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1.
The electronic cigarette (EC) is a new source of indoor airborne particles. To better understand the impacts of secondhand vaping (SHV) emissions on indoor air quality, real-time measurements of particle size distribution, particle number concentration (PNC), fine particulate matter (PM2.5), CO2, CO, and formaldehyde were conducted before, during, and after 10 min EC-use among 13 experienced users in an 80 m3 room. To assess particle transport in the room, multiple sampling locations were set up at 0.8, 1.5, 2.0, and 2.5 m away from the subjects. The arithmetic mean (standard deviation) of background PNC and PM2.5 concentrations in the room were 6.39 × 103 (1.58 × 102) particles/cm3 and 8 (1) μg/m3, respectively. At 0.8 m away from EC users, right after initiation of puffing, the PNC and PM2.5 concentrations can reach a peak of ~105 particles/cm3 and ~3 × 103 µg/m3, respectively, and then dropped quickly to background levels within 20 s due to dilution and evaporation. At the 0.8 m sampling location, the mean PNC and PM2.5 concentrations during puffing were 2.48 × 104 (2.14 × 104) particles/cm3 and 188 (433) µg/m3, respectively. In addition, two modes of SHV particles were observed at about 15 and 85 nm. Moreover, concentrations of SHV particles were negatively correlated with the distances to EC users. At the 1.5 m location, PNC and PM2.5 levels were 9.91 × 103 (1.76 × 103) particles/cm3 and 19 (14) µg/m3, respectively. Large variations of mean PNC levels exhaled per puff were observed both within and between EC users. Data presented in this study can be used for SHV particle exposure assessment.

Copyright © 2017 American Association for Aerosol Research  相似文献   


2.
Particulate matter (PM) air pollution is associated with human morbidity and mortality. Measuring PM oxidative potential has been shown to provide a predictive measurement between PM exposure and adverse health impacts. The dithiothreitol (DTT) assay is commonly used to measure the oxidative potential of PM2.5 (PM less than 2.5?µm aerodynamic diameter). In the common, kinetic form of this assay, the decay of DTT is quantified over time (indirectly) using 5,5′-dithiobis(2-nitrobenzoic acid) (DTNB, Ellman’s reagent) via UV/vis absorbance spectroscopy. The loss of DTT can also be quantified directly using electrochemical detection. The objectives of this work were (1) to evaluate the electrochemical assay, using commercially available equipment, relative to the UV/vis absorbance assay and (2) to apply the electrochemical method to a large (>100) number of PM2.5 filter samples. Also presented here is the comparison of an endpoint assay to the kinetic assay, in an attempt to reduce the time, labor, and materials necessary to quantify PM oxidative potential. The endpoint, electrochemical assay gave comparable results to the UV/vis absorbance assay for PM2.5 filter sample analysis. Finally, high filter mass loadings (higher than about 0.5?µg PM per mm2 filter) lead to suboptimal DTT assay performance, which suggests future studies should limit particle mass loadings on filters.

Copyright © 2019 American Association for Aerosol Research  相似文献   


3.
The characteristics of fugitive dust emitted from vehicles traveling on unpaved dirt roads were measured using a suite of instruments including a real-time fugitive dust sampler. The fugitive dust sampler is formed from a combination of a large particle inlet and an optical particle spectrometer that reports particle sizes from 6 to 75 µm. The large particle inlet permits the sampling of particles up to 75 µm with only a moderate dependence of sampling efficiency on wind-speed. Measurements made with the sampler showed that particles as large as ~50 µm were suspended from vehicular movement on the dirt roads, with the mode of the fugitive dust particle number size distribution ~2 µm, while the mass distribution mode was ~7 µm. A comparison of the fugitive dust sampler measurements with those made using standard PM instruments showed that the conventional instruments have a wind-direction bias that can result in under-sampling of large particles. The current measurements suggest that particles suspended from dirt roadways are of importance for local air quality within the near-road environment.

