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1.
A new type of inorganic‐polymer hybrid materials of epoxy/silica‐titania had been prepared by incorporating grafted epoxy, which had been synthesized by epoxy and tetraethoxysilane (TEOS), with highly reactive TEOS and tetrabutyltitanate (TBT) by using the in situ sol–gel process. The grafted epoxy was confirmed by Fourier transform infrared spectroscopy (FT‐IR) and 1H‐NMR spectroscopic technique. Results of FT‐IR spectroscopy and atomic force microscopy (AFM) demonstrated that epoxy chains have been covalently bonded to the surface of the SiO2‐TiO2 particles. The particles size of SiO2‐TiO2 are about 20–50 nm, as characterized by AFM. The experimental results showed that the glass‐transition temperatures and the modulus of the modified systems were higher than that of the unmodified system, and the impact strength was enhanced by two to three times compared with that of the neat epoxy. The morphological structure of impact fracture surface and the surface of the hybrid materials were observed by scanning electron microscopy and AFM, respectively. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1075–1081, 2006 相似文献
2.
Organic‐acid‐catalyzed sol–gel route for preparing poly(methyl methacrylate)–silica hybrid materials
Jui‐Ming Yeh Kuan‐Yeh Huang Chung‐Feng Dai B. G. Chand Chang‐Jian Weng 《应用聚合物科学杂志》2008,110(4):2108-2114
In this study, a series of organic–inorganic hybrid sol–gel materials consisting of a poly(methyl methacrylate) (PMMA) matrix and dispersed silica (SiO2) particles were successfully prepared through an organic‐acid‐catalyzed sol–gel route with N‐methyl‐2‐pyrrolidone as the mixing solvent. The as‐synthesized PMMA–SiO2 nanocomposites were subsequently characterized with Fourier transform infrared spectroscopy and transmission electron microscopy. The solid phase of organic camphor sulfonic acid was employed to catalyze the hydrolysis and condensation (i.e., sol–gel reactions) of tetraethyl orthosilicate in the PMMA matrix. The formation of the hybrid membranes was beneficial for the physical properties at low SiO2 loadings, especially for enhanced mechanical strength and gas barrier properties, in comparison with the neat PMMA. The effects of material composition on the thermal stability, thermal conductivity, mechanical strength, molecular permeability, optical clarity, and surface morphology of the as‐prepared hybrid PMMA–SiO2 nanocomposites in the form of membranes were investigated with thermogravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis, gas permeability analysis, ultraviolet–visible transmission spectroscopy, and atomic force microscopy, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
3.
Jui‐Ming Yeh Chi‐Fa Hsieh Chia‐Wen Yeh Mei‐Jyun Wu Hsing‐Chung Yang 《Polymer International》2007,56(3):343-349
A series of sol–gel‐derived organic–inorganic hybrid materials that comprise organic poly(methyl methacrylate) (PMMA) and inorganic silica (SiO2) was successfully prepared using aniline as an organic base catalyst to catalyze the sol–gel reactions of tetraethylorthosilicate (TEOS). Aniline was adopted not only as a catalyst but also as a dispersing agent during the preparation of the hybrid materials. The as‐prepared hybrid materials were then characterized using transmission electron microscopy, SEM/energy dispersive X‐ray spectroscopy and Fourier transform infrared spectroscopy. The characteristic temperatures (including Td and Tg) of the hybrid materials slightly exceeded those of neat PMMA, as revealed from thermogravimetric analysis and differential scanning calorimetry evaluations. Studies of the protection against corrosion demonstrated that the hybrid coatings all improved the protection performance on cold‐rolled steel coupons relative to that of neat PMMA coatings, according to measurements of electrochemical corrosion parameters. Additionally, incorporating silica particles into the polymer may effectively reduce the gas permeability of the polymer membrane. Reducing the size of silica particles (at the same silica feeding) further improved the gas barrier property. Optical clarity studies indicated that introducing silica particles into the PMMA matrix may slightly reduce the optical clarity of the films/membranes, as determined by UV‐visible transmission spectroscopy. The contact angle of H2O of the hybrid films increased with the amount of aniline. Copyright © 2006 Society of Chemical Industry Society of Chemical Industry 相似文献
4.
