Changes of chemical composition and dough rheology in two fractions of sieve-classified Polish spring wheat flour

The study of chemical composition and dough rheology changes in sieve-classified two fractions (up to 60 and 60-240 microm particles) of wheat flour was the subject of this study. The straight grade flours were obtained by the milling of three Polish varieties of spring wheat, differing in particle size index (PSI) values. The flours were separated with the use of an SZ-1 laboratory sifter. The yield of fine fraction was in the range 50.0-55.7%. The obtained fractions were assayed for the content and composition of free lipids, gluten proteins, damaged starch, ash, water absorption and amylograph viscosity. Dough rheology (extrusion in OTMS cell, alveograph and farinograph tests) and baking trials were also performed. The content of free lipids, including the non-polar and phospholipids was lower and the content of glycolipids was higher in fine flours. Those fractions were more rich in linoleic acid but the lower content of oleic and linolenic acids resulted in a higher oxidizability index of free lipids. Fine flours contained less ash and significantly more damaged starch. At the same time, they were characterized by a higher content of wet gluten, water absorption, amylograph viscosity and better dough parameters. This was reflected in the bread volume, which was higher by 6.3-10.7%. The influence of the changes in composition and the content of free lipids upon the rheology of the dough after the 90 days flour storage has not been defined unambiguously and requires further research.     

Impact of endogenous constituents from different flour milling streams on dough rheology and semi-sweet biscuit making potential by partial substitution of a commercial soft wheat flour

A flour fractionation-reconstitution procedure was used to study the substitution of a commercial soft wheat flour with gluten, water extractables, prime starch and starch tailing fractions isolated from patent and clear flour streams on dough rheology and semi-sweet biscuit characteristics. Substitution of soft wheat flour with increasing levels of the native patent and clear flour streams raised the dough consistency, hardness and elastic properties as well as the biscuit textural attributes (density, hardness). The dough stickiness of the base flour was also reduced and the biscuits were free of cracks. Gluten isolated from the patent flour had a greater impact on dough consistency, hardness and elastic properties than gluten obtained from the clear flour, likely due to the superior protein quality of the former. Additionally, with increasing gluten levels in the fortified flour there were moderate increases in biscuit density, hardness, and lower crunchiness. The addition of starch tailings produced the largest impact on consistency and hardness of the dough. This fraction also exerted a pronounced effect on biscuit density and hardness, while it lowered crunchiness, presumably due to its higher pentosan content. Overall, the dough rheological properties and biscuit characteristics were controlled by the amount-nature of the fractions added; i.e., besides gluten (amount and quality), other constituents such as pentosans and the overall composition of the flour blends can largely affect the quality of the semi-sweet biscuits.     

Chemometric Approach to Characterization of Flour Mill Streams: Chemical and Rheological Properties

The aim of the present study was to utilize chemometric methods (the principal component analysis and hierarchical cluster analysis) for monitoring the certain aspects of flour mill streams quality and their interrelation to selected rheological properties. Thirty-seven flour mill streams were separated from industrial mill of 300 t/day capacity. All flour streams were analyzed for ash, protein, wet gluten, and damaged starch content and rheological properties as determined by Brabender Farinograph, Extensograph, and Amylograph. The obtained results indicated that break, sizing, and reduction flour streams exhibited different rheological behavior in relation to a change in protein, wet gluten, ash, and mechanically damaged starch content within the milling passages. Rheological properties of dough during mixing and kneading as well as during extension were different with regard to the technological phase of milling from which they were extracted. The obtained results could be utilized for selection of certain flour streams in production of special-purpose flours.     

Role of gluten and its components in influencing durum wheat dough properties and spaghetti cooking quality

Protein is an important component of grain which affects the technological properties of durum wheat. It is known that the amount and composition of protein can influence dough rheology and pasta quality but the influence of the major classes of protein is not well documented. The influence of the various gluten components on dough and pasta properties was investigated. The protein composition of durum semolina was altered by either adding gluten fractions to a base semolina or preparing reconstituted flours with varying protein composition. The effects on semolina dough rheology and spaghetti texture were measured. Published methods to isolate relatively pure quantities (gram amounts) of glutenin, gliadin, high molecular and low molecular weight glutenin subunits were evaluated and modified procedures were adopted. Reconstituted flours with additional glutenin increased dough strength while additional gliadin and LMW‐GS decreased strength. These changes did not impact on spaghetti texture. Results from using the addition of protein fractions to a base semolina showed that gluten and glutenin addition increased the dough strength of a weak base semolina while gliadin addition weakened the base dough further. Addition of HMW‐GS greatly increased dough strength of the base while addition of LMW‐GS greatly reduced dough strength. Again, these affects were not translated into firmer pasta. Copyright © 2007 Society of Chemical Industry     

