非均匀热流下细小通道内相变微胶囊悬浮液传热特性

相变微胶囊悬浮液(MEPCMS)作为一种新型功能性热流体,在热管理、储能等诸多领域极具发展潜力。本文采用离散相模型(DPM)研究非均匀热流下细小水平矩形通道内MEPCMS的传热特性。结果表明：悬浮液中颗粒相变能够强化传热,在热流密度分布为9-5-5 W/cm²、进口流速为0.40 m/s、质量分数为10%时,悬浮液最高能够使壁面和流体温升分别降低8.79%和15.14%。热泳作用使颗粒在流动过程中会向低温区域迁移。与均匀热流条件相比,局部热流的分布会影响该区域及后边区域的传热特性。随着进口流速和质量分数提高,流体对壁面的冷却效果增强,同时进出口压降增加。     

相变微胶囊悬浮液的研究进展

相变微胶囊悬浮液是集储热与强化传热功能于一体的新型工质,在建筑与空调节能、太阳能利用以及航空等领域有广阔的应用前景。对相变微胶囊的制备方法、相变微胶囊乳化剂、相变微胶囊悬浮液稳定性以及流变特性的研究进展进行了综述。总结了相变微胶囊悬浮液的应用研究进展,通过分析相变微胶囊悬浮液的应用实例,提出了今后的研究方向。     

相变微胶囊悬浮液的对流换热特性研究进展

相变微胶囊悬浮液是既具有流动性又兼具蓄热能力的功能性流体。相变微胶囊悬浮液在工作过程中涉及复杂的流体流动与传热以及储热过程,近年来成为国内外学者研究的热点。对相变微胶囊悬浮液在圆管、小(微)通道内的对流换热特性进行了综述,重点阐述了国内外学者对于相变微胶囊悬浮液是否能强化对流换热存在的分歧,并提出了自己的分析与看法。分析了圆管与小(微)通道对流换热机理的区别,最后概述了强化相变微胶囊悬浮液对流换热的方法。     

微胶囊相变材料研究进展

首先介绍了微胶囊相变材料及其组成,并就微胶囊相变材料的制备方法、性能改进、性能表征以及在能量利用和热交换领域、温度控制领域和军事领域上的应用进行了综述.     

微胶囊相变乳状液在液冷服中的应用前景

介绍了一种能替代传统蓄冷介质的潜热型功能性热流体——微胶囊相变乳状液，它具有蓄冷密度大、传热性强、无过冷现象、价格低廉等优点。在传热量一定的条件下，微胶囊相变乳状液作为传热介质比水所需流量少，流动时摩擦阻力小，若用它作液冷服的冷却液可以大大减小换热管路的尺寸，降低循环泵的功耗。更重要的是，材料在发生相变前后其自身温度基本保持不变，解决了目前大多数液冷服穿着不舒适的问题。     

相变材料微胶囊研究进展

相变材料微胶囊有许多优点,如增加了热传导的面积,降低了相变材料与外界环境的反应活性并在相变发生时可以控制蓄能材料体积的变化.介绍了可作为芯材的相变材料及其主要性质,重点总结了2002年以来相变材料微胶囊的制备方法、表征与材料特点,同时讨论了国内外相变材料微胶囊在建筑节能、纺织及其他领域中的应用现状、存在的问题以及发展前景.     

乙烯基微胶囊相变材料的研究进展

综述了微胶囊相变材料及其特性,介绍了几种常用制备方法和其目前的应用领域,并重点总结归纳了乙烯基系微胶囊相变材料的研究进展,同时指出了目前存在的问题及今后的发展趋势。     

石蜡相变微胶囊及石蜡相变复合材料研究进展

介绍了石蜡相变微胶囊及石蜡相变复合材料的性能特点,阐述了原位聚合、界面聚合等主要的石蜡相变微胶囊制备方法,综述了石蜡相变微胶囊及石蜡相变复合材料在各领域内,特别是相关军事领域中的应用。     

