等离子喷涂金属-陶瓷阶梯涂层

描述了阶梯涂层的等离子喷涂并利用简单的物理模型分析了阶梯涂层中间过渡区的金属一陶瓷界面，特别值得一提的是，确立了主要的控制沉积参数、粉末特性和选粉装置等在阶梯涂层中所起的重要作用．后者控制了金属一陶瓷阶梯涂层中的过渡区的结枸组成。在对遗些参数的有关知识进行了一定的了解的基础上．对基体的同一区域金属和陶瓷粉粒瞬时沉积的均匀性特征，推导出了一十新颖的计算公式。此外，描述了阶梯区金属一陶瓷界面非常重要的局部规整关系。各种结构分析技术和简单的热力学计算能够对金属和陶瓷组分之间的站台给出新的解释．预测的金属陶瓷阶梯涂层的结台强度比用金属作打底层的陶瓷涂层的结合强度迁高．用NiCr-Zr02(Mg0)阶梯涂层的实例对结果进行了说明。     

等离子喷涂制备典型涂层研究进展

从航空航天到交通运输、电子设备和医疗器械等,大大小小的行业中均可见到涂层的应用,涉及到这些领域的涂层种类主要有耐磨、耐蚀涂层、热障涂层、压电陶瓷涂层和生物陶瓷涂层等。等离子喷涂技术具有喷涂材料范围广、工艺简单等优点,是制备上述典型涂层的常用工艺方法。虽然同种工艺可制备出不同种类涂层,但由于所选的喷涂材料、喷涂参数不同,所获得的涂层性能和涂层结构之间也存在着一定差异,须对等离子喷涂各类涂层的研究进行分析与总结。基于此,文中简要介绍了国内外等离子喷涂涂层的应用现状,之后从不同种类涂层功能需求和技术特点出发,分析喷涂工艺对涂层结构和性能的影响。最后对提升涂层性能的工艺方法进行总结,并对今后等离子喷涂涂层技术的发展趋势进行了展望。     

等离子喷涂陶瓷涂层的应用

简述等离子喷涂陶瓷涂层的研究进展与现状,依据陶瓷涂层应用的分类,从等离子喷涂陶瓷涂层的耐磨涂层、热障涂层、耐蚀涂层、超导涂层、压电陶瓷涂层、生物活性涂层方面介绍了目前常用的等离子喷涂陶瓷材料的性能及其应用的研究现状。     

等离子喷涂陶瓷耐磨涂层的研究进展

介绍了传统陶瓷耐磨涂层及等离子喷涂陶瓷耐磨涂层,重点介绍了等离子喷涂陶瓷耐磨涂层的表面结构、摩擦磨损性能和磨损机制,并对等离子喷涂陶瓷涂层的发展趋势进行了展望。     

等离子喷涂陶瓷涂层后氧化处理的研究

对比研究了后氧化处理、封孔和退火、真空退火对大气等离子喷涂 (Al/Ni Cr2 O3 )陶瓷涂层硬度、结合强度等性能的影响。结果表明 ,合理的后氧化能够明显改善涂层性能 ,且氧的扩散是发挥作用的重要因素之一。     

界面温度对等离子喷涂金属—陶瓷涂层附着性能的影响

金属－陶瓷涂层主要作为热障涂层（ＴＢＣ）工艺广泛应用于工业化用途,等离子喷涂是制造ＴＢＣ最常用的工艺。常规的热障涂层包括一层金属粘合底层和一层隔热陶瓷面层。分层涂层或者功能递变型涂层也已经用来解决等离子喷涂的常规ＴＢＣ早期脱落的问题。等离子喷涂时的温度及其梯度,特别是刚与基体表面碰撞时的粉粒的温度对涂层质量具有重要的影响。当喷涂象金属与陶瓷那样的不同材料时,该因素的影响显著增强。在本研究中,是将金属－陶瓷涂层涂覆到金属基体上。用光学高温计测量界面温度,用热电偶测量基体温度。涂层的结合情况用标准的ＡＳＴＭ试验测定,并与测量的温度有关。结果表明,在一般情况下,具有较低附着值的涂层是那些具有较低界面温度的涂层。     

