共查询到18条相似文献,搜索用时 78 毫秒
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甲醇气相脱水制二甲醚反应为固体酸催化反应,常用的固体酸催化剂有γ-Al2O3和分子筛类。γ-Al2O3表面存在弱酸中心或中等强度酸中心,催化剂有较好的初始催化活性,但活化所需的反应温度较高,耐水稳定性差;分子筛类催化剂表面有许多强酸性位,低温下催化活性较高,但在高温反应条件下易产生烃类副产物和积炭,热稳定性差。为改善这两类催化剂的催化性能,对催化剂进行了各种改性研究,改性后催化剂的活性、选择性和稳定性均有一定程度提高。综述了近年来在γ-Al2O3和分子筛催化剂上进行的改性研究,总结并展望了甲醇脱水催化剂的发展方向。 相似文献
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甲醇脱水制二甲醚及其分离精制 总被引:5,自引:0,他引:5
本文阐述了甲醇脱水制二甲醚的反应原理,目前所使用催化剂存在的问题及针对这些问题所进行的长效催化剂的研究情况,并介绍了日本小见善明等人研究成功的改进的二甲醚分离精制流程及其优越性。 相似文献
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甲醇脱水制备二甲醚的负载型杂多酸催化剂 总被引:2,自引:0,他引:2
制备了以γ-Al2O3为载体的负载型杂多酸催化剂。以N2吸附、BET、吡啶吸附IR光谱、XRD和XPS等测试手段对催化剂进行了表征。并对催化剂的活性进行了评价。结果表明:负载型杂多酸复合催化剂对甲醇脱水制二甲醚的最佳工艺条件为反应压力0.70—0.80MPa,反应温度280—320℃,质量空速(MHSV)1.5—2.5h-1。 相似文献
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甲醇脱水制二甲醚工艺研究 总被引:1,自引:0,他引:1
介绍二甲醚的用途,根据甲醇脱水制二甲醚反应的特点,编制了一个规模为5000t/a两塔流程的甲醇气相催化脱水制二甲醚工艺。模拟后得到了一套数据,每吨二甲醚消耗甲醇的定额为1.414t。 相似文献
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甲醇催化脱水制二甲醚 总被引:3,自引:0,他引:3
研究了甲醇在ZSM-5沸石分子筛上催化脱水制二甲醚反应条件的影响。并在等温积分反应器中进行了本征动力学测试、对动力学模型进行筛选参数估值,获得反应速率方程。 相似文献
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研究了甲醇在ZSM-5沸石分子筛上催化脱水制二甲醚反应条件的影响。并在等温积分反应器中进行了本征动力学测试,对动力学模型进行筛选和参数估值,获得反应速率方程。 相似文献
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甲醇脱水制二甲醚宏观反应速率的计算和测定陈银飞,孙勤,葛忠华(浙江工业大学,杭州310014)关键词:甲醇,二甲醚,宏观动力学1前言二甲醚作为一种甲基化剂,在制药、染料、农药等工业中有许多独特的用途。最近,有人提出并开发用二甲醚作为城市煤气或液化燃料... 相似文献
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完全液相法催化剂上甲醇脱水合成二甲醚的动力学及DFT研究 总被引:1,自引:1,他引:0
采用完全液相法制备AlOOH催化剂并进行了浆态床反应器中甲醇脱水制备二甲醚的反应动力学和DFT的研究。在3种甲醇脱水制备二甲醚的反应机理中,以表面反应即两个同时吸附的甲醇反应生成二甲醚作为速控步骤,所建立动力学模型的计算值和实验值吻合较好。采用DFT计算了液体石蜡环境中AlOOH(100)面的脱水反应,其反应过程和活化能结果与动力学模型结果基本一致,进一步表明采用该模型可以合理描述完全液相法制备的AlOOH催化剂表面甲醇脱水反应过程。 相似文献
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The conversion of methanol to dimethyl ether was carried out over various commercial mordenite and ion-exchanged catalysts to evaluate the catalytic performance of mordenite catalysts with different pore structures and acidities. These catalysts were compared for their catalytic properties in a fixed-bed reactor at 1 atm, 573 K and LHSV of 2.84 h− 1. The catalysts were characterized by BET, ICP, NH3-TPD, XRD, TGA and FT-IR techniques. The ion-exchanged mordenite showed higher activity, selectivity and good stability in dehydration of methanol due to the addition of medium acid sites. Also, the effect of water on catalyst deactivation was investigated over two selected catalysts in order to develop a suitable catalyst for synthesis of dimethyl ether. It was found that the H-mordenite catalyst supplied by Süd-chemie Co., (MCDH-1) was more active and less deactivated than another one in a feed containing 20 wt.% water. 相似文献
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采用溶胶-凝胶法制备了用于甲醇气相脱水制二甲醚的新型催化剂全氟磺酸树脂/二氧化硅,应用X射线衍射、红外光谱、热重-差示扫描量热、低温氮物理吸附和氨程序升温脱附法对所得催化剂进行了表征。考察了反应温度、甲醇液空速、全氟磺酸树脂含量对甲醇气相催化脱水制二甲醚反应性能和催化剂稳定性的影响。结果表明,催化剂比表面积达820m2/g,在全氟磺酸树脂负载量10.0%、甲醇液空速1h?1、反应温度184℃时,甲醇转化率92.0%,二甲醚选择性99.9%,经350h实验测试,活性和稳定性没有明显变化。 相似文献
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《Journal of Industrial and Engineering Chemistry》2014,20(1):222-227
A series of Al-HMS with different Si/Al ratio was used as a solid acid catalyst for methanol dehydration to dimethyl ether (DME). The effect of temperature, feed composition, space velocity, and the catalyst Si/Al ratio on the catalytic dehydration of methanol was investigated. By decreasing Si/Al, the temperature required to reach equilibrium conversion of methanol decreased due to the increased number of acidic sites. Compared to commercial γ-Al2O3, Al-HMS-5 and Al-HMS-10, catalysts exhibited a high yield of DME. Among all Al-HMS catalysts, Al-HMS-10 exhibited an optimum yield of 89% with 100% selectivity and excellent stability for methanol dehydration to DME. 相似文献
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The conversion of methanol to dimethyl ether was carried out over various commercial zeolites and modified H-ZSM-5 catalysts to evaluate their catalytic performance. A series of commercially available zeolite samples were used for vapor-phase dehydration of methanol to DME. Catalyst screening tests were performed in a fixed-bed reactor under the same operating conditions (T = 300 °С, P = 16 barg, WHSV = 3.8 h−1). It was found that all the H-form zeolite catalysts in this study were active and selective for DME synthesis. According to the experimental results MDHC-1 catalyst exhibited the highest activity in dehydration of methanol.After finding the most active catalyst, the H-MFI90 zeolite was modified with Na content varying from 0 to 120 mol%, via wet-impregnation method to further improve its selectivity. All of catalysts were characterized by BET, XRD, NH3-TPD, ICP, TGA, SEM, FT-IR and TPH techniques. It was found that these materials affected activity of MDHC-1 zeolite by changing its acidity. Ultimately, among all the catalysts studied, Na100-modified H-MFI90 zeolite exhibited optimum activity, selectivity and stability at methanol dehydration reaction. 相似文献