Effect of Continuous use of Sodic Irrigation Water with and without Gypsum, Farmyard manure, Pressmud and Fertilizer on Soil Properties and Yields of Rice and Wheat in a Long term Experiment

A long term field experiment was conducted for 8 years during 1994–2001 to evaluate the effect of N, P, K and Zn fertilizer use alone and in combination with gypsum, farmyard manure (FYM) and pressmud on changes in soil properties and yields of rice and wheat under continuous use of sodic irrigation water (residual sodium carbonate (RSC) 8.5 meq l⁻¹, and sodium adsorption ratio (SAR) 8.8 (m mol/l)^1/2 at Bhaini Majra experimental farm of Central Soil Salinity Research Institute, Karnal, India. Continuous use of fertilizer N alone (120 kg ha⁻¹) or in combination with P and K significantly improved rice and wheat yields over control (no fertilizer). Phosphorus applied at the rate of 26 kg P ha⁻¹ each to rice and wheat significantly improved the yields and led to a considerable build up in available soil P. When N alone was applied, available soil P and K declined from the initial level of 14.8 and 275 kg ha⁻¹ to 8.5 and 250 kg ha⁻¹ respectively. Potassium applied at a rate of 42 kg K ha⁻¹ to both crops had no effect on yields. Response of rice to Zinc application occurred since 1997 when DTPA extractable Zn declined to 1.48 kg ha⁻¹ from the initial level of 1.99 kg ha⁻¹. Farmyard manure 10 Mg ha⁻¹, gypsum 5 Mg ha⁻¹ and pressmud 10 Mg ha⁻¹ along with NPK fertilizer use significantly enhanced yields over NPK treatment alone. Continuous cropping with sodic water and inorganic fertilizer use for 8 years slightly decreased the soil pH_e and SAR from the initial value of 8.6 and 29.0 to 8.50 and 18.7 respectively. However, treatments involving the use of gypsum, FYM and pressmud significantly decreased the soil pH and SAR over inorganic fertilizer treatments and control. Nitrogen, phosphorus and zinc uptake were far less than additions made by fertilizer. The actual soil N balance was much lower than the expected balance thereby indicating large losses of N from the soil. There was a negative potassium balance due to greater removal by the crops when compared to K additions. The results suggest that either gypsum or FYM/pressmud along with recommended dose of fertilizers must be used to sustain the productivity of rice – wheat system in areas having sodic ground water for irrigation.     

Dynamics of copper fractions and solubility in a savanna soil under continuous cultivation

An understanding of the influence of soil management practices on the distribution, form and solubility of trace metals in soils is required to formulate appropriate guidelines for the applications of organic manures and inorganic fertilizers for sustainable soil fertility and environmental protection. The distribution, forms and solubility of Cu were investigated in a savanna soil under long-term cultivation and varying management practices which included fertilization with NPK, farmyard manure (FYM), NPK+FYM and a control which received neither NPK nor FYM for 50 years. Total Cu varied between 5 and 13 mg kg^–1. Long-term application of FYM and FYM+NPK significantly increased DTPA extractable Cu in the surface horizon, and in the subsurface horizon in FYM fertilized fields. Averaged across the sampling depths, cultivation and management history did not affect the concentration of DTPA extractable Cu, water-soluble Cu, organically complexed Cu and residual Cu. But fertilization with FYM and FYM+NPK significantly increased organically complexed Cu in the surface layer as compared to NPK fertilization. Solubility equilibria studies indicated that Cu²⁺ activities in soil solution approached an apparent equilibrium with cupric ferrite (CuFe₂O₄), suggesting that the control on Cu²⁺ solubility was either a CuFe₂O₄ or a Cu solid with solubility similar to cupric ferrite. The soil management practices involving combined application of inorganic fertilizers and farmyard manure did not seem to pose any risk of inducing Cu deficiency, but sole application of inorganic NPK poses such a risk.     

