The effect of environmental and structural factors on indoor air quality of apartments in Korea

The indoor air quality (IAQ) was measured in newly built Korean apartments before and after occupancy in a survey of 158 residences in 24-apartment complexes nationwide. Factors that might affect pollutant concentration, such as temperature, humidity, housing size, and duration of occupancy, were analyzed in relation to the measured concentrations. Average pollutant levels were consistent with the Ministry of the Environment's recommended standards; however, pollutant levels in some apartments exceeded the current standards. We found that the concentrations of formaldehyde and toluene often exceeded the more stringent guidelines that will soon be enacted. Our results suggest that stronger countermeasures are therefore required to control these two chemicals. The results show that the pollution concentration was generally proportional to temperature and humidity, but that, in some cases, the concentration measurements were inversely proportional to these two factors, and in a few others the relationship between these factors was not clear. Indoor air pollution readings were highest in the 30-pyeong apartments, followed by 10-, and 20-pyeong residences. The pollutant concentrations decreased to about half of their initial levels after one year of occupancy, but the concentration of formaldehyde in indoor air persisted for a longer period. The duration of the apartment's occupancy affected indoor air pollutant concentrations more so than other factors such as temperature, humidity, and apartment size.     

Nasal hyperreactivity in allergic and non-allergic rhinitis: a potential risk factor for non-specific building-related illness

Self-reported non-allergic nasal symptom triggers in non-allergic ('vasomotor') rhinitis overlap with commonly identified environmental exposures in non-specific building-related illness. These include extremes of temperature and humidity, cleaning products, fragrances, and tobacco smoke. Some individuals with allergic rhinitis also report non-allergic triggers. We wished to explore the phenotypic overlap between allergic and non-allergic rhinitis by ascertaining self-reported non-allergic nasal symptom triggers among allergic rhinitics. Sixty subjects without work-related respiratory exposures or symptoms, aged 19-68 years, stratified by age, gender and (skin test-proven) allergic rhinitis status, were queried with regard to self-reported non-allergic nasal symptom triggers (aggregate score 0-8). In this sample, the number of self-reported non-allergic triggers was bimodal, with peaks at 1 and 5. Forty-two percent of seasonal allergic rhinitic subjects reported more than three non-allergic triggers, compared with only 3% of non-allergic non-rhinitics (P < 0.01). Subjects over 35 years were more likely to report one or more non-allergic triggers, particularly tobacco smoke (P < 0.05). Allergic rhinitics reported more non-allergic symptom triggers than did non-allergic, non-rhinitics. As indexed by self-reported reactivity to non-specific physical and chemical triggers, both non-allergic rhinitics and a subset of allergic rhinitics may constitute susceptible populations for non-specific building-related illness. PRACTICAL IMPLICATIONS: Judging by self-report, a substantial subset of individuals with allergic rhinitis--along with all individuals with nonallergic rhinitis (by definition)--are hyperreactive to non-allergic triggers. There is overlap between these triggers (elicited in the process of obtaining a clinical diagnosis) and environmental characteristics associated with 'problem buildings.' Since individuals with self-identified rhinitis report an excess of symptoms in most epidemiologic studies of problem buildings (even in the absence of unusual aeroallergen levels), rhintics may be acting as a 'sentinel' subgroup when indoor air quality is suboptimal. Together, non-allergic rhinitics plus allergic rhinitics with prominent non-allergic triggers, are thought to constitute approximately one-sixth of the US population.     

The Indoor Environment in Dwellings: A Study of Air-exchange,Humidity and Pollutants in 115 Danish Residences

A total of 115 Danish dwellings were investigated during the winter season in order to evaluate the indoor environment. The sample was considered representative of Danish dwellings. Measurements of air-exchange rates in the bedrm showed a very low natural venthtion with a median air-exchange rate of 0.28 air changes per hour (ach) (interqmmle range (IQR): 0.12 –0.56).18% of the dwellings had a natural air-exchange below a detectable limit of 0.10 ach and 72% had air-exchanges rates below the requirements in Danish Building Codes of 0.50 ach. The investigations showed a statistically signifiant inverse correlation between air-exchange rates and absolute indoor humidity. Concentrations of formaldehyde and volatile organic compounds were measured in 36 dwellings. The median formaldehyde concentration was 0.037 mg/m³ which is well below the recommended indoor TLV The concentration of VOC in some cases reached a level that may be of importance for persons with sensitive airways. It is concluded that natural ventilation in a great number of Danish dwellings is too low fiom a health point of view and that the requirements in Danish Building codes are insufficient to ensure acceptable air-exchange rates.     

