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用光致荧光谱、傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)对用阳极氧化法制成的多孔硅层在1%NH3/H2O2溶液中的腐蚀现象进行了研究。红外分析表明,Si-O键和H-O键的强度随NH3/H2O2溶液的腐蚀时间的增加而增加,Si-H键强主匠随腐蚀时间增加而减少。光致荧光谱的峰值在腐蚀开始时先下降后上升,半高宽变窄,谱峰的以边明显蓝移。分析研究表明,1%NH3/H2O2溶液对多孔硅层有腐蚀 相似文献
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本文叙述了采用金属有机物钛酸四乙酯(Ti[OC2H5]4取代四氯化钛,运用PCVD外加热法沉积Ti(CN)涂层,并对涂层进行了X射线衍射(XRD)、扫描电镜(SEM)、X光电子(XPS)分析,其显微硬度可达到1600kg/mm2,膜层结构仍为柱状晶 相似文献
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GaAs衬底层选择性腐蚀技术 总被引:2,自引:1,他引:1
本文在GaAsGaAlAs选择性腐蚀的基础上进行了腐蚀GaAs衬底层获得GaA/GaAlAs外延层薄膜的二次腐蚀技术。最终选用了C3H4(OH)(COOH)3.H2O-H2O2系选择性腐蚀液和H2SO4-H2O2系腐蚀液,获得了快速,可控制,重复性好的可全部可局部去除衬底的腐蚀方法。 相似文献
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用XPS研究了多晶纯镉置于空气中形成的表面化学态。结果表明,Cd表面上除有大量吸附碳、氧外,还形成了CdO和Cd(OH)2。O1s谱的最佳曲线拟合表明有三个O1s分量存在,其结合能分别为532.7eV,529.6eV,531.3eV。他们分别是吸附氧,CdO和Cd(OH)2中O1s的特征。本文推断Cd先与O2反应生成CdO,再在水汽作用下形成Cd(OH)2,表面形成的CdO和Cd(OH)2薄层阻挡 相似文献
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GaAs、GaP、InP、InGaAsP、AlGaAs、InAlGaAs的化学腐蚀研究 总被引:2,自引:0,他引:2
许兆鹏 《固体电子学研究与进展》1996,16(1):56-63
为研制全集成光开关、微片式激光器等,对GaAs、GaP、InGaAsP、InAIGaAs、AlGaAs等材料的化学腐蚀进行了实验研究。为了研制InAlGaAs/InAlAs/InAlGaAs微片式激光器,开发了H3PO4/H2O2/H2O薄层腐蚀液和HCl/H2O选择性腐蚀液;为了研制InGaAsP/InP/InGaAsPTbar型光波导,开发了HCl/H3PO4/H2O2薄层腐蚀液和HCl/H2O2选择性腐蚀液;为了研制GaP、InGaP光波导,开发了HCl/HNO3/H2O薄层腐蚀液。它们都具有稳定、重复性好、速率可控、腐蚀后表面形貌好等特点。除此之外,蚀刻成的GaP光波导侧壁平滑无波纹起伏。此种结果尚未见报导。 相似文献
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采用NH4F/H2O2作为p-CZT晶片的表面钝化剂,对未钝化与钝化表面处理的p-CZT晶片的C-V特性进行了对比研究.用XPS分析了钝化前后CZT晶体表面成分,发现钝化后CZT晶片表面形成厚度为3.1 nm的TeO2氧化层.用Agilent 4294A高精度阻抗分析仪,在1 MHz下对未钝化的和钝化的CZT晶片进行C-V测试.对测试结果的计算表明,钝化提高了Au与CZT接触的势垒高度(∮)b.未钝化的(∮)b为1.393 V,钝化后(∮)b变为1.512 V. 相似文献
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The periodic arrays of nanostructure were successfully patterned on Si wafers by ultraviolet nanoimprint lithography (UV-NIL) using nanosphere lithography (NSL). Two-dimensional (2D) well ordered self-assembled arrays were obtained on Si wafer by using nanosphere and the tilted-drain method. We tried to combine two techniques and hard mold of Si mold for NIL and polymer mold of acrylate-based polymer were fabricated by NSL. The Si master mold and polymer mold were formed by Cr lift-off and ICP-RIE process. The surface has a low surface energy at the interface with 1H, 1H, 2H, 2H-perfluorooctyl-trichlorosilane (FOTS) vapor-coating, which can eliminate the problem of the adherence to the surface of the mold during demolding. Finally, nanopatterns were formed by UV-NIL, where the residual layer was not observed. 相似文献