The distribution and transformation of iron and manganese in soil fractions in a savanna Alfisol under continuous cultivation

Data on the responses of micronutrients in definable soil fractions to cultivation and management are required to design judicious fertilization practices to improve soil fertility in the savanna. Iron and manganese fractions are particularly sensitive to cultivation and management practices. The objectives of this study were to determine the sizes and changes in Fe and Mn fractions in a savanna Alfisol cultivated for 50 years and fertilized with (i) NPK, (ii) farmyard manure (FYM), (iii) FYM + NPK, (iv) a control plot, and (v) a natural site adjacent to the experimental field. The mean concentration of total Fe (Fe_T) ranged from 9.4 g kg^–1 in the surface layer to 45 g kg^–1 in the subsurface layer, whereas total mangenese (Mn_T) concentration ranged from 79 mg kg^–1 in the surface layer to 279 mg kg^–1 in the subsurface layer. The distribution of Fe_T followed the distribution of clay in the soil profile across the field. The distribution of Mn_T did not, however, follow the characteristic depth distribution of clay as observed for Fe_T, suggesting that Mn movement and distribution in this soil might be independent of clay movement and distribution. The concentrations of DTPA extractable Fe and Mn were much higher than the critical levels delineated for soils. Application of FYM increased the concentration of amorphous oxide bound Fe over the natural site and reduced the concentration of residual or inextractable Fe in the soil. Similarly, fertilization with FYM reduced the concentration of residual Mn, and increased the exchangeable, amorphous oxide bound and reducible Mn compared to the natural site. It seems that sole application of FYM or application in combination with NPK rather than NPK alone can mobilize non-labile Mn and Fe sources into labile and plant available forms of Fe and Mn in a savanna Alfisol.     

Long term effects of fertilization on carbon and nitrogen sequestration and aggregate associated carbon and nitrogen in the Indian sub-Himalayas

An understanding of the dynamics of soil organic carbon (SOC) as affected by farming practices is imperative for maintaining soil productivity and also for restraining global warming by CO₂ evolution. Results of a long-term (30 year) experiment in the Indian Himalayas under rainfed soybean (Glycine max L.)—wheat (Triticum aestivum L.) rotation was analyzed to determine the influence of mineral fertilizer and farmyard manure (FYM) application at 10 Mg ha⁻¹ on SOC and total soil nitrogen (TSN) stocks and distribution within different aggregate size fractions. Fertilizers (NP, NK and NPK) and FYM in combination with N or NPK were applied before the soybean crop every year and no nutrient was applied before the wheat crop. Results showed that addition of FYM with N or NPK fertilizers increased SOC and TSN contents. The overall gain in SOC in the 0- to 45-cm soil depth interval in the plots under NPK + FYM treatment over NPK was 17.18 Mg C ha⁻¹ in 30 year. The rate of conversion of input C to SOC was about 19% of each additional Mg C input per hectare. SOC content in large size aggregates was greater than in smaller size aggregates, and declined with decreased aggregate size. Thus, long-term soybean–wheat rotation in a sandy loam soil of the Indian Himalayas sequestered carbon and nitrogen. Soil organic C and TSN sequestration in the 0.25- to 0.1-mm size fraction is an ideal indicator of long-term C and N sequestration, since this fraction retained maximum SOC/TSN stock.     

Continuous synthesis of Zn2SiO4:Mn fine particles in supercritical water at temperatures of 400-500 °C and pressures of 30-35 MPa

Sub-micron sized Zn₂SiO₄:Mn²⁺ phosphors particles were continuously synthesized in supercritical water with a flow reactor. Colloidal silica or sodium silicate was used as the Si source. Zn and Mn sources were chosen from their nitrates, sulfates, and acetates. The syntheses were carried out at temperatures from 400 to 500 °C, at pressures from 30 to 35 MPa, at NaOH concentrations from 0.014 to 0.025 M, and for residence times from 0.025 to 0.18 s. Sodium silicate formed α- and β-Zn₂SiO₄:Mn²⁺ phases regardless of the Zn and Mn sources, while colloidal silica formed phases dependent on the type of Zn and Mn sources used in addition to the use of alkali. As the reaction temperature increased, the crystallinity of α-Zn₂SiO₄:Mn²⁺ phase increased and the Mn substitution into the Zn sites of the α-Zn₂SiO₄ phase decreased. Of the conditions studied, the most highly crystalline α-Zn₂SiO₄:Mn²⁺ was produced at a temperature of 400 °C, a pressure of 30 MPa, a NaOH concentration of 0.14 M, and a residence time of 0.13 s with Zn and Mn sulfates and colloidal silica as starting materials. The α-Zn₂SiO₄:Mn²⁺ fine particles synthesized were round in shape, had an average diameter of 268 nm, and exhibited a green-emission with a peak wavelength of 524 nm.     

