共查询到19条相似文献,搜索用时 78 毫秒
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EPDM/CSM(95/5)的并用体系与单纯EPDM相比较,改善了胶料的流变性能,提高了交联速度和硫化胶的拉伸强度,并降低了生产成本,产品性能满足GB 12528—90标准规定。 相似文献
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研究了不同并用比的氯醚橡胶(ECO)与NBR-26,NBR-33和NBR-41并用胶的力学性能、耐老化性能和耐油性能。结果表明,NBR-26,NBR-33和NBR-41的用量在10~40份的范围内,对胶料的拉伸强度和扯断伸长率的影响不大;随着NBR-26的用量增大,硫化胶在油中的体积变化率增大,而且在100℃油中的体积变化率尤为明显,随着NBR-23的用量增大,硫化胶在100℃油中的体积变化率呈上升的趋势;随着NBR-41的用量增大,硫化胶在100℃油中的体积变化率明显下降。 相似文献
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ECO/NBR共混胶的性能 总被引:2,自引:0,他引:2
考察二元共聚氯醚橡胶(ECO)与不同丙烯腈质量分数的NBR共混胶的物理性能、耐老化性能及耐油性能。结果表明,共混胶的物理性能提高,ECO/NBR-4l共混胶的耐热老化性能优于ECO/NBR-35和ECO/NBR-26共混胶.NBR-4l的耐油性能最好。共混比为60/40的ECO/NBR-4l共混物具有优异的耐油性能,玻璃化温度范围为-46~-43℃,可满足耐寒制品的使用要求。 相似文献
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研究NBR/氯磺化聚乙烯(CSM)并用比、硫黄用量、炭黑品种与用量、增塑剂及防老剂品种对NBR/CSM并用胶物理性能的影响。NBR/CSM并用胶优化配方为:NBR40,CSM60,炭黑N55055,氧化锌2.5,硬脂酸1,氯化石蜡10,防老剂MB1,硫黄1,促进剂TMTD0.5,促进剂CZ0.9。该配方并用胶的综合物理性能良好。 相似文献
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研究了不同共混比对氯化聚乙烯橡胶(CM)/羧基丁腈橡胶(XNBR)并用胶在热空气老化前后的力学性能、耐油性的影响。结果表明,随着XNBR用量的增加,焦烧时间缩短,硫化速度加快,拉断伸长率、拉伸强度先减小后增加;100%定伸应力出现极大值;拉伸永久变形、撕裂强度、体积磨耗量和高温下浸油前后的体积和质量变化率均按一定规律减小;常温下体积和质量变化率均很小;硬度明显提高且基本稳定;热空气老化后,拉断伸长率整体下降,拉伸强度,100%定伸应力和撕裂强度均有明显提升,DIN磨耗量除CM纯胶有明显降低外,其他配比的磨耗体积基本维持不变;热油老化后,伸长率、拉伸强度、100%定伸应力均有所下降。 相似文献
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Blends of 80/20 CPE/NR filled with various silica loadings were prepared, and their properties were determined. It was found that cure properties are influenced significantly by the addition of precipitated silica. Scorch time and cure time decrease with increasing silica loading, which could be explained by the thermal history attributed to the shear heating in the blending stage. An increase in crosslink density as a function of silica loading is believed to be caused by a migration of curatives to the NR phase. In terms of phase morphology, with increasing silica loading, the NR dispersed phase size decreases due to the increase in compound viscosity and, thus, the shear stress available for efficient blending. An increase in silica loading also enhances resistance to oil due to the decrease in the NR dispersed phase size associated with the dilution effect, but gives no significant impact on thermal aging resistance. According to the change in damping peak height associated with the shift in Tg of the CPE phase, silica appears to preferentially migrate to the CPE phase due to the strong interaction between CPE and silanol groups of the silica surfaces. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 2218–2224, 2005 相似文献
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研究了不同种类及用量的填料对ECO/NBR共混胶硫化特性、力学性能、耐老化性能、高温耐油性能的影响,结果发现综合考虑如上性能配方中最合适的补强剂是N539,用量以70份为最佳。 相似文献
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Zhen Xiu Zhang Chun Hua Chen Xin Wen Gao Jin Kuk Kim Zhen Xiang Xin 《应用聚合物科学杂志》2011,120(2):1180-1185
The miscibility and some physicomechanical characteristics of chlorinated polyethylene rubber (CPE) and nitrile rubber (NBR) blends have been investigated. Calculation of the heat of mixing, differential scanning calorimetry, and scanning electron microscopy analysis showed that CPE was miscible with NBR in all proportions. The cure and scorch times decreased with the increase in NBR content, whereas the maximum torque increased. The tensile strength, 100% modulus, elongation at break, tear strength, and compression set decreased with increasing of NBR content. After aging, hardness and tensile strength increased, and there was no drastic change in elongation at break on aging. The thermal aging resistance and the abrasion resistance of NBR are improved after blending with CPE, but the oil resistance decreased. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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研究用NBR改善NR/PVC共混物的耐油性能 ,通过测试所设计的各配方共混物的拉伸强度、扯断伸长率、硬度、耐磨性和耐油性等性能 ,得出NBR改性NR/PVC共混体系的最佳配比关系。最佳配方为 :PVC 30 ;NR 10 0 ;NBR 2 5 ;硫黄 3;促进剂TMTD 0 8;促进剂D 1 5 ;促进剂DM 1 5 ;白炭黑 40 ;轻质碳酸钙 30 ;氧化锌 5 ;硬脂酸 1 5 ;防老剂D 2。共混物的耐油性能可达到NBR制品的要求 相似文献