共查询到20条相似文献,搜索用时 890 毫秒
1.
2.
3.
用SFP-AQ法(亚硫酸钠和甲醛―蒽醌)预处理麦秸秆,研究预处理条件对酶解还原糖得率的影响。结果表明,较适宜的预处理和酶解条件分别为:蒸煮温度150℃,保温时间1 h,Na2SO3用量为12%,纤维素酶、木聚糖酶、β-纤维二糖酶三种复合酶用量为20 FPU/g,pH值4.8,酶解温度50℃,酶解时间48 h。此时,还原糖得率可达到46.4%。 相似文献
4.
5.
6.
7.
8.
对SFP-AQ法(亚硫酸钠和甲醛―蒽醌)预处理麦秸秆酶解葡萄糖得率进行了研究。结果表明:葡萄糖得率随着预处理中Na2SO3用量的增加先升高后降低,在12%时葡萄糖得率最高;葡萄糖得率随着酶用量的增加而迅速升高,当酶用量超过20 FPU/g时,提高缓慢;蒸煮最高温度和保温时间对葡萄糖得率的影响不明显。较适宜的预处理和酶解条件分别为:蒸煮最高温度150℃,保温时间1 h,Na2SO3用量为12%,纤维素酶、木聚糖酶、β-纤维二糖酶三种复合酶用量为20 FPU/g。此时,葡萄糖得率可达到31.7%,酶解葡萄糖对原料中葡萄糖的转化率为91.6%。 相似文献
9.
10.
银杏黄酮的酶法提取工艺研究 总被引:1,自引:0,他引:1
研究了银杏叶中黄酮的酶法提取工艺,银杏叶原料经纤维素酶预处理后浸提,总黄酮得率显著提高,对叶得率可达到2.01%。其酶解过程的最优参数为:料液中酶的质量浓度为0.125g/L,酶与底物配比为1∶1200,酶解温度45℃,自然pH值,酶解时间2h。 相似文献
11.
High temperature, high pressure e.s.r. measurements of the hydrogenation reaction of Taiheiyo coal in the presence of catalysts were carried out to understand the stabilization of thermally and/or catalytically induced free radicals. A decrease in free radical concentration with increasing temperature was observed for ZnCl2 and SnCl2 · 2H2O catalysts at 10MPa under hydrogen gas. High pressure modified single-cell d.t.a. and p.d.a. equipment augmented the uniquely designed high temperature, high pressure e.s.r. cell. The hydrogenation reaction was monitored under the same experimental conditions as for e.s.r. From the results of the combination of high temperature, high pressure e.s.r. with high pressure d.t.a. and p.d.a., it was established that H2 molecules can react efficiently with free radicals from coal molecules created by the presence of ZnCl2 and SnCl2 · 2H2O catalysts. 相似文献
12.
Most of the individual methylolmelamines that occur in melamine–formaldehyde adduct mixtures have been separated by preparative high-performance liquid chromatography (h.p.l.c.) and recovered in amounts sufficient to allow their characterisation by high-field 1H- and 13C-n.m.r. Particular attention has been paid to the chemical shifts of the aromatic azine carbons of the melamine nuclei. These carbon shifts are shown broadly to be in agreement with some values previously published, but additional assignments have been made. It is shown that a satisfactory quantitative analysis of the methylolmelamines in a melamine–formaldehyde adduct mixture can be carried out either by h.p.l.c. or by 13C-n.m.r. 相似文献
13.
The cycloaliphatic epoxy resins were studied by various two-dimensional nuclear magnetic resonance (2D n.m.r.) spectroscopies. The 13C n.m.r. spectra of the epoxy resins were assigned by using DEPT and 2D INADEQUATE techniques and the 1H n.m.r. spectra were assigned by using 2D 1H---1H and 1H---13C COSY techniques. Complete characterization of the samples synthesized by the oxidation of cyclohexene derivatives not only revealed the existence of the stereochemical isomers resulting from the structural difference of the oxide rings in the samples but also provided the composition ratio of the isomers. 相似文献
14.
E.s.r. spectra of several oil shales from eastern and western USA have been measured at 9 and 25 GHz. The spectra of the western shales were similar to previously reported spectra and consist of a Mn2+ signal and a featureless organic signal. The eastern spectra consist of a V4+ signal and a complex and unusual organic signal consisting of at least four component signals. The organic signal has been characterized in terms of g factor, line-width and saturation characteristics. The effect of oxygen on the signal has also been examined. Electron nuclear double resonance (ENDOR) signals have been obtained from the organic signals of the eastern oil shales. 相似文献
15.
The 1H and 13C nuclear magnetic resonance (n.m.r.) spectra of a delayed coking feedstock and products, presented in a previous paper, are analysed here in detail by matching results from inspection of both nuclei. The conventional spectra of whole samples are used in combination with elemental analysis data, and substantial agreement is obtained. Differences are explored to yield valuable information. Interpretation of some band assignments is modified to account for new results. This approach results in a detailed quantitative estimation of a few key structures that contain the main functional groups that characterize these petroleum fractions. 相似文献
16.
Akabira coal-derived neutral oil was separated into 25 narrow boiling range fractions covering 183–423 °C, and subsequently separated into compound class fractions : alkanes, monoaromatics, naphthalene-type diaromatics, fluorene-type diaromatics and tri- and/or tetraaromatics, by high performance liquid chromatography (h.p.l.c.). The compound type analyses of the distillate/h.p.l.c. fractions were performed using electron impact mass spectroscopy (e.i.m.s.) or field ionization mass spectroscopy (f.i.m.s.). Aromatic/hydroaromatic compound types and the alkyl side-chain carbon distribution of the distillate/h.p.l.c. fractions were clarified, based on the separation behaviour of h.p.l.c. and the type analyses according to Z value by m.s. By the distillation/h.p.l.c./m.s. method, coal-derived oil was characterized in terms of the distribution of the numbers of aromatic rings, naphthenic rings and carbons of alkyl groups attached to these rings. The variations in chemical structure in a compound class with distillation temperature are discussed in terms of these chemical structural factors. 相似文献
17.
18.
Saudi Arabian heavy crude oil was separated into six fractions, including five distillate fractions (<93, 93–204, 204–260, 260–343 and 343–454 °C) and a >454 °C distillation residue. Each fraction was analysed by 1H and 13C n.m.r. spectroscopy, and combined gained information from these analyses provided reliable average structural parameters. These included estimation of aliphatic and aromatic content, average paraffinic chain length, and estimation of hydrogen, methyl and alkyl bearing aromatic carbons for each of the six fractions. The extent of branching in paraffinic chains and amount of aromatic bridgehead carbons were also calculated. 相似文献
19.
13C n.m.r. spectroscopy has been applied to investigate a number of coal tar and petroleum-derived carbon black feedstocks. Application of the J-modulated spin echo technique is especially rewarding, as this method renders the quaternary carbons directly detectable. Thus the quality of carbon black feedstocks can additionally be gauged on the basis of the contents of quaternary carbons, which is a direct indication of the carbon yield in the carbon black production process. 相似文献
20.
Changes in the macroscopic structure of coal have been observed as an outburst-prone area is approached. Associated with this structural change was an increase in the concentration of paramagnetic centres. Initial results suggested that this increase was not due to variation in maceral content within the coal samples but to the mechano-chemical degradation of the coal as a result of tectonic forces applied over geological time. 相似文献