On the possibility of growth quantum dot arrays in InAs/GaAs system by droplet epitaxy under MOVPE conditions

We have experimentally studied the possibility of obtaining InAs quantum dot arrays on GaAs(100) substrates by droplet-island growth under low-temperature (160–360°C) metalorganic vapor phase epitaxy (MOVPE) conditions. It is established that trimethylindium (In source) exhibits decomposition even at the lower boundary of the indicated temperature interval. The height of In drops formed on the substrate surface was 3–12 nm with a density of ∼(0.4−1.4) × 109 cm⁻² depending on the H-MOVPE conditions. In order to retain the dimensions of InAs nanocrystals formed at the subsequent stage, the process should be carried out at an increased rate of arsine supply.     

Reliability analysis of transparent conductive tracks embossed in ZnO and Al-ZnO sol–gel materials

In this paper, we present a low-cost rapid replication approach to fabricate ZnO and Al-doped ZnO Transparent Conductive Oxide electrode structures using both hard UV curable polyurethane acrylate and soft thermal curable polydimethylsiloxane moulds. The thin films of the ZnO and Al-ZnO sol–gel precursor solution prepared from zinc acetate monoethanolamine and isopropanol were cast into a polydimethylsiloxane or polyurethane acrylate mould containing the electrode design. For soft mould embossing, the sol–gel coated substrate and polydimethylsiloxane mould were dried under vacuum at 70 °C for 3h. While for hard mould embossing, the system was heated at 150 °C for 30 min with 100 N applying force and then demoulded at 80 °C. The formed electrode patterns can be further densified or annealed giving a stable film that retains the embossed shape. The difference of surface profile obtained by soft and hard moulding is detailed and the hard mould is shown to be more suitable for low aspect ratio conductors. And the reliability study on embossed ZnO and Al-ZnO conductive tracks prepared with hard moulds shows that the embossed structure still retains good quality.     

Optical and electrical properties of obliquely deposited a-GeSe<Subscript>2</Subscript> films

Oblique deposition and exposure to photons of energy greater than the bandgap have a marked effect on the structure and consequently on electrical and optical properties of amorphous chalcogenides. This paper presents a detailed study of photoinduced effect and oblique deposition effect on electrical and optical properties of a-GeSe₂ films deposited at different angles (0°–80°). The indirect-optical bandgap energy (2.18 eV) was found to be independent of angle of incidence. The spectral response of refractive index and extinction coefficient has been determined in the wavelength range of 0.6–1 μm using the transmission spectra. Refractive index decreases with the increase in angle of incidence. The value of refractive index was observed to be 2.28 for 0° and 2.00 for 80° films at 0.646 μm. An increase in bandgap was also observed on exposure to the UV light for ∼120 min. The change in bandgap became more significant with the increase in angle of incidence (∼ 2.3% for 0° and ∼10.6% for 80°). The temperature dependence of conductivity along with time dependence and spectral response of photocurrent has also been investigated.     

Behavior of mass concrete under biaxial compression-tension and triaxial compression-compression-tension

To meet the requirement of nonlinear analysis and design for mass concrete structures, the mechanical characteristics of mass concrete specimens 25 × 25 × 40 cm with three-graded aggregate 5–80 mm under biaxial compression-tension and triaxial compression-compression-tension was studied experimentally with the multiaxial concrete apparatus. In comparison with the corresponding wet-screened concrete specimens 15 × 15 × 30 cm with two-graded aggregate 5–40 mm, it was found that the wet-screened effect and size effect under complex stress states were obvious, as under uniaxial stress state. By regression of the tests results, respective failure criteria for mass concrete in principal stress space and octahedronal stress space were proposed.     