Indoor air quality in Michigan schools

Indoor air quality (IAQ) parameters in 64 elementary and middle school classrooms in Michigan were examined for the purposes of assessing ventilation rates, levels of volatile organic compounds (VOCs) and bioaerosols, air quality differences within and between schools, and emission sources. In each classroom, bioaerosols, VOCs, CO(2), relative humidity, and temperature were monitored over one workweek, and a comprehensive walkthough survey was completed. Ventilation rates were derived from CO(2) and occupancy data. Ventilation was poor in many of the tested classrooms, e.g., CO(2) concentrations often exceeded 1000 ppm and sometimes 3000 ppm. Most VOCs had low concentrations (mean of individual species <4.5 microg/m(3)); bioaerosol concentrations were moderate (<6500 count per m(3) indoors, <41,000 count per m(3) outdoors). The variability of CO(2), VOC, and bioaerosol concentrations within schools exceeded the variability between schools. These findings suggest that none of the sampled rooms were contaminated and that no building-wide contamination sources were present. However, localized IAQ problems might remain in spaces where contaminant sources are concentrated and that are poorly ventilated. PRACTICAL IMPLICATIONS: Indoor air quality (IAQ) is a continuing concern for students, parents, teachers, and school staff, leading to many complaints regarding poor IAQ. Investigations of these complaints often include air sampling, which must be carefully conducted if representative data are to be collected. To better understand sampling results, investigators need to account for the variability of contaminants both within and between schools.     

Cleaning for Improved Indoor Air Quality: an Initial Assessment of Effectiveness

Abstract A study was conducted to characterize the indoor environment of a multifloor, multiuse, nonproblem, noncompliant building through long-term monitoring for biological, chemical, and particulate pollutants. The study also assessed the effects of cleaning on indoor air quality by providing a program to monitor baseline levels, providing a rigorous (deep) cleaning of the building, and then continuing to monitor after implementation of a standardized, improved, cleaning program. To assess the effectiveness of the cleaning program, air, surface, and dust data from monitoring prior to the cleaning program were compared with those obtained while the improved housekeeping program was in place. Correlations between pollutants and other environmental factors were studied. The data suggest that the improved cleaning program contributed to indoor air quality through the reduction of airborne dust mass, total volatile organic compounds, and culturable bacteria and fungi.     

Cleaning products and air fresheners: emissions and resulting concentrations of glycol ethers and terpenoids

Experiments were conducted to quantify emissions and concentrations of glycol ethers and terpenoids from cleaning product and air freshener use in a 50-m3 room ventilated at approximately 0.5/h. Five cleaning products were applied full-strength (FS); three were additionally used in dilute solution. FS application of pine-oil cleaner (POC) yielded 1-h concentrations of 10-1300 microg/m3 for individual terpenoids, including alpha-terpinene (90-120), d-limonene (1000-1100), terpinolene (900-1300), and alpha-terpineol (260-700). One-hour concentrations of 2-butoxyethanol and/or d-limonene were 300-6000 microg/m3 after FS use of other products. During FS application including rinsing with sponge and wiping with towels, fractional emissions (mass volatilized/dispensed) of 2-butoxyethanol and d-limonene were 50-100% with towels retained, and approximately 25-50% when towels were removed after cleaning. Lower fractions (2-11%) resulted from dilute use. Fractional emissions of terpenes from FS use of POC were approximately 35-70% with towels retained, and 20-50% with towels removed. During floor cleaning with dilute solution of POC, 7-12% of dispensed terpenes were emitted. Terpene alcohols were emitted at lower fractions: 7-30% (FS, towels retained), 2-9% (FS, towels removed), and 2-5% (dilute). During air-freshener use, d-limonene, dihydromyrcenol, linalool, linalyl acetate, and beta-citronellol) were emitted at 35-180 mg/day over 3 days while air concentrations averaged 30-160 microg/m3. PRACTICAL IMPLICATIONS: While effective cleaning can improve the healthfulness of indoor environments, this work shows that use of some consumer cleaning agents can yield high levels of volatile organic compounds, including glycol ethers--which are regulated toxic air contaminants--and terpenes that can react with ozone to form a variety of secondary pollutants including formaldehyde and ultrafine particles. Persons involved in cleaning, especially those who clean occupationally or often, might encounter excessive exposures to these pollutants owing to cleaning product emissions. Mitigation options include screening of product ingredients and increased ventilation during and after cleaning. Certain practices, such as the use of some products in dilute solution vs. full-strength and the prompt removal of cleaning supplies from occupied spaces, can reduce emissions and exposures to 2-butoxyethanol and other volatile constituents. Also, it may be prudent to limit use of products containing ozone-reactive constituents when indoor ozone concentrations are elevated either because of high ambient ozone levels or because of the indoor use of ozone-generating equipment.     