Copyright © 2017 American Association for Aerosol Research  相似文献   


4.
A new palm-sized optical PM2.5 sensor has been developed and its performance evaluated. The PM2.5 mass concentration was calculated from the distribution of light scattering intensity by considering the relationship between scattering intensity and particle size. The results of laboratory tests suggested that the sensor can detect particles with diameters as small as ~0.3 µm and can measure PM2.5mass concentrations as high as ~600 µg/m3. Year-round ambient observations were conducted at four urban and suburban sites in Fukuoka, Kadoma, Kasugai, and Tokyo, Japan. Daily averaged PM2.5 mass concentration data from our sensors were in good agreement with corresponding data from the collocated standard instrument at the Kadoma site, with slopes of 1.07–1.16 and correlation coefficients (R) of 0.90–0.91, and with those of the nearest observatories of the Ministry of the Environment of Japan, at 1.7–4.1 km away from our observation sites, with slopes of 0.97–1.23 and R of 0.89–0.95. Slightly greater slopes were observed in winter than in summer, except at Tokyo, which was possibly due to the photochemical formation of relatively small secondary particles. Under high relative humidity conditions (>70%), the sensor has a tendency to overestimate the PM2.5 mass concentrations compared to those measured by the standard instruments, except at Fukuoka, which is probably due to the hygroscopic growth of particles. This study demonstrates that the sensor can provide reasonable PM2.5 mass concentration data in urban and suburban environments and is applicable to studies on the environmental and health effects of PM2.5.

Copyright © 2018 American Association for Aerosol Research  相似文献   


5.
The objective of the present study was to characterize the performance of a federal reference method (FRM) PM10 size-selective inlet using analysis methods designed to minimize uncertainty in measured sampling efficiencies for large particles such as those most often emitted from agricultural operations. The performance of an FRM PM10 inlet was characterized in a wind tunnel at a wind speed of 8 km/h. Data were also collected for 20 and 25 μm particles at wind speeds of 2 and 24 km/h. Results of the present sampler evaluation compared well with those of previous studies for a similar inlet near the cutpoint, and the sampler passed the criteria required for certification as a FRM sampler when tested at 8 km/h. Sampling effectiveness values for particles with nominal diameters of 20 and 25 μm exceeded 3% for 8 and 24 km/h wind speeds in the present study and were statistically higher than both the “ideal” PM10 sampler (as defined in 40 CFR 53) and the ISO (1995) standard definition of thoracic particles (p < 0.05) for 25 μm particles leading to the potential for significant sampling bias relative to the “ideal” PM10 sampler when measuring large aerosols.

Copyright 2014 American Association for Aerosol Research  相似文献   


6.
Aerosol sampling and identification is vital for the assessment and control of particulate matter pollution, airborne pathogens, allergens, and toxins and their effect on air quality, human health, and climate change. In situ analysis of chemical and biological airborne components of aerosols on a conventional filter is challenging due to dilute samples in a large collection region. We present the design and evaluation of a micro-well (µ-well) aerosol collector for the assessment of airborne particulate matter (PM) in the 0.5–3 µm size range. The design minimizes particle collection areas allowing for in situ optical analysis and provides an increased limit of detection for liquid-based assays due to the high concentrations of analytes in the elution/analysis volume. The design of the collector is guided by computational fluid dynamics (CFD) modeling; it combines an aerodynamic concentrator inlet that focuses the aspirated aerosol into a narrow beam and a µ-well collector that limits the particle collection area to the µ-well volume. The optimization of the collector geometry and the operational conditions result in high concentrations of collected PM in the submillimeter region inside the µ-well. Collection efficiency experiments are performed in the aerosol chamber using fluorescent polystyrene microspheres to determine the performance of the collector as a function of particle size and sampling flow rate. The collector has the maximum collection efficiency of about 75% for 1 µm particles for the flow rate of 1 slpm. Particles bigger than 1 µm have lower collection efficiencies because of particle bounce and particle loss in the aerodynamic focusing inlet. Collected samples can be eluted from the device using standard pipettes, with an elution volume of 10–20 µL. The transparent collection substrate and the distinct collection region, independent of particle size, allows for in situ optical analysis of the collected PM.

