Isotopic and chemical composition of parbati valley geothermal discharges, North-West Himalaya, India

The isotopic compositions of the waters discharged from Parbati Valley geothermal areas indicate a higher altitude meteoric origin, with discharge temperatures reflecting variations in the depth of penetration of the waters to levels heated by the existence of a ‘normal’ geothermal gradient. On the basis of mixing models involving silica, tritium, discharge temperatures and chloride contents, deep equilibration temperatures of 120–140°C were obtained for Manikaran, possibly reaching 160°C at even greater depth. Geothermometers based on sulfate-water ¹⁸O exchange and gas reactions point to similar temperatures. Exceptionally high helium contents of the discharges correspond to apparent crustal residence times of the waters in the order of 10–100 Ma; relative nitrogen-argon contents support a largely meteoric origin of the waters with a possible fossil brine, but no detectable magmatic component.     

Isotopic zoning and origin of the aquifers in the discharge area of the geothermal fields of ahuachapán and Chipilapa, El Salvador

The northern discharge areas of the Ahuachapán, and Chipilapa geothermal fields can be subdivided into four different zones based on their structural position, and the isotopic and chemical composition of their waters. In general, the contribution of geothermal waters from these two fields was estimated to be less than 10%. Elevation effects are of little importance, whereas a slight trend towards higher isotopic values with increasing water temperatures may exist.The NNW-SSE-trending Escalante and Agua Caliente faults represent lateral groundwater barriers, and provide vertical conduits for the ascending geothermal waters. The western discharge areas seem to be more influenced by the Ahuachapán, geothermal field, whereas those to the east are more influenced by the Chipilapa field.Groundwaters in the Northern Plain are mainly from shallow northward-flowing aquifers. These waters show temperature effects, mixing with geothermal waters and are affected by the geology of the area. However, none of these factors alone can explain the isotopic variations observed in the waters of the northern discharge areas.     

Volcano–tectonic structures, gravity and helium in geothermal areas of Tuscany and Latium (Vulsini volcanic district), Italy

Since the early 1980s, geological and structural mapping, gravity, and helium soil–gas studies have been performed in the eastern sector of the Vulsini Volcanic District (Roman Magmatic Province) in an attempt to locate potential geothermal reservoirs. This area is characterised by an anomalous geothermal gradient of >100°C/km, and by widespread hydrothermal mineralization, thermal springs, high gas fluxes, and fossil and current travertine deposits. The results of these surveys indicate the existence of a number of fault systems, with N–S and E–W structures that appear to be superimposed on older NW–SE and NE–SW features. Comparison of the results of the various studies also reveals differences in permeability and potential reservoir structures at depth.     

Geochemical exploration of the three most significant geothermal areas of Lesbos Island, Greece

Lesbos Island has several thermal manifestations linked to extensional active faults that act as channels for the ascent of deep thermal fluids.The present work describes detailed geochemical exploration aimed at evaluating the potential of the Lesbos Island geothermal resource. Exploration was carried out on the three sites (Kalloni-Stipsi, Petra-Argenos and Polichnitos) that have the most favourable hydrogeological and structural setting on the island.Hydrogeochemical data reveal the presence between Kalloni and Stipsi of a shallow thermal aquifer with temperatures below boiling point, which coincides with carbon dioxide and temperature anomalies in the overlying groundwaters. All the thermal waters in the study area have fairly similar physico-chemical features; their geochemical temperature is in the range 115–125°C. While low-medium enthalpy geothermal resources are relatively abundant in the three selected areas of Lesbos Island, the presence of a high enthalpy geothermal system is still the subject of debate.     

Fluid flow processes in the BEPPU geothermal system, Japan

The Beppu geothermal system is centred beneath the late Quaternary volcanoes of Tsurumi and Garandake at the northern end of the Ryukyu volcanic arc. The deep fluid has a temperature of at least 250–300°C, and an inferred chloride concentration of 1400–1600 mg/kg. Apart from fumarolic areas near the summits of the two volcanoes, most thermal activity occurs at low elevation along the two main outflow paths towards the coast. The hot spring waters of downtown Beppu have originated from outflow along the Asamigawa Fault, with their chemistry indicating predominantly dilution of the deep fluid by groundwater. The second outflow zone towards the hot spring area of downtown Kamegawa coincides with a ridge of lavas. Here boiling, steam loss, and subsequent mixing with steam-heated groundwaters have significantly modified both the deep fluid and host rocks. The area of the geothermal system above 200°C is at least 15 km² at sea level, and the total natural heat output is inferred to be at least 250 MW. Most of this heat output occurs as subsurface hot water outflows towards the coast due to the 1300 m of topographic relief across the system.     