石蜡相变微胶囊的热学性能与红外隐身性能

本研究以石蜡（PW）为芯材、三聚氰胺脲醛树脂（MUF）为壁材,采用原位聚合法制备石蜡相变微胶囊（PM）。通过ESEM、FTIR、DSC、红外热成像仪、热循环实验和破碎率测试与分析微胶囊的微观形貌、化学结构、储热性能、红外隐身性能和热稳定性。结果表明,PM1（芯壁比3∶2）和PM2（芯壁比2∶1）具有良好的储热性能,包封率分别为74.82%和75.12%,相变潜热分别为140.54 J/g和141.10 J/g。PM2具有良好的热稳定性,质量损失率为8.8%,破碎率为2.5%。掺PM2的环氧树脂具有良好的红外隐身性能,在80℃水浴加热12 min,PMER-40%(m微胶囊∶m环氧树脂=4∶6)的表面温度比环氧树脂降低了12.9℃。     

基于热管技术的相变材料强化传热技术进展

相变材料以其高蓄能密度成为蓄能领域的研究热点,但由于相变材料导热系数较低其应用受到很大的限制。针对此类现象,综述了微胶囊、金属材料、碳材料及热管技术强化相变材料传热性能的研究,并通过分析总结各种强化相变材料传热的方法的优点及缺陷。研究发现,发现热管与相变材料耦合的优势及潜力,但目前该研究处于初级阶段,仍需大量的研究工作以完善其耦合体系及其强化传热机理。     

Free convective melting-solidification heat transfer of nano-encapsulated phase change particles suspensions inside a coaxial pipe

The nano encapsulated phase change materials are of the great energy storage potential in various engineering applications. Since they are new nanomaterials, new models for understanding their thermal behavior and capability are essential. This work aims to investigate the unsteady thermal behavior of Nano-Encapsulated Phase Change Material (NEPCM) suspensions in a cylindrical cavity. The particles contain a Phase Change Material (PCM) core, which can absorb/release a substantial amount of thermal energy upon phase change. The phase change particles are well dispersed in a liquid fluid and freely move along with the fluid. The flow, heat transfer, and the particle phase change were modeled using partial differential equations. A non-dimensional approach was employed to generalize the study. The unsteady charging and discharging behavior of the NEPCM suspension are investigated for the volume fraction of the NEPCM particles, fusion temperature of nanoparticles, Stefan number, and the Rayleigh number. Numerical results show that an increment in the Stefan number, i.e., Ste, can significantly reduce the Nusselt number, i.e., Nu_a, at the charging mode of the system. However, the dependency of the Nu_a at the discharging mode on the Ste is negligible. Also, it was found that the effect of the fusion temperature of the particle’s core (θ_f) on heat transfer depends on the working mode of the system. In the charging mode, using a higher value of θ_f decreases the heat transfer rate. Reversibly, a higher value of θ_f inhibits the Nu_a during discharging state. Furthermore, the results show that for Ra = 10⁶, Ste = 0.2, and θ_f = 0.1, a rise of ϕ from 0 to 0.05 leads in about 1.73 and 1.55 times of improvement in the value of Nu_a for the cases of the melting and solidification of the core of NEPCM particles.     

Design of microencapsulated phase change material by one-step swelling polymerization in Pickering emulsion

Microencapsulated phase change materials (MePCMs) based on swelling polymerization in Pickering emulsion were demonstrated. Monodisperse poly(glycidyl methacrylate-co-2-hydroxyethyl methacrylate) P(GMA-co-HEMA) particles were prepared by dispersion polymerization. The introduction of hydrophilic monomer HEMA endowed the obtained particles with suitable surface hydrophilicity for stabilizing Pickering emulsion. MePCMs with PGMA–polystyrene interpenetrating composite shell were formed when non-crosslinked particles were employed as stabilizer, while MePCMs with particles-embedded shell were prepared with crosslinked particles as Pickering stabilizer. Phase change property, thermal stability and thermal reliability of two kinds of MePCMs were investigated by TGA, FT-IR, DSC and cycling test. The temperature of 10% weight loss of MePCMs with interpenetrating shell was 11 °C higher than that of MePCMs with particles-embedded shell. After cycling test, the percentage of leached core materials from MePCMs with interpenetrating shell was approximately one-third of that from MePCMs with particles-embedded shell. The results showed that MePCMs with an integral shell presented better thermal stability, tightness and thermal reliability than MePCMs with particles-embedded shell. The research developed a simple process for MePCMs with excellent performance.     