Gluten‐free spaghetti made with chickpea,unripe plantain and maize flours: functional and chemical properties and starch digestibility

The development of gluten‐free spaghetti with a low amount of glycaemic carbohydrate was investigated. The goal of this study was to determine the chemical composition, cooking quality and starch digestibility of gluten‐free spaghetti elaborated with mixtures of chickpea, unripe plantain and maize flours. The gluten‐free spaghetti presented a higher protein, fat and ash content than the control semolina spaghetti. The solid loss among all the gluten‐free spaghetti was in the range of 10.04–10.91% and not significantly different from each other. These values were almost at the limit of acceptability to be considered as good cooking quality. Total starch in the gluten‐free spaghetti was lower than the control spaghetti. The lower available starch (AS) and higher resistant starch contents in the gluten‐free spaghetti were associated with their lower rate of hydrolysis and predicted glycaemic index. There is a potential for developing gluten‐free spaghetti with reduced amount of glycaemic carbohydrates from unconventional food ingredients such as chickpea, unripe plantain and maize flours.     

Effect of the shape of rice starch granules on flour characteristics and gluten‐free bread quality

The effect of three different rice varieties with different starch shapes (Seolgaeng (SG), round starch structure; Samkwang (SK), polygonal starch structure and Boramchan (BRC), polygonal starch structure) on rice flour characteristics and gluten‐free bread baking quality was investigated. Rice flours were produced by dry milling and passed through a 200 mesh sieve. Electron microscopy revealed that the structure of SG grains, with round starch granules, possessed larger void spaces than SK and BRC, composed of polygonal starch granules. For this reason, SG grain had low grain hardness and consequently, it was milled to a fine flour with low damaged starch content. The thermo‐mechanical properties were determined by Mixolab, which revealed that SG was gelatinised rapidly and maintained high viscosity after gelatinisation. These characteristics gave SG flour the ability to build up bread structure without gluten. Specific volume and crumb hardness of gluten‐free rice breads made of SG, SK and BRC flours were 3.37, 3.11 and 2.12 mL g^?1 and 2.61, 2.76 and 6.46 N, respectively. The SG flour with round starch structure is appropriate for making gluten‐free rice breads.     

Effects of endogenous flour lipids on the quality of short‐dough biscuits

Fractionation and reconstitution techniques were used to study the contribution of endogenous flour lipids to the quality of short‐dough (shortcake type) biscuits. Biscuit flour was defatted with chloroform and baked with bakery fat, but without endogenous lipid. Short‐dough biscuits baked from defatted flour had smaller diameters, and were flatter, denser and harder than control biscuits. Defatted flour shortcake doughs exhibited different rheological behaviour from the control samples, showing higher storage and loss moduli (G′ and G″ values), ie higher viscoelasticity. Functionality was restored when total non‐starch flour lipids were added back to defatted flour. The polar lipid fraction had a positive effect in restoring flour quality whereas the non‐polar lipid fraction had no effect. Both fractions were needed for complete restoration of both biscuit quality and dough rheological characteristics. A study of the microstructure of defatted biscuits revealed that their gluten protein was more hydrated and developed than the gluten of the control biscuits. This conclusion was supported by the higher water absorption of the defatted gluten. Copyright © 2004 Society of Chemical Industry     

Significance of lipid binding on the functional and nutritional profiles of single and multigrain matrices