Geochemistry and groundwater contamination in the La Selva geothermal system (Girona, Northeast Spain)

Hot spring waters of the La Selva geothermal system show high concentrations of Cl, F, Ca, Na, K, Li, Si, As, Ba, and Rb, whereas cold waters show low salinity, high concentrations of NO₃, and significant As content when mixed with geothermal waters.Modeling of the geothermal fluids indicates that the fluid is supersaturated with aragonite and calcite, which matches the travertine precipitation close to the present discharge areas. Moreover, the barite and fluorite are also are near equilibrium levels, indicating possible control of Ba and F solubility by these mineral phases, which also precipitate in some discharge areas. Likewise, the fluid is supersaturated with respect to quartz, indicating the possibility of siliceous precipitation near the discharge areas of the present geothermal fluids.Taking into account the Na-K, Na-K-Ca, and SiO₂-temperature geothermometers, the temperature of the reservoir may be estimated to be about 135 °C.The chemistry of the geothermal fluids has changed from a recent high-enthalpy system, which precipitated siliceous deposits, to the present low-enthalpy system, which precipitates carbonated deposits (travertine).Multivariate analysis of the groundwater shows high correlations between K, Ca, As, Br, Ag, and Ba, suggesting that As is introduced to the environment via geothermal fluids. Moreover, As concentrations in hot groundwater are associated with high concentrations of Li and Si, as has been observed in other geothermal fields. Metal concentrations in the hydrothermal deposits show high values of Ag, As, Ba, Pb, Sb, and Zn, mainly in the siliceous deposits of the town of Caldes de Malavella, where the geothermal system deposited materials with high As concentrations (123-441 ppm).The similarities between the geochemical characteristics of the hydrothermal deposits and the groundwater suggest that the metals in these deposits and fluids have the same origin.     

Appraisal of the Tokaanu–Waihi geothermal field and its relationship with the Tongariro geothermal field, New Zealand

Tokaanu–Waihi geothermal field is situated near the southern end of the Taupo Volcanic Zone, New Zealand. Neutral chloride thermal waters discharge at Tokaanu and Waihi in the north of the field on flat land between the andesite volcanoes Tihia and Kakaramea and the shore of Lake Taupo, while steam-heated thermal features occur at Hipaua on the northern flanks of Kakaramea. Electrical resistivity surveys have been made over the field using several different measurement techniques. In the north of the field where roads and tracks allow vehicle access, resistivity profiling using Schlumberger arrays with electrode spacings (AB/2) of 500 m and 1000 m show that Tokaanu, Waihi and Hipaua all lie within a continuous region of low apparent resistivity (5–20 Ωm) and are thus part of the same geothermal system. Along the eastern edge of the system there is a sharp transition to apparent resistivities greater than 100 Ωm in the cold surrounding region. Surveys on Lake Taupo using an equatorial bipole-bipole electrode array towed behind boats (spacing equivalent to AB/2=500 m) found that the low resistivity zone extends offshore by about 1 km. The steep, bush-clad, southern part of the field was surveyed with magnetotelluric (MT) resistivity measurements using both naturally occurring signals and the 50 Hz radiation from the power wires as sources. These measurements found low resistivities over the north-eastern slopes and around the summits of Tihia and Kakaramea, indicating thermal activity. However, the measurements were too widely spaced to allow the field boundary to be clearly delineated. Interpretation of the resistivity and other data suggests that the Tokaanu–Waihi thermal waters rise nearly vertically from a source deep beneath the elevated southwestern part of the field to the water table. These waters then flow north to discharge at the surface near Lake Taupo. Neighbouring geothermal systems, which occur at Tongariro about 18 km south of Tokaanu–Waihi, and at Motuoapa about 10 km to the northeast, are separated from the Tokaanu–Waihi field by high resistivity ground. This suggests that the thermal fluids discharging at the three fields do not have a common source, as has been suggested previously.     

