Highly reliable non-conductive adhesives for flip chip CSP applications

Non-conductive adhesives (NCA), widely used in display packaging and fine pitch flip chip packaging technology, have been recommended as one of the most suitable interconnection materials for flip-chip chip size packages (CSPs) due to the advantages such as easier processing, good electrical performance, lower cost, and low temperature processing. Flip chip assembly using modified NCA materials with material property optimization such as CTEs and modulus by loading optimized content of nonconductive fillers for the good electrical, mechanical and reliability characteristics, can enable wide application of NCA materials for fine pitch first level interconnection in the flip chip CSP applications. In this paper, we have developed film type NCA materials for flip chip assembly on organic substrates. NCAs are generally mixture of epoxy polymer resin without any fillers, and have high CTE values un-like conventional underfill materials used to enhance thermal cycling reliability of solder flip chip assembly on organic boards. In order to reduce thermal and mechanical stress and strain induced by CTE mismatch between a chip and organic substrate, the CTE of NCAs was optimized by filler content. The flip chip CSP assembly using modified NCA showed high reliability in various environmental tests, such as thermal cycling test (-55/spl deg/C/+160/spl deg/C, 1000 cycle), high temperature humidity test (85/spl deg/C/85%RH, 1000 h) and high temperature storage test (125/spl deg/C, dry condition). The material properties of NCA such as the curing profile, the thermal expansion, the storage modulus and adhesion were also investigated as a function of filler content.     

Effects of silica filler and diluent on material properties and reliability of nonconductive pastes (NCPs) for flip-chip applications

In this paper, thermomechanical and rheological properties of nonconductive pastes (NCPs) depending on silica filler contents and diluent contents were investigated. And then, thermal cycling (T/C) reliability of flip chip assembly using selected NCPs was verified. As the silica filler content increased, thermomechanical properties of NCPs were changed. The higher the silica filler content was added, glass transition temperature (T/sub g/) and storage modulus at room temperature became higher while coefficient of thermal expansion (CTE) decreased. On the other hand, rheological properties of NCPs were significantly affected by diluent content. As the diluent content increased, viscosity of NCP decreased and thixotropic index increased. However, the addition of diluent deteriorated thermomechanical properties such as modulus, CTE, and T/sub g/. Based on these results, three candidates of NCPs with various silica filler and diluent contents were selected and used as adhesives for reliability test of flip chip assemblies. T/C reliability test was performed by measuring changes of NCP bump connection resistance. Results showed that flip chip assembly using NCP with lower CTE and higher modulus exhibited better T/C reliability behavior because of reduced shear strain in NCP adhesive layer.     

Filler size and content effects on the composite properties of anisotropic conductive films (ACFs) and reliability of flip chip assembly using ACFs

Flip chip assembly on organic board using anisotropic conductive films (ACFs) is gained more attention because of its many advantages. But to obtain more reliable flip chip assembly, it is necessary to have low coefficient of thermal expansion (CTE) value of ACFs. To control the CTE of ACF materials, non-conductive silica fillers were incorporated into ACFs. The effect of non-conductive silica filler content and size on cure kinetics and thermo-mechanical properties of ACFs was studied. Furthermore, filler content and size effects on reliability of flip chip assembly using ACFs were also investigated. In accordance with increasing filler content, curing peak temperature and storage modulus (E′) increased. But CTE decreased as the filler content increased. The effect of filler size on composite properties and assembly reliability showed similar tendency with the filler content effect. The smaller filler size was applied, the better composite properties and reliability were obtained. Conclusively, incorporation of non-conductive fillers, particularly in case of smaller size and higher content, in ACFs improves the material properties significantly, and as a result, flip chip assembly using ACFs is resulted in better reliability.     