Reagent decontamination of the finely dispersed fraction of soils

The possibilities of reagent treatment of the finely dispersed (<0.1 mm) fraction of soils by agitation leaching at 80°C for 7 h at the liquid to solid ratio of 2: 1 were examined. The reagents were 2–8 M H₂SO₄ and mixtures of H₂SO₄ with H₃PO₄ and NH₄F. The maximal attained decontamination factor (DF) does not exceed 8–10, and the soil loss for the dissolution does not exceed ∼12%. Reagent treatment with 1–5 M sulfuric acid in a pressure vessel in the temperature range 80–140°C allowed the maximal DF value of ∼70 to be attained, with the soil weight loss reaching 15% and acid consumption, 3 mol per kilogram of soil. The reagent treatment of the finely dispersed fraction can be successfully combined with the decontamination method based on separation of the finely dispersed fraction by gravity sedimentation in water, especially at a high content of the finely dispersed substance.     

1.94-μm light-emitting diodes for moisture-content measurements

High-power light-emitting diodes are demonstrated; they are characterized by a quantum efficiency of 5.5%, utilize a symmetric GaAlAsSb/GaInAsSb/GaAlAsSb double heterostructure, have a spontaneous-emission maximum at a wavelength of 1.94 μm, and operate in the temperature range from −80°C to +60°C. A continuous-wave optical power of 3.7 mW and a peak optical power of 90 mW in pulsed operation (τ∼1–5 ms, f=1 kHz) are attained at room temperature. The principal electrical and emission characteristics are given. Pis’ma Zh. Tekh. Fiz. 23, 19–25 (October 26, 1997)     

Development of a universal accelerated test for alkali-silica and alkali-carbonate reactivity of concrete aggregates

A universal accelerated test for both alkali-silica and alkali-carbonate reactivity was proposed based on extensive comparative studies on existed Accelerated Mortar Bar Test (AMBT), (e.g., ASTM C1260, CSA A23. 2–25A, RILEM TC191-ARP-AAR02) and Chinese accelerated procedures. A single size fraction of 2.5–5.0 mm aggregate particles is used in the test instead of five-graded requirements in the AMBT, and 0.15–0.80 mm fine particles for ASR, 5–10 mm particles for ACR in existed Chinese accelerated tests. Three short-fat bars, 40 × 40 × 160 mm, made at fixed cement-aggregate ratio of 1:1, and water-cement ratio of 0.33 are used and the length change of the bars is monitored till 28 days in 1 M NaOH solution at 80°C after being soaked in 80°C water for 24 h. Over 40 kinds of aggregates from various origins, which include both ASR and ACR aggregates and show a broad range of reactivity levels in the concrete prism test (CPT), were used to evaluate the reliability of the new test in this study. Experimental results indicate that, for ASR aggregates, the new test gives a better indication than the AMBT does of both the reactive/nonreactive characteristic and reactive levels of almost all tested aggregates based on an acceptance criteria of 0.093% at 14 days, although some very highly reactive aggregates show low expansions relative to the CPT. The “abnormal” low expansion of some highly reactive aggregate in the test is mainly due to the rapid formation and loss of fair amount of low viscosity ASR product into the soaking alkali solution. The results on some typical ACR aggregates usually undetected by the AMBT show that the new test gives the same outcome as using 5–10 mm particles in the Chinese Accelerated Concrete Microbar Test for ACR aggregates and is in agreement with the CPT, which suggests that it has good potentials to be used for ACR aggregate when an expansion criteria of 0.1% after 28 days is used.     

Elevated temperature sliding wear behavior of WCP-reinforced ferrous matrix composites