Geochemistry of the Rehai and Ruidian geothermal waters, Yunnan Province, China

The geochemical characteristics of the hot spring waters in the Rehai and Ruidian geothermal fields, Tengchong County, Yunnan Province, China, are described and their possible environmental impact assessed. The results show that the alkaline spring waters contain high levels of K, Na, F, Cl, SiO₂, whereas the only acidic spring water in Rehai geothermal field contains high levels of SO₄²⁻, Mn and Fe. As and Sb in the spring waters are in the range 43.6–687 μg/L and 0.38–23.8 μg/L, respectively. As(III) occurs in most spring waters, and constitutes up to 91% of the total As. A fraction of the geothermal As and Sb is trapped in the sinter deposits while most enters the environment. The diffusion of As and Sb into groundwater and downstream crop fields constitutes a threat to the health of the local population.     

Temperature evaluation of the Bugok geothermal system, South Korea

Using a variety of chemical geothermometers and statistical analysis, we estimate the temperature of a possible deeper geothermal reservoir at Bugok, Southern Korea. Shallow thermal aquifers (down to about 400 m depth) are under exploitation in this area; the temperatures (up to 78 °C) of the produced fluids are the highest found in South Korea. Based on hydrochemical data and occurrence, the groundwaters at Bugok can be classified under three groups: Na-SO₄ thermal groundwaters (CTGW) occurring in the central (about 0.24 km²) part of the area; Ca-HCO₃ cold groundwater (SCGW) found in shallow peripheral parts of the CTGW; the intermediate-type groundwater (STGW). The CTGW type is typical of the Bugok thermal waters; they have the highest discharge temperatures and contain very high concentrations of Na (75.1–101.0 mg/L), K (2.9–6.9 mg/L) and SiO₂ (62.0–84.5 mg/L) and are rich in sulfates.The major ion composition of the CTGW suggests that these waters are in partial equilibrium with rocks at depth. The application of various alkali-ion geothermometers yields temperature estimates in the 88–198 °C range for the thermal reservoir. Multiple-mineral equilibrium calculations indicate a similar but narrower temperature range (from about 100 to 155 °C). These estimates for CTGW are significantly higher than the measured discharge temperatures. Considering the heat losses occurring during the ascent of the waters, one can infer the presence of a deeper (around 1.8 km) thermal reservoir in the Bugok area that could be developed for district heating or other direct applications of geothermal heat.     

Geophysical investigations of the Seferihisar geothermal area, Western Anatolia, Turkey

Self-potential (SP), magnetic and very low frequency electromagnetic (EM-VLF) surveys were carried out in the Seferihisar geothermal area to identify major and minor fault zones and characterize the geothermal system. The SP study provided useful information on the local faults and subsurface fluid flow. The main SP anomalies appear mostly along and near active fault zones in the area of the Cumalı, Tuzla and Doğanbey hot springs. Two of these anomalies near the Tuzla hot springs were further evaluated by SP modelling. Total magnetic field values increase from the Doğanbey to the Cumalı hot springs. Modelling performed on the magnetic data indicates that between these two spring areas are four different regions or units that can be distinguished on the basis of their magnetic susceptibility values. Fraser filtering of EM-VLF data also indicates that there are three significant conductive zones in the regions around the Cumalı, Tuzla and Doğanbey hot springs, and that they lie between important fault systems. The EM-VLF and total (stacked) SP data show that the conductive tilt anomalies obtained by Fraser filtering generally coincide with negative SP areas.According to our geophysical investigations, new exploratory wells should be drilled into the conductive zones located between the Cumalı and Tuzla hot springs. We further recommend that resistivity and magnetotelluric methods be carried out in the area to obtain additional information on the Seferihisar geothermal system.     

Long-term changes associated with exploitation of the Beppu hydrothermal system, Japan

Exploitation of the Beppu hydrothermal system started mainly in the lowland areas as early as the 1880s, and by the 1920s the number of wells had increased to about 1000. This caused the piezometric head of the thermal groundwater to draw down, and seawater to intrude into the thermal groundwater aquifer near the coast. A second flurry of exploitation occurred during the 1960s–70s, by which time there were over 2300 wells, and the mass and heat flows had increased due mainly to the discharge of high-temperature chloride waters in the highland areas. This caused a decline in piezometric head of the deep chloride water, a decline in the subsurface flow of chloride water towards the lowlands, and intrusion of steam-heated shallow water into the chloride water layer.     

