Geochemical evidence of drawdown in the Cerro Prieto geothermal field

Some wells of the Cerro Prieto geothermal field have undergone changes in the chemistry of fluids produced which reflect reservoir processes. Pressure decreases due to production in the southeastern part of the field have produced both drawdown of lower chloride fluids from an overlying aquifer and boiling in the aquifer with excess steam reaching the wells. These reservoir changes are indicated by changes in fluid chloride concentrations, Na/K ratios and measured enthalpies and by comparisons of aquifer fluid temperatures and chloride concentrations calculated from enthalpy and chemical measurements. Fluid temperatures have not been greatly affected by this drawdown because heat contained in the rock was transferred to the fluid. When this heat is exhausted, fluid temperatures may drop rapidly.     

Regional and local networks of horizontal control, Cerro Prieto geothermal area

The Cerro Prieto geothermal area in the Mexicali Valley 30 km southeast of Mexicali, Baja California, is probably deforming due to (1) the extraction of large volumes of steam and hot water, and (2) active tectonism. Two networks of precise horizontal control were established in Mexicali Valley by the U.S. Geological Survey in 1977 – 1978 to measure both types of movement as they occur. These networks consisted of (1) a regional trilateration net brought into the mountain ranges west of the geothermal area from survey stations on an existing U.S. Geological Survey crustal-strain network north of the international border, and (2) a local net tied to stations in the regional net and encompassing the area of present and planned geothermal production. Survey lines in this net were selected to span areas of probable ground-surface movements in and around the geothermal area.Electronic distance measuring (EDM) instruments, operating with a modulated laser beam, were used to measure the distances between stations in both networks. The regional net was run using a highly precise long-range EDM instrument, helicopters for transportation of men and equipment to inaccessible stations on mountain peaks, and a fixed wing airplane flying along the line of sight. Precision of measurements with this complex long-range system approached 0–2 ppm of line length. The local net was measured with a medium-range EDM instrument requiring minimal ancillary equipment. Precision of measurements with this less complex system approached 3 ppm for the shorter line lengths.The detection and analysis of ground-surface movements resulting from tectonic strains or induced by geothermal fluid withdrawal is dependent on subsequent resurveys of these networks.     

Isotopic evidence for magmatic and meteoric water recharge and the processes affecting reservoir fluids in the palinpinon geothermal system, Philippines

Stable isotopic compositions of meteoric and geothermal waters indicate that the Palinpinon geothermal system of Southern Negros is fed by a parent water that originated from a mixture of local meteoric (80%) and magmatic (20%) waters. The meteoric water has an isotopic concentration of −8.5‰ and −54‰ in ¹⁸O and ²H, respectively, which corresponds to an average infiltration altitude of about 1000 m above sea level. With exploitation of the system and injection of wastewaters to the reservoir, the stable isotopic composition became heavier due to significant mixing of geothermal fluids with injection waters. Incursion of cooler meteoric waters, which is confirmed by the presence of tritium, also leads to the formation of acid-sulfate waters. Stable isotopes are effective as “natural tracers” to determine the origin and mixing of different fluids in the reservoir.     

Isotopic and chemical composition of parbati valley geothermal discharges, North-West Himalaya, India

The isotopic compositions of the waters discharged from Parbati Valley geothermal areas indicate a higher altitude meteoric origin, with discharge temperatures reflecting variations in the depth of penetration of the waters to levels heated by the existence of a ‘normal’ geothermal gradient. On the basis of mixing models involving silica, tritium, discharge temperatures and chloride contents, deep equilibration temperatures of 120–140°C were obtained for Manikaran, possibly reaching 160°C at even greater depth. Geothermometers based on sulfate-water ¹⁸O exchange and gas reactions point to similar temperatures. Exceptionally high helium contents of the discharges correspond to apparent crustal residence times of the waters in the order of 10–100 Ma; relative nitrogen-argon contents support a largely meteoric origin of the waters with a possible fossil brine, but no detectable magmatic component.     

