The Role of Ferric Oxide Nanoparticles in Improving Lubricity and Tribo-Electrochemical Performance During Chemical–Mechanical Polishing

The role of ferric oxide nanoparticles on the lubricating characteristics of passivating films formed on stainless steel (SS) was discussed in this study. The tribo-electrochemical behavior of mirror-like polished AISI 304 SS, used as an exemplary material, was evaluated in various electrolytes by means of a simulated chemical–mechanical polishing process in laboratory scale. It was clearly demonstrated that a suitable combination of abrasives (ferric oxide nanoparticles) and an oxidizer (nitric acid) can act as an effective lubricant that lowers the friction and wear of the AISI 304 SS surfaces. The excellent lubricating and anti-corrosion properties shown by a slurry containing a high content of ferric oxide nanoparticles at high nitric acid concentrations were attributed to the formation of a stable and robust passive film that was composed of chromium oxide and a mixture of iron oxides. The lack of ferric oxide nanoparticles in two solutions containing nitric acid of different concentrations led to pitting corrosion and abrasive wear. When low concentrations of both ferric oxide nanoparticles and nitric acid were used, wear-accelerated corrosion became the dominant mechanism that was caused by the presence of third-body wear particles in the contact zone.     

Chemical Mechanical Polishing of Glass Substrate with α-Alumina-g-Polystyrene Sulfonic Acid Composite Abrasive

Abrasive is the one of key influencing factors during chemical mechanical polishing(CMP) process. Currently, α-Alumina (α-Al2O3) particle, as a kind of abrasive, has been widely used in CMP slurries, but their high hardness and poor dispersion stability often lead to more surface defects. After being polished with composite particles, the surface defects of work pieces decrease obviously. So the composite particles as abrasives in slurry have been paid more attention. In order to reduce defect caused by pure α-Al2O3 abrasive, α-alumina-g-polystyrene sulfonic acid (α-Al2O3-g-PSS) composite abrasive was prepared by surface graft polymerization. The composition, structure and morphology of the product were characterized by Fourier transform infrared spectroscopy(FTIR), X-ray photoelectron spectroscopy(XPS), time-of-flight secondary ion mass spectroscopy(TOF-SIMS), and scanning electron microscopy(SEM), respectively. The results show that polystyrene sulfonic acid grafts onto α-Al2O3, and has well dispersibility. Then, the chemical mechanical polishing performances of the composite abrasive on glass substrate were investigated with a SPEEDFAM-16B-4M CMP machine. Atomic force microscopy(AFM) images indicate that the average roughness of the polished glass substrate surface can be decreased from 0.835 nm for pure α-Al2O3 abrasive to 0.583 nm for prepared α-Al2O3-g-PSS core-shell abrasive. The research provides a new and effect way to improve the surface qualities during CMP.     

The Application of Chip Removal and Frictional Contact Analysis for Workpiece–Fixture Layout Verification

In this paper, a workpiece–fixture layout verification approach with the application of frictional contact and chip removal effects using a finite-element technique, is presented. The objective of the proposed system is to overcome the deficiencies of existing fixture design approaches. Workpiece–fixture layout verification analysis is carried out for time varying machining forces to ensure that the workpiece will be held against the cutting and clamping forces. The chip removal effect and frictional contact between the workpiece and the fixture elements are taken into account using a material removal approach based on element death technique and nonlinear finite-element analysis. A case study illustrates the application of the proposed approach. ID="A1"Correspondance and offprint requests to: Professor F. ?ztürk, Department of Mechanical Engineering, Mühendislik-Mimarlik Fakültesi, G?r¨kle Kampusu, Bursa 16059, Turkey. E-mail: ferruh@uladag.edu.tr     

Experimental Analysis and Modeling of the Effects of Oil–Air Lubrication Parameters on Bearings Friction Loss of High-Speed Motorized Spindle

The friction loss of an angular contact ball bearing is a key factor restricting the development of a high-speed motorized spindle. To quantitatively calculate the effects of the oil–air lubrication parameters on the friction loss of high-speed bearings, the drag resistance and the churning resistance generated by the movement of the rolling elements in the lubricant are theoretically modeled and the percentage volume of the lubricant in the bearing cavity (XCAV) is used to characterize the effects. The friction loss of bearings is tested by two novel methods: the free deceleration method and the energy-balance method. The experimental results show that the viscous resistance loss is a major component of bearing friction loss and oil–air lubrication parameters have important influence on it. A comparison of the theoretical calculations and the experimental results is used for deriving the empirical formula of XCAV with respect to the lubricant flow, gas pressure, rotating speed, and pitch diameter. The research results of this study have important significance for the measurement, prediction and reduction of the friction loss of high-speed bearings.     

