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以八甲基环四硅氧烷(D4)、苯基三(二甲基硅氧烷基)硅烷(PTDMS,俗称三氢封头剂)或四(二甲基硅氧基)硅烷(TDMS,俗称四氢封头剂)为原料,通过开环聚合法合成了三端氢基聚硅氧烷(PDMS-H3)和四端氢基聚硅氧烷(PDMS-H4);再将其与甲基丙烯酸叔丁酯(t-BMA)在氯铂酸-四氢呋喃(THF)溶液催化下通过硅氢加成反应得到三端酯基聚硅氧烷(PDMS-t-BMA3)和四端酯基聚硅氧烷(PDMS-t-BMA4);最后在浓硫酸催化下水解制得三端羧基聚硅氧烷(PDMS-COOH3)和四端羧基聚硅氧烷(PDMS-COOH4)。采用FT-IR、1H NMR和GPC对各阶段产物的结构和摩尔质量及其分布进行表征。结果表明,通过开环聚合、硅氢加成、酸性水解三步反应能够获得结构清晰、摩尔质量可控的多臂端羧基聚硅氧烷,且叔丁酯基聚硅氧烷酸性水解反应效率高,后处理简单,对硅氧烷主链的影响较小。 相似文献
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烃羧基硅油制备的新工艺研究 总被引:1,自引:0,他引:1
以单体甲基丙烯酸甲酯和大分子的聚甲基氢硅氧烷为原料进行硅氢加成反应和水解反应,将含氢硅油改性合成烃羧基硅油,反应收率较高,并通过实验确定了最佳反应条件。 相似文献
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以端环氧基烯丙基聚醚、含氢硅油为原料,采用第二代铂金催化剂,通过硅氢加成反应制备环氧基改性硅油。研究了反应时间、反应温度、物料配比对反应转化率的影响。通过单因素试验得到最佳反应条件为:反应时间7 h、反应温度100℃、含氢硅油与端环氧基聚醚的摩尔比为1∶1.1。在此条件下含氢硅油的转化率为91%。红外表征证实,产物接上了端环氧基烯丙基聚醚。 相似文献
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《有机硅材料及应用》2009,(5):333-333
甘肃农业职业技术学院的冯武将烯丙基缩水甘油醚与自制的聚乳酸-聚乙二醇共聚物在锌粉催化下反应,得到4-(3-烯丙氧-2-羟基)丙氧基封端的聚乳酸-聚乙二醇共聚物;再与含氢硅油进行硅氢加成反应,制得带可降解侧链的亲水性聚硅氧烷;并测定了其相对密度、折射率、数均摩尔质量、重均摩尔质量及其分布指数,胶膜的水接触角。 相似文献
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烃羧基硅油 总被引:1,自引:1,他引:0
许璐茵 《有机硅材料及应用》2011,(3):216-216
衢州学院的姚方等人以含氢硅油与甲基丙烯酸甲酯为原料、苯为溶剂、氯铂酸为催化剂,通过硅氢加成反应,制得了烃羧酸甲酯硅油;纯化后加入NaOH水溶液进行水解反应,经中和、洗涤、干燥后,得到烃羧基硅油。硅氢加成反应的较佳条件是氯铂酸用量为含氢硅油质量的60×10^-6,甲基丙烯酸甲酯与含氢硅油的量之比为1.4, 相似文献
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我国脂肪酸的生产和应用 总被引:3,自引:0,他引:3
陆蠡珠 《精细与专用化学品》2007,15(1):24-28
简要介绍脂肪酸的分类、原料来源、生产工艺、品种以及用途。并对我国脂肪酸的生产现状进行了分析。重点介绍了脂肪酸在我国橡胶工业中、塑料助剂等领域的应用,脂肪酸甲酯作为表面活性剂在不同领域的广泛应用,最后还简述了癸二酸和改性醇酸树脂应用。 相似文献
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酸液体系的研究现状分析和现场应用 总被引:1,自引:0,他引:1
酸化解堵与压裂改造相比,它具有施工相对简单和成本相对较低等特点,所以酸化解堵是一项各油田广泛使用的油气田增产技术。酸化解堵技术已有将近100历史,现已研制出具有不同特点的酸液体系,如乳化酸、泡沫酸、固体酸、多氢酸等,基本能满足复杂地质条件对酸液的要求。 相似文献
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The Growth‐Inhibiting Effects of Beef Fatty Acids on MCF‐7 Cells Are Influenced Mostly by the Depot Location and Inconsistently by the Biohydrogenation Intermediate Content 下载免费PDF全文
Payam Vahmani David C. Rolland Katherine E. Gzyl Danica D. S. Baines Michael E. R. Dugan 《Lipids》2018,53(7):699-708
Biohydrogenation intermediates (BHI) including conjugated linoleic acid (CLA) isomers are formed during ruminal biohydrogenation of polyunsaturated fatty acids (PUFA) in ruminants. Although many studies have examined the anticarcinogenic effects of CLA, few studies have reported the anticarcinogenic properties of BHI in their natural form found in dairy and beef fats. The present study compared the growth‐inhibitory effects of fatty acids from beef perirenal fat (PRF) or subcutaneous fat (SCF) with low or high levels of BHI in MCF‐7 human breast cancer cells. Cells were exposed for 72 h to media containing increasing doses (50 to 400 μM) of different beef fat treatments. Fatty‐acid analysis showed that BHI were readily incorporated into cell phospholipids (PL) in a treatment‐dependent manner, but higher BHI in PL did not consistently inhibit growth. Culturing with low‐BHI PRF or high‐BHI PRF did not lead to growth inhibition, but low‐BHI SCF inhibited growth, and inhibition was further increased by high‐BHI SCF. Other classes of fatty acids may, therefore, be interacting with BHI resulting in differential effects on growth inhibition in human breast cancer cells. 相似文献
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介绍了磷钼杂多酸的合成。通过正交试验探讨了反应物料量比、三氧化钼浓度、反应温度和反应时间对产物产率的影响。结果表明,最适宜的反应条件为:反应物量比n(三氧化钼)∶n(磷酸)=12∶1.0、反应温度t=70℃、反应时间7 h、三氧化钼与水的质量比1∶8。经红外光谱分析及熔点测定确定所得产品为磷钼杂多酸化合物。并以磷钼杂多酸取代硫酸作催化剂制备乙酸乙醋来研究其催化活性,并与硫酸做催化剂进行对比实验收率为70.75%,超过硫酸催化剂水平。 相似文献
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Claudio Guilherme Portela de Carvalho Matheus Felipe da Silva José Marcos Gontijo Mandarino Anna Karolina Grunvald Nilza Patrícia Ramos José Lopes Ribeiro Vicente de Paulo Campos Godinho 《Journal of the American Oil Chemists' Society》2018,95(1):61-67