Hydrothermal mineral zones in the geothermal reservoir of Cerro Prieto

Detailed petrologic studies completed to date on ditch cuttings and core from 23 wells in the Cerro Prieto field have led to recognition of regularly distributed prograde metamorphic mineral zones. The progressive changes in mineralogy exhibit a systematic relationship with reservoir temperature.The Cerro Prieto reservoir consists of a series of sandstones, siltstones, and shales composing part of the Colorado River delta. The western part of the field contains relatively coarser sediments apparently also derived from the delta and not from the basin margins as formerly thought. The most abundant detrital minerals in the sediments include quartz, feldspar, kaolinite, montmorillonite, illite, chlorite, mixed-layer clays, calcite, dolomite and iron hydroxides. Some of these minerals were also formed diagenetically.The following progressive stages of post-depositional alteration in response to increasing temperature have been observed: (1) diagenetic zone (low temperature), (2) illite-chlorite zone (above ~ 150°C), (3) calc-aluminum silicate zone (above ~ 230°C) and the biotite zone (above ~ 325°C). These zones are transitional to some degree and can be further subdivided based on the appearance or disappearance of various minerals.One immediate application of these studies is the ability, from a study of cuttings obtained during drilling of a well, to predict the temperatures which will be observed when the well is completed.     

Fluid-inclusion evidence for past temperature fluctuations in the Kilauea East Rift Zone geothermal area, Hawaii

Heating and freezing data were obtained for fluid inclusions in hydrothermal quartz, calcite, and anhydrite from several depths in three scientific observation holes drilled along the lower East Rift Zone of Kilauea volcano, Hawaii. Compositions of the inclusion fluids range from dilute meteoric water to highly modified sea water concentrated by boiling. Comparison of measured drill-hole temperatures with fluid-inclusion homogenization-temperature (T_h) data indicates that only about 15% of the fluid inclusions could have formed under the present thermal conditions. The majority of fluid inclusions studied must have formed during one or more times in the past when temperatures fluctuated in response to the emplacement of nearby dikes and their subsequent cooling. The fluid-inclusion data indicate that past temperatures in SOH-4 well were as much as 64°C hotter than present temperatures between 1000 and 1500 m depth and they were a maximum of 68°C cooler than present temperatures below 1500 m depth. Similarly, the data show that past temperatures near the bottoms of SOH-1 and SOH-2 wells were up to 45 and 59°C, respectively, cooler than the present thermal conditions; however, the remainder of fluid-inclusion T_h values for these two drill holes suggest that the temperatures of the trapped waters were nearly the same as the present temperatures at these slightly shallower depths. Several hydrothermal minerals (erionite, mordenite, truscottite, smectite, chlorite-smectite, chalcedony, anhydrite, and hematite), occurring in the drill holes at higher temperatures than they are found in geothermal drill holes of Iceland or other geothermal areas, provide additional evidence for a recent heating trend.     

Geochemical evidence of chemical equilibria in the South Meager Creek geothermal system, British Columbia, Canada

Meager geothermal reservoir appears to be in “thermochemical” equilibrium as indicated by constant ion-concentration ratios (B/Li, B/K, Na/Li, Na/CI etc.). The Na/Li ratio describes the thermal conditions of the first and the deepest equilibrium reached by the thermal waters, whereas the Na/K indicates a secondary and shallower equilibrium. Analysis of the correlations between K, Na and CI indicate that discharge from well MC1 is probably a mixture between a single brine and high-chloride cool waters.     

Distribution of hydrothermal mineral zones in the Cerro Prieto geothermal field of Baja California, Mexico

Our ongoing studies of water-rock interaction at Cerro Prieto have now been extended to include samples from 40 wells. We have confirmed the regular sequence of progressive hydrothermal alteration zones previously described, and have mapped these alteration zones across the geothermal field. Our earlier work showed the relationships between hydrothermal mineralogy, temperature and permeability, in that alteration occurs at lower temperature in sandstone than in the less permeable shales. The effects of chemical parameters such as silica activity and differences in CO₂ fugacity have also become apparent when mineral assemblages are compared in sandstones from different wells at the same temperature. A rather complete picture of the shape of the reservoir and the nature of its boundaries is developing, and we have begun to identify patterns in the observed hydrothermal mineral zonations which are characteristic of different temperature gradients. We infer such different gradients to be indicative of different parts of the hydrothermal flow regime. In certain wells mineral zones are closely spaced, indicating steep thermal gradients, while in others they are much farther apart. We believe that patterns characteristic of recharge, discharge and upwelling zones as well as areas of primarily horizontal flow can be recognized.The geothermal circulation system at Cerro Prieto appears to be rather young and shows no indication of retrograde reactions due to cooling. The pattern of fluid flow does not seem to be significantly affected by faults, stratigraphic horizons or by the presence of a cap-rock. The mineral zones define a thermal dome which is apparently fed from the east and spreads westward.     

