共查询到20条相似文献,搜索用时 109 毫秒
1.
乙烯、乙炔分子球棍模型在有机化学课程教学过程中广泛使用,但是目前广泛使用的乙烯、乙炔分子球棍模型容易引起学生的一些误会,建议在乙烯、乙炔分子球棍模型中,弧形弯曲连接杆表示π键,用直线连接杆表示δ键,这样既有效的区分出了π键、δ键类型的不同;通过弧形弯曲连接杆比直线连接杆长,也形象地表示出了π键没有δ键稳定,π键易断裂,发生加成反应这一实验事实。 相似文献
2.
3.
4.
利用电子密度拓扑分析的方法对乙烷、乙烯、乙炔以及乙烷的卤代物和同系物中C-C键的性质的理论分析,研究其递变规律和递变原因。找到乙烯、乙炔分子的霄键键鞍点研究其递变规律和原因。 相似文献
5.
本文通过对乙烯和乙炔的化学键构成、键能的比较 ,以及对乙烯和乙炔与卤化氢和卤素的亲电加成反应中间体物质的分析 ,说明乙烯的亲电加成反应活性大于乙炔的亲电加成反应活性。 相似文献
6.
7.
8.
非共价键键和的超分子聚合物具有典型的可逆性,通过合适的刺激响应能够赋予聚合物材料一定的自修复性能。本文主要综述了非共价键(氢键、金属配位键、π-π相互作用等)键和的自修复超分子聚合物的研究进展。 相似文献
9.
以C(60)为代表的富勒烯分子是一类由五元及六元碳环相互连接构成的封闭中空球状分子。分子中每个碳原子均与相邻另三个碳原子以σ键连接,所有碳原子各自贡献一个剩余的价电子形成离城球面大π键。富勒烯分子的发现给炭化学的发展开辟了新里程。 相似文献
10.
以C60为代表的富勒烯分子是一类由五元及六元碳环相互连接构成的封闭中空球状分子,分子中每个碳原子均与相邻另三个碳原子以σ键连接,所有碳原子各自贡献一个剩余的价电子形成离域球面大π键。富勒烯分子的发现给炭化学的发展开辟了新里程。 相似文献
11.
苯乙烯是重要的石油化工原料。本文介绍了国内外苯乙烯生产的发展概况,合成乙苯,苯乙烯所用的催化剂种类,并就苯乙烯生产及催化剂的发展趋势提出了自己的观点。 相似文献
12.
Synthesis and characterization of homopolymers and copolymers of various acrylates and acrylonitrile
Various homopolymers and copolymers of methyl acrylate, ethyl acrylate, butyl acrylate, and acrylonitrile in different feed ratios were synthesized. These were characterized by IR, 13C-NMR, DSC, DTA, and TGA. Spectroscopic characterization helped in differentiating copolymers of different mol ratios. Thermal analysis revealed different degradation patterns for homopolymers and copolymers. The temperature and energy changes associated with various phase transitions were dependent on the chemical composition of homo- and copolymers, as expected. © 1993 John Wiley & Sons, Inc. 相似文献
13.
14.
The variation of the Au 4f binding energy of Au clusters with the cluster size has been established by measuring the binding energies of clusters whose size distributions were independently determined by HREM and STM. The binding energy increases significantly when the cluster size is less than 2 nm. Au-Cu bimetallic clusters of the composition Cu3Au have been deposited for the first time on carbon substrates. The shifts in the core level binding energies of the bimetallic clusters show the effect of alloying in the case of large clusters, but show effects of both alloying and cluster size in the case of the small clusters. The interaction of CO with Cu3Au clusters is stronger than with a bulk Cu metal. The interaction of CO with small Cu clusters also seems to be stronger than with bulk Cu or with large Cu clusters. 相似文献
15.
16.
《国际聚合物材料杂志》2012,61(1-4):113-122
Abstract Kinetics and mechanisms of oxidation of 6 acetals by molecular oxygen and ozone in liquid phase have been studied. Reaction with molecular oxygen (70°C, 15–16 hr) leads to the formation monoethers of the corresponding glycols with 68–90% selectivity. Salts of metals and complexes with crown-ethers have increased the reaction rate significally. Ozone have reacted with acetals with formation similar products. The mechanisms of intermediate stages have been proposed. 相似文献
17.
G. R. Hamed 《The Journal of Adhesion》1983,16(1):31-39
A substantially greater detachment energy is required to strip a polyethylene tereph-thalate (Mylar) film from a styrene-butadiene-styrene (SBS) triblock copolymer compared to that for peeling from a random styrene-butadiene (SBR) copolymer. This is true even though the intrinsic interaction between the Mylar and each elastomer is expected to be similar because of their virtually identical chemical composition. It is proposed that this difference in peel strength (between the SBS and SBR) is a consequence of the much higher dissipative capacity of the former elastomer. Another manifestation of this is the higher cohesive tear strength of the SBS compared to the SBR. Extents of energy dissipation within each elastomer during detachment of the Mylar adherend are consistent with the hypothesis that the average maximum stress experience before detachment is some similar fraction of each elastomer's tensile strength. 相似文献
18.
责任是人应主动承担的角色义务和对其因过失所造成后果应承担的责罚.有两层涵义:一是义务;二是后果.责任心是个体自觉做好分内事务和履行道德义务的心理倾向,是个性心理品质成分中自我特征维度上的重要内容.责任心具有两个方面的涵义:一是角色分内职责;二是角色道德义务.责任心是一种通过责任认知、责任个性和责任适应的动态形式表现出来的静态品质,责任心是责任心过程结构与责任心关系结构相互制约、相互影响的统一体. 相似文献
19.
20.
Polypentafluorostyrene (PPFS), polymethylacrylate (PMA), and poly(pentafluorostyrene-co-methylacrylate), poly(PFS-co-MA) were prepared and the wetting characteristics of polymer blends of PPFS and PMA were compared with that of poly(PFS-co-MA) via contact angle measurements. The critical surface tension of polypentafluorostyrene was found to be 22.6 dyne/cm, which is comparable to the value reported for polytrifluoroethylene (22 dyne/cm). The critical surface tension of poly(PFS-co-MA) is not linearly related to its composition. The polymer blends of PPFS and PMA exhibit significant surface enrichment of the fluoropolymer. The harmonic-mean method1 was employed to determine surface tensions of these polymers and many known polymers. It is found that the method produces useful surface tension data provided the contact angle values are derived from testing liquids of dissimilar polarity. 相似文献