Fertilization effects on yield sustainability and soil properties under irrigated wheat–soybean rotation of an Indian Himalayan upper valley

To date, the sustainability of wheat (Triticum aestivum)–soybean (Glycine max) cropping systems has not been well assessed, especially under Indian Himalayas. Research was conducted in 1995–1996 to 2004 at Hawalbagh, India to study the effects of fertilization on yield sustainability of irrigated wheat–soybean system and on selected soil properties. The mean wheat yield under NPK + FYM (farmyard manure) treated plots was ~27% higher than NPK (2.4 Mg ha⁻¹). The residual effect of NPK + FYM caused ~14% increase in soybean yield over NPK (2.18 Mg ha⁻¹). Sustainable yield index values of wheat and the wheat–soybean system were greater with annual fertilizer N or NPK plots 10 Mg ha⁻¹ FYM than NPK alone. However, benefit:cost ratio of fertilization, agronomic efficiency and partial factor productivity of applied nutrients were higher with NPK + FYM than NPK, if FYM nutrients were not considered. Soils under NPK + FYM contained higher soil organic C (SOC), total soil N, total P and Olsen-P by ~10, 42, 52 and 71%, respectively, in the 0–30 cm soil layers, compared with NPK. Non-exchangeable K decreased with time under all treatments except NPK. Total SOC in the 0–30 cm soil layer increased in all fertilized plots. Application of NPK + FYM also improved selected soil physical properties over NPK. The NPK + FYM application had better soil productivity than NPK but was not as economical as NPK if farmers had to purchase manure.     

Emissions of ammonia and nitrous oxide following incorporation into the soil of farmyard manures stored at different densities

Before spreading to land, farmyard manures (FYM) from pigs (Sus scrofa) and beef cattle (Bos taurus) were stored, for c. 120–150 days, either uncompacted or compacted. Compaction was carried out as the manures were put into store and the compacted manures were covered with plastic sheeting. Both compacted and uncompacted FYM were either incorporated by ploughing immediately after spreading, within 4 h, within 24 h or left on the surface until the soil was cultivated prior to planting. Despite greater amounts of total ammoniacal nitrogen (TAN) remaining in the compacted pig FYM, ammonia (NH₃) emissions following spreading were not significantly greater than from the uncompacted FYM, even when left on the soil surface. Incorporation of pig FYM reduced NH₃ emissions by c. 90, 60 and 30% for immediate, within 4 h and within 24 h incorporation, respectively. There were no effects of compaction during storage on nitrous oxide (N₂O) emissions following spreading for the measurement period of 60 days. Incorporation had no effect on N₂O emissions from pig FYM following spreading in the first experiment, but reduced emissions following spreading in the second year and reduced N₂O emissions following the spreading of cattle FYM in both experiments. These results indicate that rapid incorporation of FYM after spreading to land is an effective means of reducing NH₃ emissions and need not lead to increases in N₂O emissions.     

Soil organic carbon fractions after 16-years of applications of fertilizers and organic manure in a Typic Rhodalfs in semi-arid tropics