Vitrinite reflectance geothermometry and apparent heating duration in the Cerro Prieto geothermal field

Vitrinite reflectance measured in immersion oil (R_o) on kerogen extracted from hydrothermally altered mudstones in borehole M-84 at the Cerro Prieto geothermal field exhibit an increase in mean reflectance ( ) from 0.12 per cent at 0.24 km depth to 4.1 per cent at 1.7 km depth. Downhole temperatures measured over this interval increase from about 60° to 340°C. These data plotted against temperature fall along an exponential curve with a coefficient of determination of about 0.8. Other boreholes sampled in the field show similar relationships. A regression curve calculated for temperature and in borehole M-105 correctly predicts temperatures in other boreholes within the central portion of the geothermal system. The correlation between the reflectance values and logged temperature, together with consistent temperature estimates from fluid inclusion and oxygen isotope geothermometry, indicates that changes in are an accurate and sensitive recorder of the maximum temperature attained. Therefore, vitrinite reflectance can be used in this geothermal system to predict the undisturbed temperature in a geothermal borehole during drilling before it regains thermal equilibrium. Although existing theoretical functions which relate to temperature and duration of heating are inaccurate, empirical temperature- curves are still useful for geothermometry.A comparison of temperature- regression curves derived from nine boreholes within the Cerro Prieto system suggests that heating across the central portion of the field occurred penecontemporaneously, but varies near margins. Boreholes M-93 and M-94 appear to have cooled from their maximum temperatures, whereas M-3 and Prian-1 have only recently been heated.Comparison of the temperature- data from the Salton Sea, California, geothermal system indicates that the duration of heating has been longer there than at the Cerro Prieto field.     

Oxygen and carbon isotope studies of calcite from the Cerro Prieto geothermal field

The inferences derived from oxygen and carbon isotope data for calcite samples from the Cerro Prieto geothermal field depend on the sample type. The δ¹⁸O values for calcite in sandstone provide a reliable basis for estimating stable reservoir temperatures and the δ¹⁸O values for calcite in shale can be related to the extent and spatial distribution of subsurface flow. The δ¹⁸O values for vein calcite record short-lived polythermal fracture-filling episodes at temperatures that may differ from those in the adjacent stable reservoir. The oxygen isotope data for shales indicate a minimum water - rock volume ratio of 2:1. Even this high flow was greatly exceeded in sandstones, with the result that the reservoir fluids are isotopically well-mixed and of relatively low salinity.     

Rock-water interactions in the Fenton Hill, new Mexico, hot dry rock geothermal systems I. fluid mixing and chemical geothermometry

The chemistry of fluids circulated through an artificially-stimulated, hot dry rock (HDR) fractured geothermal reservoir system in granitic rock is described in terms of mixing phenomena, geothermometry, and approach to saturation with reservoir rock minerals. Based on the similar dynamic behavior of Na⁺, K⁺, Li⁺, CI⁻, and B species and other isotopic evidence, the presence of a concentrated in-situ pore fluid was identified. Mixing and displacement of this in-situ fluid with meteoric make-up water is responsible for the observed behavior of the major dissolved species in the circulated fluid of this HDR system.     