UV‐curable, transparent hybrid material of urethane‐acrylate resin was prepared by the sol‐gel process using 3‐(trimethoxysilyl)propylmethacrylate (TMSPM) as a coupling agent between the organic and inorganic phases. The effects of the content of acid and silica on the morphology and mechanical properties of UV‐curable polyurethane‐acrylate/silica hybrid (UA‐TMSPM)/SiO2 materials have been studied. The results of thermogravimetric analysis for the (UA‐TMSPM)/SiO2 hybrid materials indicated that the thermal stability of the hybrids is greatly improved. It was found that with the increase of HCl content, the interfacial interaction between organic and inorganic phases had been strengthened, as demonstrated by field emission scanning electron microscopy. Without sacrificing flexibility, the hybrid materials showed improved hardness with increasing content of acid and silica. Compared with the pure organic counterpart UA/hexanediol diacrylate (UA/HDDA) system, abrasion resistance of the hybrids improved with increasing acid content, at low silica content. Copyright © 2004 Society of Chemical Industry 相似文献
5.
Milena pírkov Jií Brus Drahomíra Hlavat Helena Kamiov Libor Matjka Adam Strachota 《应用聚合物科学杂志》2004,92(2):937-950
Hybrid organic–inorganic coatings and free‐standing films were prepared and characterized. The hybrids were prepared from [3‐(glycidyloxy)propyl]trimethoxysilane, diethoxy[3‐(glycidyloxy)propyl]methylsilane, poly(oxypropylene)s of different molecular weights end‐capped with primary amino groups (Jeffamines D230, D400, and T403), and colloidal silica particles with hydrochloric acid as a catalyst for the sol–gel process and water/propan‐2‐ol mixtures as solvents. The structure evolution during the network formation was followed by NMR spectroscopy and small‐angle X‐ray scattering; the surface morphology was tested by atomic force microscopy. The influence of the reaction conditions (the organosilicon precursor, oligomeric amine, ratio of functional groups, and method of preparation) on the network buildup and product properties was studied and examined. The mechanical testing, based on stress–strain experiments, in combination with dynamic mechanical thermal analysis served as an effective instrument for the optimization of the reaction conditions for the preparation of products with desired properties. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 937–950, 2004 相似文献
6.
Anion‐exchange organic‐inorganic hybrid membranes were prepared through sol‐gel reaction and UV/thermal curing of positively charged alkoxysilane and the alkoxysilane containing acrylate or epoxy groups. Properties of prepared hybrid membranes were varied by control of the molar ratio of the precursors. It was shown that the thermal degradation temperatures (Td) of the membranes were in the range of 212–226°C, water uptakes in the range of 9.6–14.6% and IEC values in the range of 0.9–1.6 mmol g?1. The hybrid membranes show high permeability to anions, as reflected by the high static transport number (t?) of the anion (Cl?). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
7.
The effects of a few reaction parameters, namely, type of solvents, tetraethoxysilane (TEOS)‐to‐water mole ratio, and temperature of gelation at constant concentration of TEOS (45 wt %) and pH of 1.5 were investigated for acrylic rubber/silica hybrid nanocomposites prepared by sol‐gel technique. Infrared spectroscopic studies indicated the maximum silica generation within the system when tetrahydrofuran was used as the solvent for the sol‐gel reaction. The distribution of the silica particles (average dimension 100 nm) forming a network type of structure within the composite was confirmed by scanning electron microscopic studies (SEM). The other solvents studied here produced a lower amount of silica because of either high polarity of the solvents (methyl ethyl ketone and dimethyl formamide) or their limited miscibility with water (for ethyl acetate). An increase in the proportion of water caused silica agglomeration. Energy dispersive X‐ray analysis (EDAX) silicon mapping also demonstrated the existence of agglomerated silica structures at high TEOS‐to‐water mole ratio (>2). Higher temperature for gelation of the composites caused the aggregation of silica particles. The uncured composites containing nanolevel (<90 nm) dispersion of silica particles demonstrated slightly higher storage modulus, lower value of tan δmax, and higher glass transition temperature compared to the composites with silica particles of a larger dimension (>2 μm). Improvement in tensile strength and modulus was observed in the uncrosslinked as well as in the crosslinked state (cured by a mixed crosslinking system of hexamethylenediamine carbamate and ammonium benzoate). However, the extent of improvement in strength and modulus for the nanocomposites was higher (247 and 57%, respectively) compared to the microcomposite (150 and 27%, respectively) in the cured state. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1418–1429, 2005 相似文献
8.