等离子喷涂纳米陶瓷涂层研究

从纳米喂料的制备、纳米陶瓷涂层的制备及其结构和特性三方面评述了等离子喷涂纳米陶瓷涂层研究的进展,探讨了等离子喷涂纳米陶瓷涂层研究中存在的主要问题,并展望了等离子喷涂纳米陶瓷涂层的发展前景。     

爆炸喷涂和等离子喷涂陶瓷涂层的性能

一、前言 采用爆炸喷涂和大气等离子喷涂Al2O3基和Cr2O3涂层。研究了涂层的微观结构和显微硬度值。用橡胶轮磨损试验做涂层的耐磨试验。     

等离子喷涂纳米结构ZrO2陶瓷涂层的工艺研究

研究工艺参数对等离子喷涂纳米结构ZrO2陶瓷涂层微观组织和力学性能的影响,采用三因素三水平正交试验法对喷涂电压、电流和主气流速三个主要参数进行了优化设计.采用定量金相分析法分析了涂层未熔化区域的大小,并测定了涂层的结合强度、裂纹扩展抗力和磨损性能.结果表明,制备纳米结构ZrO2陶瓷涂层的最佳工艺参数为电流540A,电流63V,主气流量45 L/min.     

等离子喷涂氧化铝陶瓷涂层微观结构研究

采用等离子喷涂方法２１Ｃｒ－６Ｎｉ－９Ｍｎ奥氏体不锈钢表面喷涂不同成分的氧化铝陶瓷涂层,并对其微观结构进行了分析。结果表明,等离子喷涂氧化铝陶瓷涂层与基体为机械结合,涂层中存在大量气孔且元素分布不均匀,其主要相为γ－Ａｌ２Ｏ３。     

等离子喷涂热障陶瓷涂层冷却累计残余应力的有限元模拟与验证

Plasma sprayed ZrO2 ceramic coating has been widely used in many industrial fields due to its simple manufacturing process, low cost, and good heat insulation effect. However, the structure and service conditions of thermal barrier coatings are complex, and residual stresses will inevitably occur during the preparation process as well as application. Residual stress has the most obvious influence on the life of thermal barrier coatings, seriously reducing the bonding strength between the coating and the substrate, and ultimately showing the cracking and spalling of the coating, greatly reducing the service time and stability of the coating during service. To realize the prediction and detection of the residual stress, it is necessary to seek a reliable detection method for thermal barrier coating to effectively predict the accumulated residual stress in the cooling process of coating and reduce the influence of residual stress on the stability of the coating. In this paper, the finite element model of plasma-sprayed ZrO2 coating was established by using the birth and death element method. Gauss heat source was used to simulate the heat source condition of plasma spraying, and the residual stress and its distribution of the coating cooling to room temperature were studied. The residual stress of ZrO2 coating prepared by plasma spraying was detected by X-ray diffraction and Raman spectroscopy to explore the accurate detection method of residual stress in ceramic coating. Through the analysis of the finite element results, it is found that the number of elements is reasonable and the calculation time is short when the mesh unit size of the model is 1.75 mm. The maximum temperature of the coating temperature field obtained by simulation is consistent with the test temperature in the experiment, and the simulation results are accurate. It can be concluded that the residual stresses in the central region of the plasma spraying coating after cooling to room temperature are larger than those in the edge region, which are mainly concentrated in the central region of heat flow. There is large stress at the bonding interface of each layer, which causes the stress to change significantly along the thickness direction of the coating. The equivalent stress of the coating is 160-220 MPa. The X-ray method was used to detect the residual stress of plasma sprayed coating. To obtain an isolated, complete, high peak position and high peak intensity with enough diffraction peaks to avoid the influence of texture, (331) crystal plane with a high multiplicity factor was selected as the characteristic peak. The test results show that the residual stress in the coating will make the position of the characteristic diffraction peak shift to a high angle at 2θ=153°. The residual stresses of 180-185 MPa were detected by X-ray diffraction. The I6 peak in the Raman spectrum of the coating was used as the characteristic peak of the spectrum to represent the frequency shift of the Raman spectrum band. Compared with the original spraying powder, the position of the Raman characteristic peak of the ceramic coating shifted to the low-frequency direction, indicating that there was residual tensile stress after the coating was cooled. The Raman-stress factor of the ZrO2 coating was calibrated to be 8.33 (cm·GPa)-1, and the residual stress of the coating was calculated to be 174-180 MPa. In this paper, the finite element method can effectively simulate the residual stress inside the coating when the plasma spraying reaches room temperature. It has good matching with the XRD and Raman spectrum detection results. There is about 180 MPa residual stress inside the coating when the coating is cooled to room temperature, seriously affecting the stability of the coating. © 2023 Chongqing Wujiu Periodicals Press. All rights reserved.     