Mechanical and tribological properties of sputtered Mo–Se–C coatings

Transition metal dichalcogenides belong to the more developed class of materials for solid lubrication. However, the main limitation of these materials is the detrimental effect of air humidity causing an increase in the friction. In previous works, molybdenum diselenide has been shown to be a promising coating retaining low friction even in very humid environment. In this study, Mo–Se–C films were deposited by sputtering from a C target with pellets of MoSe₂. Besides the evaluation of the chemical composition, the structure, the morphology, the hardness and the cohesion/adhesion, special attention was paid to the tribological characterization.The C content varied from 29 to 68 at.% which led to a progressive increase of the Se/Mo ratio. As a typical trend, the hardness increases with increasing C content. The coatings were tested at room temperature with different air humidity levels and at temperatures up to 500 °C on a pin-on-disc tribometer. The friction coefficient of Mo–Se–C coatings increased with air humidity from ～0.04 to ～0.12, while it was as low as 0.02 at temperature range 100–250 °C. The coatings were very sensitive to the elevated temperature being worn out at 300 °C due to adhesion problems at coating–titanium interface.     

Application of the Shack–Hartmann Wavefront Sensor for Monitoring the Parameters of a Supersonic Gas Jet

Results of an experimental study of the density distribution in a small-size (1–2 mm in diameter) supersonic gas jet in vacuum are reported. The measurements are performed by the developed Shack–Hartmann wavefront sensor, which consists of a microlens array with 100 × 100 elements and a video camera with a resolution of 2048 × 2048 pixels. The reliability of measurements in terms of the space and time resolution, as well as in terms of the minimum levels of phase changes induced by the tested object, is analyzed.     

Structure and Mechanical Properties of Al–Mg Alloy Workpieces in Multilayer Surfacing with Interlayer Deformation

Russian Engineering Research - Al–Mg alloy samples are produced by multilayer surfacing according to various strategies, with and without interlayer deformation. The samples undergo tensile...     

Clearance Regulation of Mechanical Gas Face Seals: Part II—Analysis and Control

This article presents the analysis and control of noncontacting mechanical gas face seals based on the state space model developed in Part I. Methods to analyze the controllability and observability of axial and tilt modes are described. The controllability analysis determines to what extent the dynamic response of the seal system modes can be shaped in a closed-loop feedback system, and the observability analysis determines if the seal system modes can be reconstructed from specific state measurements of the axial clearance and stator tilts. The error state-space method is employed to design a tracking controller to regulate the seal at a prescribed axial clearance. The control law is a function of all axial states; therefore, reduced order linear observers are designed to observe the unmeasured axial and tilt seal states. The axial clearance and tilt state estimates are used to reconstruct the gas film axial force and moments, which cannot be directly measured, for design and analysis. The analysis and control techniques are applied to the illustrative example presented in Part I. The results demonstrate that the gas film forces and moments can be estimated well and the seal system can be satisfactorily regulated with a sufficiently damped response that is within the bandwidth of today's electropneumatic actuators.     

Development and Analysis of Foil Electrodes for High Speed Electrolytic In‐Process Wheel Dressing

This paper discusses the development of an effective electrolytic in‐process dressing technique for high speed grinding. An innovative foil electrode has been designed and tested. The performance of a hydrodynamic foil electrode is discussed. Experimental investigations confirm that foil electrodes show significant improvement on electrolytic in‐process dressing even when the electrolyte supply rate is low.     

Analysis of Thermal Stability of High-Performance Rolling–Sliding Contacts in Mixed Lubrication

Thermal instability has been considered by pioneer researchers to be one of the most promising lines for a fundamental investigation into the failure mechanisms of rolling–sliding contacts. This article uses a recently developed mixed lubrication model that integrates interrelated topographical, mechanical, thermal, and tribochemical aspects to study the thermal instability of high-performance rolling–sliding contacts. The effects of various system parameters on the relation between the system bulk temperature and the heat generation in the contact are analyzed. The parameters include surface roughness; contact component size; surface and lubricant mechanical, thermal, and tribochemical properties; and operating conditions. Key results and their implications to system design and operation considerations are summarized in the Conclusion section of the article in relation to enhancing the thermal stability of the contact, particularly under adverse lubrication conditions.     

Comparison of Magnetic Parameters of Quenched Pipe Steels with X-Ray–Evaluated Residual Macro- and Microstresses

Russian Journal of Nondestructive Testing - Residual micro- and macrostresses have been determined by X-ray diffraction analysis in 22KhG2A, 30KhMA, and 32G2 grade steels quenched and tempered from...     

