Thermomechanic behavior of a polymer upon its formation in a crystallization process: Theoretical principles,hypotheses, and mathematical model

A model of thermomechanic behavior of a polymer upon its formation in a crystallization process is proposed. Based on methods of nonequilibrium thermodynamics governing relationships are obtained which make it possible to establish the dependence of the final degree of crystallicity of the material on the history of the crystallization process and to explain the mechanism of formation of the remanent stresses in a polymer article.Notation u translation vector - v velocity vector - acceleration vector - absolute temperature - density - c specific heat capacity - deformation tensor - strain tensor - specific enthropy - U ^* internal energy - z specific free enthalpy - _i internal parameters of state - t time - q heat flux vector - matrix of heat conduction coefficients - W ^* energy dissipation - F vector of mass forces - the 4th rank tensor of elastic pliabilities - matrix of heat expansion coefficients - tensor of contribution of structural variations to deformation - function of equilibrium value ^* - p mean pressure - deviator of the tensor of deformations - spherical part of the deformation tensor - deviator of the tensor of stresses - K volume modulus - unity tensor - Q enthalpy of the crystallization process - Q _eq enthalpy of the equilibrium crystallization process - _g glass transition temperature - ^*() the curve obtained in the equilibrium crystallization process - f final degree of crystallicity Institute of Mechanics of Continuous Media of the Ural Branch of the Russian Academy of Sciences, Perm', Russia. Institute of Technical Chemistry of the Ural Branch of the Russian Academy of Sciences, Perm', Russia. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 68, No. 3, pp. 479–485, May–June, 1995.     

The contributions of microrotation of lubricant molecules in a thin film journal bearing

Summary Characteristics of a journal bearing were computed for thin film lubrication accounting for microrotation of the lubricant molecules using both the half-Sommerfeld and Reynolds boundary conditions. Although the Reynolds boundary conditions produced higher pressure and loads, the effects of microrotation studied by both schemes showed similar trends. Primary characteristics that effect the contributions of microrotation to the load carrying capacity of the journal bearing were identified. These characteristics were varied and their effects on the load capacity of the journal bearing are shown.Nomenclature a circumference of the shell, 2R - a ₁,a ₂,a ₃ constants - c radial difference between the shaft and shell, [R-r] - c ₁,c ₂,c ₃,c ₄ solving partial differential equations constants - e eccentricity - F ^* body force per unit mass - G substitute function for integration - h film thickness - j microinertia constant of the fluid - K ₁,K ₂ defined after Eq. (2.27) - l material length, - L ^* body couple - m - N coupling number, - p pressure - p ₀ ambient pressure - Q fluid flux flow through the cavity cross section - r shaft radius - R shell radius - R _h modified Reynold number, - R _l Reynolds number, - t time - u, v velocity components inx-andy-direction, respectively - u ₀ velocity of the shaft surface - V velocity vector - W load carrying capacity - W load component resulting from pressure parallel to the line of centers - W load component resulting from pressure perpendicular to the line of centers - x, y, z Cartesian coordinates - , , , micropolar viscosity coefficients - ₁, ₂ parameters of boundary conditions for the microrotation vector at the shell and shaft, respectively - the deviate angle of the load direction from the line of centers - e/c - , Newtonian viscosity coefficients - microrotation velocity vector - microrotation velocity component in thez-direction - angular velocity of the shaft - ^* thermodynamic pressure - mass density of the lubricant fluid - polar angle around the journal bearing - ^* angle which satisfies Reynold's B.C.     

On type-II superconductors with a first-order transition at the lower critical field

The free energy of a superconductor in the mixed state is obtained to first order in 1–(T/T _c) and – in terms of the solutions of the Ginzburg-Landau equations for = . The circular cell approximation is used to evaluate the lower critical field and the discontinuity in the magnetization at this field for those type-II materials displaying a first-order transition at the field of first flux penetration; the cases of both singly quantized and doubly quantized vortices are considered. The main result of the numerical calculations is that the critical value of for a first-order transition is identical to the critical value of for an attractive interaction between widely separated vortices.Supported in part by the National Research Council of Canada.     