Effect of substrate flexibility on solder joint reliability

Solder joint fatigue failure is a serious reliability concern in area array technologies, such as flip chip and ball grid array packages of integrated-circuit chips. The selection of different substrate materials could affect solder joint thermal fatigue lifetime significantly. The reliability of solder joint in flip chip assembly for both rigid and compliant substrates was evaluated by accelerated temperature cycling test. Experimental results strongly showed that the thermal fatigue lifetime of solder joints in flip chip on flex assembly was much improved over that in flip chip on rigid substrate assembly. Debonding area of solder joints in flip chip on rigid board and flip chip on flex assemblies were investigated, and it was found that flex substrate could slow down solder joint crack propagation rate. The mechanism of substrate flexibility on improving solder joint thermal fatigue was investigated by thermal mechanical analysis (TMA) technique. TMA results showed that flex substrate buckles or bends during temperature cycling and this phenomenon was discussed from the point of view of mechanics of the flip chip assembly during temperature cycling process. It was indicated that the thermal strain and stress in solder joints could be reduced by flex buckling or bending and flex substrates could dissipate energy that otherwise would be absorbed by solder joints. It was concluded that substrate flexibility has a great effect on solder joint reliability and the reliability improvement was attributed to flex buckling or bending during temperature cycling.     

Anisotropic conductive adhesives with enhanced thermal conductivity for flip chip applications

This paper presents the development of new anisotropic conductive adhesives (ACAs) with enhanced thermal conductivity for improved reliability of adhesive flip chip assembly under high current density condition. As the bump size in the flip chip assembly is reduced, the current density through the bump also increases. This increased current density causes new failure mechanisms, such as interface degradation due to intermetallic compound formation and adhesive swelling resulting from high current stressing. This process is found especially in high current density interconnection in which the high junction temperature enhances such failure mechanisms. Therefore, it is necessary for the ACA to become a thermal transfer medium that allows the board to act as a new heat sink for the flip chip package and improve the lifetime of the ACA flip chip joint. We developed the thermally conductive ACA of 0.63 W/m·K thermal conductivity by using a formulation incorporating the 5-μm Ni-filled and 0.2-μm SiC-filled epoxy-based binder system. The current carrying capability and the electrical reliability under the current stressing condition for the thermally conductive ACA flip chip joints were improved in comparison to conventional ACA. This improvement was attributed to the effective heat dissipation from Au stud bumps/ACA/PCB pad structure by the thermally conductive ACA.     

Effect of substrate flexibility on solder joint reliability. Part II: finite element modeling

Solder joint fatigue failure is a serious reliability concern in area array technologies, such as flip chip and ball grid array packages of integrated-circuit chips. The selection of different substrate materials could affect solder joint thermal fatigue life significantly. The mechanism of substrate flexibility on improving solder joint thermal fatigue was investigated by thermal mechanical analysis (TMA) technique and finite element modeling. The reliability of solder joints in real flip chip assembly with both rigid and compliant substrates was evaluated by accelerated temperature cycling test. Finite element simulations were conducted to study the reliability of solder joints in flip chip on flex assembly (FCOF) and flip chip on rigid board assembly (FCOB) applying Anand model. Based on the finite element analysis results, the fatigue lives of solder joints were obtained by Darveaux’s crack initiation and growth model. The thermal strain/stress in solder joints of flip chip assemblies with different substrates were compared. The results of finite element analysis showed a good agreement with the experimental results. It was found that the thermal fatigue lifetime of FCOF solder joints was much longer than that of FCOB solder joints. The thermal strain/stress in solder joints could be reduced by flex buckling or bending and flex substrates could dissipate energy that otherwise would be absorbed by solder joints. It was concluded that substrate flexibility has a great effect on solder joint reliability and the reliability improvement was attributed to flex buckling or bending during temperature cycling.     