Hydrogeochemistry and geothermal characteristics of the White Lake basin, South-central British Columbia, Canada

Hydrogeochemistry and geothermal characteristics of the Tertiary White Lake basin are described in order to provide constraints on the hydrogeology and thermal regime of the basin. The basin can be divided into three flow subsystems on the basis of chemical and isotopic variations. The groundwaters evolve chemically from young Ca–Mg–HCO₃ type waters in the shallow surficial sediments to Na-dominated waters in the deeper intermediate system. Surface waters and shallow groundwaters collected from wells completed in overburden have undergone extensive evaporation as evidenced by their enriched δ¹⁸O and δ²H composition. Minor evaporation identified in the isotope composition of groundwater from domestic wells completed in bedrock, as well as from springs, suggests a local to intermediate origin for these waters, and perhaps mixing with shallow evaporative waters. In contrast, the uniform isotope signatures of deep basin waters measured both spatially and vertically suggest recharge at higher elevations, and a much deeper circulation system that is essentially isolated from the shallow subsurface. Chemical geothermometry indicates that spring waters and bedrock well waters have equilibrated at temperatures of less than 20 and 60°C, respectively. Groundwaters encountered by deep diamond drill holes, with equilibration temperatures of less than 80°C, are representative of intermediate flow systems, and may serve to modify the heat flow regime in the basin. Regional groundwater flow within the basin is complex due to numerous faults that exert a strong influence on fluid circulation patterns. Transport of heat in the subsurface, which has resulted in variations in the measured thermal gradients across the basin, occurs either at depths greater than those investigated in this study or has been significantly influenced by the circulation of cooler groundwater in the central part of the basin.     

Induced micro-seismicity during well discharge: OW-719, Olkaria, Kenya rift

A micro-seismic survey was carried out in concurrence with reservoir interference tests around Olkaria well 719, which has a mass output of 140–160 ton/h. The correlation between output and micro-seismicity shows that the seismic intensity peaks have a time lag of 6 to 11 days behind the mass output peaks. Seismicity spreads from the well bore in two major directions, a faster NE–SW trend at about 0.6 m/h and a slow NW–SE trend at about 0.4 m/h. These rates are comparable to those obtained by injecting organic tracers and monitoring in adjacent wells. Fluid feeder zones are at 1300–1400 m and 1600–1800 m depth and are coincident with contacts between different lithologies that provide capping and horizontal permeability. A possible NNE–SSW trending barrier to fluid flow has been observed between OW-719 and OW-718 wells.     

Chilean geothermal resources and their possible utilization

Most of the hot spring areas in Chile are located along the Andean Cordillera, associated with Quaternary volcanism. The volcanic—geothermal activity is mainly controlled by the subduction processes of the Nazca and Antarctic oceanic plates under the South America continental plate, and occurs at three well-defined zones of the Chilean Andes: the northern zone (17°30′–28°S), the central—south zone (33φ–46°S) and the southern-most or Austral zone (48°–56°S).Some tested high temperature geothermal fields, and geological and geochemical surveys of many other hot spring areas, evidence a great potential of geothermal resources in this country. Both electrical and non-electrical applications of this potential are considered in this paper.Taking into account the potentially available geothermal resources, the development of natural resources, the geographic and social—economic conditions existing in the different regions of Chile, it is concluded that power generation, desalination of geothermal waters, recovery of chemicals from evaporite deposits and brines and sulfur-refining are the main possible applications of geothermal energy in northern Chile; in central—south Chile geothermal energy is suitable for agribusiness such as greenhouses, aquaculture and animal husbandry.     

Thermal waters of the Yemen Arab Republic

Thermal waters (30–61°C) occur in springs and shallow drill-holes (max. 300 m) in several areas of the Yemen Arab Republic. Their mineral content is generally low (< 1000 – 2000 ppm TDS) except for waters with high CO₂ content and those directly influenced by the evaporitic Baid formation (Tertiary) in the Western Lowlands along the Red Sea. The temperature anomalies occur in areas of Quaternary basaltic volcanism (Aden formation) and in fault zones connected with the eastern margin of the Red Sea graben. In the latter zones radiogenic heat may be contributed by Tertiary granitic intrusions.     

Geothermal systems in Iceland: Structure and conceptual models—II. Low-temperature areas