Die Entwicklung von Längswirbeln in zeitlich anwachsenden Grenzschichten an konkaven Wänden

Zusammenfassung Messungen des Anwachsens von Längswirbeln in zeitlich anwachsenden Grenzschichten an konkav gekrümmten Wänden (Görtler-Taylor-Wirbel) ergaben drei deutlich getrennte Bereiche: Es traten zunächst Wirbel mit der Wellenläge 0,9 auf (=Grenzschichtdicke, =Höhe einer Zelle, die zwei gegensinnig drehende Wirbel enthält). Je nach Größe der mit der Verdrängungsdicke ₁ der Grenzschicht gebildeten Reynolds-Zahl erschienen dann kurze Zeit später Wirbel mit 2,5, wenn war. Im Bereiche dagegen traten stattdessen bei den hier durchgeführten Versuchen immer Wirbel mit der Wellenlänge 6,5 auf. Bei werden die ersten Tollmien-Schlichting-Wellen mit der Wellenlänge _TS 6· angefacht. In ihren wandnahen Bereichen der Wellentäler könnten sich dann die oben genannten Längswirbel der Wellenlänge 6,5· ausbilden, die die zwei-in eine dreidimensionale Störung allseits gleicher Größenordnung verwandeln können.

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The development of longitudinal vortices in boundary layers growing with time along concave walls

Summary Measurements of the growth of longitudinal vortices in boundary layers growing with time along concave walls (Görtler-Taylor vortices) rendered three distinctly separated regions. First, vortices with a wave-length 0.9 appeared (-boundary layer thicness, =height of a cell containing two counterrotating vortices). Then, depending on the Reynolds number R _{a 1}/v ₁=displacement thickness), vortices with 2.5 appeared shortly afterwards, provided . In the region , however, the wave-length was 6.5. For the first Tollmien-Schlichting waves with _TS 6 were excited. In the wave-throughs close to the wall the abovementioned longitudinal vortices with wave length 6.5 may then be formed. This might transform the two-dimensional into a three-dimensional flow of equal order of magnitude in all directions.

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Zeichenerklärungen R _a Innenradius - Re _a Reynolds-Zahl gebildet mit dem InnenradiusR _a - Reynolds-Zahl gebildet mit der Verdrängungsdicke ₁ - kritische Taylor-Zahl - h Standhöhe der Flüssigkeit im Zylinder - t Zeit - z Anzahl - Steigungswinkel der Geraden - Grenzschichtdicke - ₁ Verdrängungsdicke - Wellenlänge (enthält ein gegensinnig rotierendes Längswirbelpaar) - v kinematische Zähigkeit - Winkelgeschwindigkeit Indizes K Knickpunkt der Geradensteigung - L unterhalb des Knickpunktes der Geradensteigung - TS Tollmien-Schlichting - e Einsatz der Wirbelentstehung     