© 2017 American Association for Aerosol Research  相似文献   


7.
Aerosol instruments provide more informative engine exhaust particulate matter (PM) data than the gravimetric filter and solid particle number methods prescribed by regulations. Yet their lack of conformity to the regulatory methods can limit their acceptance for vehicle development. This article examines the ability of the Dekati Mass Monitor (DMM), Engine Exhaust Particle Sizer (EEPS), and Micro Soot Sensor (MSS) to measure PM2.5 mass and solid particle number relative to current motor vehicle PM emissions standards. Simultaneous PM measurements are made by these three instruments and the two regulatory methods for 50 tests of six gasoline direct injection and two port fuel injection vehicles over the U.S. Federal Test Procedure. DMM and EEPS determinations of PM mass correlate well to gravimetric values (regression slopes of 1.06 ± 0.04 and 0.98 ± 0.08) down to a few mg/mile, below which filter weighing variability becomes problematic. The MSS exhibits a lower slope of 0.79 ± 0.03 consistent with it measuring the soot fraction, rather than total PM. At emissions rates above ~1013 particles/mile, solid particle number determined from DMM and EEPS data correlates respectably with, but overestimates the regulatory method (regression slopes are 1.7 ± 0.1 and 1.4 ± 0.15, respectively). Below this emissions rate, the correlation degrades. EEPS estimates of PM mass are significantly improved with the recent soot optimized inversion algorithm (slope improves from 0.45 to 0.98). While they cannot replace filters and solid particle counting, the present study suggests that these instruments can be used as more informative surrogates during motor vehicle development.

© 2016 Ford Motor Company  相似文献   


8.
The Aerodyne Aerosol Chemical Speciation Monitor (ACSM) is well suited for measuring non-refractory particulate matter up to approximately 1.0 µm in aerodynamic diameter (NR-sub-PM1). However, for larger particles the detection efficiency is limited by losses in the sampling inlet system and through the standard aerodynamic focusing lens. In addition, larger particles have reduced collection efficiency due to particle bounce at the vaporizer. These factors have limited the NR-sub-PM1 ACSM from meeting PM2.5 (particulate matter with aerodynamic diameter smaller than 2.5 µm) monitoring standards. To overcome these limitations, we have redesigned the sampling inlet, the aerodynamic lens, and particle vaporizer. Both the new lens and vaporizer are tested in the lab using a quadruple aerosol mass spectrometer (QAMS) system equipped with light scattering module. Our results show that the capture vaporizer introduces additional thermal decomposition of both inorganic and organic compounds, requiring modifications to the standard AMS fragmentation table, which is used to partition ion fragments to chemical classes. Experiments with mixed NH4NO3 and (NH4)2SO4 particles demonstrated linearity in the NH4+ ion balance, suggesting that there is no apparent matrix effect in the thermal vaporization-electron impact ionization detection scheme for mixed inorganic particles. Considering a typical ambient PM2.5 size distribution, we found that 89% of the non-refractory mass is detected with the new system, while only 65% with the old system. The NR-PM2.5 system described here can be adapted to existing Aerodyne Aerosol Mass Spectrometer (AMS) and ACSM systems.

Copyright © 2017 American Association for Aerosol Research  相似文献   


9.
Based on the theories of acoustic agglomeration and dust wet removal, an experimental apparatus was constructed to study the combined effects of acoustic agglomeration and atomization humidification in the pretreatment process to analyze the filtration performance of filter material. According to the concentration of coal-fired fly ash chosen in the experiments, the proper amount of atomization humidification and the proper sound pressure level (SPL) were determined. Under the relative humidity (RH) of 69% and with SPL in the range of 100 dB to 135 dB, the removal efficiency of fly-ash, the compressibility of the fly-ash particle layer on the filter media, and the performance of pulse filter cleaning were studied. The results indicate that the combined effects of sound fields and atomization humidification can effectively remove PM10 and PM2.5, and change the interaction and movement of particles, which can improve the pore structure of the fly-ash particle layer and increase the porosity of the dust layer. The results also indicate that with the proper amount of atomization humidification and appropriate SPL, the joint acoustic-atomization pretreatment can delay the filter material blocking, which reduces the pulse filter cleaning frequency and extends the filter cleaning cycle. It can also reduce the residual resistance after filter cleaning and prolong the operating lifetime of the filter media.