A review and assessment of data pertaining to the origin and nature of low-temperature geothermal activity in Iceland are presented. This activity is widely distributed in Quaternary and Tertiary formations on the American plate in western Iceland west of the active belts of volcanism and rifting but it is very sparse on the European plate east of these belts. Low-temperature systems occur in a few places within the active volcanic belts. Temperatures range from just above ambient to a little over 150°C. Generally speaking, resevoir temperatures decrease with increasing distance from the active volcanic belts. The distribution of the low-temperature areas can be correlated to a large extent with active tectonism. In Iceland the European plate is tectonically stable but in the American plate the shear stress field is complicated, leading to complex fracturing and faulting of the crust at present. No single generalized conceptual model describes the basic features of all low-temperature areas in Iceland. Low-temperature geothermal activity is considered to develop by one of the following four processes, or any combination of them: (1) deep flow of groundwater from highland to lowland areas through permeable structures driven by the hydraulic gradient; (2) convection in young fractures formed by tectonic movements in old and relatively impermeable bedrock; (3) drift of high-temperature geothermal systems out of the active volcanic belts in conjunction with their cooling and extinction of the magma heat source; and (4) magma intrusion into Quaternary or Tertiary formations adjacent to the active volcanic belts. Formation of permeable fractures by recent earth movements is probably the most common process responsible for the development of low-temperature activity through convection in these fractures. Convection in low-temperature systems with temperatures above some 60°C is probably mostly driven by pressure differences created by a relatively light hot water column within the system and a denser cold water column outside it. In systems of lower temperature the convection is driven by hydrostatic head in the recharge areas. The source of the low-temperature waters is largely meteoric. However, in some coastal areas a significant seawater-groundwater component is present, up to 10%. Waters not containing a seawater component are low in dissolved solids, or in the range 150–500 ppm. The reason is the low content of anions, particularly Cl, in the basaltic rock forming soluble salts with the major aqueous cations. Geothermal waters from the low-temperature areas in Iceland typically possess lower δD-values (more negative) than the local precipitation. This difference is variable; most often it lies in the range of 10–30% δD, but it may be as large as 70‰. This difference has been considered to indicate that the recharge areas to the low-temperature areas lie inland on higher ground, the distance being as much as 150 km. The interpretation favoured here is that at least some of the low-temperature waters contain a component of “ice-age water”, i.e. water that is older than about 10, 000 years. The “ice-age water” is depleted in deuterium relative to today's precipitation. When “ice-age water” is present in the geothermal water, deuterium cannot be used as a tracer to locate the recharge areas to the geothermal areas and in this way to deduce about regional groundwater flow.     

Geology and fluid chemistry of the Fushime geothermal field, Kyushu, Japan

The Fushime geothermal field is located in a depression close to the coast line. The system is characterized by very high reservoir temperature (>350°C), and a high salinity production fluid. Geological analysis shows that the main reservoir in this field occurs in a fractured zone developed around a dacite intrusion located in the center of the field. High permeability zones recognized by drilling data are found to be associated with fault zones. One of these zones is clearly associated with a NW–SE trending andesite dike swarm which was encountered in some wells.Alteration in the system can be divided into four zones, in order of increasing temperature, based on calcium–magnesium aluminosilicate mineral assemblages: i.e., the smectite, transition, chlorite and epidote zones. The feed zone is located in the chlorite and epidote zones, which can be further divided into three sub-zones according to their potassium or sodium aluminosilicate mineralogy, from the center of the discharge zone: K-feldspar–quartz, sericite–quartz, and albite–chlorite zones.Chloride concentration of the sea-water is 19,800 mg/l, and Br/Cl mole ratio is 1.55. Based on geochemical information, the reservoir chloride concentration of this field ranges from 11,600 to 22,000 mg/kg. The Clres (Cl in reservoir), Br/Cl ratios and stable isotope data indicate that the Fushime geothermal fluid originated from sea-water and is diluted by ground water during its ascent. Some fluids produced from geothermal wells show low pH (about 4). It is thought that sulfide mineral (PbS, ZnS) precipitation during production produces this acidic fluid.     

Hydrogeochemical exploration of geothermal prospects in the Tecuamburro Volcano region, Guatemala

