Ti离子辐照诱发焦绿石Gd2Zr2O7相变的电子显微研究

通过高分辨和剖面电子显微技术研究了离子注入在单晶焦绿石Gd2Zr2O7中的产生的结构相变.在单晶Gd2Zr2O7中注入200keV Ti+离子,注量为1×1017ions/cm2,注入温度为常温.电子显微研究表明,1×1017ions/cm2的Ti+离子注入没有使样品非晶化,而是诱发了单晶Gd2Zr2O7从焦绿石结构转变成萤石结构.从高分辨像和选区电子衍射花样发现Gd3+和Zr3+发生了阳离子无序.重离子入射产生的级联碰撞致使阳离子无序被认为是相变发生的物理机制.     

Optical and DSC studies of the Na2B4O7-Pb3O4 glass system

A series of glass samples were prepared from admixtures of Na₂B₄O₇ and Pb₃O₄ and results are reported for optical absorption, infrared absorption spectra and differential scanning calorimetry (DSC) as a function of lead content up to 40mol%. It is found that the addition of lead oxide decreases the optical energy gap and shifts the optical absorption edges towards lower energies in the range from 4.96 to 3.29 eV. The addition of lead oxide does not seem to introduce any new absorption band as compared with the infrared spectrum of pure sodium tetraborate glass.     

Solvothermal synthesis of Mn2P2O7 and its application in lithium-ion battery

Manganese pyrophosphate, Mn₂P₂O₇ was synthesized by a simple solvothermal method using Mn metal powder and P₂S₅ in ethylene glycol medium at 190–220 °C. Morphology and crystalline structure of the products were characterized by X-ray diffraction and scanning electron microscopy. The flower-like microspheres with diameters of about 2–5 μm are composed of a number of nanoplatelets with thickness of 20–40 nm. The effect of reaction temperature and reaction time on the microstructure of Mn₂P₂O₇ was investigated. The samples were used as active anode materials for lithium-ion battery and their electrochemical properties were examined by constant current charge–discharge cycling. The Mn₂P₂O₇ electrodes exhibited initial reversible capacities of 440–330 mAh g^? 1 depending on the synthetic conditions. From these results, a possible reaction mechanism of Mn₂P₂O₇ with lithium was proposed.     

Raman spectroscopy study of the phase transformations of LiB3O5 and Li2B4O7 during heating and melting

The incongruent melting of LiB₃O₅ (LBO) single crystals and transformations of the boron-oxygen groups in glasses and melts with the compositions Li₂O · 2B₂O₃ and Li₂O · 3B₂O₃ have been studied by Raman spectroscopy. The vapor over superheated melts of these condensed lithium borates has been shown to contain [BO₂] radicals.     

Influence of CuO addition to BaSm2Ti4O12 microwave ceramics on sintering behavior and dielectric properties

Microwave dielectric ceramics of tungsten–bronze-type BaSm₂Ti₄O₁₂ were prepared by doping CuO (up to 2 wt.%) as the liquid-phase sintering aid. The effects of CuO additive on the densification, micro structure and dielectric properties were investigated. Due to the liquid-phase effect, the sintering temperature of BaSm₂Ti₄O₁₂ ceramics with 1 wt.% CuO addition can be effectively reduced to 1160 °C, about 200 °C lower than that of pure BaSm₂Ti₄O₁₂ ceramics, while good microwave dielectric properties of ɛ_r = 75.8, Q*f = 4914.6 GHz and τ_f = −7.65 ppm/°C were still achieved.     

Preparation and luminescence properties of novel K2ZnP2O7: Mn2+ green phosphor

Novel green-emitting phosphors K₂Zn_1???xP₂O₇: x mol% Mn²⁺ have been successfully prepared using classical solid-state reaction method in air atmosphere, doped by different Mn²⁺ ion contents, namely x?=?0.5, 1, 1.25 and 1.5 mol%. The samples were characterized by the thermogravimetric (ATD/ATG/DSC), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), steady and time-resolved photoluminescence techniques. It was found that all K₂Zn_1???xP₂O₇: x mol% Mn²⁺ samples crystallize in the tetragonal phase with P4₂/mnm space group. Upon 425 nm excitation, K₂ZnP₂O₇: Mn²⁺ exhibits an intense broad green asymmetric emission band peaking at 520 nm, owing to the ⁴T₁→⁶A₁(⁶ S) transition of Mn²⁺ ion in K₂ZnP₂O₇. In addition, it is suggested that Mn²⁺ ions occupy more than one symmetry site in the host K₂ZnP₂O₇. The optimal Mn²⁺ ion concentration in K₂ZnP₂O₇:Mn²⁺ phosphor is 1 mol % and with the lifetime 9.81 ms.

     

0.64BaTi4O9-0.36BaEu2Ti4O12/BaTi4O9纤维复合陶瓷的介电性研究

对0.64BaTi4O9-0.36BaEu2Ti4O12/BaTi4O9纤维复合陶瓷新材料的相组成、介电性能和样品表面原子的化学组成及Ti元素的价态变化进行了研究.研究结果表明该复合陶瓷新材料只由BaTi4O9和BaEu2Ti4O12两相组成.加入BaTi4O9纤维后,复合陶瓷材料中Ti3+离子和Ti2+离子的含量降低,氧元素的含量提高,并且BaTi4O9纤维对该材料体系的介质损耗有明显的改善作用,其中含10vol%BaTi4O9纤维的BET10试样的性能最佳,其εr=55,tgδ=3×10-4(在1MHz条件下).     

VOC2O4·H2O热分解制备纳米VO2粉体及相变特性

提出了一种采用草酸氧钒(VOC2O4·H2O)热分解制备纳米VO2的方法.通过热分析(TG-DSC)、XRD和TEM手段,分析了草酸氧钒前驱体的热分解过程,纳米VO2的结构和形貌,测定了纳米VO2粉体的电阻-温度曲线.实验结果表明VOC2O4·H2O热分解开始温度为343℃,在380℃,真空度为20～50Pa的条件下,热分解获得VO2的平均尺寸为22nm,相变温度为69℃.     

Structure and Thermodynamic Properties of the DyGaTi2O7 and EuGaTi2O7 Titanates

Inorganic Materials - The DyGaTi2O7 and EuGaTi2O7 titanates have been prepared by solid-state reactions in a starting mixture of Dy2O3 (Eu2O3), Ga2O3, and TiO2 via firing in air at temperatures of...     

A Study of Structural and Physical Properties of Heavily Co-doped LaSr2Mn2O7 Bi-layered Manganite

In this paper, we report the influence of cobalt doping on the structure and magnetic properties of bilayered-perovskite LaSr₂Mn_2?x Co _x O₇ (x=0.25,0.3). Parent and doped samples were synthesized through the sol-gel method under optimized conditions. X-ray diffraction studies coupled with the Rietveld refinement of xrd data, show that both doped and parent samples crystallize in a Sr₃Ti₂O₇-type layered perovskite structure. Temperature dependent magnetic behavior of the parent sample exhibits an antiferromagnetic and a charge-ordering state around 220 K. Magnetic field dependence of magnetization M(H) for doped samples at 20 K show well-defined M–H loops confirming the formation of intrinsic ferromagnetic ordering due to the Co doping. Additionally, we studied the ac–magnetic susceptibility and magnetization relaxation process in our samples. Dynamic scaling analysis hints an existence of glassy magnetic states in doped samples. Electrical and magnetic properties of our samples further demonstrate that Co doping suppresses charge ordering in bilayered LaSr₂Mn₂O₇.