Encapsulation of phase change materials (PCM) using a poly(methyl methacrylate) network‐silica hybrid as the shell material has been developed. n‐Octadecane melted at 28°C was used as PCM. Based on the suspension polymerization process, the microcapsules were prepared successfully by mixing and by the reaction of ethylene glycol dimethacrylate with precopolymer solution with tetraethoxysilane (TEOS), whose resultant microcapsules had higher latent heat (ΔH = 151 J/g) than those without TEOS (ΔH = 88.3 J/g). The average size of the PCM microcapsules was about 10 μm. The silica content, n‐octadecane content, and latent heat of microcapsules were changed with varying ageing conditions, ageing time, and temperature. The highest amount of latent heat (ΔH = 178.9 J/g) and n‐octadecane content (73.3%) of the microcapsule were obtained when the inorganic/organic ratio of the microcapsule was 5%. It was difficult to increase n‐octadecane content (74% to 55.7–67.9%) and latent heat (180.5 J/g to 135.9–165.7 J/g) of the microcapsules by introducing different functional groups of coupling agents. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
9.
The sol–gel reaction of a polycarbonate (PC) oligomer having triethoxysilyl groups at both ends of the PC chain (PCS) with a tetraethoxysilane or tetramethoxysilane oligomer provided transparent or semitransparent films of higher silica containing organic–inorganic hybrid materials (HSPC‐HMs). The films were superior to those from PC and from PCS in terms of the morphological homogeneity, heat resistance, and surface hardness. The HSPC‐HM films had minimum oxygen permeability at a PCS/tetraethoxysilane ratio of 3/7. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4273–4279, 2006 相似文献
10.
Titania‐containing coatings were prepared through a dual‐cure process involving radical photopolymerization of a polysiloxane diacrylate and subsequent condensation of alkyltitanate groups. The kinetics of photopolymerization and condensation reaction was investigated as a function of the inorganic phase precursor (titanium tetraisopropoxide) content. AFM analysis gave evidence of a strong interaction between the organic and inorganic phase with the formation of titania domains in the nanoscale region. An increase of hydrophilicity in the coatings surface with increasing TiO2 content was evidenced. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4659–4664, 2006 相似文献
11.
Silica-embedded titania photocatalyst (X-silica/titania, X denotes at.% of silicon) of improved photoactivity was prepared by the sol–gel technique. The photoactivity of the X-silica/titania particles was increased by increasing the silica content and reached a maximum. The highest photoactivity was obtained when silica content was 30% and five times higher than that of Degussa P25. The embedding of amorphous silica into nanophase titania matrix helped to increase the thermal stability of titania which suppressed the formation of anatase into rutile and made it possible to calcine the silica/titania particles at higher calcination temperature. This high temperature heat treatment resulted in the high crystallinity of the silica/titania particles. Surface area of X-silica/titania particles was monotonically increased by increasing the silica content. The average pore size and pore volume, however, has a maximum at 30%, at which mesopores larger than 30 nm were observed. Therefore, we concluded that the large pore size and pore volume were responsible for the optimum composition of silica to titania. The enhanced photoactivity of silica-embedded titania particles was achieved by simultaneously increasing both the surface area and the crystallinity through embedding amorphous silica into titania. 相似文献
12.
Organosoluble polyimide/silica hybrid materials were prepared using the sol–gel process. The organosoluble polyimide was based on pyromellitic anhydride (PMDA) and 4,4′‐diamino‐3,3′‐dimethyldiphenylmethane (MMDA). The silica particle size in the hybrid is increased from 100–200 nm for the hybrid containing 5 wt % silica to 1–2 µm for the hybrid containing 20 wt % silica. The strength and the toughness of the hybrids are improved simultaneously when the silica content is below 10 wt %. As the silica content is increased, the glass transition temperature (Tg) of the hybrids is increased slightly. The thermal stability of the hybrids is improved obviously and their coefficients of thermal expansion are reduced. The hybrids are soluble in strong polar aprotic organic solvents when the silica content is below 5 wt %. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 2977–2984, 1999 相似文献
13.