© 2017 American Association for Aerosol Research  相似文献   


10.
The objective of this study was to obtain the multi-metric occupational exposure assessment to graphene family nanomaterials (GFNs) particles of workers engaged in the large-scale production of graphene. The study design consisted of the combination of (i) direct-reading instruments, used to evaluate the total particle number concentrations relative to the background concentration (time series with spatial approach) and the mean size-dependent characteristics of particles (mean diameter and surface-area concentration) and (ii) filter-based air sampling for the determination of size-resolved particle mass concentrations. The data obtained from direct reading measurement were then used to estimate the 8-h time weighted average (8-h TWA) exposure to GFNs particles for workers involved in different working tasks. Workers were generally exposed to 8-h TWA GFNs particle levels lower than the proposed reference value (40,000 particle/cm3). Furthermore, despite high short-term exposure conditions were present during specific operations of the production process, the possibility of significant exposure peaks is not likely to be expected. The estimated 8-h TWA concentration showed differences between the unexposed (<100 particle/cm3; <0.05 µg/m3) and exposed subjects (mean concentration ranging from 909 to 6438 particle/cm3 and from 0.38 to 3.86 µg/m3). The research outcomes can be of particular interest because the exposure of workers in real working conditions was assessed with a multi-metric approach; in this regard, the study suggests that workers who are directly involved in some specific working task (material sampling for quality control) have higher potential for occupational exposure than operators who are in charge of routine production work.

© 2016 American Association for Aerosol Research  相似文献   


11.
Integrated particle size distribution (IPSD) is a promising alternative method for estimating particulate matter (PM) emissions at low levels. However, a recent light-duty vehicle (LDV) emissions study showed that particle mass estimated using IPSD (MIPSD) with the TSI Engine Exhaust Particle Sizer (EEPS) Default Matrix was 56–75% lower than mass derived using the reference gravimetric method (MGrav) over the Federal Test Procedure (FTP). In this study, MIPSD calculated with a new inversion matrix, the Soot Matrix, is compared with MGrav and also photoacoustic soot mass (MSoot), to evaluate potential improvement of the IPSD method for estimating PM mass emissions from LDVs. In addition, an aerodynamic particle sizer (APS) was used to estimate mass emission rates attributed to larger particles (0.54–2.5 µm in aerodynamic diameter) that are not measured by the EEPS. Based on testing of 10 light-duty vehicles over the FTP cycle, the Soot Matrix significantly improved agreement between MIPSD and MGrav by increasing slopes of MIPSD/MGrav from 0.45–0.57 to 0.76–1.01 for gasoline direct injected (GDI) vehicles; however, for port-fuel injection (PFI) gasoline vehicles, a significant discrepancy still existed between MIPSD and MGrav, with MIPSD accounting for 34 ± 37% of MGrav. For all vehicles, strong correlations between MIPSD and MSoot were obtained, indicating the IPSD method is capable of capturing mass of soot particles. The discrepancy between the MIPSD and MGrav for PFI vehicles, which have relatively low PM emissions (0.22 to 1.83 mg/mile), could be partially due to limited size range of the EEPS by not capturing larger particles (0.54–2.5 µm) that accounts for ~0.08 mg/mile of PM emission, uncertainties of particle effective density, and/or gas-phase adsorption onto filters that is not detected by in situ aerosol instrumentation.

Copyright © 2016 American Association for Aerosol Research  相似文献   


12.
A water-based fast integrated mobility spectrometer (WFIMS) with enhanced dynamic size range is developed. The WFIMS builds on two established technologies: the fast integrated mobility spectrometer and laminar flow water-based condensation methodology. Inside WFIMS, particles of differing electrical mobility are separated in a drift tube and subsequently enlarged through water condensation. Particle size and concentration are measured via digital imaging at a frame rate of 10 Hz. By measuring particles of different mobilities simultaneously, the WFIMS resolves particle diameters ranging from 8 to 580 nm within 1 s or less. The performance of WFIMS was characterized with differential mobility analyzer (DMA) classified (NH4)2SO2 particles with diameters ranging from 8 to 265 nm. The mean particle diameters measured by WFIMS were found to be in excellent agreement with DMA centroid diameters. Furthermore, detection efficiency of WFIMS was characterized using a condensation particle counter as a reference and is nearly 100% for particles with diameter greater than 8 nm. In general, measured and simulated WFIMS mobility resolutions are in good agreement. However, some deviations are observed at low particle mobilities, likely due to the non-idealities of the WFIMS electric field.