WC_P-reinforced ferrous matrix composites were processed by direct addition of WC_P (100–150 μm) and the melt of the matrix alloy to a rotating mold at 1000 rpm. Dry sliding wear behaviors of the composites containing about 80 vol.% of WC_P and high-speed steel counterpart were investigated at room temperature and 400 °C against a rotating die steel ring. And wear experiments were performed under loads of 50, 100, and 150 N and a fixed sliding velocity of 30 m/s. Results show that at room temperature, both materials exhibited a marked increase in wear rate with load applied. Wear rates of the composites and high-speed steel under loads of 50, 100, and 150 N at room temperature achieved 1.61 × 10⁻⁶, 2.14 × 10⁻⁶, 3.56 × 10⁻⁶, and 3.11 × 10⁻⁶, 23.08 × 10⁻⁶, 57.39 × 10⁻⁶ g/m, respectively. At a testing temperature of 400 °C, the composites exhibited a marked increase in wear rates and high-speed steel exhibited mild wear (characterized by extremely low wear rates) over the range of loads considered in these experiments. Wear rates of both the composites and high-speed steel at 400 °C achieved 2.42 × 10⁻⁶, 5.19 × 10⁻⁶, 6.64 × 10⁻⁶, and 4.1 × 10⁻⁶, 8.92 × 10⁻⁶, 26.02 × 10⁻⁶ g/m, respectively, under different loads. Finally, the wear-mechanism was discussed in this article.     

Optical properties of laterally aligned Si nanowires for transparent electronics applications

We have investigated the optical properties of laterally aligned Si nanowire (SiNW) arrays in order to explore their potential applicability in transparent electronics. The SiNW array exhibited good optical transparency in the visible spectral range with a transmittance of ∼90% for a NW density of ∼20–25 per 10 μm. In addition, polarization-dependent measurements revealed a variation in transmittance in the range of 80%–95% depending on the angle between the polarization of incident light and the NW axis. Using the SiNWs, we demonstrated that transparent transistors exhibit good optical transparency (greater than 80%) and showed typical p-type SiNW transistor characteristics.      

Microwave dielectric properties of 3Li2O–Nb2O5–3TiO2 ceramics with Li2O–V2O5 additions

A new Li₂O–Nb₂O₅–TiO₂ (LNT) ceramic with the Li₂O:Nb₂O₅:TiO₂ mole ratio of 3:1:3 has been investigated. The compound is composed of two phases, the Li₂TiO₃ and “M-phase” solid solution phase. The microwave dielectric ceramic has low sintering temperature (∼1100 °C) and good microwave dielectric properties of a relatively high permittivity (∼51), high Q × f value up to 8700, and small temperature coefficient (∼37 ppm/°C). The low-amount doping of 0.83Li₂O–0.17V₂O₅ (LV) can effectively lower the sintering temperature from 1100 to 900 °C and induce no obvious degradation of the microwave dielectric properties. Typically, the 1 wt.% LV-doped ceramic sintered at 900 °C has better microwave dielectric properties of ε_r = 51.3, Q × f = 7235 GHz, τ _f  = 22 ppm/°C, which suggests that the ceramics can be applied in microwave LTCC devices.     

Effect of freeze–thaw cycles on the stress–strain curves of unconfined and confined concrete

An experimental research was performed on the complete compressive stress–strain relationship for unconfined and confined concrete after exposure to freeze–thaw cycles. For the unconfined concrete, tests were carried out on three series of prisms specimens (100 mm × 100 mm × 300 mm) with water/cement ratio of 0.60, 0.54 and 0.48 respectively. While for confined concrete, two series of tied columns (150 mm × 150 mm × 450 mm prisms) with confinement index of 0.317 and 0.145 were prepared. Analytical models for the stress–strain relationship of frozen-thawed unconfined and confined concrete were empirically developed respectively. Through the regression analysis, formulations for the main parameters were established, including the compressive strength, peak strain and elastic modulus. Compared with the available experimental data, the proposed models were shown to be applicable to concrete after different numbers of freeze–thaw cycles.     