Lipid fractions and starch- and protein-lipid binding of single and blended oat, rye, buckwheat and wheat flour, dough and bread matrices were investigated, and results correlated with the functional and nutritional properties of the grain matrices during mixing and baking. Non-starch lipid was the most prominent fraction in terms of absolute content and as a percentage of total lipids. Free lipids, starch lipids and bound lipids were, respectively, the major, intermediate and minor lipid fractions in flours, doughs and breads. Great differences in total lipid content due to sampling result in divergences amongst lipid fraction content and distribution, especially for starch and bound lipid fractions. Lipids bound to proteins during dough mixing are translocated and bound to starch during baking. In blended samples, the higher fibre content seems to provoke a reduction of the lipid–protein and lipid–starch linkages due to interactions between fibres and endogenous biopolymers. Starch lipid showed the most significant correlations with parameters related to dough and bread performance during breadmaking, especially over the mixing step. Valuable fresh bread functional characteristics, such as high specific volume and high sensory score for softness and overall acceptability, correspond to a starch lipid’s increase due to mixing. The higher the free and starch lipids decrease by reason of temperature treatment—baking—the larger the starch hydrolysis and the higher β-glucans and total dietary fibre contents.     

Influence of maize flour particle size on gluten‐free breadmaking

BACKGROUND: Maize, one of the suitable grains for coeliac consumption, is, together with rice, the most cultivated cereal in the world. However, the inclusion of maize flour in gluten‐free bread is a minority and studies are scarce. This paper analyses the influence of different maize flour types and their particle sizes on the quality of two types of bread without gluten (80% and 110% water in the formulation) obtained from them. We also analysed the microstructure of the dough and its behaviour during the fermentation. RESULTS: Finer flours had a lower dough development during fermentation in all cases. Among the different types of flour, those whose microstructure revealed compact particles were those which had higher specific bread volume, especially when the particle size was greater. Among the formulations, the dough with more water gave breads with higher specific volume, an effect that was more important in more compact flours. The higher volume breads had lower values of hardness and resilience. CONCLUSION: The type of corn flour and mainly its particle size influence significantly the dough development of gluten‐free bread during fermentation and therefore the final volume and texture of the breads obtained. The flours having coarser particle size are the most suitable for making gluten‐free maize bread. © 2012 Society of Chemical Industry     

Effects of hydrocolloids on chemical properties and cooking quality of gluten‐free spaghetti

The effects of different hydrocolloids on chemical composition and cooking quality of spaghetti based on maize and oat flours were investigated. Rheological and texture properties of the gluten‐free dough were also assessed. Amount of 2% of gellan gum, carboxymethylcellulose, pectin, agar, egg protein powder, tapioca starch, guar seed flour and chitosan were separately added to the formulation. The samples enriched with hydrocolloids generally showed a different rheological behaviour compared with the control samples. As regards chemical composition, spaghetti with chitosan showed a value of insoluble dietary fibres (8.0%) higher than the control ones (3.9%). Moreover, results highlighted that most hydrocolloids improved cooking quality and texture properties of spaghetti (adhesiveness, cooking loss, hardness), thus supporting their application in gluten‐free pasta.     

INFLUENCE OF NATIVE LIPIDS ON THE RHEOLOGICAL PROPERTIES OF WHEAT FLOUR DOUGH AND GLUTEN

We report on the viscoelastic properties of dough and gluten (prepared by ultracentrifugation) after the flour lipids had been removed by solvents differing in polarity (chloroform, ethanol and diethylether). The extracted lipids were fractionated by thin layer chromatography. The flours differed in lipid composition after the extraction. Ethanol removed more polar lipids than the other solvents. Removal of lipids (0.6–0.9% on flour weight) altered the viscoelastic properties of dough significantly, whereas those of gluten were only marginally affected. The storage modulus (G′) of dough increased with used solvent polarity. The highest value of G′ was observed for the dough made with the flour where the lipids were removed by ethanol. This was consistent with a marked decrease in the frequency dependence of G′ of dough when the lipids were removed.     

Separation of bread wheat flours into starch and gluten fractions: effect of water temperature alone or in combination with water to flour ratio