Agricultural soils can act as a potential sink of the increased carbon dioxide in the atmosphere if managed properly by application of organic manures and balanced fertilizers. However, the rate of carbon (C) sequestration in soils is low in warm climates and thus the short term changes in soil organic carbon (SOC) contents are almost negligible. Therefore, the knowledge about other C fractions that are more sensitive or responsive and indicative of the early changes in SOC can help to determine the effect of the management practices on soil C sequestration. The objective of this study was to determine the soil C sequestration after 16-years of applications of chemical fertilizers and farmyard manure (FYM) to rice (Oryza sativa)—cowpea (Vigna unguiculata) rotation system in a sandy loam soil (Typic Rhodalfs). The treatments were—(1) one control (no fertilizer or FYM); (2) three chemical fertilizer treatments [100 kg N ha⁻¹ (N), 100 kg N ha⁻¹ + 50 kg P₂O₅ ha⁻¹ (NP), 100 kg N ha⁻¹ + 50 kg P₂O₅ ha⁻¹ + 50 kg K₂O ha⁻¹ (NPK)]; (3) one integrated treatment [(50 kg N ha⁻¹ + 25 kg P₂O₅ ha⁻¹ + 25 K₂O ha⁻¹) + (50 kg N ha⁻¹ from FYM)]; and (4) one organic treatment at10 Mg ha⁻¹ FYM. Compared to the control treatment, the increase in SOC was 36, 33, and 19% greater in organic, integrated, and NPK treatments. The 16-years application of fertilizers and/or FYM resulted in much greater changes in water soluble C (WSC), microbial biomass C (MBC), light fraction of C (LFC), and particulate organic matter (POM) than SOC. Of the SOC, the proportion of POM was highest (24–35%), which was followed by LFC (12–14%), MBC (4.6–6.6%), and WSC (0.6–0.8%). The application of fertilizers and/or FYM increased the mean weight diameter of soil aggregates; thus provided physical protection to SOC from decomposition. Our results suggests that the application of fertilizers and/or FYM helps to sequester C in the soil and that the labile fractions of C can be used as indicators to determine the amount of C sequestered as a result of different management practices.     

Fractions of organic carbon in soils under different crop rotations, cover crops and fertilization practices

We investigated the long-term effects (13–48 years) of crop rotations, cover crops and fertilization practices on soil organic carbon fractions. Two long-term experiments conducted on a clay loam soil in southeastern Norway were used. From the crop rotation experiment, two rotations, one with two years grain + four years grass and the second with grain alone (both for 6 years), were selected. Each rotation was divided into moderate fertilizer rate (30–40 kg N ha^–1), normal fertilizer rate (80–120 kg N ha^–1) and farmyard manure (FYM 60 Mg ha^–1 + inorganic N at normal rate). Farmyard manure was applied only once in a 6-year rotation, while NPK was applied to every crop. The cover crop experiment with principal cereal crops consisted of three treatments: no cover, rye grass and clover as cover crops. Each cover crop was fertilized with 0 and 120 kg ha^–1 N rates. Soil samples from both experiments were taken from 0–10 cm and 10–25 cm depths in the autumn of 2001. The classical extraction procedure with alkali and acid solution was used to separate humic acid (HA), fulvic acid (FA) and humin fractions, while H₂O₂ was used to separate black carbon (BC) from the humin fraction. The rotation of grain + grass showed a significantly higher soil organic carbon (SOC) compared with grain alone at both depths. Farmyard manure application resulted in significantly higher SOC than that of mineral fertilizer only. However, cover crops and N rates did not affect SOC significantly. Organic carbon content of FA, HA and humin fractions accounted for about 29%, 25% and 44% of SOC, respectively. The rotation of grain+grass gave a higher C content in HA and humin fractions, and a lower C in the FA fraction as compared with the rotation with grain alone. Farmyard manure increased HA and humin fractions more than did chemical fertilizers. Clover cover crop increased the C proportion of humin more than rye grass and no cover crop. No significant differences in C contents of FA, HA and humin fractions were observed between N rates. Effects of cover crop and N rates as well as fertilization with NPK on black carbon (BC) content were significant only at 10–25 cm depths. Farmyard manure increased the BC fraction compared with chemical fertilizers. Clover crop also enhanced the accumulation of the BC fraction. Application of 120 kg N ha^–1 resulted in a significant increase of the BC fraction.     