Metal-Matrix Nanocomposites with Tailored Coefficients of Thermal Expansion for Improved Thermomechanical Reliability

Ensuring the thermomechanical reliability of various interfaces in thermoelectric (TE) devices during manufacture and operation is challenging, especially for those incorporating TE materials with small coefficients of thermal expansion (CTEs). In this paper, we describe our recent progress in the development of metal-matrix nanocomposites with tailorable CTEs, for use as electrodes or as interfacial bonding layers for creating segmented TE elements. The composites incorporate ceramic nanoscale fillers with isotropic negative thermal expansion (NTE) to effectively offset the high CTE of the metal phase. The NTE fillers, synthesized using a sol?Cgel route, were mixed with metal powders and hot pressed to yield nanocomposites having CTE values decreasing approximately linearly with filler volume fraction. Composites with 54/46 v/v Ag/zirconium tungstate (ZrW₂O₈) achieved average CTE of 7.2?ppm/K, with electrical and thermal conductivities approximately 50% of that of Ag nanopowders hot pressed under identical conditions. X-ray diffraction (XRD) analyses suggest that the composites are thermally stable at temperatures as high as 920?K. This research provides a foundation upon which to investigate alternative electrode and interface materials with tailored CTEs for achieving improved thermomechanical reliability of TE modules and other thermal and electronic devices.     

Reduced thermal strain in flip chip assembly on organic substrateusing low CTE anisotropic conductive film

Flip chip assembly directly on organic boards offers miniaturization of package size as well as reduction in interconnection distances, resulting in a high performance and cost-competitive packaging method. This paper describes the usefulness of low cost flip-chip assembly using electroless Ni/Au bump and anisotropic conductive films on organic boards such as FR-4. As bumps for flip chip, electroless Ni/Au plating was performed as a low cost bumping method. Effect of annealing on Ni bump characteristics informed that the formation of crystalline nickel with Ni₃P precipitation above 300°C causes an increase of hardness and an increase of the intrinsic stress. As interconnection material, modified ACFs composed of nickel conductive fillers for conductive fillers, and nonconductive fillers for modification of film properties, such as coefficient of thermal expansion (CTE), were formulated for improved electrical and mechanical properties of ACF interconnection. Three ACF materials with different CTE values were prepared and bonded between Si chips and FR-4 boards for the thermal strain measurement using moire interferometry. The thermal strain of the ACF interconnection layer, induced by temperature excursion of 80°C, was decreased according to the decreasing CTEs of ACF materials. This result indicates that the thermal fatigue life of ACF flip chip assembly on organic boards, limited by the thermal expansion mismatch between the chip and the board, could be increased by low CTE ACF     

Effects of the Functional Groups of Nonconductive Films (NCFs) on Material Properties and Reliability of NCF Flip-Chip-On-Organic Boards

Nonconductive films (NCFs) are one of the polymer interconnect materials for flip-chip interconnection. NCFs containing no conductive particles play several roles such as adhesion, insulation, and underfilling at the same time. The most important issue of NCF flip-chip-on-board (FCOB) assemblies is thermal cycling reliability. Thermomechanical properties of cured NCFs, such as glass transition temperature (T_g), storage modulus (E'), and coefficient of thermal expansion (CTE), significantly affect the thermal cycling reliability of NCF FCOB assemblies. In this paper, the improvement of thermomechanical properties of NCFs was investigated by controlling the number of functional groups of NCF resins. To compare the reliability of conventional and modified NCF FCOB assemblies after thermal cycling test, electrical analysis and scanning acoustic microscopy investigation were performed. Thermal deformations of NCF FCOB assemblies under thermal cycling environment were also investigated, and quantitatively compared using high sensitivity Twyman-Green interferometry and portable engineering Moire interferometry. According to these results, the functional groups of NCFs have significant effects on thermomechanical properties of cured NCFs, thermal deformation, and thermal cycling reliability of NCF-bonded FCOB assemblies. As a result, the functionality modified NCF FCOB assemblies showed significantly enhanced reliability compared conventional NCFs in thermal cycling test.     