Indoor and outdoor air concentrations of BTEX and determinants in a cohort of one-year old children in Valencia, Spain

BTEX is the commonly used term for a group of toxic compounds (benzene, toluene, ethyl benzene, ortho-xylene and meta- and para-xylene), some of which, most notably benzene, are known carcinogens. The aim of this study is to measure the BTEX levels both inside and outside the homes of 352 one-year old children from the Valencia cohort of the INMA study (Spain) and to analyze the determinants of these levels. Passive samplers were used to measure BTEX levels during a 15 day period and a questionnaire was administered to gather information on potentially associated factors (sociodemographics, residential conditions, and lifestyle). The average concentrations of benzene, toluene, ethyl benzene, ortho-xylene, and meta- and para-xylene were 0.9, 3.6, 0.6, 0.6, and 1.0 μg/m³, respectively. On average, the indoor levels of all the compounds were approximately 2.5 times higher than those observed outdoors. Factors associated with higher BTEX concentrations inside the home were being the child of a mother of non-Spanish origin, living in a house that had been painted within the last year, living in an apartment, and not having air conditioning. Higher outdoor concentrations of BTEX depend on the residence being situated in a more urban zone, being located within the city limits, having living in a building with more than one story, residing in an area with a greater frequency of traffic, and the season of the year in which the sample was taken. The data thus obtained provide helpful information not only for implementing measures to reduce exposure to these pollutants, but also for evaluating the relation between such exposure and possible health risks for the children in the cohort.     

Indoor air pollution and its impact on children under five years old in Bangladesh

Indoor air concentrations of volatile organic compounds (VOCs), carbon monoxide (CO), carbon dioxide (CO2), nitrogen dioxide (NO2), and dust particles were measured for 49 biomass and 46 fossil fuel users in urban slums of Dhaka, Bangladesh. The health impacts of these pollutants were assessed on 65 and 51 children under five years old from families who use biomass and fossil fuel as main source of energy, respectively. Mean concentrations of CO were found to be significantly higher in biomass fuel users (P = 0.010), while geometric mean concentrations of benzene, xylene, toluene, hexane, total VOCs, and NO2 were significantly higher (P < 0.01) in the fossil fuel users. Symptoms such as redness of eyes, itching of skin, nasal discharge, cough, shortness of breath, chest tightness, wheezing, or whistling chest were found to be associated with the choice of biomass fuel, with the odds ratio ranging from 4.0 to 6.3. No significant association of use of biomass fuel with respiratory diseases, eczema, diarrhea, or viral fever was observed after adjustment for potential confounders. These results suggest a significant association between the biomass fuel-using population and respiratory symptoms. These symptoms may not be due to the pollutants only, as some other underlying causes may be present. PRACTICAL IMPLICATIONS: The health of children under five years old in Bangladesh, especially those living in poor socioeconomic conditions, is considered to be worsening because of indoor air pollution. It is commonly suggested that biomass fuel should be replaced by fossil fuel, as pollution levels are believed to be higher with biomass fuel. Our findings, however, suggest that pollution can be higher with fossil fuels, and indicate that a switch in fuel from biomass to fossil does not necessarily improve the children's health. Awareness programs should therefore be undertaken to avoid the unnecessary use of gas. Clean fuels and clean stoves should also be ensured to reduce emissions of indoor air pollutants.     

Exposure to Volatile Organic Compounds of Microbial Origin (MVOC) during Indoor Application of Water-based Paints

The market for water-based paints (WBP) is growing, and these paints are favoured due to their low emission of volatile organic compounds (VOC). Because of the risk for microbial growth, biocides are usually added to WBP. Our study aimed to measure exposure to VOCs potentially of microbial origin (MVOC), during indoor application of typical Scandinavian WBP. Low concentrations of three MVOCs, 3-methyl-furan, 1-octen-3-ol, and 2-octen-1-ol, were detected during 5 out of 20 painting operations (25%). Mean exposures to MVOC and TVOC were 0.15 and 5000 μg/m³, respectively. No relation between MVOC and TVOC was observed. The highest exposure to MVOC was measured from an ecological paint, claimed to be low in VOCs and chemical additives. The results suggest that microbial growth in WBP may occur, and that measurements of MVOCs could be used as a means of quality control for WBP. The use of biocides in paint should be guided by the principle of a balance between the risk of contact allergies or other possible health hazards from the biocides, and the risk of microbial growth. If microbial growth occurs in paint, it may cause both unpleasant odor and potential health hazards for house painters and dwellers.     