Copyright © 2017 American Association for Aerosol Research  相似文献   


13.
A new primary standard method for calibrating optical particle counters (OPC) has been developed based on quantitative gravitational deposition on a silicon wafer and accurate counting of the particles by a wafer surface scanner (WSS). The test aerosol consists of 3-μm diameter monodisperse polystyrene latex (PSL) spheres at concentrations in the range of 0.1 cm?3 to 1 cm?3. A key element to the calibration is the ability to generate monodisperse PSL spheres without residue particles by use of a virtual impactor and differential mobility analyzer. The use of these devices reduced the percentage of residue particles from more than 99.98% to about 5%. The expanded relative uncertainty (95% confidence level) in the number concentration determined with a WSS for a deposition of 200 particles is 17.8%. The major uncertainty component arises from the Poisson fluctuations in the aerosol concentration because of the low concentration. This methodology has advantages of a fast scanning time by the WSS of minutes compared to hours or days by microscopy and of counting every particle deposited compared to often only a small fraction via microscopy.

The WSS was used in the calibration of an OPC based on 12 depositions with concentrations ranging from 0.1 cm?3 to 1 cm?3 for each deposition. Make-up air was added to the aerosol entering the OPC so that the lowest achievable concentration for the OPC measurement is about 0.01 cm?3 in this study. The detection efficiency of the OPC was measured to be 0.984 with an expanded uncertainty of 13.4%.

Copyright 2014 American Association for Aerosol Research  相似文献   


14.
Accurate, cost-effective methods are needed for rapid assessment of traffic-related air pollution (TRAP). Typically, real-time data of particulate matter (PM) from portable sensors have been adjusted using data from reference methods such as gravimetric measurement to improve accuracy. The objective of this study was to create a correction factor or linear regression model for the real-time measurements of the RTI’s Micro Personal Exposure Monitor (MicroPEM?) and AethLab’s microAeth® black carbon (AE51) sensor to generate accurate real-time data for PM2.5 (PM2.5RT) and black carbon (BCRT) in Cincinnati metropolitan homes. The two sensors and an SKC PM2.5 Personal Modular impactor were collocated in 44 indoor sampling events for 2?days in residences near major roadways. The reference filter-based analyses conducted by a laboratory included particle mass (SKC PM2.5 and MicroPEM? PM2.5) and black carbon (SKC BC); these methods are more accurate than real-time sensors but are also more cumbersome and costly. For PM2.5, the average correction factor, a ratio of gravimetric to real time, for the MicroPEM? PM2.5 and SKC PM2.5 utilizing the PM2.5RT and was 0.94 and 0.83, respectively, with a coefficient of variation (CV) of 84% and 52%, respectively; the corresponding linear regression model had a CV of 54% and 25%. For BC, the average correction factor utilizing the BCRT and SKC BC was 0.74 with a CV of 36% with the associated linear regression model producing a CV of 56%. The results from this study will help ensure that the real-time exposure monitors are capable of detecting an estimated PM2.5 after an appropriate statistical model is applied.

Copyright © 2019 American Association for Aerosol Research  相似文献   


15.
Black carbon (BC) is important for climate forcing, and its effects on the Earth's radiative balance remain a major uncertainty in climate models. In this study, we investigated the mixing state of refractory black carbon (rBC) and aerosol optical properties in a polluted atmosphere at Xi’an, western China. The average rBC mass concentration was 9.9 μg m?3 during polluted periods, 7.6 times higher than that in clean periods. About 48.6% of the rBC was internally-mixed or coated with nonrefractory materials during polluted periods; this was 27% higher than in clean periods. Correlation analysis between the number fraction of thickly-coated rBC particles (fBC) and the major particulate species indicate that organics may be the primary contributor to rBC coatings during polluted periods. The average mass absorption cross section of rBC (MACBC) particles at λ = 870 nm was 7.6 ± 0.02 m2 g?1 for the entire campaign. The MACBC showed a positive correlation with fBC, and the enhancement of MACBC due to internal mixing was 1.8 times. These observations suggest that an enhancement of BC absorption by a factor of ~2 could be appropriate for climate models associated with high PM2.5 levels.