Low-cost direct chip attach: comparison of SMD compatible FCsoldering with anisotropically conductive adhesive FC bonding

Small modules on the basis of laminate substrates are often used as a functional subunit in electronic applications. Currently most of them are made by chip and wire technique as one kind of bare chip assembly to fulfill the requirements of size reduction. Low cost flip-chip technology is one of the most promising approaches for further cost and size reduction. In this paper a special car radio submodule is chosen for exemplification. We compare a SMD compatible FC soldering process using eutectic solder bumps and underfilling with an anisotropically conductive adhesive (ACA) FC bonding process using tape or paste materials. FC Soldering: For FC soldering an electroless, maskless Ni/Au plating for under bump metallization (UBM) was chosen. The solder deposition itself is done by stencil printing whereas other cost efficient deposition techniques in the market have been observed. The FC assembly is integrated into a standard SMD line. Different underfill methods for quick underfilling are shown and failure mechanisms and lifetime predictions of assembled flip chips are demonstrated. ACA-FC Bonding: For this process electroless Ni/Au bumping is used as well. An assembly process for ACAs using a semiautomatic FC bonder is developed. In order to reduce the time for mounting the ACA has been precured. The aspects of different process flows including ACA deposition techniques, tape and paste adhesives and filler materials are discussed. The influence of high current, climate, and thermal cycling on the contact resistance and the low frequency noise spectrum is shown. In summarizing this work we describe the benefits and disadvantages of both techniques and discuss the potential for further developments and applications     

Monolayer-protected silver nano-particle-based anisotropic conductive adhesives: Enhancement of electrical and thermal properties

Two types of self-assembled monolayers (SAMs), dicarboxylic acid and dithiol, were used to treat the silver nanoparticles. Thermogravimetric analyzer (TGA), differential scanning calorimeter (DSC), and contact angle results indicated that the SAMs were well coated on the silver nanoparticles and thermally stable below 150°C. By introducing the monolayer-coated silver nanoparticles into the anisotropic conductive adhesives (ACAs), the electrical properties and thermal conductivity of ACAs were significantly improved. The joint resistance of the ACA decreased from 10⁻³ Ohm to 10⁻⁵ Ohm with SAMs-coated silver fillers, and the current carrying capability of ACAs was also obviously improved. The improved electrical properties are due to the stronger bonding between nanofillers and the SAM coating materials; consequently, this improved the ACA interfacial properties. The enhanced interfacial properties with the SAM-protected nanofillers also attributed to the improved thermal conductivity of ACAs.     

Material properties of anisotropic conductive films (ACFs) and their flip chip assembly reliability in NAND flash memory applications

In this paper, the material properties of anisotropic conductive films (ACFs) and ACF flip chip assembly reliability for a NAND flash memory application were investigated. Measurements were taken on the curing behaviors, the coefficient of thermal expansion (CTE), the modulus, the glass transition temperature (T_g), and the die adhesion strength of six types of ACF. Furthermore, the bonding processes of the ACFs were optimized. After the ACF flip chip assemblies were fabricated with optimized bonding processes, reliability tests were then carried out. In the pressure cooker test, the ACF with the highest adhesion strength showed the best reliability and the ACF flip chip assembly revealed no delamination at the chip-ACF interface, even after 96 h. In the high temperature storage test and the thermal cycling test, the reliability of the ACF flip chip assembly strongly depends on the T_g value of the ACF. In the thermal cycling test, in particular, which gives ACF flip chip assemblies repetitive shear stress, high value of CTE above T_g accelerates the failure rate of the ACF flip chip assembly. From the reliability test results, ACFs with a high T_g and a low CTE are preferable for enhancing the thermal and thermo-mechanical reliability. In addition, a new double-sided chip package with a thickness of 570 μm was demonstrated for NAND flash memory application. In conclusion, this study verifies the ACF feasibility, and recommends the optimum ACF material properties, for NAND flash memory application.     

Guidelines to select underfills for flip chip on board assemblies and compliant interposers for chip scale package assemblies

