共查询到19条相似文献,搜索用时 217 毫秒
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介绍了官能团衍生化、接枝共聚、交联等瓜胶衍生物的制备方法及影响因素、瓜胶及其衍生物在药物控制释放领域的应用现状,并指出改性瓜胶具有比原粉更好的药物控制释放效果,因此经过配方设计,瓜胶及其衍生物有望成为药物控制释放尤其是靶向结肠给药领域的理想载体。 相似文献
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《精细化工原料及中间体》2009,(4)
羟丙基瓜儿胶属高分子非离子表面活性剂,是由天然瓜儿胶经环氧丙烷改性的产品。本产品具有良好的交联性,充分考虑了分子量、取代度、交联性之间的关系,具有良好的性能。可用作化妆品及油田助剂,也可用作纺织印染助剂等。 相似文献
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以羟丙基瓜胶和甜菜碱单体为原料,硝酸铈铵为引发剂,采用溶液聚合法制备甜菜碱接枝羟丙基瓜胶,对目标物结构进行了IR、质谱表征。考察了接枝反应温度、接枝反应时间、引发剂浓度、原料配比对目标产物增稠性能的影响,结果表明,当反应温度为20℃,引发剂浓度为5 mmol/L,反应时间为24 h,m(甜菜碱单体)∶m(羟丙基瓜胶)=1∶1时,单体转化率为36.5%,相对分子质量为1.28×10~6;常温下,配制目标产物质量分数0.5%的水溶液,20 min内充分溶解,初始黏度为75 m Pa·s;目标产物耐盐性优于羟丙基瓜胶,水溶性和增稠性良好。 相似文献
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研究了一种能粘多种材质的溶剂型鞋用大底胶。该胶为一种聚氨酯改性氯丁、SBS接枝胶,粘接范围广,对PU、TPR、SBS等材质粘接性能比氯丁接枝胶好,适合鞋厂流水生产线;所用溶剂毒性相当低,对人无害,有利于劳动保护和环境保护。 相似文献
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Commonly used crosslinker agents often have a low crosslinking efficiency with guar gum, the major component of fracturing fluid for crude oil recovery, and it often required a high loading of guar gum for achieving desired recovery from low-permeability reservoir. Nevertheless, a high-loading of guar gum might result in excessive residue and reduce the conductivity of the reservoir. Therefore, boric acid, a commonly used crosslinking agent, was introduced onto the surface of pentaerythritol to afford a composite crosslinking agent denoted as PB. The as-prepared PB crosslinker was characterized by Fourier-transform infrared spectrometry. The guar gum fracturing gel crosslinked with the PB had fantastic viscoelasticity and thermal stability and could reduce the guar gum loading by 16.7%, with boric acid as a control. Besides, the gel-broken liquid had good compatibility with the simulated water and caused reduced damage to rock core, showing potential for hydraulic fracturing of low-permeability reservoirs. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48528. 相似文献
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Guofu Ma Enke Feng Feitian Ran Zhibao Dong Ziqiang Lei 《Polymer-Plastics Technology and Engineering》2015,54(7):703-710
A novel guar gum/poly(acrylic acid)/loess (GG-g-PAA/loess) organic-inorganic composite used as chemical sand-fixing agent (CSFA) is successfully prepared in aqueous solution by polymerization guar gum (GG), neutralized acrylic acid (AA) and loess. The correlations between the content of prepared composite and the sand-fixing properties are investigated. The results show that the CSFA can significantly improve the compressive strength of the sand fixation specimens. Meanwhile, the sand fixation specimens have good thermal, freeze-thaw and UV-radiation aging stabilities to withstand the changes in temperature and strong UV radiation. Besides, the specimens treated with sand-fixing agent shows excellent water retention capacity. 相似文献
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有机锆对羧甲基羟丙基瓜胶的交联性能研究 总被引:1,自引:0,他引:1
以氧氯化锆和柠檬酸等为原料,合成了适用于羧甲基羟丙基瓜胶在酸性条件下交联的有机锆交联剂,考察了pH值、温度、羧甲基羟丙基瓜胶和交联剂加量等对体系成胶时间的影响,评价了形成冻胶的抗温抗剪切性能、滤失性能和破胶性能.实验发现,在pH值为3.0时,羧甲基羟丙基瓜胶/有机锆体系具有可控的延缓交联特性,质量分数为0.5%和0.6... 相似文献
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Gamma ray induced synthesis of Ag clusters in the aqueous medium has been carried out using natural polysaccharide guar gum as a stabilizer. The results showed that guar gum is very effective in binding the Ag clusters and restricts their size in the nano region. The surface plasmon resonance band in the wavelength range of 410–425 nm of visible region has confirmed the formation of Ag clusters. The size of the clusters is governed by the concentration of both, i.e. precursor Ag+ and guar gum. The clusters were characterized by TEM and XRD, which shows that the size of clusters is in the range of 10–30 nm. The results have shown that silver clusters stabilized by guar gum are stable in acid media and alkaline media is not a desired media for the synthesis. From thermogravimetric analysis it has been demonstrated that incorporation of nano sized Ag clusters within guar gum improves the thermal properties of irradiated guar gum. To the best of our knowledge, the use of guar gum as a stabilizer in the gamma ray induced synthesis of Ag nano clusters is being reported first time in the literature. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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羧甲基瓜尔胶絮凝剂的合成及其絮凝性能研究 总被引:3,自引:0,他引:3
以植物瓜尔胶为原料,采用半干法快速合成了羧甲基瓜尔胶,研究了合成反应温度、氯乙酸量、碱量等因素对其取代度的影响,得到了最佳合成工艺条件:瓜尔胶、氯乙酸、氢氧化钠的质量比为1.6∶1.2∶1,反应温度为70℃,反应时间为1h,室温搅拌20min。在最佳合成条件下,羧甲基瓜尔胶的取代度为0.51,黏度为3960mPa·s,采用红外光谱、热重分析等测试方法分析羧甲基瓜尔胶的结构及热稳定性,并将其应用于微污染水源水的强化处理工艺中,试验结果表明:羧甲基瓜尔胶对浊度的去除率可达90%以上。 相似文献
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Jeong Hee Kim Hye Jo Min Kun Park Jin Kim 《Korean Journal of Chemical Engineering》2017,34(8):2236-2240
Guar gum is an effective agent for use as a natural adhesive ingredient that can be used to replace the hazardous ingredients of spirit gum. This study describes the possibility of using guar gum as a renewable substituent for cosmetic adhesive. An adhesive base and cosmetic adhesive containing guar gum were prepared by a two-step process. The samples were tested for safety (cell toxicity test and patch test), stability (centrifugation, cycling and viscosity), and effectiveness (tensile strength). The results from the MTT assay show that the growth activity of human fibroblast skin cells was over 89% in all concentrations of cosmetic adhesive containing guar gum. In addition, no special skin reactions were reported in the patch test prepared adhesive containing guar gum. Moreover, the stability test demonstrated proper stability of all adhesive samples: the composition stability, heat stability, and viscosity of the adhesive samples maintained stable conditions. The efficacy test confirmed the superiority of the guar gum adhesive samples over spirit gum concerning the tensile strength. This study demonstrated that guar gum may be a viable replacement for synthetic rosins and also as a substituent in cosmetic. 相似文献