On‐Line Preconcentration and Analysis of Zinc in Water by Flow Injection‐Knotted Reactor: Application to Geological and Environmental Exploration

Abstract

A preconcentration on‐line system composed of flow injection (FI) and a knotted reactor (KR), associated with inductively coupled plasma atomic emission spectrometry (ICP‐AES) has been used to determine Zn concentrations in river water. The zinc was retained as Zn‐2(5‐bromo‐2‐pyridilazo)5‐diethylaminofenol precipitated complex on the knotted reactor (KR). The limit of detection (0.09 µg L^?1 of Zn) of this method makes it particularly suitable for hydrochemical exploration in geological and environmental projects. This application has been validated in the volcanogenic gold (copper, zinc, lead) deposit of La Carolina in the province of San Luis, Argentina. The Carolina Stream and the Grande River have been sampled for water downstream this deposit. The regional background in river water is 2 µg L^?1. Six times this concentration has been observed at more than 6.5 km from the source, La Carolina mine.     

Analysis of the Contribution of Adhesion and Hysteresis to Shoe–Floor Lubricated Friction in the Boundary Lubrication Regime

Slip and fall accidents cause frequent occupational injuries. Despite recent evidence that boundary lubrication is relevant to slipping, few studies have examined the mechanisms that contribute to shoe?Cfloor friction in this lubrication regime. This study aims to identify the contributions of adhesion and hysteresis to friction in boundary lubrication. Three shoe materials (40 Shore A hardness polyurethane, 60 Shore A hardness rubber, and 70 Shore A hardness rubber), two floor materials (vinyl and marble), and six lubricants (water, 1.5?% detergent, 25?% glycerol?C75?% water, 50?% glycerol?C50?% water, 75?% glycerol?C25?% water, and canola oil) were tested at a single sliding speed (0.01?m?s^?1). Dry adhesion and hysteresis were quantified for each of the shoe?Cfloor combinations and lubricated adhesion was quantified for all shoe?Cfloor-fluid combinations. The contribution of adhesion and hysteresis to shoe?Cfloor-lubricant friction was affected by both the shoe and floor material due to differences in hardness and roughness. Lubricated adhesion was complex and multifactorial with contributions from the shoe, fluid, shoe?Cfloor interaction, floor-lubricant interaction, and shoe-lubricant interactions. A simple regression model including two fluid coefficients and the dry adhesion friction force was able to predict 49?% of the lubricated adhesion friction variability.     

Mechanical Characteristics and Adhesive Strength of Nickel–Chromium Coatings Applied by Laser Cladding

Russian Engineering Research - The mechanical characteristics and adhesive strength of nickel–chromium coatings produced by the laser fusion of Ni12CrFe and PR-NiCr16SiB3 powder are compared...     

Using Methods of Analysis of Optical Images of Friction Surfaces of Ti–Al–N Based Coatings for Assessing Accumulation of Damage and Diagnostics of Failure in Tribological Tests

Russian Journal of Nondestructive Testing - The processes of damage accumulation and failure in thin ceramic coatings based on the Ti–Al–N system deposited on ductile steel and brittle...     

Structural Sensitivity of the Parameters of Asymmetric “Coercive Return–Magnetization” Cycle in Heat-Treated Low-Carbon Steels

Russian Journal of Nondestructive Testing - It has been shown both theoretically and experimentally that as the tempering temperature of quenched low-carbon steels increases up...     

The Lubricating Performance of an “in Situ” Process MoS2 Film in Air and in Liquids

The performance of a synthetic MoS₂ film, produced by electrodeposition of molybdic oxide followed by a temperature-pressure H₂S conversion to a molybdenum sulfide compound, is examined under extreme pressure conditions immersed in various fluids. Friction wear and EP characteristics, measured on various test machines, are compared to those of the fluids alone and also to conventional bonded films.

The fluids examined include: mineral oil, jet fuel, hydraulic fluid, silicone fluid.

The dry films include: burnished MoS₂ powder, MIL-L-8937 resin bonded film, MIL-L-8129 silicate bonded film and the synthetic “in situ” MoS₂ film.

The performance of the synthetic MoS₂ film on titanium and stainless steel is also examined.     

Mechanical and tribological properties of NiCr–Al2O3 composites at elevated temperatures

The effect of Al₂O₃ content on the mechanical and tribological properties of Ni–Cr alloy was investigated from room temperature to 1000 °C. The results indicated that NiCr–40 wt% Al₂O₃ composite exhibited good wear resistance and its compressive strength remained 540 MPa even at 1000 °C. The values obtained for flexural strength and fracture toughness at room temperature were 771 MPa, 15.2 MPa m^1/2, respectively. Between 800 °C and 1000 °C, the adhesive and plastic oxide layer on the worn surface of the composite was claimed to be responsible for low friction coefficient and wear rate.