Isotopic zoning and origin of the aquifers in the discharge area of the geothermal fields of ahuachapán and Chipilapa, El Salvador

The northern discharge areas of the Ahuachapán, and Chipilapa geothermal fields can be subdivided into four different zones based on their structural position, and the isotopic and chemical composition of their waters. In general, the contribution of geothermal waters from these two fields was estimated to be less than 10%. Elevation effects are of little importance, whereas a slight trend towards higher isotopic values with increasing water temperatures may exist.The NNW-SSE-trending Escalante and Agua Caliente faults represent lateral groundwater barriers, and provide vertical conduits for the ascending geothermal waters. The western discharge areas seem to be more influenced by the Ahuachapán, geothermal field, whereas those to the east are more influenced by the Chipilapa field.Groundwaters in the Northern Plain are mainly from shallow northward-flowing aquifers. These waters show temperature effects, mixing with geothermal waters and are affected by the geology of the area. However, none of these factors alone can explain the isotopic variations observed in the waters of the northern discharge areas.     

The Geysers-Clear Lake geothermal area, California—An updated geophysical perspective of heat sources

The Geysers-Clear Lake geothermal area encompasses a large dry-steam production area in The Geysers field and a documented high-temperature, high-pressure, water-dominated system in the area largely south of Clear Lake, which has not been developed. Both systems have been extensively studied with geophysical techniques, drilling, and geological mapping during the past 20 years. An updated view is presented of the geological/geophysical complexities of the crust in The Geysers-Clear Lake region in order to address key unanswered questions about the heat source and tectonics. Early geophysical interpretations used a gravity low centered in the area between Clear Lake and The Geysers to suggest that a large magma chamber existed at depths starting at about 7 km. This first-order assumption of a large magma chamber expressed in the gravity data was used as a guide in subsequent geophysical and geological interpretations. Drill-hole temperature evidence is strongly suggestive of a shallow, hot-intrusive body, but in this paper the complexities are documented of the geological and geophysical data sets that make it difficult to pinpoint the location of “magma” or hot, solidified intrusive material. Forward modeling, multidimensional inversions, and ideal body analysis of the gravity data, new electromagnetic sounding models, and arguments made from other geophysical data sets suggest that many of the geophysical anomalies have significant contributions from rock property and physical state variations in the upper 7 km and not from ”magma“ at greater depths. Regional tectonic and magmatic processes are analyzed to develop an updated scenario for pluton emplacement that differs substantially from earlier interpretations. In addition, a rationale is outlined for future exploration for geothermal resources in The Geysers-Clear Lake area.     

Hot spring activity in the Dakongbeng geothermal area, China

The Dakongbeng geothermal area, whose hot springs reach a temperature of up to 96°C, has been considered one of the potential high-temperature hydrothermal systems in south-west China. The concentration of dominant cations and anions indicates an NaHCO₃ type of thermal water, whose major constituents in decreasing order are: Na>K>Ca>Mg, HCO₃>SiO₂>Cl>SO₄. On the basis of the silica geothermometer, cation geothermometers, gas geothermometer and activity diagram, the reservoir temperature is estimated at about 200°C. All the thermal waters have originated from meteoric water of a higher altitude that circulated as ground water at considerable depth along faults. The stability of their contents of Cl, SiO₂, δD, δ¹⁸O and of the Cl/B, Na/Li ratios suggests that the main heat loss process is through steam loss. The geochemistry of the initial liquid has been estimated by single and continuous steam loss. On the basis of its geologic and geographic setting, the Dakongbeng geothermal area appears to belong to the Himalayan geothermal belt and is thus regarded as an area of interest for further study.     

Geochemistry of the high-salinity geothermal field of Asal,Republic of Djibouti,Africa

In 1987–1988 deep exploratory geothermal wells were drilled in the Asal Rift in the Republic of Djibouti. The salinity of the brines produced in the Asal field exceeded 100 000mg/kg, with a low gas content of the order of 0.6 mmol/mol. Measured temperatures in the producing zones and at wellbottom vary from about 260 to 359°C. The sphalerite and galena scaling observed in producing wells starts at the flash level located at about 850 m depth. The calculated geochemical temperatures are close to 260°C, which is the average temperature of the main reservoir located at depths between 1000 and 1300 m. As a result of sulphide precipitation, about 90% of H₂S is removed from the original fluid before discharge. The computed composition of the brine at reservoir conditions is compatible with the presence of stable phases of epidote, (MgFe)-chlorite, albite, K-feldspar, K-mica, pyrite and anhydrite. The main recharge water is seawater.     