Carbon sequestration in soil aggregates under different crop rotations and nitrogen fertilization in an inceptisol in southeastern Norway

Effects of crop rotation and fertilization (nitrogen and manure) on concentrations of soil organic carbon (SOC) and total soil nitrogen (TSN) in bulk soil and in soil aggregates were investigated in a long-term field experiment established in 1953 at Ås, Norway. The effect of these management practices on SOC sequestration was estimated. The experiment had three six-course rotations: (I) continuous spring grain, (II) spring grain for 3 years followed by root crops for 3 years, and (III) spring grain for 2 years followed by meadow for 4 years. Three fertilizer treatments compared were: (A) 30–40 kg N ha^–1; (B) 80–120 kg N ha^–1; and (C) a combination of B and 60 Mg farmyard manure (FYM) ha^–1. All plots received a basal rate of PK fertilizer. Soil samples from these treatments were collected in autumn 2001 and analyzed for aggregate size, SOC and TSN concentrations. There were significant increases in 0.6–2 mm and < 0.6 mm aggregate size fractions, and reduction in the 6–20 mm and the > 20 mm sizes for rotation III only. There were also significant differences among rotations with regard to water stable aggregation. The order of increase in stability was II < I < III. Fertilizer treatment had no effect on aggregation or aggregate size distribution, but there was a slight tendency of increased stability with the application of FYM. Aggregate stability increased with increasing concentration of SOC (r2 = 0.53). The SOC and TSN concentrations in bulk soil were significantly higher in rotation III than in rotations II and I. Application of FYM increased SOC and TSN concentrations significantly in the 0–10 cm soil depth, but there were few significant differences between fertility treatments A and B. There was a trend of increase in concentration of SOC and TSN with decreasing aggregate size, but significant differences in these parameters in different aggregate size fractions were found only in few cases. The SOC and TSN concentrations were higher in >0.25 mm than in < 0.25 mm aggregates. The SOC sequestration rate was 77–167 kg SOC ha^–1 yr^–1 by increasing the N rate and 40–162 kg SOC ha^–1 yr^–1 by applying FYM. The SOC sequestration rate by judicious use of inorganic fertilizer was the greatest in the grain–meadow rotation, while that by application of FYM was the greatest in the all grain rotation.     

Urea management for lowland transplanted rice as affected by application of farmyard manure

Farmyard manure (FYM) applied to rice-growing soils can substitute for industrial fertilizers, but little is known about the influence of FYM on the effectiveness and optimal management for industrial N fertilizers. A field experiment was conducted in northern Vietnam on a degraded soil in the spring season (February to June) and summer season (July to November) to determine the effect of FYM on optimal timing for the first application of urea. The experimental design was a randomized complete block with two rates of basal incorporated FYM (0 or 6 Mg ha^–1) in factorial combination with two timings of the first application of 30 kg urea-N ha^–1 (basal incorporated before transplanting or delayed until 14 to 16 d after transplanting). The FYM was formed by composting pig manure with rice straw for 3 months. Basal incorporation of FYM, containing 23 kg N ha^–1, increased rice grain yield in both seasons. The yield increase cannot be attributed to reduced ammonia loss of applied urea-N, because FYM did not reduce partial pressure of ammonia (pNH₃) following urea application in either season. Basal and delayed applications of urea were equally effective in the absence of FYM, but when FYM was applied rice yields in both seasons were higher for delayed (mean = 3.2 Mg ha^–1) than basal (mean = 2.9 Mg ha^–1) application of urea. Results suggest that recommendations for urea timing in irrigated lowland rice should consider whether farmers apply FYM.     

Burning of a Cotton Fabric Impregnated by Synthetic Zinc Carbonate Hydroxide as a Flame Retardant

Zinc carbonate hydroxide [ZnCO₃·Zn(OH)₂] synthesized by means of the multiple-bath method was deposited onto a cotton fabric, and its uniformity was ensured by means of squeeze rolls. Prolonged burning was observed on treated specimens: 200.5 sec for 20.20% of ZnCO₃·Zn(OH)₂ added to 100 g of a dry fabric increased to 337.5 sec for a 45.39% addition. The ashes of the treated specimens were subjected to X-ray diffraction analysis, and the result was compared with data for zinc and zinc-oxide powders. The existence of zinc oxide was detected in the ashes, but no traces of the metallic zinc were discovered. Therefore, it can plausibly be assumed that a reduction-oxidation reaction occurs during the smoldering process.__________Translated from Fizika Goreniya i Vzryva, Vol. 41, No. 4, pp. 73–77, July–August, 2005.     