Solidification microstructure of super-α2 alloy prepared by gas atomization

Ti–25Al–10Nb–3V–1Mo alloy has been prepared by gas atomization with atomizing pressure above 8 MPa. The cooling rate of 5 × 10³ ∼ 3 × 10⁵ K s^-1 was obtained according to secondary dendritic arm spacing, as the particle size is 30 ∼ 300 μm. It is known that in the big particles two dendrite morphologies can be found, cellular dendrite and well-developed dendrite, and in small particles there exists only well-developed dendrite. The surface of particles is characteristic of solidification that is identical to the observation on the cross-sectional views. The micrographs of cross-sectional views show that the big particles, whether of cellular dendrite or well-developed dendrite, solidify by multiple nucleation events while the small particles of well-developed dendrite solidify from a single nucleation event. The microstructure of the alloy consists of single β0 phase. This revised version was published online in November 2006 with corrections to the Cover Date.     

Determination of thermal properties of dilute LiBr-water solutions

We are developing an absorption air cooling system which can supply 2°C chilled water for air cooling by the usage of dilute solutions of LiBr in water with an evaporating temperature of −6°C as a nonfreezing refrigerant. However, there are few published data for the thermal properties of dilute LiBr water solutions (0 to 30%) below 10°C. In this paper, the freezing temperature and the saturated vapor pressure are reported. The results clearly show the possibility of developing a new type of LiBr absorption refrigerating machine to generate evaporating temperatures below 0°C. To obtain accurate data for the design of this new type of absorption refrigerating machine, an apparatus has been developed to measure the thermal properties of dilute LiBr water solutions below 10°C. The experimental arrangement consists of a cooling bath (340×240×190 mm) filled with fluorocarbon, a glass measuring bottle (ϕ120×100 mm), and an absolute pressure gauge (0–1.3 kPa). The accuracy of the temperature, pressure, and density are within ±0.1°C, 0.01 kPa, and ±0.005%, respectively. Paper presented at the Fourth Asian Thermophysical Properties Conference, September 5–8, 1995, Tokyo, Japan.     

Studies on tin oxide films prepared by electron beam evaporation and spray pyrolysis methods

Transparent conducting tin oxide thin films have been prepared by electron beam evaporation and spray pyrolysis methods. Structural, optical and electrical properties were studied under different preparation conditions like substrate temperature, solution flow rate and rate of deposition. Resistivity of undoped evaporated films varied from 2.65 × 10⁻² ω-cm to 3.57 × 10⁻³ ω-cm in the temperature range 150–200°C. For undoped spray pyrolyzed films, the resistivity was observed to be in the range 1.2 × 10⁻¹ to 1.69 × 10⁻² ω-cm in the temperature range 250–370° C. Hall effect measurements indicated that the mobility as well as carrier concentration of evaporated films were greater than that of spray deposited films. The lowest resistivity for antimony doped tin oxide film was found to be 7.74 × 10⁻⁴ ω-cm, which was deposited at 350°C with 0.26 g of SbCl₃ and 4 g of SnCl₄ (SbCl₃/SnCl₄ = 0.065). Evaporated films were found to be amorphous in the temperature range up to 200°C, whereas spray pyrolyzed films prepared at substrate temperature of 300– 370°C were poly crystalline. The morphology of tin oxide films was studied using SEM.     

Characterization of nonwoven structures by spatial partitioning of local thickness and mass density

In this investigation the distributions of local mass, thickness, and density for various nonwoven materials were mapped and analyzed. Non-contacting twin laser profilometry was used to map 10 mm square regions to a resolution of 25 μm. The areal distribution of mass was obtained using β-transmission radiographic imaging. Samples were selected from three common categories: nonwoven hybrids, polymer extruded nonwovens, and wet laid nonwovens. Several samples had embossed regions where the structure was compressed by melt bonding to impart strength. Structural maps were partitioned using binary masks to isolate the embossed features from the stochastic background structure. The joint distributions of thickness versus areal density were plotted and used to characterize the separated regions. Based on the structural distributions obtained from mapped regions, the background structure of most of the samples provided similar results to those observed for other stochastic fibrous web materials, such as paper. The wet laid samples and one spun-bonded extruded polymer nonwoven appeared stochastic with good correlation between local thickness and local areal mass density. In contrast samples with induced features such as embossing, melt bonding, and calendering show that thickness became independent of mass as a result. Examination of the thickness distributions within embossed regions for different samples showed different responses to compression that appeared dependent on material density and thickness.     