This study aimed to evaluate the fatty acid profiles of sunflower oil extracted from hybrid grains produced and stored in different environments. The trials were conducted in Teresina (Piauí), Vilhena (Rondônia), and Jaguariúna (São Paulo) in randomized complete block design with 4 replicates. After harvesting, grains from 1 high oleic and 3 traditional hybrids were packed in kraft paper bags and stored in a covered shed and in a cold chamber up to 12 months. The fatty acid profiles were determined by gas chromatography after 0, 4, 8, and 12 months of storage. Analyses of variance were conducted in a split‐plot design, with hybrids being considered as whole plots and storage times as subplots. Tukey's test was performed to compare hybrids and regression analyses for storage times. The initial fatty acid profile of the grains of the same hybrid varied depending on the production location. The grain storage of high oleic and traditional sunflower hybrids during 12 months in covered shed and in cold chamber resulted in little changes in oil fatty acid profiles, regardless of the initial contents. These changes occurred only for linoleic and palmitic acids. 相似文献
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Claudio Guilherme Portela de Carvalho Luana Fernanda Mazzola José Marcos Gontijo Mandarino Flávio Carlos Dalchiavon José Lopes Ribeiro Aluisio Brigido Borba Filho Alberto Donizete Alves 《Journal of the American Oil Chemists' Society》2019,96(9):1019-1025
This study aimed to verify whether the fatty acid profiles of mid-oleic genotypes grown in the tropical region of Brazil fit the Codex Alimentarius and to examine the possibility of using traditional inbred lines to produce high-oleic hybrids. For this purpose, we assessed the fatty acid profile of six mid-oleic hybrids grown in environments with different minimum temperatures during oil formation in the achenes. The tests were conducted between 2015 and 2017 in an experimentally randomized complete block design with four replications. The oleic, linoleic, palmitic, and stearic acid contents were determined using gas chromatography. The mid-oleic hybrids presented varying levels of fatty acids, with oleic acid ranging between 43.6% and 84.6%, linoleic acid between 8.5% and 45.6%, palmitic acid between 3.9% and 5.7%, and stearic acid between 2.2% and 6.2%. Some of the fatty acid values were outside the ranges established by the CODEX STAN 210-1999 and were characteristic of high-oleic type sunflowers. This finding shows that we can take advantage of the potential of combining traditional inbred lines to produce high-oleic hybrids for faster and more economical breeding programs in these environments. 相似文献
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Claudio Guilherme Portela de Carvalho Luana Fernanda Mazzola Andressa Caldeira Flávio Carlos Dalchiavon José Marcos Gontijo Mandarino 《Journal of the American Oil Chemists' Society》2019,96(7):789-794
The objective of this work was to evaluate the quality of the oil extracted from sunflower achenes grown in Campo Novo de Parecis, the main producing region of Brazil, to optimize its use by the processing and food industries. In addition, the fatty acid profiles of the oil were checked for their adherence to the CODEX STAN 210–1999. Traditional and high-oleic genotypes were grown between 2014 and 2017 during trials with a randomized complete block experimental design with four replications. The contents of oleic, linoleic, palmitic, and stearic acids were determined using gas chromatography. The fatty acid profiles of traditional genotypes were observed to be outside the ranges established by the CODEX, with an oleic acid content above 39.4% and linoleic, palmitic, and stearic acid values lower than 48.3%, 2.7%, and 5.0%, respectively, as well as high-oleic sunflower oil with a stearic acid content of less than 2.6%. The availability of this information can, on the one hand, positively impact industries and encourage the use of better quality raw materials that are more technologically and nutritionally adequate. On the other hand, the commercialization of sunflower oil with a fatty acid profile outside the ranges established by CODEX can be difficult, because the contents are out of specification due to the climatic conditions in the cropping region. 相似文献
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丘宝增胡静怡汤吉海等 《化工时刊》2014,(2):1-4
采用廉价的浓硫酸为催化剂,氧气为自由基捕集剂,以十二酸为原料,经氯化合成α-氯代十二酸。系统考察了反应温度、催化剂用量、氯气流量、氧氯比、反应时间等因素的影响,得到最佳工艺条件:十二酸20 g,在反应温度135℃、催化剂10%、氯气流量50 mL·min-1、vO2/vCl2=1∶2、反应时间3 h,可实现十二酸基本完全转化,目标产物α-氯代十二酸选择性达到94.5%。 相似文献