We focused on the synthesis and optical properties of new organic–inorganic hybrid materials containing azobenzene groups for rewritable optical recording media. Hybrid material (SGUR19‐n's) design has the structure of azobenzene group with urethane bonds in the silica network. The structures of the synthesized monomers and precursors were confirmed by FTIR and 1H NMR spectrophotometer. Also, we reported on the effects of the direction of the polarized beam, the intensity of the induced beam, and the structures of SGUR19‐n's materials on the diffraction efficiency of SGUR19‐n's films. It was revealed that SGUR19‐n's films prepared by the sol–gel process have adequate writing–erasing–rewriting properties when used as a reversible optical storage material. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4811–4818, 2006 相似文献
14.
Silica based poly(vinyl acetate)/inorganic hybrid composites were prepared via a sol–gel process under acidic conditions. Because the phase behaviour of the hybrids is greatly affected by weak interactions such as hydrogen bonding between organic polymer and inorganic network, two types of silane coupling agent (vinyl trimethoxysilane and 3‐(trimethoxysilyl)propyl methacrylate) were used to introduce specific interactions and to control phase behaviour in the interface between polymer and silica. The interfacial interactions between polymer and inorganic segment in the presence of silane have been investigated by Fourier transform infrared spectroscopy. Thermogravimetric analysis shows that the thermal stability of organic components in the hybrids is enhanced by addition of silane coupling agents. Scanning electron micrographs reveal that silica particles are homogeneously dispersed in the organic matrix as a result of the specific interactions. © 2001 Society of Chemical Industry 相似文献
15.
The effects of chemical structure of diamines on the properties of polyetherimide (PEI) nanocomposite films prepared by the sol‐gel process were investigated. For meta diamine, nanocomposites with improved thermal, mechanical, and dielectric properties can be prepared by a sol‐gel process from soluble PEI via chemical imidization, with silica content up to 10%. However, for the PEI with pPDA as diamine and bisphenol A dianhydride, a two‐stage sol‐gel process via thermal imidization was necessary to prepare the nanocomposites. The thermal stability and mechanical properties were improved with the addition of up to 5 wt % of silica content. The variation could be attributed to the fact that differences in the compatibility between PEI and SiO2 for two kinds of PEI with the different meta and para structure of the diamine monomer. The morphology of the fracture surfaces investigated by SEM showed a finely interconnected or cocontinuous phase for PEI nanocomposites with the silica content of up to 10% and 5 wt % for mPDA and pPDA as diamine, respectively. At higher silica contents, thermal and mechanical properties were reduced due to the aggregation of SiO2. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
16.
The formation of covalent bonds between silanols in copolymer and those in silica prevents organic–inorganic phase separation. Two series of hybrid composite materials, poly(vinyl acetate‐co‐vinyl trimethoxysilane)/TEOS and poly[vinyl acetate‐co‐3‐(trimethoxysilyl)propyl methacrylate]/TEOS, were fabricated using a modified sol‐gel process. The hybrids were transparent. Two kinds of silane coupling agents, vinyl trimethoxysilane (VTS) and 3‐(trimethoxysilyl)propyl methacrylate (γ‐MPS), were used to prevent macrophase separation through formation of covalent bonds. Thermal analysis showed that γ‐MPS was more effective than VTS for the formation of covalent bonds. Enhancement of thermal stability of the hybrids was investigated by thermogravimetric analysis. Photomicrographs of scanning electron microscopy and images of atomic force microscopy indicated that inorganic silica particles were homogeneously dispersed in less than 50 nm in organic matrix. The morphological properties of hybrids were strongly dependent on the organic–inorganic composition. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 2310–2318, 2001 相似文献
17.