Two different commercial bread wheat flours (BF‐I, 65% extraction and BF‐V, 86% extraction) were separated into gluten and starch milk by making a dough, allowing some time for maturation, dispersing the dough in water and wet sieving/washing. The effect of using of warm water (20–45 °C) for dough making and washing on separation was studied for BF‐I flour at 640 g kg^?1 water to flour ratio of and 300 s maturation time, and the separation was found to improve with increase in temperature. The combined effects of water temperature (20–50 °C) and water to flour ratio (640–780 g kg^?1 for BF‐I and 620–870 g kg^?1 for BF‐V) were studied at 600 s maturation time. The quantities and dry matter contents of the gluten fraction and starch milk were measured; a sample of starch milk was centrifuged to obtain decantate, tailing and prime starch fractions, and the dry matter contents of each were determined. All the dried samples were also analysed for protein content, and the fractional recoveries of dry matter and protein in the gluten fraction, prime starch, tailings and decantate were calculated. The results indicated the optimum point for BF‐I flour to be the combination of optimum farinograph water absorption and 40 °C. BF‐V showed very poor separation behaviour within the ranges studied. At the optimum farinograph water absorption the use of warm water for dough making and 20 °C water for washing steps was also tried, but no significant improvement over the 20 °C results was obtained. © 2002 Society of Chemical Industry     

不同品种粳米-低筋小麦混合粉体系粉质特性研究

采用市售低筋粉分别与5种粳米粉组成混合粉体系,对其粉质和拉伸特性变化规律,及其与各品种粳米粉的组成成分的相关性进行分析。结果表明:随粳米粉添加量的增加,吸水率以及拉伸比值整体呈上升变化趋势;面团形成时间、稳定时间、评价值以及面团抗拉伸阻力整体略呈下降变化趋势;延伸性呈显著性下降;弱化度整体先升高后降低。当粳米粉添加量不同时,除蛋白质和灰分外的其它组分均与粳米-低筋小麦混合粉面团的各项粉质特性参数指标呈现显著相关性。     

Dynamic rheology of wheat flour dough. I. Non‐linear viscoelastic behaviour

Controlled stress rheometry was used to investigate the effects of starch and gluten fractions on the non‐linearity of wheat flour dough. Flour–water dough showed non‐linear viscoelastic behaviour over all stress values in a cyclic stress sweep. The amplitude‐dependent behaviour of the starch and amplitude‐independent nature of the gluten revealed that starch is responsible for the non‐linearity of the flour–water dough system. Adding starch to gluten caused a substantial narrowing of its linear viscoelastic range. © 2002 Society of Chemical Industry     

The composition of a gel formed when wheat flour is suspended in phenol-acetic acid-water (1:1:1, w/v/v)

A gel which formed when wheat flour was suspended in phenol-acetic acid-water (1:1:1, w/v/v/) was fractionated into a protein-rich soluble fraction and a carbohydrate-rich insoluble fraction. Gel electrophoresis showed that the soluble fraction contained several proteins and had an amino acid composition with a high content of proline and glutamyl residues and a low content of lysine. The soluble fraction also contained lipids which were mainly phospholipids, phospholipid derivatives and glycolipids and other compounds, which yielded galactose and glucose after acid hydrolysis. The insoluble fraction contained a polysaccharide with similar properties to starch, and lipids which were mainly neutral fats, sterols and sterol esters. Both fractions contained arabinoxylans and mannans. The gel did not contain any nucleic acids. The protein-rich soluble fractions of gels prepared from other wheat flours and air-classified flour fractions, from wheat gluten and from rye and barley flours, showed marked differences in amino acid composition. It is concluded that a heterogeneous class of proteins, rather than specific proteins in fixed proportions, is involved in gel formation.     

Impact of brown foxtail millet (Setaria italica) flour on thermo-mechanical properties of flours from different rice varieties

The physical, functional and thermo-mechanical properties of rice flours prepared from long, round and medium rice grain and of foxtail millet (Setaria italica) flour were investigated. The impact of foxtail millet flour addition on the thermo-mechanical properties to the rice flours was also explored. Rice flour from long grain had higher amylose content (26.37%), while the rice flour from round grain had better hydration properties compared to the other rice flours. The dough from long grain rice flour exhibited higher starch gelatinisation temperature and cooking stability and lower starch retrogradation compared to the other investigated rice flours. Foxtail millet flour addition to the rice flours exerted a lower impact on the thermo-mechanical properties of the dough based on rice flour from long grain compared to the other investigated rice flours. These differences might be due to the differences in terms of starch properties and proximate composition of the flour samples.     