Diffusion of promethium in silicon

The first investigations have been made on the diffusion of promethium in silicon. In the temperature range from 1100 to 1250 °C the diffusion constant of promethium increases from ∼1×10⁻¹³ cm²/s to ∼1.5×10⁻¹² cm²/s. The temperature dependence of the diffusion coefficient can be described by D = 5 x 10⁻¹ exp[-(3.3 eV/kT]cm²/s. Pis’ma Zh. Tekh. Fiz. 23, 46–50 (January 26, 1997)     

Emissive characteristics of mesa-stripe lasers (λ=3.0–3.6 μm) made from InGaAsSb/InAsSbP double heterostructures

The directional patterns, current-voltage characteristics, and spectral characteristics of mesastripe lasers with InGaAsSb active layers, emitting at λ=3.0–3.6 μm (77 K) and having threshold currents ≥15 mA (j _th≥200 A/cm²), are investigated. The maximum output power is 1.4 mW (λ∼3.3 μm), the differential quantum efficiency ∼3%(τ=5–30 μs, f=500 Hz) for lasing in a longitudinal mode with beam divergences ΔΘ∥∼15° and ΔΘ ⊥ ∼30°. The relationship of the differential quantum efficiency to the order of the spatial mode of the lasing is demonstrated. A single-mode, current-tunable (−30 cm⁻¹/A) laser is used to measure the transmission of methane in the region of the ν ₃ absorption band. Pis’ma Zh. Tekh. Fiz. 24, 40–45 (June 26, 1998)     

The X-ray Quantum Calorimeter Sounding Rocket Experiment: Improvements for the Next Flight

We have developed a new calorimeter array to increase our collecting area by a factor of four. The 6×6 pixel device has a total area of 144 mm², making it one of the largest X-ray microcalorimeter arrays yet constructed. A relatively thin high-z absorber consisting of a 0.7 μm HgTe layer supported on 15 μm high-purity silicon provides good efficiency up to photon energies of 1.5 keV. The heat capacity of this composite is low enough to obtain an energy resolution of ∼6 eV FWHM on the 2 mm×2 mm pixels when operated at a base temperature of 50 mK. The infrared blocking filters have also been improved. Room temperature radiation must be attenuated by about 9 orders of magnitude between 2 μm and 2 cm to avoid having photon shot noise dominate the detectornoise. Accomplishing this while maintaining a high transmission for very soft X-rays that can penetrate only a few μg cm⁻² is a problem common to all soft X-ray calorimeters that observe external targets. We are constructing monolithic silicon two-layer support meshes with a 350 μm pitch front layer on a 5 mm pitch backing layer. These are 98% open and have >95% effective transmission over a 60° field of view, while providing robust support for 38 mm diameter filters consisting of 20 nm of aluminum on 50 nm of polyimide. Five of these filters in series provide the necessary infrared attenuation. Integral deicing heaters are ion implanted in the fine mesh to remove contamination when necessary.      

Synthesis and electrical properties of Gd<Subscript>2</Subscript>MO<Subscript>5</Subscript> (M = Zr,Hf)

Polycrystalline Gd₂ZrO and Gd₂HfO₅ have been prepared by heat-treating coprecipitated oxide mixtures, and their order-disorder phase transitions have been studied in the range 20–1600°C. The materials have been shown to consist of nanostructured grains with a nanodomain size of ∼40 nm. Their electrical conductivity has been determined by impedance spectroscopy in air between 300 and 1000°C. The 1000°C conductivities of Gd₂ZrO₅ and Gd₂HfO₅ are 3.7 × 10⁻³ and 1.8 × 10⁻³ S/cm, and the respective effective activation energies are 1.37 and 1.56 eV.