The effect of thermomechanical properties of underfill and compliant interposer materials, such as coefficient of thermal expansion (CTE) and stiffness (Young's modulus) on reliability of flip chip on board (FCOB) and chip scale packages (CSPs) under thermal cycling stresses is investigated in this study. Quasi-three-dimensional viscoplastic stress analysis using finite element modeling (FEM) is combined with an energy partitioning (EP) model for creep-fatigue damage accumulation to predict the fatigue durability for a given thermal cycle. Parametric FEM simulations are performed for five different CTEs and five different stiffnesses of the underfill and compliant interposer materials. The creep work dissipation due to thermal cycling is estimated with quasi 3-D model, while 3-D model is used to estimate the hydrostatic stresses. To minimize the computational effort, the 3-D analysis is conducted only for the extreme values of the two parameters (CTE and stiffness) and the results are interpolated for intermediate values. The results show that the stiffness of the underfill material as well as the CTE play important role in influencing the fatigue life of FCOB assemblies. The fatigue durability increases as underfill stiffness and CTE increase. In the case of compliant interposers, the reverse is true and durability increases as interposer stiffness decreases. Furthermore, the interposer CTE affects the fatigue durability more significantly than underfill CTE, with durability increasing as CTE decreases. The eventual goal is to define the optimum design parameters of the FCOB underfill and CSP interposer, in order to maximize the fatigue endurance of the solder joints under cyclic thermal loading environments.     

Effects of Heating Rate on Material Properties of Anisotropic Conductive Film (ACF) and Thermal Cycling Reliability of ACF Flip Chip Assembly

In this paper, the effects of heating rate during anisotropic conductive film (ACF) curing processes on ACF material properties such as thermomechanical and rheological properties were investigated. It was found that as the heating rate increased, the coefficient of thermal expansion (CTE) of the ACF increased, and the storage modulus and glass transition temperature $(T _{g})$ of the ACF decreased. Variation of the ACF material properties are attributed to cross-linking density, which is thought to be related with the ACF density. In addition, as the heating rate increased, the minimum viscosity of the ACF decreased and the curing onset temperature increased during the curing process. The similar phenomenon was also found in in-situ contact resistance measurement. As the heating rate increased, contact resistance establishing temperature increased and the contact resistances of the ACF flip chip assemblies decreased. The decrease in contact resistance was due to larger conductive particle deformation which leads to larger electrical contact area. The effect of the heating rate of ACFs on thermal cycling (T/C) reliability of flip chip assemblies was also investigated. As the heating rate increased, the contact resistances of the ACF flip chip assembly rapidly increased during the T/C test. The T/C reliability test result was analyzed by two terms of shear strain and conductive particle deformation. Reduced gap of joints due to reduced ACF viscosity resulted in larger shear strain. Moreover, many cracks were observed at metal-coated layers of conductive particles due to larger deformation.      

Effects of Thermal Cycling on Material Properties of Nonconductive Pastes (NCPs) and the Relationship Between Material Properties and Warpage Behavior During Thermal Cycling

In this paper, the effects of thermal cycling on material properties such as coefficient of thermal expansion (CTE), modulus, and glass transition temperature $({rm T}_{rm g})$ of nonconductive pastes (NCPs) for flip chip applications were investigated. Using a thermomechanical analyzer, the dimensional changes of NCPs and an underfill material were measured. The dimensional changes of all materials during the first cycle rapidly increased near ${rm T}_{rm g}$. However, the rapid increase of dimensional change near ${rm T}_{rm g}$ was not observed during the second and third cycles. Furthermore, using a dynamic mechanical analyzer, the modulus and ${rm T}_{rm g}$ were measured. The modulus in the first cycle was smaller than that in the second cycle for all materials. After the first cycle, the modulus curves followed the second cycle curve. Next, the warpage behavior of the flip chip assemblies was observed using the Twyman–Green interferometry method to investigate how material property changes affect warpage behavior during thermal cycling (T/C) and it was found that the warpage of the flip chip assembly decreased after the first cycle. However, after the first cycle, the amount of warpage was constant for the following five cycles. As a result, it was verified that the material properties of NCPs and the underfill material change after the first thermal cycle, and the material property changes are closely related to the warpage hysteresis behavior during T/C. Finally, warpage hysteresis was understood as shear strain.      

