1?x(CS)xM) (x = 0.02–0.10) ceramics were prepared by the conventional solid-state reaction method. The correlations between the chemical bond parameters and microwave dielectric properties were calculated and analyzed by using the Phillips–Van Vechten–Levine (P–V–L) theory. Phase composition and microstructures were evaluated by scanning electron microscopy and X-ray diffraction patterns. Lattice parameters were obtained by Rietveld refinements based on XRD data. Excellent properties for Ce2[Zr0.96(Ca1/3Sb2/3)0.04]3(MoO4)9 ceramic sintered at 775 °C: εr = 10.68, Q×f = 85,336 GHz and τf = ?7.58 ppm/°C were achieved.  相似文献   

13.
Using the conventional high temperature solid‐state reaction method Ba2Ca(PO4)2:Eu2+ phosphors were prepared. The phase structure, photoluminescence (PL) properties, and the PL thermal stability of the samples were investigated, respectively. Under the excitation at 365 nm, the phosphor exhibited an asymmetric broad‐band blue emission with peak at 454 nm, which is ascribed to the 4f–5d transition of Eu2+. It was further proved that the dipole–dipole interactions results in the concentration quenching of Eu2+ in Ba2Ca1?x (PO4)2:xEu2+ phosphors. When the temperature turned up to 150°C, the emission intensity of Ba2Ca0.99(PO4)2:0.01Eu2+ phosphor was 59.07% of the initial value at room temperature. The activation energy ΔE was calculated to be 0.30 eV, which proved the good thermal stability of the sample. All the properties indicated that the blue‐emitting Ba2Ca(PO4)2:Eu2+ phosphor has potential application in white LEDs.  相似文献   

14.
The evolution of the metastable phases in metakaolin/Ca(OH)2 systems cured at high temperatures, remains mostly unknown, newer techniques may now help to establish both the kinetic mechanism of the pozzolanic reaction and the thermodynamic stability of the main hydrated hexagonal phases: Stratlingite (C2ASH8) and tetra calcium aluminate hydrate (C4AH13). For this reason this work examines the kinetics of the pozzolanic reaction in the MK/Ca(OH)2 system over 123 d at 60°C using nuclear magnetic resonance spectroscopy (27Al and 29Si NMR). The results obtained by 27Al and 29Si NMR show that during the first 30 h, the metastable phases C2ASH8 and C4AH13, coexist with the cubic phase (C3ASH6) obtained directly from the pozzolanic reaction. The gel C–S–H is clearly identified after 21 h of reaction, whereas at shorter times the C–S–H bands overlap those with the unreacted metakaolin ones. After 123 d of pozzolanic reaction, the first signs of the cubic phase are detected, a consequence of the conversion reaction of the metastable phases, and a phenomenon not previously identified.  相似文献   

15.
We developed a new Li2O–Al2O3–SiO2 (LAS) ultra‐low expansion glass‐ceramic by nonisothermal sintering with concurrent crystallization. The optimum sintering conditions were 30°C/min with a maximum temperature of 1000°C. The best sintered material reached 98% of the theoretical density of the parent glass and has an extremely low linear thermal expansion coefficient (0.02 × 10?6/°C) in the temperature range of 40°C–500°C, which is even lower than that of the commercial glass‐ceramic Ceran® that is produced by the traditional ceramization method. The sintered glass‐ceramic presents a four‐point bending strength of 92 ± 15 MPa, which is similar to that of Ceran® (98 ± 6 MPa), in spite of the 2% porosity. It is white opaque and does not have significant infrared transmission. The maximum use temperature is 600°C. It could thus be used on modern inductively heated cooktops.  相似文献   

16.
The effect of Ca2+ substitution on the structure, microstructure, and microwave dielectric properties of Sr–gehlenite (Sr2Al2SiO7) ceramic has been investigated. The structure and microstructure of Sr2?xCaxAl2SiO7 ceramics were analyzed via X‐ray diffraction (XRD) as well as scanning and transmission electron microscopic techniques. While the end‐members (x = 0 and 2) form isostructural compounds, a highly defective, nonstoichiometric, Ca‐rich secondary phase was observed via bright‐field transmission electron microscopy and energy dispersive X‐ray spectroscopy in compositions corresponding to x = 0.75 and 1.5. The concentration of secondary phase in x = 0.75 is too low to be detected via XRD or scanning electron microscopy. Identical selected‐area electron‐diffraction patterns of the compounds (x = 0, 1, and 2) confirmed that they belong to the space group P21m (no. 113) with tetragonal crystal symmetry. The porosity‐corrected relative permittivity at microwave frequencies showed a gradual increase with Ca2+ content; however, Ca2+ substitution made only marginal changes to the microwave dielectric properties except in the case of x = 1.5, in which the secondary phase reduced the quality factor considerably. Thermal conductivity decreased with increasing Ca2+ content, and the compounds with defective structures showed the lowest thermal conductivity. All the compounds exhibited low coefficients of linear thermal expansion, with values varying in the range 2.3–3.6 ppm/°C.  相似文献   