Fluid-inclusion evidence for previous higher temperatures in the miravalles geothermal field, Costa Rica

Heating and freezing data were obtained for liquid-rich secondary fluid inclusions in magmatic quartz, hydrothermal calcite and hydrothermal quartz crystals from 19 sampled depths in eight production drill holes (PGM-1, 2, 3, 5, 10, 11, 12 and 15) of the Miravalles geothermal field in northwestern Costa Rica. Homogenization temperatures for 386 fluid inclusions range from near the present measured temperatures to as much as 70°C higher than the maximum measured well temperature of about 240°C. Melting-point temperature measurements for 76 fluid inclusions suggest a calculated salinity range of about 0.2–1.9 wt% NaCl equivalent. Calculated salinities as high as 3.1–4.0 wt% NaCl equivalent for 20 fluid inclusions from the lower part of drill hole PGM-15 (the deepest drill hole) indicate that higher salinity water probably was present in the deeper part of the Miravalles geothermal field at the time these fluid inclusions were formed.     

Hydrogeologic reconnaissance of the beowawe geysers geothermal area,Nevada

The Beowawe Geysers in north-central Nevada are the discharge from a hydrothermal-convection system in a region of high heat flow. The site of thermal-fluid upflow (at about 18 kg/s before drilling and well testing) appears to be related to the intersection at depth of two major fault zones. Assuming steady-state conditions, recharge within the drainage basin could account for both thermal and nonthermal ground-water discharge. Circulation of thermal fluid to depths exceeding 5 km is required to attain estimated temperatures of more than 220°C.     

Potential use of geothermal energy sources for the production of lithium-ion batteries

The lithium-ion battery is one of the most promising technologies for energy storage in many recent and emerging applications. However, the cost of lithium-ion batteries limits their penetration in the public market. Energy input is a significant cost driver for lithium batteries due to both the electrical and thermal energy required in the production process. The drying process requires 45–57% of the energy consumption of the production process according to a model presented in this paper. The model is used as a base for quantifying the energy and temperatures at each step, as replacing electric energy with thermal energy is considered. In Iceland, it is possible to use geothermal steam as a thermal resource in the drying process. The most feasible type of dryer and heating method for lithium batteries would be a tray dryer (batch) using a conduction heating method under vacuum operation. Replacing conventional heat sources with heat from geothermal steam in Iceland, we can lower the energy cost to 0.008USD/Ah from 0.13USD/Ah based on average European energy prices. The energy expenditure after 15 years operation could be close to 2% of total expenditure using this renewable resource, down from 12 to 15% in other European countries. According to our profitability model, the internal rate of return of this project will increase from 11% to 23% by replacing the energy source. The impact on carbon emissions amounts to 393.4–215.1 g/Ah lower releases of CO₂ per year, which is only 2–5% of carbon emissions related to battery production using traditional energy sources.     

Geophysical investigations of the Seferihisar geothermal area, Western Anatolia, Turkey

Self-potential (SP), magnetic and very low frequency electromagnetic (EM-VLF) surveys were carried out in the Seferihisar geothermal area to identify major and minor fault zones and characterize the geothermal system. The SP study provided useful information on the local faults and subsurface fluid flow. The main SP anomalies appear mostly along and near active fault zones in the area of the Cumalı, Tuzla and Doğanbey hot springs. Two of these anomalies near the Tuzla hot springs were further evaluated by SP modelling. Total magnetic field values increase from the Doğanbey to the Cumalı hot springs. Modelling performed on the magnetic data indicates that between these two spring areas are four different regions or units that can be distinguished on the basis of their magnetic susceptibility values. Fraser filtering of EM-VLF data also indicates that there are three significant conductive zones in the regions around the Cumalı, Tuzla and Doğanbey hot springs, and that they lie between important fault systems. The EM-VLF and total (stacked) SP data show that the conductive tilt anomalies obtained by Fraser filtering generally coincide with negative SP areas.According to our geophysical investigations, new exploratory wells should be drilled into the conductive zones located between the Cumalı and Tuzla hot springs. We further recommend that resistivity and magnetotelluric methods be carried out in the area to obtain additional information on the Seferihisar geothermal system.