Crop Management Affecting Methane Emissions from Irrigated and Rainfed Rice in Central Java (Indonesia)

Methane (CH₄) emissions were determined from 1993 to 1998 using an automated closed chamber technique in irrigated and rainfed rice. In Jakenan (Central Java), the two consecutive crops encompass a gradient from low to heavy rainfall (wet season crop) and from heavy to low rainfall (dry season crop), respectively. Rainfed rice was characterized by very low emission at the onset of the wet season and the end of the dry season. Persistent flooding in irrigated fields resulted in relatively high emission rates throughout the two seasons. Average emission in rainfed rice varied between 19 and 123 mg CH₄ m^–2 d^–1, whereas averages in irrigated rice ranged from 71 to 217 mg CH₄ m^–2 d^–1. The impact of organic manure was relatively small in rainfed rice. In the wet season, farmyard manure (FYM) was completely decomposed before CH₄ emission was initiated; rice straw resulted in 40% increase in emission rates during this cropping season. In the dry season, intensive flooding in the early stage promoted high emissions from organically fertilized plots; seasonal emissions of FYM and rice straw increased by 72% and 37%, respectively, as compared with mineral fertilizer. Four different rice cultivars were tested in irrigated rice. Average emission rates differed from season to season, but the total emissions showed a consistent ranking in wet and dry season, depending on season length. The early-maturing Dodokan had the lowest emissions (101 and 52 kg CH₄ ha^–1) and the late-maturing Cisadane had the highest emissions (142 and 116 kg CH₄ ha^–1). The high-yielding varieties IR64 and Memberamo had moderately high emission rates. These findings provide important clues for developing specific mitigation strategies for irrigated and rainfed rice.     

Effects of 15 years of manure and inorganic fertilizers on soil organic carbon fractions in a wheat-maize system in the North China Plain

Soil organic carbon (SOC) and its labile fractions are strong determinants of chemical, physical, and biological properties, and soil quality. Thus, a 15-year experiment was established to assess how diverse soil fertility management treatments for winter wheat (Triticum aestivum L.) and summer maize (Zea mays L.) cropping system affect SOC and total N (TN) concentrations in the North China Plain. The field experiment included three treatments: (1) unfertilized control (CK); (2) inorganic fertilizers (INF); and (3) farmyard manure (FYM). Concentrations of SOC, TN, and different labile SOC fractions were evaluated to 1-m depth. In comparison with INF and CK, FYM significantly increased SOC and TN concentrations in the 0–30 cm depth, and also those of dissolved organic C (DOC), microbial biomass C (MBC), hot-water extractable C (HWC), permanganate oxidizable C (KMnO₄–C), and particulate organic C (POC) in the 0–20 cm depth. Despite the higher crop yields over CK, application of INF neither increased the SOC nor the labile C fractions, suggesting that by itself INF is not a significant factor affecting SOC sequestration. Yet, POC (18.0–45.8% of SOC) and HWC (2.0–2.8%) were the most sensitive fractions affected by applications of FYM. Significantly positive correlations were observed between SOC and labile organic C fractions in the 0–20 cm depth. The data support the conclusion that, wherever feasible and practical, application of FYM is important to soil C sequestration and improving soil quality under a wheat/maize system in the North China Plain.     

Zinc diffusion and extractability as affected by zinc carrier and soil chemical properties

This work was carried out to evaluate the effect of soil chemical properties, Zn carrier and time elapsed after fertilizer application on the diffusion and extractability of Zn. A soil block technique was used to study zinc diffusion and DTPA extractability from ZnEDTA and ZnSO₄ fertilizers in three soils that varied in texture, CaCO₃ content, organic matter content, and pH using Zn⁶⁵ tracer. ZnEDTA diffused readily in all soils, moving 20–25 mm from the fertilizer layer after three days. The rate of Zn diffusion and the extractability of Zn, however, varied among the soils and were lowest in Baha soil with the highest clay content, organic matter, and CEC despite its lower pH. The high pH and CaCO₃ content in Dirab soil did not restrict the diffusion or reduce the extractability of ZnEDTA in this soil. On the other hand, the diffusion of Zn from ZnSO₄ fertilizer was largely restricted in all soils and was confined to 5 mm from the fertilizer layer after 13 d. The extractability of ZnSO₄ fertilizer was largely affected by soil pH and CaCO₃ content and was lowest in Dirab calcareous soil. Organic matter amendment at 5% (as alfalfa) considerably reduced the diffusion and the extractability of ZnSO₄ in both Dirab calcareous and Bakyria noncalcareous soils. The application of 1% (w/w) elemental S reduced soil pH and increased Zn diffusion from ZnSO₄ fertilizer in Bakyria soil but had slight effect on Dirab calcareous soil.     