17.
The hydraulic properties of the Ca7ZrAl6O18 (C7A3Z) phase as well as the hydration products and thermal decomposition mechanism of this hydrated phase were studied. Microcalorimetric analysis has shown that the C7A3Z phase reacts with water very quickly, especially in the first 2 h after the start of the experiment. Hydration of calcium zirconium aluminate proceeds with the formation of high refractory calcium zirconate (with melting point 2345 °C), apart from the hydrated, nearly amorphous material. According to the DTA–TG–EGA, FT-IR and SEM/EDS examinations it has been found that not only the hydrates CAH10, C2AH8 and C4AH19 are present, but also C3AH6 (C = CaO, A = Al2O3, H = H2O), the only hydrated calcium aluminate which is a thermodynamically stable phase above 40 °C. Unhydrated Ca7ZrAl6O18 and CaZrO3 phases have been found by XRD, but crystalline hydrates have not been detected.  相似文献   

18.
Ca3SnSi2-xGexO9 (0 ≤ x ≤ 0.8) and (1–y) Ca3SnSi1.6Ge0.4O9 – y CaSnSiO5 – 2 wt% LiF (y = 0.4 and 0.5) microwave dielectric ceramics were prepared by traditional solid-state reaction through sintering at 1250°C–1425°C for 5 h and at 875°C for 2 h, respectively. Ge4+ replaced Si4+, and Ca3SnSi2-xGexO9 (0 ≤ x ≤ 0.4) solid solutions were obtained. At 0.1 ≤ x ≤ 0.4, the Ge4+ substitution for Si4+ decreased the sintering temperature of Ca3SnSi2-xGexO9 from 1425 to 1300°C, the SnO6 octahedral distortions, and the average CaO7 decahedral distortions, which affected the τf value. The large average decahedral distortions corresponded with nearer-zero τf values at Ca3SnSi2-xGexO9 (0.1 ≤ x ≤ 0.4) ceramics. The τf value and sintering temperature of Ca3SnSi2-xGexO9 (x = 0.4) ceramic were adjusted to near-zero by CaSnSiO5 and decreased to 875°C upon the addition of 2 wt% LiF. The (1 – y) Ca3SnSi1.6Ge0.4O9 – y CaSnSiO5 – 2 wt% LiF (y = 0.5) ceramic sintered at 875°C for 2 h exhibited good microwave dielectric properties: εr = 10.3, Q × = 14 300 GHz (at 12.2 GHz), and τf = ‒5.8 ppm/°C.  相似文献   

19.
New cementitious materials based on calcium hydrosilicate hydrates were recently developed as potential substitutes for ordinary portland cement, but with a reduced CO2 footprint. The materials are produced by hydrothermal processing of SiO2 and Ca(OH)2, giving rise to calcium silicate hydrates, followed by mechanical activation of the latter via cogrinding with various siliceous materials. Thus, the chemical composition in terms of C/S ratio could be adjusted over a broad range (1–3). In this study the synthesis of a previously unknown cementitious material produced via the combination of mechanical activation in a laboratory mill and thermal treatment of a mixture of quartz and hydrothermally synthesized calcium silicate hydrates: α‐Ca2[HSiO4](OH) (α‐C2SH) and Ca6[Si2O7](OH)6 (jaffeite) are reported. It forms independently of the type of mill used (eccentric vibrating mill, vibration grinding mill) after thermal treatment of the ground materials at 360°C–420°C. The new material is X‐ray amorphous and possesses a CaO/SiO2 ratio of 2. A characteristic feature in regards to the silicate anionic structure is the increased silicate polymerization (up to 27% Si2O7 dimers) as revealed by the trimethylsilylation method. Infrared (IR) spectra show a very broad absorption band centered at about 935 cm?1. Another characteristic feature is the presence of ~2.5 wt% H2O as shown by thermogravimetry (TG) coupled with IR spectroscopy. As this water is bound mostly as hydroxyl to Ca, we refer to this new cementitious material as calcium‐oxide–hydroxide–silicate (C–CH–S). Calorimetric measurements point to a very high hydraulic reactivity which is beyond that for typical C2S materials. The influence of the type of grinding on the thermal behavior of α‐C2SH upon its transformation into water‐free Ca2SiO4 modifications is discussed.  相似文献   

20.
《Ceramics International》2022,48(22):32827-32836
To investigate the crystal structure, electrical properties, and magnetic properties of Ca–Sn co-doped Y3-xCaxFe5-xSnxO12 (x = 0.00–0.25 in steps of 0.05), solid-state reaction experiments, first principles calculations, and complex crystal bonding theoretical calculations were performed. The relative permittivity (εr) is strongly correlated with the average bond ionicity when Ca2+ is added. Furthermore, appropriate Sn4+ substitution significantly lowers the dielectric loss (tanδε) associated with the lattice energy. The right amount of Ca–Sn co-doping can change the saturation magnetization (4πMS) and improve the microscopic morphology of YIG, lowering the ferromagnetic resonance linewidth (ΔH) of YIG. The optimized microwave dielectric and magnetic properties are as follows: εr = 14.7, tanδε = 4.15 × 10?4, 4πMS = 1680 G, and ΔH = 53 Oe for Y2.8Ca0.2Fe4.8Sn0.2O12 sintered for 6 h at 1425 °C. Based on this material, a simple 3D model of a strip-line circulator with an insertion loss of less than 0.3 dB at each port and isolation greater than 20 dB in the 10–12 GHz range was developed, indicating the potential of the material for microwave high-frequency components such as circulators.  相似文献   

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