Tangent modulus tensor in plasticity under finite strain

Summary The tangent modulus tensor, denoted as , plays a central role in finite element simulation of nonlinear applications such as metalforming. Using Kronecker product notation, compact expressions for have been derived in Refs. [1]–[3] for hyperelastic materials with reference to the Lagrangian configuration. In the current investigation, the corresponding expression is derived for materials experiencing finite strain due to plastic flow, starting from yield and flow relations referred to the current configuration. Issues posed by the decomposition into elastic and plastic strains and by the objective stress flux are addressed. Associated and non-associated models are accommodated, as is plastic incompressibility. A constitutive inequality with uniqueness implications is formulated which extends the condition for stability in the small to finite strain. Modifications of are presented which accommodate kinematic hardening. As an illustration, is presented for finite torsion of a shaft, comprised of a steel described by a von Mises yield function with isotropic hardening.Notation B strain displacement matrix - C=F ^T F Green strain tensor - compliance matrix - D=(L+L ^T )/2 deformation rate tensor - D fourth order tangent modulus tensor - tangent modulus tensor (second order) - d VEC(D) - e VEC() - E Eulerian pseudostrain - F, F _e ,F _p Helmholtz free energy - F=x/X deformation gradient tensor - f consistent force vector - residual function - G strain displacement matrix - h history vector - h time interval - H function arising in tangent modulus tensor - I, I ₉ identity tensor - i VEC(I) - k ₀,k ₁ parameters of yield function - K _g geometric stiffness matrix - K _T tangent stiffness matrix - k _k kinematic hardening coefficient - J Jacobian matrix - L=v/x velocity gradient tensor - m unit normal vector to yield surface - M strain-displacement matrix - N shape function matrix - n unit normal vector to deformed surface - n ₀ unit normal vector to undeformed surface - n unit normal vector to potential surface - r, R, R ₀ radial coordinate - s VEC() - S deformed surface - S ₀ undeformed surface - t time - t, t ₀ traction - t VEC() - VEC( ) - t VEC() - t _r reference stress interior to the yield surface - t t–t _r - T kinematic hardening modulus matrix - u=x–X displacement vector - U permutation matrix - v=x/t particle velocity - V deformed volume - V ₀ undeformed volume - X position vector of a given particle in the undeformed configuration - x(X,t) position vector in the deformed configuration - z, Z axial coordinate - vector of nodal displacements - =(F ^T F–I)/2 Lagrangian strain tensor - history parameter scalar - , azimuthal coordinate - elastic bulk modulus - flow rule coefficient - twisting rate coefficient - elastic shear modulus - iterate - Second Piola-Kirchhoff stress - Cauchy stress - Truesdell stress flux - deviatoric Cauchy stress - Y, Y yield function - residual function - plastic potential - X, Xe, Xp second order tangent modulus tensors in current configuration - X, Xe, Xp second order tangent modulus tensors in undeformed configuration - (.) variational operator - VEC(.) vectorization operator - TEN(.) Kronecker operator - tr(.) trace - Kronecker product     

An exact calculation of Price's law for the law of Lotka

Price's law asserts — in its simpliest version — that authors produce half of the papers made by the total ofN authors. More generally: the topN (0<<1) authors produce a fraction (0<<1) of the papers made by the total ofN authors and the Price's law says that . In this paper — using Lotka's law — we prove a mathematical relationship of in function of and the parameter (the mean number of papers per author) and investigate when . More-over our reasoning uses the theory of the 80/20 rule as developed in: L. EGGHE, On the 80/20-rule,Scientometrics, 10 (1986) 55–68, thereby also showing the relation betwwen the 80/20-rules (being an arithmetical form of measuring elitarism) and Price's law (being a geometric form of measuring elitarism).     

The Dual-Phase-Lag Heat Conduction Model in Thin Slabs Under a Fluctuating Volumetric Thermal Disturbance

In the present work, the thermal behavior of a thin slab, under the effect of a fluctuating volumetric thermal disturbance described by the dual-phase-lag heat conduction model is investigated. It is found that the use of the dual-phase-lag heat conduction model is essential at large frequencies of the volumetric disturbance. It is found that the hyperbolic wave model deviates from the diffusion model when and the dual-phase-lag model deviates from the diffusion model when . where is the angular velocity of the fluctuating wall temperature, is the phase-lag in the heat flux vector and is the phase-lag in the temperature gradient vector.     

Viscous response of an anchored spinning liquid column to various axial excitations

Summary For a solidly rotating viscous cylindrical liquid column of finite length the response to axial synchronous, counter- and one-sided excitation is determined for anchored contact lines at the disc-rim. For a rotating column additional responses of inertial waves (hyperbolic range) appear for < 2 ₀, while in the elliptic range < 2 ₀ the sloshing response occurs. The various responses for the free surface displacement have been numerically evaluated. Only in the one-sided exitation case all resonance peaks appear, while for synchronous excitation only the odd resonances and for counter-excitation only the even resonance peaks occur.Notation a radius of column - h length of liquid bridge - I _n modified Bessel function - p liquid pressure - r, ,z cylindrical polar coordinates - t time - u, v, w velocity distribution - Weber number - z ₀ excitation amplitude - liquid density - surface tension - surface tension parameter - Ohnesorge number - liquid surface displacement - kinematic viscosity - ₀ rotational speed - dimensionless rotational speed - forcing frequency - dimensionless forcing frequency - dimensionless forcing frequency for non-viscous liquid - a= root of bi-cubic Eq.(33) - root of bi-cubic Eq.(33)     

Higher approximations for supersonic flow past slowly oscillating bodies of revolution

Summary Supersonic flow past slowly oscillating pointed bodies of revolution is studied. Starting from the complete nonlinear potential equation an elementary linearized solution is discussed and it is shown how this solution together with the method of matched asymptotic expansions can be used to derive an elementary second-order slender body theory. This approach is further demonstrated for the oscillating cone and its range of validity is evaluated by comparison with other theoretical methods.