Characterization of underfill materials for functional solderbumped flip chips on board applications

The curing conditions and material properties such as the TCE (thermal coefficient of expansion), T_g (glass transition temperature), flexural storage modulus, tangent delta, and moisture content of nine different underfill materials from three different vendors are measured. Their flow rate and the effect of moisture content on mechanical (shear) strength in solder bumped flip chips on organic substrate are also determined experimentally. Furthermore, their effects on the electrical performance (voltage) of functional flip chip devices on organic substrate are measured. Finally, a simple methodology is presented for the selection of underfills from the measurement results of these nine different underfill materials     

Study of adhesive flip chip bonding process and failure mechanisms of ACA joints

The flip chip bonding process using anisotropic conductive adhesives (ACA) and the consequent joint reliability were studied. The substrates used were rigid FR-4 boards, which are interesting due to their low cost and wide range of applications. The problems associated with the technique are discussed in this paper from the reliability point of view. Also, some aspects concerning production are introduced.The reliability of the joints was studied by accelerated environmental tests. A temperature cycling test was performed between temperatures −40 and +125 °C. Constant humidity testing was conducted at 85 °C and RH85%. In addition, reflow aging tests were performed using a conventional Sn/Pb reflow profile. For reducing the bonding cycle time, a two-stage curing process was used, which also utilizes the reflow process.The results show that the three bonding parameters, temperature, time, and pressure, all affect joint reliability. Most detrimental, however, seems to be reflow treatment performed after bonding. Most failures occurred only very briefly during the temperature cycling at the moment the temperature changed, while the joints were still conducting at both temperature extremes. However, a different failure mechanism caused a different kind of behavior during temperature cycling. The relationship between the failure modes and the failure mechanisms was studied using a scanning electron microscopy.     

Experimental Analysis of Mechanical and Electrical Characteristics of Metal-Coated Conductive Spheres for Anisotropic Conductive Adhesives (ACAs) Interconnection

An accurate characterization for the deformation behavior of conductive particles is important: 1) to understand the anisotropic conductive adhesive (ACA) interconnection and 2) to optimize the ACA bonding parameter. This paper introduces an experimental technique, which has been developed to allow continuous monitoring of deformation characteristics of a single conductive particle. The load-deformation curve of a single conductive particle is measured, which provides the quantitative estimation of the mechanical and electrical characteristics of metal-coated polymer spheres used in ACAs. Based on the load-deformation result of a single conductive particle and the number of trapped particles on a bump, equivalent spring models are used to predict the deformation degree of conductive particles after flip chip assembly. For two kinds of conductive particles with different polymer cores, the mechanical and electrical characteristics of ACA interconnection were studied. Such results are used to further achieve a more sophisticated approach of the ACA bonding process and contact reliability.     

Effects of Anisotropic Conductive Film Viscosity on ACF Fillet Formation and Chip-On-Board Packages

In this paper, the effects of anisotropic conductive film (ACF) viscosity on ACF fillet formation and, ultimately, on the pressure cooker test (PCT) reliability of ACF flip chip assemblies were investigated. The ACF viscosity was controlled by varying the molecular weight of the epoxy materials. It was found that the ACF viscosity increased as the increase of molecular weight of the epoxy materials. However, there was little variation of the thermomechanical properties among the evaluated ACFs with different viscosites. Also, the results showed that the ACFs have no differences in moisture absorption rate, die adhesion strength, and degree-of-cure. In scanning electron microscopy images, the lower ACF viscosity resulted in the smoother ACF fillet shape and the higher fillet height. From the results of PCT, the ACF flip chip assembly with the smoother fillet shape showed better reliability in terms of contact resistance changes. After 130 h of PCT, the flip chip assembly with lower ACF viscosity also showed a lesser degree of delamination at the ACF/chip interface.     

耐高温耐湿性环氧树脂封装材料的制备

以双酚型液体环氧树脂作为基体环氧树脂,具有疏水性支链的芳香胺作为固化剂,疏水型熔融二氧化硅为填料,并配以触变剂、消泡剂、促进剂等助剂,通过DSC、TGA、TMA、回流焊等热分析手段以及高压蒸煮试验来对封装材料的性能进行表征,并对配方优化,获得了具有良好耐水性以及耐热性的单组分液体环氧树脂封装材料。结果表明:该封装材料具有良好的耐湿性和耐高温性能,可以满足COB(Chip on Board)封装客户对高压蒸煮及回流焊等可靠性测试的性能要求。