Experimental analysis on desiccant regeneration in a packed column with structured and random packing

This paper presents the experimental tests on desiccant regeneration carried out in a packed column with the hygroscopic solution H₂O/LiBr. Two different packed columns have been tested: a random column consisting of 1” Pall Ring elements and a structured column Mellapack 250Y. The experimental results are reported in terms of desiccant concentration increase, regeneration effectiveness and air side pressure drop. The experimental tests show that desiccant regeneration requires a temperature level around 50 °C that can be easily obtained by using solar energy or heat recovered from an industrial process or from a thermal engine. The random column shows regeneration performance 20-25% higher than structured column, whereas the structured column shows air side pressure drop from 65% to 75% lower. The experimental results have been compared against a one-dimensional simulation code of a packed column: a fair agreement is found between experiments and simulation.     

A packed bed dehumidifier/regenerator for solar air conditioning with liquid desiccants

A packed column air-liquid contactor has been studied in application to air dehumidification and regeneration in solar air conditioning with liquid desiccants. A theoretical model has been developed to predict the performance of the device under various operating conditions. Computer simulations based on the model are presented which indicate the practical range of air to liquid flux ratios and associated changes in air humidity and desiccant concentration. An experimental apparatus has been constructed and experiments performed with Monoethylene Glycol (MEG) and Lithium Bromide as desiccants. MEG experiments have yielded inaccurate results and have pointed out some practical problems associated with the use of Glycols. LiBr experiments show very good agreement with the theoretical model. Preheating of the air is shown to greatly enhance desiccant regeneration. The packed column yields good results as a dehumidifier/regenerator, provided pressure drop can be reduced with the use of suitable packing.     

Experimental comparison and analysis on silica gel and polymer coated fin-tube heat exchangers

In this paper, two desiccant-coated heat exchangers, which are actually fin-tube heat exchanging devices coated with silica gel and polymer materials respectively, are investigated experimentally. Due to the hygroscopic properties of the desiccant materials, both the sensible heat and the latent heat of the process air can be handled by using this kind of heat exchanger. An experimental setup was designed and built to test the performance of this unit. It is found that this desiccant-coated fin-tube heat exchanger well overcomes the side effect of adsorption heat which occurs in desiccant dehumidification process, and achieves good dehumidification performance under given conditions. The silica gel coated heat exchanger behaves better than the polymer one. The influences of regeneration temperature, inlet air temperature and humidity on the system performance in terms of average moisture removal rate D_avg and thermal coefficient of performance COP_th were also analyzed.     

Development of a novel two-stage liquid desiccant dehumidification system assisted by CaCl2 solution using exergy analysis method

Air conditioning system based on liquid desiccant has been recognized as an efficient independent air humidity control HVAC system. To improve thermal coefficient of performance, a novel two-stage liquid desiccant dehumidification system assisted by calcium chloride (CaCl₂) solution is developed through exergy analysis based on the second thermodynamic law. Compared with the basic liquid desiccant dehumidification system, the proposed system is improved by two ways, i.e. increasing the concentration variance and the pre-dehumidification of CaCl₂. The exergy loss in the desiccant–desiccant heat recovery process can be significantly reduced by increasing desiccant concentration variance between strong desiccant solution after regeneration and weak desiccant solution after dehumidification. Meanwhile, the pre-dehumidification of CaCl₂ solution can reduce the irreversibility in the regeneration/dehumidification process. Compared to the basic system, the thermal coefficient performance and exergy efficiency of the proposed system are increased from 0.24 to 0.73 and from 6.8% to 23.0%, respectively, under the given conditions. Useful energy storage capacity of CaCl₂ solution and LiCl solution at concentration of 40% reach 237.8 and 395.1 MJ/m³, respectively. The effects of desiccant regeneration temperature, air mass flux, desiccant mass flux, etc., on the performance of the proposed system are also analyzed.     

Study of an aqueous lithium chloride desiccant system: air dehumidification and desiccant regeneration

Desiccant systems have been proposed as energy saving alternatives to vapor compression air conditioning for handling the latent load. Use of liquid desiccants offers several design and performance advantages over solid desiccants, especially when solar energy is used for regeneration. For liquid–gas contact, packed towers with low pressure drop provide good heat and mass transfer characteristics for compact designs. This paper presents the results from a study of the performance of a packed tower absorber and regenerator for an aqueous lithium chloride desiccant dehumidification system. The rates of dehumidification and regeneration, as well as the effectiveness of the dehumidification and regeneration processes were assessed under the effects of variables such as air and desiccant flow rates, air temperature and humidity, and desiccant temperature and concentration. A variation of the Öberg and Goswami mathematical model was used to predict the experimental findings giving satisfactory results.     