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Etching was performed on(100) silicon wafers using silicon-dissolved tetramethylammonium hydroxide (TMAH) solutions without the addition of surfactant.Experiments were carried out in different TMAH concentrations at different temperatures for different etching times.The surface phenomena,etching rates,surface morphology and surface reflectance were analyzed.Experimental results show that the resulting surface covered with uniform pyramids can be realized with a small change in etching rates during the et... 相似文献
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Binn Kim Hae-Yeol Kim Hyun-Sik Seo Sung Ki Kim Chang-Dong Kim 《Electron Device Letters, IEEE》2003,24(12):733-735
Self-aligned, p-channel polycrystalline silicon thin-film transistors (TFTs) were fabricated by electric field enhanced crystallization of a-Si:H in contact with the Ni catalyst, where a chemical solution of 97.5% H/sub 2/O:1% HF:1.5% H/sub 2/O/sub 2/ was used for a surface treatment on polycrystalline silicon films. The wet surface treatment was found to remarkably improve the electrical properties of TFTs, especially the leakage current and subthreshold slope. The enhanced performance was confirmed to be from the removal of the Ni impurity remaining as defect states at the surface and also from the ameliorated surface roughness of the polycrystalline silicon films. 相似文献
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H2SO4/H2O2/H2O、HNO3/HF和HF/H2O2/H2O为半导体芯片生产过程中三种去除硅片背面铜污染的化学清洗液。在单片湿法清洗机上采用这三种化学液对直径300 mm具有类似于实际生产中铜污染的硅片进行了清洗,结果发现H2SO4/H2O2/H2O在清洗过程中不对硅片表面的Si3N4膜产生损伤,但铜污染的去除效率较低;HNO3/HF和HF/H2O2/H2O对Si3N4膜产生微量刻蚀,从而去除扩散至硅片内部铜污染,从而显示出较佳的去除效果。通过比较HF/H2O2/H2O中HF体积分数与Si3N4膜刻蚀深度和清洗后铜原子浓度,HF的体积分数为1.5%时,可以使硅片表面铜原子浓度降至1010cm-2以下,并且Si3N4膜厚的损失小于1 nm。 相似文献
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R. N. Bekimbetov Yu. A. Nikolaev V. Yu. Rud’ Yu. V. Rud’ E. I. Terukov 《Semiconductors》2000,34(9):1064-1067
Heterostructures in an a-Si:H/InSe system were grown by the deposition of a-Si:H films onto the surface (001) of InSe single-crystal wafers and also by deposition of pure indium films with their subsequent selenization, in which case InSe films were synthesized at the a-Si:H surface. The photovoltaic effect was observed and studied for both types of heterostructures. It was concluded that the heterostructures obtained may be used as wide-band photoconverters of radiation. 相似文献
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研究了一种新型湿法化学清洗半导体GaAs表面的方法。通过简单设计清洗工艺能使GaAs表面产生最低的损伤。GaAs表面清洗必须满足三个条件:(1)清除热力学不稳定因素和表面粘附的杂质,(2) 除去GaAs表面氧化层,(3)提供一个光滑平整的GaAs表面。本文采用旋转超声雾化方式用有机溶剂除去GaAs表面的杂质,再用NH4OH:H2O2:H2O= 1:1:10和HCl:H2O2:H2O=1:1:20顺次腐蚀非常薄的GaAs层,去除表面的金属污染,并在GaAs表面形成一个非常薄的氧化层表面,最后用NH4OH:H2O= 1:5溶液来清除GaAs表面氧化层。测试GaAs表面的特性,分别用X射线光电光谱仪、X射线全反射荧光光谱仪和原子力显微镜测试了GaAs表面氧化的组分、GaAs表面金属污染和GaAs表面形貌,测试结果表明通过旋转超声雾化技术清洗可提供表面无杂质污染、金属污染和表面非常光滑的GaAs衬底,以供外延生长。 相似文献