WC等离子喷涂涂层摩擦磨损特性研究

采用自制的销盘式摩擦磨损试验机、光学显微镜,研究了WC等离子喷涂涂层与GCr15钢配副的摩擦磨损特性.结果表明:WC涂层的耐磨性能比基体材料(HT250)提高了两个数量级,摩擦系数高于灰铸铁,对配副材料造成的磨损率基本相当.因此,WC涂层可显著提高钢铁制动摩擦副的使用性能和使用寿命.     

吸波涂料的研究现状

重点对吸波涂料的种类进行了论述，并对吸波涂料的应用情况和发展趋势进行了简单描述。     

等离子喷涂Al2O3-13%TiO2复合陶瓷涂层的组织及热氧化性能的研究

采用大气等离子喷涂法在Q235钢上喷涂了常规微米、纳米Al2O3-13%TiO2复合涂层,对2种涂层进行了高温热氧化实验。利用XRD对比分析了2种涂层及其相应粉末的相组成,利用SEM观察了涂层的表面、截面形貌,并运用EDS对2种涂层的组分分布情况进行分析,比较2种涂层的不同结构及热氧化性能,初步探讨了涂层热氧化失效的原因。结果表明:2种粉末在喷涂之后,涂层中的α-Al2O3均有所减少,生成了γ-Al2O3,金红石TiO2相转变成了板钛矿型TiO2相,增加了涂层的内应力,加剧了裂纹的扩展;常规微米涂层中的孔洞细小但密集,纳米涂层中的孔洞较大但不密集,且大部分的气孔都存在于部分熔化区的内部;涂层在喷涂过程中所生成的气孔以及热氧化过程中由于热应力而产生的裂纹是造成涂层失效的直接原因。     

Co-P合金镀层的研究现状

Cr涂层的性能优异,在工业中应用广泛,但Cr(Ⅵ)化合物易致癌,需寻找具有优良摩擦学和耐蚀性能的涂料来替代电镀Cr(Ⅵ)。Co-P合金镀层作为Cr(Ⅵ)涂层的替代品之一,以其独特的物理、化学性能,成为复合材料发展的新秀,日益受到人们的关注和研究。经热处理后的Co-P合金镀层的硬度可达到1224HV,可媲美硬Cr镀层。相较于其他镀层(如纯Ni、纯Co、Ni-P、Ni-Fe、Ni-Co等),Co-P合金镀层具有更好的热稳定性。热循环时,随着循环次数的增加,Co-P合金镀层发生塑性变形→产生热裂纹→与基体脱离→基体受到损害等变化。Co-P合金镀层的厚度均匀且致密,不会产生点蚀等局部效应,大大提高了镀层的耐蚀性能,且高P镀层的耐蚀性优于低P镀层,非晶态Co-P合金镀层的耐蚀性也优于晶态Co-P合金镀层。Co-P合金镀层的摩擦磨损性能较纯Co镀层有很大提高,但P质量分数超过2%后,其耐磨性提升不大。Co-P合金镀层中会有片状磁畴存在,自发磁化强度方向和Co晶粒易磁化方向平行,且镀层越厚,自发磁化的趋向性越强。然而,在制备Co-P合金镀层的过程中,镀液配制和保存,以及废液的回收-处理-再利用环节不够完善等问题没有引起足够的重视。综述了Co-P合金镀层的硬度、热稳定性、耐蚀性、高温耐磨性以及磁性能等的研究现状。     

聚苯胺防腐蚀涂料的研究现状

概述了国内外聚苯胺防腐蚀涂料的研究情况,具体涉及聚苯胺的结构、性能和聚苯胺防腐蚀涂层的制备方法;介绍了聚苯胺涂层的作用原理和应用情况;提出了聚苯胺的研究方向、具体研究内容及方法。