太阳能再生式除湿换热器动态除湿性能研究

提出了一种新型再生式除湿换热器,建立了物理和数学模型。通过实验得到了该除湿换热器的实际动态除湿性能;将除湿器除湿性能的模拟结果与实验结果进行比较,验证了数学模型的可靠性。研究结果表明:该文研制的再生式除湿换热器具有良好的除湿性能,在给定工况(温度为24.7℃,含湿量为12.41g/kg)下除湿率可达到43.8%;还分析了处理风速、再生温度以及除湿换热器厚度对除湿性能和压降的影响,获得了使除湿换热器性能最佳的管排、翅片间距和迎面风速参数。     

Performance characterisation of liquid desiccant columns for a hybrid air-conditioner

Use of liquid desiccant-vapor compression hybrid system is encouraged for low humidity applications. The liquid desiccant is primarily used to further dehumidify the supply air. In the present study, by using psychrometric equations and liquid desiccant property data, heat and mass transfer analysis for the dehumidifier and regenerator columns in counter flow configuration has been carried out. The simulation of the columns corresponds to low solution to air (S/A) flow ratio where precooled air gets dehumidified in the absorber while preheated air is used for regeneration of the solution. A detailed study of the performance characteristics for the absorber and regenerator columns confirms the requirement of the desiccant loop for additional dehumidification of the conditioned air. This need develops the main motive towards the concept of hybrid air conditioning.     

Thermodynamic analysis of a counter flow adiabatic dehumidifier with different liquid desiccant materials

Liquid desiccant systems have been proposed as energy saving alternatives to the conventional vapor compression systems for handling the latent load. This paper presents the results from a study of the performance of a counter flow liquid desiccant dehumidifier. A heat and mass transfer theoretical model of an adiabatic packed column has been developed, based on the Runge-Kutta fixed step method, to predict the performance of the device under various operating conditions. Good agreement was found between experimental tests and the theoretical model, with the maximum deviation being ±2.9% in air outlet temperature, ±15.9% in air outlet humidity ratio and ±2.8% in solution outlet temperature. Following the model validation, the rate and the efficiency of the dehumidification process were assessed under the effects of variables, such as air temperature and humidity, desiccant temperature and humidity and air and desiccant flow rates. The three most commonly used liquid desiccant solutions, namely LiCl, LiBr and CaCl₂ were evaluated against each other. The results show that high absorber efficiency and system efficiency could be achieved under humid conditions, low air mass flow rates and LiCl as the desiccant solution.     

Performance evaluation of a solar-powered flat-plate multichannel liquid desiccant air conditioning system

There has been a limited application of liquid desiccant (LD) dehumidification systems in space air conditioning until now. The key elements responsible for this restricted implementation are leakage of desiccant solution, corrosion of components, and solution carryover along with the processed air to the space to be conditioned. To remove these problems, an evacuated tube solar heat collector-driven multichannel liquid desiccant air conditioning system has been proposed and experimentally investigated. In this study, dehumidification and regeneration rate, their effectiveness, cooling effect of the dehumidifier, and indirect evaporative cooling unit have been analyzed. The results obtained indicate that the process air has been dehumidified and cooled by 6.32 g kg⁻¹ and 5.26°C, respectively. The regeneration rate and effectiveness have been obtained to be 0.26 g s⁻¹ and 0.31, respectively. In terms of the cooling effect, the system output of 0.703 and 0.130 kW has been obtained from the dehumidifier and indirect evaporative cooling unit of the system, respectively. The proposed system validates the possibility of the novel solar-powered liquid desiccant air conditioning system concept and provides growth and development of the LD air conditioning technology for space air conditioning.     