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Zusammenfassung Es wird die Überschallströmung um langsam schwingende spitze Rotationskörper untersucht. Ausgehend von der vollständigen nichtlinearen Potentialgleichung wird zuerst eine elementare linearisierte Lösung besprochen und gezeigt, wie diese Lösung im Verein mit der Method of matched asymptotic expansions zur Herleitung einer elementaren Schlankkörpertheorie zweiter Ordnung verwendet werden kann. Die Theorie wird am Beispiel des schwingenden Kegels näher erläutert und mit anderen Methoden verglichen.

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Symbols a Velocity of sound - c _N Normal force coefficient - Damping coefficient - F _(x) Dipole distribution - k Reduced frequency - M Mach number - R (x) Meridian profile - t Time - x, r, Cylindrical coordinates - - Ratio of specific heats - Amplitude of oscillation - Thickness ratio - Perturbation potential - Zero angle of attack potential - æ - Velocity potential - Out-of-phase potential - - In-phase potential - - Source coordinate With 4 Figures     

Axi-symmetric natural frequencies and response of a spinning liquid column under strong surface tension

Summary The response of a solidly rotating anchored finite liquid column consisting of frictionless liquid is subjected to axial harmonic excitation. The response of the free liquid surface elevation and velocity distribution has been determined analytically in the elliptic (>2 ₀) and hyperbolic frequency range (>2 ₀). For the liquid surface displacement the response has been evaluated numerically as a function of the forcing frequency/2 ₀. In addition the first natural stuck-edge frequency has been determined and compared with the slipping case.List of symbols a radius of liquid bridge - h length of liquid bridge - I ₀,I ₁ modified Besselfunctions - J ₀,J ₁ Besselfunctions - p liquid pressure - r, ,z cylindrical polar coordinates - t time - u, v, w velocity distribution in rotating liquid - Weber number - z₀ axial excitation amplitude - elliptic case (>2 ₀) - hyperbolic case (>2 ₀) - liquid density - surface tension - liquid surface displacement - acceleration potential - ₀ rotational speed - axial forcing frequency - natural frequency of rotating system - _0n natural frequency of harmonic axial response     

Order parameters and energies of analytic and singular vortex lines in rotating3He-A

We present the expressions of the generalized Ginzburg-Landau (GL) theory for the free energy and the supercurrent in terms of thed vector, the magnetic fieldH, and operators containing the spatial gradient and the rotation. These expressions are then specialized to the Anderson-Brinkman-Morel (ABM) state. We consider eight single-vortex lines of cylindrical symmetry and radiusR=[2m/]^–1/2: the Mermin-Ho vortex, a second analytic vortex, and six singular vortices, i.e., the orbital and radial disgyrations, the orbital and radial phase vortices, and two axial phase vortices. These eight vortex states are determined by solving the Euler-Lagrange equations whose solutions minimize the GL free energy functional. For increasing field, the core radius of the texture of the Mermin-Ho vortex tends to a limiting value, while the core radius of the texture goes to zero. The gap of the singular vortices behaves liker forr 0, where ranges between and . The energy of the radial disgyration becomes lower than that of the Mermin-Ho vortex for fieldsH6.5H*=6.5×25 G (atT=0.99T _c and forR=10L*=60 µm, or=2.9 rad/sec). ForR 2 _T ( _T is the GL coherence length) or _c2 (upper critical rotation speed), the energies of the singular vortices become lower than the energies of the analytic vortices. This is in agreement with the exact result of Schopohl for a vortex lattice at _c 2. Finally, we calculate the correction of order (1 -T/T _c ) to the GL gap for the axial phase vortex.     

