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聚苯胺性状及其含量对镍粉/聚苯胺涂层屏蔽性能的影响 总被引:1,自引:0,他引:1
系统分析了金属粉末/聚苯胺复合电磁屏蔽材料中导电聚苯胺的性状,体积分数对微观结构和电磁屏蔽效能的影响.从二次掺杂的导电聚苯胺的电磁性能讨论了聚苯胺对电磁屏蔽效能的贡献.研究了二次掺杂聚苯胺性状对电磁屏蔽涂层微观结构形貌以及与金属粉末的复合效应对电磁屏蔽效能的贡献.研究的结果表明导电聚苯胺的加入有利于增加电磁屏蔽材料对于高频电磁波的电磁屏蔽效能,但是对低频部分的电磁波的屏蔽效能与纯金属粉末电磁屏蔽材料相比有所降低,这可能是由于聚苯胺加入导致的导电组分分布不均匀所引起的.实验结果表明胶状体聚苯胺和粉末状聚苯胺在电磁屏蔽涂料基体树脂中具有完全不同的形态,分析了对电磁屏蔽效能的影响. 相似文献
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制备了导电聚苯胺/纳米镍粉复合屏蔽材料.实验中把导电聚苯胺与镍粉以28的比例制成复合粉,然后再将复合粉与环氧树脂以37的比例混合,制成屏蔽涂料.检测结果显示,当聚苯胺电导率为102S/cm、镍粉颗粒尺寸为50~180nm、涂层厚度为0.45mm时,在30~1500MHz的频段范围可获得80~100dB的屏蔽效能.分析表明,大幅度提高吸收损耗,适当降低反射损耗可以减少二次电磁污染.这种屏蔽涂料不仅可用于电器机壳,而且也可用于电子元件、器件. 相似文献
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铁镍合金对复合电磁屏蔽材料性能的影响 总被引:1,自引:0,他引:1
在导电组分中添加磁性合金粉末,利用复合效应增加电磁屏蔽材料的吸收损耗,以获得较好的屏蔽效能。通过在12%体积分数的金属镍粉中添加不同体积分数的FeNi合金,研究了复合材料中FeNi合金对电磁屏蔽效能的影响。实验结果表明,当加入4%体积分数的FeNi合金时,屏蔽效能最好。分析得出FeNi合金粉末的加入能够增加材料的磁导率,增加材料对电磁波的吸收,在提升屏蔽效能的同时达到低二次污染的目的。 相似文献
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针对低频频段(<1.5GHz)的电磁屏蔽涂层,采用快速混合法制备出导电聚苯胺纳米线,使用透射电镜(TEM)对其形貌和尺度进行表征,研究了搅拌方式对聚苯胺/聚氨酯涂层的导电性能和电磁屏蔽性能的影响。研究表明,由于磁场的作用,采用电磁搅拌法可以缩短聚苯胺聚合反应时间,合成均一的导电聚苯胺纳米线,其渗滤阈值为33.3%,含量为33.3%的聚苯胺纳米线的聚苯胺/聚氨酯涂层的电磁屏蔽性能为32.2dB,优于含量为45%的机械搅拌法制备的聚苯胺粉体,这可能是由于线性结构的导电聚苯胺在基体中能够较容易形成三维导电网络结构所致。 相似文献
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Electromagnetic interference shielding characteristics and shielding effectiveness of polyaniline-coated films 总被引:1,自引:0,他引:1
The study aims to investigate the electromagnetic interference (EMI) shielding characteristics and shielding effectiveness (SE) of polyaniline (PANI)-coated films. Free-standing films of emeraldine salt were obtained by PANI-emeraldine base with dode-cylbenzensulfonic acid on a polyethylene terephthalate film. The four-point probe method was employed to measure the electrical resistivity for investigating the electromagnetic characteristics of PANI-coated films. In addition, the SE of the PANI-coated films was measured in two different ways: a flanged coaxial shielding effectiveness test and a shielding effectiveness on the testbed having a box-type chamber equipped with instruments for electromagnetic shielding testing under real conditions. The overall SE measured from experiments was also compared with the approximate SE value calculated from a theoretical method. The present study has shown the possibility of utilizing PANI-coated films as EMI shielding/absorption materials. 相似文献
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B对Pb-Mg-Al-B屏蔽功能材料的显微组织与屏蔽性能的影响 总被引:1,自引:0,他引:1
利用立式高频感应炉制备出铸造Pb-Mg-Al-B屏蔽材料,并对其显微组织和屏蔽性能进行了研究。结果表明,随着B的添加,材料组织中AlB2颗粒增多;室温抗拉强度可达105MPa,布氏硬度为160;厚度为20mm、B含量为2.0%(质量分数)的Pb-Mg-Al-B屏蔽材料对能量为250、118和65keV的X射线屏蔽率分别为90.29%、99.22%和97.9%,对γ射线的屏蔽率达到49.75%(137Cs源)和34.21%(60Co源),对中子的屏蔽率高达92.7%,说明屏蔽材料具有强度高、X(γ)射线与中子屏蔽性能优异,具备结构-功能(屏蔽)一体化的特点。 相似文献