An experimental study of structured packing dehumidifier/regenerator operating with liquid desiccant

The present work presents an experimental investigation on the performance of the structured packing cross flow desiccant dehumidification system (DDS). This system is referred as DDS; its heart is the dehumidifier/regenerator. It is used to meet a latent heat load by air dehumidification. Calcium chloride (CaCl₂) solution is used as the working desiccant material in this system. The structured packing has a density (specific surface area) of 390 m²/m³, corrugation angle of 60° and void fraction of 0.88. The effect of relevant parameters such as air flow rate, desiccant solution flow rate, desiccant solution temperature and concentration and packing thickness on the performance of the system is studied. The performance of the system is evaluated using the mass transfer coefficient, moisture removal rate (MMR), effectiveness and the coefficient of performance (COP). The remarkable increase of mass transfer coefficient and MRR for both deh/reg is observed by increasing both air and solution flow rates. Eventually, the payback period (PP) of the DDS is 11 months with annual running cost savings (ΔC_RC) of about 31.24% compared with vapor compression system (VCS) dehumidification. The overall environmental impacts of DDS are nearly 0.63 of VCS. This may emphasize the need of incorporating a desiccant system along with air conditioning applications.     

The research and development of the key components for desiccant cooling system

An air conditioning option, that is, desiccant cooling system (DCS) in which alternative energy source, such as solar energy, nature gas and rejected heat, can play their part for the benefit of environment and saving energy is constructed by regenerative dehumidification component combined with heat exchanger (recuperator) and evaporative cooler.The mathematical model of an rotary desiccant wheel that can be used to calculate the performance of stationary or rotary bed and transient or steady state operation is founded by considering many terms. A computer program for this new model has been compiled and some results of computer simulation compared with experimental value, they are good in agreement.The performance of evaporator is estimated by computer. We developed some kinds of evaporator of which the COP is about 1015 to decrease the room temperature and clean the air in drier climates. Using a new kind of chemical refrigerant invented by Zu-She Liu, the air conditioner will be simple in construction and very efficient (COP > 30).     

Investigation of an open cycle liquid desiccant system for the air conditioning of an university building

The paper reports on the experimental results recorded in a liquid desiccant system for the air conditioning of an university building. The plant is composed by a desiccant column to treat the exhausted air fed by a solution H₂O–LiBr, operating both in winter and in summer mode. In winter the system operates an effective heat recovery on the exhaust air; in summer the plant dehumidifies the ambient air to face the latent load. The measured performances during winter operation are presented to evaluate the behaviour of the system as a whole and of the various components. Copyright © 2006 John Wiley & Sons, Ltd.     

Introduction of a new definition for effectiveness of desiccant wheels

In common air conditioning methods, both sensible and latent loads are handled by cooling systems. Utilizing desiccant, individual cooling and dehumidification processes are possible. In this paper, desiccant wheel operation has been investigated by experimental study. Experimental conditions include different climates (hot dry and hot humid) at different operating parameters (regeneration temperature and wheel speed). Due to the temperature and humidity measurements of inlet and outlet streams, the desiccant wheel efficiency in each definition was calculated. All experiments show that enthalpy of the outlet process air is notably higher than that of the inlet air. This event leads to a novel efficiency definition which presents the deviation of the outlet process air enthalpy from the inlet air enthalpy. By increase in the dehumidification efficiency, the adiabatic efficiency decreases, whereas it increases by the regeneration efficiency. Hence in some situations the adiabatic efficiency will have an optimum value. According to the adiabatic efficiency concept, it seems to be related to the coefficient of performance of the desiccant cooling systems.     

蓄能型液体除湿蒸发冷却系统中除湿性能的实验研究

提出了一种新型空调系统——液体除湿冷却空调系统的设计方案并搭建一功率为3kW的实验台，考虑到除湿过程和再生过程是该系统性能优良的决定性环节，设计加工了水冷型波纹板降膜式结构的除湿器和以丝网填料作为内部填料的再生器。在此实验装置上对系统的除湿过程以及其蓄能能力特性进行了实验研究，得出影响该系统除湿能力、蓄能能力等方面的主要因素，为系统的优化设计和运行提供依据。     

Experiments in a solar simulator on solid desiccant regeneration and air dehumidification for air conditioning in a tropical humid climate

This paper presents an indoor and analytical study to evaluate the performance of a desiccant cooling system that uses silica gel as desiccant, electric light bulbs to simulate solar radiation, and forced flow of air through an IDC (integrated Desiccant/Collector). In the regeneration process, the rate at which water is removed from the desiccant increases with irradiation and decreases with air flowrate. In the air dehumidification process, the adsorption rate decreases with irradiation and increases slightly with flowrate. Comparisons between analytical calculations and experimental data show good agreement, and the calculations show that it should be possible to operate this system in tropical humid climates using the regeneration process in the day and the air dehumidification in the night time.     