Thermal properties measurement and heat storage analysis of paraffin/graphite composite phase change material

This study aims at the preparation of a paraffin/graphite waste composite for thermal energy storage application at low temperature. In this composite material, the paraffin is characterized by high phase change latent heat and graphite serves as the heat transfer promoter. An investigation by means of a Differential Scanning Calorimeter (DSC), a periodic temperature method and a heat storage/release performance unit was conducted in order to measure the phase transition properties, the thermal conductivity and the melting time of the paraffin/graphite waste composites respectively. Experimental results indicated that the melting temperature did not change with the change of the amount of paraffin. On the other hand, the latent heat of phase change material increased with the increasing of the paraffin content. Furthermore, the heat transfer in the composite material during the heat storage process was enhanced through thermal conductivity improvement.     

原位聚合法制备相变材料微胶囊及其致密性

采用原位聚合法以三聚氰胺-尿素-甲醛预聚物为壁材, 包覆一种相变点为24 ℃、相变焓为225. 5 J / g 的有机相变材料, 制备一种具有调温储热功能的复合材料。通过改变三聚氰胺和尿素摩尔比对微胶囊壁材渗透性和强度进行研究。相变材料受热时会在微胶囊内部产生较大的蒸汽压使微胶囊壁破裂渗出芯材, 采用TGA 测定微胶囊热失重温度得到胶囊壁破裂时的温度。采用压力法观察微胶囊受力后的形貌, 对其强度进行评价。采用752型紫外分光光度仪对微胶囊壁渗透性进行表征。实验结果表明: 微胶囊呈球形, 平均粒径小于5μm , 固化剂滴加速度为0. 8 mL/ min 时微胶囊形貌最好。当尿素质量为反应总单体质量的20 %时, 与不加尿素相比, 微胶囊热失重温度大约提高30 ℃, 可以承受6. 0 MPa 压力而不破损, 并且渗透性并不增加。      

泡沫金属相变材料熔化传热过程的数值分析

以泡沫金属为基体,孔隙中填充相变材料制成的蓄热材料为研究对象,利用FLUENT凝固/熔化模型对填充和未填充泡沫金属的两种相变材料制成的蓄热球的相变传热过程进行数值模拟研究,得到了蓄热球传热过程的温度场分布、相界面移动规律。研究表明与未填充泡沫金属相变材料的蓄热球相比,填充泡沫金属相变材料的蓄热球能显著缩短其熔化时间并提高相变材料内部温度均匀性,从而能提高蓄热装置的蓄热速率,对相变问题的数值模拟以及相变蓄能装置的设计具有重要的参考价值。     

纳米SiO2和石墨改性相变储热微胶囊的研究

以固体石蜡为相变芯材,三聚氰胺-尿素-甲醛共缩聚树脂为囊壁,采用原位聚合法制备了微胶囊型相变储热材料;并针对该相变材料热导率低及亲水性差缺点,用石墨和纳米SiO2对芯材和微胶囊进行了导热性和表面性能的改性研究。采用光学显微镜(OM)、红外光谱仪(FTIR)、差示扫描量热仪(DSC)、热重分析仪(TGA)等对产品的表面形态、化学结构、热性能等进行了测试和表征。结果表明:石蜡微胶囊化后能保持原有的储热特性,相变焓为47.5J/g;球状微胶囊平均粒径为45μm,表面粗糙,石蜡包封率达80%;纳米SiO2改性后微胶囊亲水性、耐热性能、机械强度均增强;石墨改性后导热性提高。     

Effect of microencapsulated phase change materials on the thermo-mechanical properties of poly(methyl-methacrylate) based biomaterials

Microencapsulated paraffin based phase change material (PCM) have been incorporated into Poly(methyl-methacrylate) (PMMA) matrix in order to enhance the thermo-mechanical properties. Calorimetric and mechanical analyses are carried out and the thermo regulating potential of PMMA/PCM composites is investigated. Results indicate that the PCM phase has a negligible effect on the glass transition temperature of the PMMA matrix, and the thermal regulating capability spans around body temperature absorbing or releasing a thermal energy up to 30 J/g. One of the effect of the PCM phase into the cement is the reduction of the peak temperature developed during the exothermal reaction.     

多联机空气源热泵相变蓄能除霜特性试验研究

为了解决多联机空气源热泵常规除霜时间长、室内环境恶化等问题,提出多联机热泵相变蓄能除霜方法。针对提出的新方法,设计系统流程和试验方案,并在模拟室内外环境条件下完成试验研究。相对于常规除霜,新的除霜方法可以有效缩短33.7%的除霜时间,显著改善机组的除霜性能和室内供热环境。