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A method of thermal shielding of an object with the help of a material with transverse pores and forced filtering of a gaseous coolant through the material is studied.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 57, No. 5, pp. 729–735, November, 1989. 相似文献
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V Ganesan R Srinivasan S Aswathy K D Chandrasekaran B Srinivas U V Varada Raju G V Subba Rao R Gopalan T Rajasekaran 《Bulletin of Materials Science》1994,17(1):87-93
Magnetic shields of various high-temperature superconductors, YBa2Cu3O7−x
(YBCO), YBa2Cu3O7−x
-Ag composites (random inclusions as well as non-random coatings) and Bi2Sr2Ca2Cu3O
x
(BSCCO) were prepared by uniaxial as well as isostatic compression with various dimensions. The shielding properties were
measured at 77 K for dc and ac magnetic fields in the range of frequencies from 100 Hz to 10 kHz. The critical penetration
field (CPF), defined as the value of the applied magnetic field at which a detectable field was observed inside the cylinder,
varied from cylinder to cylinder and also with the ageing of the cylinders in the case of YBCO shields. The highest value
of CPF was 16 G at 77 K for YBCO shield prepared by isostatic compression. Even though the stability of BSCCO shields with
respect to ageing is good, the CPF values are very low compared to those for YBCO. Detailed studies were performed in the
case of YBCO shields. The CPF decreased as a function of time over a period of 90 days. The CPF decreased as the frequency
of the applied field was increased. The wave form of the field inside the pot for a sinusoidal applied field was highly distorted
and showed the presence of higher harmonics with appreciable amplitude. The wave form was Fourier-analysed to yield the field
inside the shield along with the harmonics. The shields with Ag addition seem to give better performance at high fields. 相似文献
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电磁屏蔽材料的发展现状 总被引:48,自引:0,他引:48
介绍了电磁屏蔽的原理 ,并重点对电磁屏蔽材料的种类 ,包括非晶合金、导电高分子、发泡金属及纤维类材料等 ,它们的性能、应用及发展状况进行了综述 相似文献
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膨胀石墨/金属网/ABS复合材料电磁屏蔽性能的研究 总被引:1,自引:0,他引:1
以膨胀石墨(EG)和金属网(MN)作为电磁屏蔽基元材料与ABS树脂采用共混、挤出、热压等成型工艺制备了电磁屏蔽复合材料,研究了膨胀石墨的含量、处理方式、复合材料的厚度和金属网的目数对电磁屏蔽复合材料屏蔽性能的影响。结果表明,在膨胀石墨/ABS电磁屏蔽复合材料中,其电磁屏蔽效能随着膨胀石墨含量增加及复合材料厚度增加而增大,膨胀石墨经超声处理后,可以提高复合材料的屏蔽效能。在两种单层金属网/ABS电磁屏蔽夹层复合材料中,屏蔽效能并不随着金属网目数增加而增大。在30MHz~1.8GHz频率范围内,200目不锈钢网/ABS复合材料和100目铜网/ABS复合材料的屏蔽性能最好,最大屏蔽效能分别为76.1和70dB。在多相电磁屏蔽复合材料中,膨胀石墨/不锈钢网/ABS复合材料的屏蔽效能比不锈钢网/ABS复合材料高约5dB。 相似文献