Shear viscosity of the B phase of superfluid3He

The shear viscosity (T) in the Balian-Werthamer (BW) state of superfluid ³ He is calculated variationally throughout the region 0t 1(t=T/T _c) from the transport equation for Bogoliubov quasiparticles. Coherence factors are treated exactly in the calculation of the collision integral. The numerical result for =_s= _s(T)/_n(T_c) agree very well with experiment in the range 0.8t1.0. Analytic expressions = 0.577 (1–1.0008t) and =1–(23/64) [=(T)/k _B T] are obtained in the low-temperature region and in the vicinity ofT _c, respectively. From the numerical analysis it is shown that the latter equation is valid only in the temperature range 0.9997t1.0.Supported by the Research Institute for Fundamental Physics, Kyoto University.     

Phonon Thermal Conductivity of Stripe Ordering La2–x Sr x NiO4

We have studied the thermal conductivity of stripe ordering La _2–x Sr _x NiO ₄. In particular, long range stripe order is well established for x = 1/3. For this composition is enhanced in the charge ordering phase and exhibits a clear maximum at low T. Even small deviations from this stochiometry cause a strong change of : the low T-maximum is suppressed and no anomaly is observed at high T. Our data confirm that the stripe phase is most stable for x = . Moreover, we find clear differences in the thermal conductivity for x > and for x < , respectively, which indicates different properties of the stripe ordered phase in these two regions of the phase diagram.     

Angular dependence of the critical magnetic field in granular superconducting films

The critical magnetic fieldH _c () of granular Al films has been measured as a function of the angle between the field direction and the plane of the film at temperatures nearT _c0 .The film thicknessd is smaller than the temperature-dependent coherence length (T), the bulk electron mean free path1 is smaller than the BCS coherence length ₀, and 1 d. The experimental data onH _c () are well fitted by the Tinkham formula. However, the observed values ofH _c/H _care not always consistent with and increase with1/d. This fact suggests that the boundary scattering of electrons at the film surface enhancesH _c () and that the enhancement ofH _cis larger than that ofH _c.On leave from Department of Physics, Faculty of Science, Kyushu University, Fukuoka, Japan.     

Slip flow past an approximate spheroid

Summary Creeping axisymmetric slip flow past a spheroid whose shape deviates slightly from that of a sphere is investigated. An exact solution is obtained to the first order in the small parameter characterizing the deformation. As an application, the case of flow past an oblate spheroid is considered and the drag experienced by it is evaluated. Special well-known cases are deduced and some observations made.Notation A _n, B_n, C_n, D_n, E_n, F_n, b₂, d₂ Constants - a, b radii of spheres - coefficient of sliding fraction - D drag - , _m parameters characterizing the deformation of the sphere - c a(1+) - viscosity coefficient - - dimensionless coordinate - I _n Gegenbauer function - P _n Legendre function - Stream function - U stream velocity at infinity     

Thermal conductivity and quantum diffusion in solid H2

The thermal conductivity of solid H₂ and the NMR absorption signal of isolated o-H₂ were measured simultaneously along isotherms 0.07<T<1.5 K as a function of time after a rapid cooldown from 2 K. The o-H₂ concentration ranged from 3.4% to 0.4%, and the pressure was 90 atm. During the measurements, clustering of o-H₂ particles occurred as seen from the changes both of the NMR signal amplitude and of with time t. The difference ^–1 = ^–1 ()– ^–1(0) between the thermal resistivity ^–1 (t=0) just after cool down and in equilibrium, ^–1 (), was found to change sign near 0.23 K, and this result is discussed with respect to previous experiments. The equilibrium resistivity attributed to the o-H₂ impurities, , is derived and is compared with previous determinations and with predictions. An analysis of the equilibration process for ^–1 and for the NMR signal amplitude is presented. It shows that the characteristic times are of comparable but not equal magnitude. Comparison of the derived from NMR data atP=90 and 0 atm favors resonant ortho-para conversion over quantum tunneling as the leading mechanism for quantum diffusion.     