Methane (CH4) and nitrous oxide (N2O) emissions from the system of rice intensification (SRI) under a rain-fed lowland rice ecosystem in Cambodia

The present field study investigated the effects of the system of rice intensification (SRI) on greenhouse gas emissions and rice yield, in the first field trial of its kind in Cambodia. The study was a 2 × 4 factorial design, including SRI and conventional management practices (CMP) with the following treatments: control, composted farmyard manure (FYM), mineral fertiliser (MF) and FYM + MF. The results indicated large seasonal variations of CH₄ patterns during the growing season with a peak emission of about 1,300 mg CH₄ m^?2 day^?1 under both production systems 2 weeks after rice transplanting. There was large temporal variability of CH₄ fluxes from morning to midday. Emission of N₂O was below the detection limit in both systems. Under each production system, the highest seasonal emission of CH₄ was under the FYM + MF treatment, namely 282 kg ha^?1 under CMP and 213 kg ha^?1 under SRI. Total CH₄ emission under SRI practices was reduced by 22 % in the FYM treatment, 17 % in the MF treatment and 24 % in the FYM + MF treatment compared to CMP. There was no effect of water management on CH₄ emission in the non-fertilized treatment. Grain yields were not significantly affected by the production system. Thus the yield-scaled global warming potential (GWP) was lower under SRI than CMP, namely 21 % in FYM and FYM + MF treatments, and 8 % in MF treatment. The application of mineral fertilisers moderately increased CH₄ emission but significantly increased rice yields, resulting in a significantly lower yield-scaled-GWP compared to farmyard manure.     

Long-term effect of fertilizer and manure application on soil-carbon sequestration and soil fertility under the wheat–wheat–maize cropping system in northwest China

Maintenance of soil organic carbon (SOC) is important for the long-term productivity of agroecosystems. An investigation was conducted to study the effects of long-term application of inorganic fertilizers and farmyard manure (FYM) on soil organic carbon (SOC), nitrogen, phosphorus, and potassium nutrient content, water-stable aggregate distribution, and aggregate-associated carbon in a field experiment started in 1982 in an arid region of northwest China. Application of inorganic fertilizer alone (N, NP, or NPK treatments) did not increase SOC concentrations compared with no application of fertilizers (CK) and SOC concentration was significantly reduced, by 18% on average, compared with the initial value at the beginning of the experiment. Application of imbalanced inorganic fertilizer (N and NP), especially, resulted in a significant decrease in available phosphorus and potassium nutrients at a depth of 20 cm. This indicates that long-term application of inorganic fertilizers were inadequate to maintain levels of SOC and nutrients under conventional management with no aboveground crop residues returning to the soil. Long-term application of FYM alone or combined with inorganic fertilizers (M (FYM), MN, MNPK, or MNPK treatments), however, improved SOC and total nitrogen concentrations from initial values of 12.1 and 0.76 g kg⁻¹, respectively, to 15.46 and 1.28 g kg⁻¹, on average, and also enhanced available nitrogen, phosphorus, and potassium concentrations by 47, 50, and 68%, respectively, during the 23-year period. Treatment with FYM resulted in a 0.48 mm greater average mean weight diameter (MWD) of aggregates and a higher percentage of macro-aggregates (>2 mm) and small macro-aggregates (2–0.25 mm) than treatment without FYM. The MWD increased with increasing SOC concentration (R ²=0.75). The SOC concentration was highest in small macro-aggregates, intermediate in macro-aggregates, and lowest in micro-aggregates (0.25–0.05 mm). Approximately 54–60% of total SOC was stored in micro-aggregates (0.25–0.05 mm) and sand+silt fractions (<0.05 mm) after treatment without FYM but 57–64% of total SOC was stored in macro-aggregates (>0.25 mm) after treatment with FYM. MNPK treatment had the greatest effect on improving the levels of SOC and NPK nutrients and in enhancing the formation and stability of macro-aggregates.     