Chemical and isotopic analyses of thermal and nonthermal waters and of gases from springs and fumaroles are used to evaluate the geothermal potential of the Tecuamburro Volcano region, Guatemala. Chemically distinct geothermal surface manifestations generally occur in separate hydrogeologic areas within this 400 km² region: low-pressure fumaroles with temperatures near local boiling occur at 1470 m elevation in a sulfur mine near the summit of Tecuamburro Volcano; non-boiling acid-sulfate hot springs and mud pots are restricted to the Laguna Ixpaco area, about 5 km NNW of the sulfur mine and 350–400 m lower in elevation; steam-heated and thermal-meteoric waters are found on the flanks of Tecuamburro Volcano and several kilometers to the north in the andesitic highland, where the Infernitos fumarole (97°C at 1180 m) is the primary feature; neutral-chloride hot springs discharge along Rio Los Esclavos, principally near Colmenares at 490 m elevation, about 8–10 km SE of Infernitos. Maximum geothermometer temperatures calculated from Colmenares neutral-chloride spring compositions are 180°C, whereas maximum subsurface temperatures based on Laguna Ixpaco gas compositions are 310°C. An exploration core hole drilled to a depth of 808 m about 0.3 km south of Laguna Ixpaco had a bottom-hole temperature of 238°C but did not produce sufficient fluids to confirm or chemically characterize a geothermal reservoir. Hydrogeochemical data combined with regional geologic interpretations indicate that there are probably two hydrothermal-convection systems, which are separated by a major NW-trending structural boundary, the Ixpaco fault. One system with reservoir temperatures near 300°C lies beneath Tecuamburro Volcano and consists of a large vapor zone that feeds steam to the Laguna Ixpaco area, with underlying hot water that flows laterally to feed a small group of warm, chloriderich springs SE of Tecuamburro Volcano. The other system is located beneath the Infernitos area in the andesitic highland and consists of a lower-temperature (150–190°C) reservoir with a large natural discharge that feeds the Colmenares hot springs.     

Chemical and light-stable isotope characteristics of waters from the raft river geothermal area and environs, cassia county, idaho; box elder county, Utah

Chemical and light-stable isotope data are presented for water samples from the Raft River geothermal area and environs. On the basis of chemical character, as defined by a trilinear plot of per cent milliequivalents, and light-stable isotope data, the waters in the geothermal area can be divided into waters that have and have not mixed with cold water. The non-mixed waters have essentially a constant value of light-stable isotopes but show a large variation in chloride content. The variation of chloride composition is not the usual pattern for deep geothermal waters, where it is normally assumed that the deep water has a single chloride composition. Different mixed waters also have hot-water sources of varying chloride composition. Plots of chloride values on cross-sections show that water circulation patterns are confused, with non-mixed waters having different chloride concentrations located in close proximity. Three models can explain the characteristics of the deep geothermal water: (1) in addition to near-surface mixing of cold and hot water, there is deep mixing of two hot waters with the same enthalpy and isotopic composition but differing chloride concentrations to produce the range of chloride concentrations found in the deep geothermal water; (2) there is a single deep hot water, and the range of chloride concentrations is produced by the water passing through a zone of highly soluble materials (most likely in the sedimentary section above the basement) in which waters have different residence times or slightly different circulation paths; (3) the varying chloride concentrations in space have been caused by varying chloride concentrations in the deep feed water through time. Some of this older water has not been flushed from the system by the natural discharge. Although one model may seem more plausible than the others, the available data do not rule out any of them. Data for water samples from the Raft River and Jim Sage Mountains show that water from these areas is probably the source for the cold mixing water determined from end-members on mixing lines. Data for water samples in the Upper Raft River Valley show that the thermal anomaly found at Almo 1 is probably not related to the Raft River geothermal area. The water is different in type as shown by its placement on a trilinear plot, and the isotopes are different enough to show that it is probably a different water. Isotopic compositions of samples from a wide area around the Raft River geothermal system indicate that the likely source of the recharge water is the southern Albion Mountains and western Raft River Mountains. The recharge area is at one end of the Narrows zone, and the geothermal area is along the Narrows zone; thus it is likely that the Narrows zone defines the circulation path.     

Hydrogeochemistry and groundwater circulation in the Xi’an geothermal field, China

Geothermal waters from the Tertiary aquifers located at 1000–3000 m beneath Xi’an city, Shaanxi Province, China, show unique isotopic composition as compared to local groundwaters from shallower Quaternary aquifers. Positive oxygen shifts of as much as 8‰ VSMOW are observed, while the corresponding δ²H values remain essentially constant at about −80‰ VSMOW, which is significantly different from those of waters in the Quaternary aquifers with a mean δ²H value of −60‰ VSMOW. The strong ¹⁸O shift is a result of isotope exchange between geothermal water and carbonate minerals such as calcite over a residence time of several thousand years up to 30,000 years, based on ¹⁴C dating. A comparison of the isotopic composition of geothermal waters with neighbouring groundwater units on both sides of the Guanzhong Basin indicates that the geothermal reservoirs are recharged by rain that falls on the northern slope of the Qinling Mountains, south of the Xi’an geothermal field, but not from the North Mountains to the north of the field. Based on chemical geothermometers the highest temperature estimated for the Tertiary aquifers of the Xi’an area is around 130 °C.