Copyright 2014 American Association for Aerosol Research  相似文献   


16.
The louvered 16.7?L min?1 PM10 inlet is commonly used in PM10 and PM2.5 FRM samplers or FEM monitors. Its sampling efficiency is influenced by particle bounce, re-entrainment, and overloading since the PM10 inlet contains a PM10 impactor with an uncoated impaction surface. In this study, a modified PM10 (M-PM10) inlet with an oil-soaked glass fiber filter substrate supported by an oil-soaked porous metal disc was developed to eliminate the particle bounce and overloading effects. The oiled M-PM10 inlet and the traditional PM10 inlets with and without grease coating were collocated at the field for long-term comparison tests. The results show that the traditional uncoated PM10 inlet which is cleaned initially but not cleaned daily afterwards oversamples PM10 concentration after one 24-h sampling day and has the high positive average sampling bias during 14 sampling days due to particle bounce and re-entrainment. The grease-coated PM10 inlet without daily cleaning shows a better performance with a smaller sampling bias, but it still oversamples PM10 concentrations after the first three 24-h sampling days and then undersamples after 10 sampling days due to particle bounce and overloading effects, respectively. In comparison, the M-PM10 inlet shows a good performance with a small average sampling bias during 35 sampling days since vacuum oil wicks up through the deposit to eliminate particle bounce and overloading. It is suggested that the oiled M-PM10 inlet can be used to replace the traditional EPA PM10 inlet and for long-term sampling of over 1 month without the frequent maintenance need.

Copyright © 2019 American Association for Aerosol Research  相似文献   


17.
Aerosol instrument characterization and verification for nanometer-sized particles requires well-established generation and classification instruments. A precise size selection of sub-3-nm charged aerosol particles requires a differential mobility analyzer (DMA), specially designed for the sub-3-nm size range. In this study, a Herrmann-type high-resolution DMA developed at Yale University was characterized in various operation conditions. A relation between sheath flow rate and tetraheptylammonium ion (C28H60N+, THA+, 1.47 nm, mobility equivalent diameter) was established. The maximum particle size that the DMA was able to classify was 2.9 nm with the highest sheath flow rate of 1427 liters per minute (Lpm), and 6.5 nm with the lowest stable sheath flow rate of 215 Lpm, restricted by the maximum and minimum flow rates provided by our blower. Resolution and transmission of DMA are reported for tetrapropylammonium (C12H28N+, TPA+, 1.16 nm), THA+, and THA2Br+ (1.78 nm) ions measured with two different central electrodes and five different sheath flow rates. The transmission varied between 0.01 and 0.22, and the resolution varied between 10.8 and 51.9, depending on the operation conditions.

Copyright © 2016 American Association for Aerosol Research  相似文献   


18.
Air pollution has been recognised as one of the major risk factors for the global burden of disease. In modern society the majority of the exposure occurs indoors where people spend most of their time. Indoor air quality may be improved with portable air cleaners utilizing various cleaning techniques, such as filtration, electrostatic precipitation, and ionization. The objective of this study was to quantify air cleaner particle removal by particle size resolved clean air delivery rates (CADR). This was obtained by utilizing particle concentration measurements and indoor aerosol modeling. Our test protocol was applied to five air cleaners designed for household and office use. For particles with diameters above 100 nm and at the chosen settings, the CADR was around 40 m3/h for an ion generator, around 70 m3/h for an electrostatic precipitator, and ranging from 100 to almost 300 m3/h for the three filter-based air cleaners. Similar performances were obtained for ultrafine particles, except for the ion generator that performed better in this size range.

Copyright 2014 American Association for Aerosol Research  相似文献   


19.
20.
Airflow around an eight-passenger-car subway train running in the underground tunnel at a cruise speed of 70 km/h was numerically simulated, and the trajectories of the particles that were assumed to be re-suspended from the ground or generated at the contact points between the wheels and rails were predicted. In addition, field experiments were conducted to measure airflow velocity and PM10 mass concentration under a T-car (trailer car without a driving cab) during the running of a subway train in straight sections of the underground tunnel of the Seoul Subway Line 5. The numerically predicted airflow velocities agreed well with the experimental data with the error of less than 30%, and the predicted particle distribution showed a similar tendency to the experimental results. The airflow under the T-car was predicted to be relatively uniform compared to the airflow under other passenger cars. Both numerical results and experimental data signified that a lot of particles could drift under the T-car by showing a higher particle concentration in the central area of the space under the T-car than in the edge area. As a result, the space underneath the T-car is anticipated to be a good place for installing a dust-removal system.

© 2016 American Association for Aerosol Research  相似文献   


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