Response of dryland wheat to fertilizer nitrogen in relation to stored water,rainfall and residual farm yard manure

Yield response of dryland wheat to fertilizer N application in relation to components of seasonal water (available soil moisture and rainfall) and residual farm yard manure (FYM) was studied for five years (1983–84 to 1987–88) on a maize-wheat sequence on sandy loam soils in Hoshiarpur district of Punjab, India. Four rates of N viz. 0, 40, 60 and 80 kg ha^–1 in wheat were superimposed on two residual FYM treatments viz. no FYM (F₀) and 15 t ha^–1 (F₁₅) to preceding maize. FYM application to maize increased the residual NO₃-N content by 19–30 kg ha^–1 in the 180 cm soil profile. For a given moisture distribution, F₁₅ increased attainable yields. Over the years, F₁₅ increased wheat yield by 230 to 520 kg ha^–1. Response to fertilizer N was lower in FYM amended plots than in unamended plots. Available soil moisture at wheat seeding and amount and distribution of rainfall during the vegetative and the reproductive phases of crop development affected N use efficiency by wheat. Available soil moisture at seeding alone accounted for 50% variation in yield. The residual effect of FYM on wheat yield could be accounted for by considering NO₃-N in 180 cm soil profile at seeding. The NO₃-N and available soil moisture at wheat seeding along with split rainfall for two main phases of crop development and fertilizer N accounted for 96% variation in wheat yield across years and FYM treatments.     

Soil aggregation and carbon and nitrogen stabilization in relation to residue and manure application in rice–wheat systems in northwest India

Soil organic matter (SOM), besides influencing carbon (C) transfer between soils and atmosphere, impacts soil functional ability and its response to environmental and anthropogenic influences. We studied the impact of continuous application of rice straw and farmyard manure (FYM) either alone or in conjunction with inorganic fertilizers on aggregate stability and distribution of C and nitrogen (N) in different aggregate fractions after 7 years of rice–wheat cropping on a sandy loam soil. Macroaggregates (>0.25 mm) constituted 32.5–54.5% of total water stable aggregates (WSA) and were linearly related (R ² = 0.69) to soil organic carbon content. The addition of rice straw and FYM significantly (P < 0.05) improved the formation of macroaggregates with a concomitant decrease in the proportion of microaggregates at all the three sampling depths (0–5, 5–10 and 10–15 cm). Macroaggregates had higher C and N density as compared to microaggregates. Application of rice straw and FYM improved C and N density in different aggregate sizes and the improvement was greatest in plots that received both rice straw and FYM each year. Application of FYM along with inorganic fertilizer resulted in a net C sequestration of 0.44 t ha⁻¹ in the plough layer after 7 years of rice–wheat cropping. Carbon sequestration was greater (1.53 t ha⁻¹) when both rice straw and FYM along with inorganic fertilizers were applied annually. It is concluded that addition of rice straw and FYM in rice–wheat system improves soil aggregation and enhances C and N sequestration in macroaggregates. This will help in sustainable rice–wheat productivity in the region.     

Extraction of lead with nitrobenzene solution of strontium dicarbollylcobaltate in the presence of 18-crown-6

From extraction experiments with ⁸⁵Sr as a tracer, the extraction constant corresponding to the equilibrium Pb²⁺(aq) + SrL²⁺(nb) ⇄ PbL²⁺(nb) + Sr²⁺(aq) taking place in the two-phase water – nitrobenzene system (L = 18-crown-6; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K_ex(Pb²⁺, SrL²⁺) = 1.5. Further, the stability constant of the PbL²⁺ complex in nitrobenzene saturated with water was calculated: log β_nb(PbL²⁺) = 12.9.