Comparative study between parallel and counter flow configurations between air and falling film desiccant in the presence of nanoparticle suspensions

A comparative numerical study is employed to investigate the heat and mass transfer between air and falling film desiccant in parallel and counter flow configurations. Nanoparticles suspensions are added to the falling film desiccant to study heat and mass transfer enhancements. The numerical results show that the parallel flow channel provides better dehumidification and cooling processes of the air than counter flow configuration for a wide range of pertinent parameters. Low air Reynolds number enhances the dehumidification and cooling rates of the air and high air Reynolds number improves the regeneration rate of the liquid desiccant. An increase in the channel height results in enhancing the dehumidification and cooling processes of air and regeneration rate of liquid desiccant. The dehumidification and cooling rates of air are improved with an increase in the volume fraction of nanoparticles and dispersion factor. Copyright © 2003 John Wiley & Sons, Ltd.     

Effectiveness of heat and mass transfer in packed beds of liquid desiccant system

A liquid desiccant system (using CaCl₂) is presented for air dehumidification using solar energy or any other low grade energy to power the system. The system utilizes two packed beds of counterflow between an air stream and a solution of liquid desiccant for the processes of air dehumidification and solution regeneration. To simplify the prediction of the performance of the system an effectiveness of heat transfer and an effectiveness of mass transfer in the packed beds are defined. A finite difference model is developed to model the heat and mass transfer in packed beds during the air dehumidification mode and the solution regeneration mode. This finite difference model is used to calculate the effectiveness of heat and mass transfer in the packed beds at various bed heights, various air and solution flow rates, various inlet temperatures of air and solution to the bed, and various concentrations of CaCl₂ solution at the bed entrance. Charts of the effectiveness of heat and mass transfer are presented in a convenient form. A designer of a liquid desiccant system may use the charts in predicting the performance of these systems without having to use the finite difference model for this purpose.     

Technical development of rotary desiccant dehumidification and air conditioning: A review

Rotary desiccant air conditioning system, which combines the technologies of desiccant dehumidification and evaporative cooling, is advantageous in being free from CFCs, using low grade thermal energy and controlling humidity and temperature separately. Compared with conventional vapor compression air conditioning system, it preserves the merits of environment-friendly, energy saving, healthy, comfortable, etc. Ongoing research and development works suggest that new desiccant materials and novel system configurations have significant potential for improving the performance and reliability and reducing the cost and size of rotary desiccant dehumidification and air conditioning system, thereby increasing its market competitiveness and breaking out the current fairly small niche market. For the purpose of providing an overview of recent efforts on these issues and showing how rotary desiccant air conditioning systems can be designed and coupled to available thermal energy, this paper presents and analyzes the status of rotary desiccant dehumidification and air conditioning in the following three aspects: the development of advanced desiccant materials, the optimization of system configuration and the utilization of solar energy and other low grade heat sources, such as solar energy, district heating, waste heat and bioenergy. Some key problems to further push forward the research and development of this technology are also summarized.     

Control performance of a dedicated outdoor air system adopting liquid desiccant dehumidification

Liquid desiccant is energy efficient for dehumidification in air-conditioning systems. In this study, a novel dedicated outdoor air system (DOAS) adopting lithium chloride solution as liquid desiccant is proposed to process supply air. The DOAS mainly consists of a membrane-based total heat exchanger, a liquid dehumidifier, a regenerator and a dry cooling coil. It can realize independent temperature and humidity controls for supply air. Control strategies for the supply air dehumidification and cooling process as well as the desiccant solution regeneration process in the DOAS are developed and verified. The control performances of the proposed dedicated outdoor air system are investigated at different operation conditions by simulation tests. The results show that the DOAS is more suitable for hot and humid climates. The effects of the total heat exchanger on the performance of the DOAS are also evaluated. It can improve the system energy performance by 19.9–34.8%.     

Parametric analysis of desiccant wheel for air conditioning application

A one‐dimensional mathematical model is developed to evaluate the operating and design parameters of the desiccant wheel for air conditioning application. In this paper, dehumidification coefficient of performance (DCOP) and sensible energy ratio (SER) are adopted as a combined performance index to reflect the dehumidification and thermal performance of the desiccant wheel. The analysis of the results reveals that for lower SER, suitable wheel length, wall thickness, channel pitch, and channel height should be 100 mm, 0.2 mm, 3 mm, and 5 mm, respectively. These design parameters have been analyzed under different operating conditions and it was found that for higher DCOP, rotational speed, regeneration temperature, process and regeneration velocity should be 20 rph, 60°C, and 2 m/s.