In the presence of 3‐aminopropyltriethoxysilane (APTES), the transparent and yellowish poly(methyl acrylate‐co‐itaconic anhydride)/TiO2 [P(MA‐co‐Itn)/TiO2] hybrid materials were prepared from the copolymer of methyl acrylate and itaconic anhydride [P(MA‐co‐Itn)] and tetrabutyl titanate (TBT) via a sol–gel process. At first, the triethoxysilane groups were incorporated into the copolymer P(MA‐co‐Itn) as pendant side chains by the aminolytic reaction between the itaconic anhydride units of the copolymer and the amino group of 3‐aminopropyltriethoxysilane (APTES), and then the covalent bonds between the organic and inorganic phases were introduced by the hydrolysis and polycondensation of the triethoxysilane groups on the copolymer with TBT. FTIR analysis proved the existence of the covalent bonds. The influences of APTES on glass transition and morphology of the hybrid materials was studied by differential scanning calorimetry, scanning electron microscope, and atomic force microscope. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 1763–1768, 2000 相似文献
18.
Polyimide (PI) materials with a low coefficient of thermal expansion (CTE) while still retaining high strength and toughness are desirable in various applications. In this study a sol–gel process was used to incorporate silica into homopolyimides and copolyimides with highly rigid structures in an attempt to pursue this aim. A number of highly rigid monomers were used, including pyromellitic dianhydride (PMDA), p‐phenylene diamine (PPA), m‐phenylene diamine (MPA), benzidine, 2,4‐diaminotoluene, and o‐toluidine. No homopolyimide flexible films were obtained. However, it was possible to obtain flexible films from the copolyimides. Therefore, a copolyimide based on PPA, MPA, and PMDA (PPA/MPA = 2/1 mol) was then chosen as the matrix to prepare the PI/silica hybrids. Flexible films were obtained when the silica content was below 40 wt %. The hybrid films possessed low in‐plane CTEs ranging from 14.9 to 31.1 ppm with the decrease of the silica content. The copolyimide film was strengthened and toughened with the introduction of an appropriate amount of silica. The thermal stability and the Young's modulus of the hybrid films increased with the increase of the silica content. The silica particle size was assessed by scanning electron microscopy and was about 100 nm for the hybrids containing 10 and 20 wt % silica and 200–500 nm for the hybrids containing 30 and 40 wt % silica. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 79: 794–800, 2001 相似文献
19.
Xiahong Zhang Jianwen Yang Zhaohua Zeng Liang Huang Yonglie Chen Haihua Wang 《Polymer International》2006,55(4):466-472
Organic–inorganic hybrid UV‐curable coatings were synthesized through blending UV‐curable components and stabilized titania sol prepared via a sol–gel process of tetrabutyl titanate (TBT) with three different stabilizers, acetylacetone (Acac), isopropyl tri(dioctyl)pyrophosphato titanate coupling agent (TTPO) and a polymerizable organic phosphoric acid (MAP). The size and the dispersion of titania particle in the UV‐cured organic matrix were dominated by the properties of these stabilizers. A cured hybrid film with titania particle size around 20 nm was obtained when TTPO was utilized as protection agent for the sol. It is interesting that the hardness and flexibility of the photocured hybrid films were improved simultaneously, in contrast to results with neat organic UV‐curable formulations. Copyright © 2006 Society of Chemical Industry 相似文献
20.
UV‐curable, transparent acrylic resin/titania organic–inorganic hybrid films were prepared by controlled hydrolysis of titanium tetrabutoxide in Span‐85/Tween 80 reverse micelles and the subsequent in situ photopolymerization of the acrylic monomers. UV–vis spectra and atomic force microscopy (AFM) indicated the presence of a nanoscale hybrid composition. The onset of absorption (λonset) of titania in the hybrids appeared between 363.4 and 383.5 nm, which exhibited blue shifts relative to that of bulk anatase (λonset = 385 nm). The titania content increased rapidly at higher temperature and higher TTB content, whereas it increased slowly with longer post‐thermal treatment times. The refractive index and UV shielding properties of the organic polymer were obviously improved with increasing titania content. AFM images showed the inorganic domains (mean size 25.3–28.8 nm) were uniformly dispersed in the polymeric networks. The roughness parameters of the hybrid material were: toughness, 1.5–2.3 nm; root mean square roughness, 4.5–4.6 nm; and peak and valley distance, 9.7–19.4 nm. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5105–5112, 2006 相似文献