Gluten‐free pasta: effect of green plantain flour addition and influence of starch modification on the functional properties and resistant starch content

Green plantain flour (GPF) is rich in indigestible carbohydrates, especially in resistant starch (RS). The objective of this study was to improve the functional pasta properties and RS content by producing gluten‐free (GF) pasta based on rice flour with different amounts of GPF addition (15–60% of total flour blend). Egg albumen (3.5–6.0% of total flour) and dough moisture (36–40%, dough humidity%), at constant emulsifier (0.5% of total flour) addition, were optimised in the first trials. The results showed that an addition up to 30% GPF with higher amount of egg albumen (6%) at dough moisture of 38% provided pasta with acceptable cooking quality and high RS content. Some qualities and/or RS content of GF pasta samples was further improved by adding 30% pregelatinised flours from the native GPF or drum‐dried green banana flour (DDGBF) in combination with applying varied steps of cooking and/or cooling, which were applied after pasta extrusion prior to drying them. The study suggests that GPF, in its native form, but particularly when pregelatinised, is a promising ingredient to be used for the production of GF pasta.     

Effects of Attrition Milling on Air Classification Properties of Hard Wheat Flours

Effects of attrition milling on yield and composition of air-classified fractions from fifth break and first middling flours of HRS wheat were investigated using image analysis to characterize flour particle size distributions. Roller-milled flours had high proportions of particles < 45 μ diameter but particles > 105 μm diameter constituted most of the flour volume. Attrition milling caused less starch damage than pin milling but increased the degree of reduction (<45 μm diameter), based on volume, from 10.3 to 100% for fifth break and from 6.9 to 100% for first middling flours. Two cuts on the air classifier produced a high protein fraction with high ash (30.5% protein, 41% starch, 2% ash, 14% moisture basis), which would have application as a gluten substitute in baking, and a medium protein fraction (14% protein, 66% starch, 0.65% ash) which could be blended into Bakers Patent. The major fraction of air classified middlings flour contained 6.5% protein, 77% starch and 0.3% ash.     

Applicability of DATEM for Chinese steamed bread made from flours of different gluten qualities

BACKGROUD: The diacetyl tartaric acid ester of monoglycerides (DATEM) is an anionic oil‐in‐water emulsifier. The effects of DATEM on bread vary with the type of flour. However, there is insufficient information concerning the effects of DATEM on the qualities of Chinese steamed bread (CSB) even though it is also sold as a CSB improver. RESULTS: The effects of DATEM on CSB varied with flours. The overall qualities of CSB made from either weak or strong wheat flours were improved by the use of the additive, but the effects for medium strong flours were slight and uncertain. The effects of DATEM on individual parameters, such as specific volume, skin and inner structure, were similar to those on overall quality. The addition of DATEM increased the gluten strength and the dough stability of weak flour, whereas it weakened gluten strength and strengthened dough stability of strong flour. The addition of DATEM weakened the gluten strength and gave variable effects on dough stabilities for two medium strong flours. CONCLUSION: The effects of DATEM on CSB quality varied with flour type, by affecting flour characteristics, such as gluten strength, dough stability and lipid content. Copyright © 2008 Society of Chemical Industry     

The Interplay Between the Main Flour Constituents in the Rheological Behaviour of Wheat Flour Dough

There is still considerable debate in the literature about the respective roles of starch and gluten in both the linear and non-linear rheology of wheat flour dough. Hence, to elucidate the individual contributions of gluten and starch to the overall dough behaviour, the rheological properties of dough and mixtures of different gluten-starch ratios were studied systematically in shear and extension, by means of an adequate rheological toolbox consisting of linear small amplitude oscillatory shear tests and non-linear tests such as creep-recovery in shear and uniaxial extension. The starch component plays a pivotal role in linear dough rheology. With increasing starch content, the linearity limit observed in oscillatory shear tests decreases as a power-law function. Starch also clearly affects the extensional viscosity at small strains. Consequently, in the linear region differences between different gluten systems may become obscured by the presence of starch. As breadmaking qualities are known to be intrinsically linked to the gluten network, it is imperative to probe the non-linear behaviour of dough in order to expose differences in flour quality. The quality differences between a strong and a weak flour type were revealed most clearly in the value of the strain-hardening index in uniaxial extension and the total recovery compliance in non-linear creep-recovery tests. Notwithstanding its earlier successful application to pure gluten gels, the accuracy of the critical gel model in predicting the linear rheological properties of dough was found to be limited, due to dough having a small linearity limit and a finite longest relaxation time.