Effect of nonlinearity of gas mixtures on the process of their partition by thermal diffusion

Under consideration is the effect of nonideality of the components in a gas mixture on the process of their separation by thermal diffusion. It is demonstrated that in the expressions for the heat flux and the mass flux, the thermodiffusion ratio and the characteristic of diffusional thermal conductivity the effect of nonideality appears in the heat of mixing.Notation p pressure - density - length of the mean free path for molecules during transport of particles - length of the mean free path for particles during a transfer of the mean velocity - n molecule concentration - M molecular weight - I particle flux - J mass flux - m mass of a molecule - t time - D_ij coefficient of interdiffusion for a binary mixture - D _i ^T coefficient of thermal diffusion - K_T thermodiffusion ratio - _T thermodiffusion constant - x_i molar fraction of the i-th component in the mixture (r), intermolecular interaction potential - r intermolecular distance - collision integrals - T temperature - T^* referred temperature - R universal gas constant - k Boltzmann constant - Ñ Avogadro's number - v mean velocity of molecules - ¯V diffusion rate - _{i, trans} thermal conductivity associated with translatory degrees of freedom - f_i(r, v, t) velocity distribution function of molecules - viscosity - _i chemical potential of the i-th component - c_i mass fraction - _o thermal conductivity at the initial instant of time - thermal conductivity in the steady state - _DT diffusional component of thermal conductivity - g and h molar thermodynamic functions - ¯g and ¯h specific thermodynamic functions - c_p specific heat - J_q heat flux - J_q reduced heat flux - B second virial coefficient - U^* transport energy - coefficient of thermal expansion - coefficient of isothermal compression - f_i activity coefficient for the i-th mixture component Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 40, No. 5, pp. 829–839, May, 1981.     

The Validity of Using the Microscopic Hyperbolic Heat Conduction Model Under a Harmonic Fluctuating Boundary Heating Source

The validity of using the microscopic hyperbolic heat conduction model under a harmonic fluctuating boundary heating source is investigated. It is found that using the microscopic hyperbolic heat conduction model is essential when . The phase shift between the electron-gas and solid-lattice temperatures is found to be . This phase shift reaches a fixed value of 1.5708 rad at very large values of . It is found that the use of the microscopic hyperbolic heat conduction model is essential when ¯>1×10⁹ rads^–1 for most metallic layers independent of their thickness.     

On internal stress and activation volume in polymers

The two-site model is developed for the analysis of stress relaxation data. It is shown that the product of d In (– )/d and (- _i) is constant where is the applied stress, _i is the (deformation-induced) internal stress and = d/dt. The quantity d In ( )/d is often presented in the literature as the (experimental) activation volume, and there are many examples in which the above relationship with (- _i) holds true. This is in apparent contradiction to the arguments that lead to the association of the quantity d In (– )/d with the activation volume, since these normally start with the premise that the activation volume is independent of stress. In the modified theory presented here the source of this anomaly is apparent. Similar anomalies arise in the estimation of activation volume from creep or constant strain rate tests and these are also examined from the standpoint of the site model theory. In the derivation presented here full account is taken of the site population distribution and this is the major difference compared to most other analyses. The predicted behaviour is identical to that obtained with the standard linear solid. Consideration is also given to the orientation-dependence of stress-aided activation.     

Natural damped frequencies and axial response of a rotating finite viscous liquid column

Summary For a finite solidly rotating cylindrical liquid column the damped natural axisymmetric frequencies have been determined. The liquid was considered incompressible and viscous. The cases of freely slipping edges and that of anchored edges have been treated. It was found that instability appears in a purely aperiodic root for the spinning liquid bridge. This is in contrast to the instability appearing in the damped oscillatory natural frequency of a nonspinning liquid column at . The spinning viscous liquid column exhibits the same instability as the frictionless liquid. It appears at for axisymmetric oscillations.List of symbols a radius of liquid column - I _m modified Bessel function of first kind and orderm - s complex frequency ( ) - r, ,z polar cylindrical coordinates - p pressure - t time - u, v, w radial-, azimuthal- and axial velocities of liquid, respectively - Weber number - h height of liquid column - dynamic viscosity of liquid - v kinematic viscosity of liquid (v=/) - density of liquid - surface tension of liquid - _r , _rz shear stress - (r, z, t) circulation - (r, z, t) streamfunction - ₀ angular velocity of liquid column about the axis of symmetry - (,t) free surface displacement