The Danish Twin Apartment Study; Part I: Formaldehyde and Long-Term VOC Measurements

Field measurements of 21 volatile organic compounds (VOC) using diffusive samplers, formaldehyde, temperature, and humidity were performed from the time of building completion throughout the following one-year period in two new semi-detached twin apartments. One of these was occupied after six weeks. Headspace analyses from all building materials and products showed 120 different VOC. Formaldehyde concentrations were strongly seasonally dependent in the vacant apartment and increased to above 400 μg/m³ during the warm season. The formaldehyde concentration generally decreased in the occupied apartment but increased again during the fall season. VOC originating from building materials generally showed a decrease in emission, but strong seasonal variations were observed. It was shown that human activity introduces several VOC to the indoor environment. Storage of motorcycle parts in the crawl space of the occupied apartment resulted in migration and an infiltration of benzene and toluene into the apartment above and probably to a delayed peak concentration in the twin vacant apartment. Similarly, large VOC increases in one apartment were reflected by a later increase of the same VOC in the twin apartment. Hexanal increased during the warm season. TVOC, as the sum of 21 VOC, was generally approximately 50 % higher in the occupied apartment during the cold season. The results indicate the difficulties in interpreting long-term measurements. The “flushing period” recommended for this type of building has been estimated to be about 130 days.     

Spatial and temporal variability in VOC levels within a commercial retail building

A study was performed to characterize the concentration of dozens of volatile organic compounds (VOCs) at 10 locations within a single large building and track these concentrations over a 2-year period. The study was performed at a shopping center (strip mall) in New Jersey. A total of 130 indoor air samples were collected from 10 retail stores within the shopping center and analyzed for 60 VOCs by US EPA Method TO-15. Indoor concentrations of up to 55,100 microg/m(3) were measured for individual VOCs. The indoor/outdoor ratio (I/O) was as high as 1500 for acetone and exceeded 100 at times for various compounds, indicating that significant indoor air sources were present. A large degree of spatial variability was observed between stores within the building, with concentrations varying by three to four orders of magnitude for some compounds. The spatial variability was dependent on the proximity of the sampling locations to the indoor sources. A large degree of temporal variability also was observed for compounds emitted from indoor sources, but the temporal variability generally did not exceed two standard deviations (sigma). For compounds not emitted from indoor sources at significant rates, both the spatial and temporal variability tended to range within an order of magnitude at each location. PRACTICAL IMPLICATIONS: Many cross-sectional studies have been published where the levels of volatile organic compounds (VOCs) were measured in indoor air at one or two locations for houses or offices. This study provides longitudinal data for a commercial retail building and also addresses spatial variability within the building. The data suggest that spatial and temporal variability are important considerations for compounds emitted from indoor sources. Elevated concentrations were found in retail spaces with no apparent emission sources due to their proximity to other retail spaces with emission sources.     

A screening assessment of emissions of volatile organic compounds and particles from heated indoor dust samples

This paper characterizes and compares emissions during heating of different dust samples relevant to the indoor environment. Characterization includes emission of volatile organic compounds when dust samples were heated to 150 and 250 degrees C (gas chromatograph-mass spectrometer), weight loss during heating to 450 degrees C (thermogravimetric analysis), and the number of particles emitted during heating towards 200 degrees C (condensation nucleus counting). Element analyses were performed for non-heated dust (inductively coupled plasma discharge instrument). Emissions of volatile organic compounds from heated dust from different sources were surprisingly similar. However, the temperature at which the emission of volatiles started varied with the dust source. For most of the samples studied, the emissions were considerable already at 150 degrees C, and increased in number of peaks and peak area at 250 degrees C. Particle emissions started around 70 degrees C regardless of the dust source. Particle emissions seemed to be affected by the content of organic material.     

Modelling of Emission and Re-emission of Volatile Organic Compounds from Building Materials with Indoor Air Applications

Polymer materials and their additives are today ever present in our daily surroundings. These materials have been found to emit a number of different volatile organic compounds (VOCs) into the ambient air, thus affecting the quality of the indoor air VOCs with detectable concentrations are exchanged between the different materials and indoor air. Materials present in the system act as sorbents as well as sources of emission, depending on the concentration of the VOCs in the air at a specific time. This work demonstrates a method of studying the phenomena of absorption/re-emission. A hypothetical room that resembles a furnished office has been studied. A PVC flooring material was used as a primary emission source in a system where materials such as wood, paint, cloth, chipboard, and cellulose were present. Mass transfer in the solid materials was assumed to be by diffusion. The results show that the mechanism of absorption/re-emission of volatiles may extend the time of residence in an indoor system considerably. A person working in this environment could risk longer exposure to toxic volatiles than if there were no absorption/re-emission effects.     

Simulation of VOC emissions from building materials by using the state-space method

There are many mass-transfer models for predicting VOC emissions from building materials described in the literature. In these models, the volatile organic compound (VOC) emission rate and its concentration in a chamber or a room are usually obtained by analytical method or numerical method. Although these methods demonstrate some salient features, they also have some flaws, e.g., for analytical method the solutions of both room or chamber VOC concentration and building material VOC emission rate are constituted of the sum of an infinite series, in which additional computation for finding roots to a transcendental function is necessary, but sometimes quite complicated. Besides, when it is applied in complex cases such as multilayer emission with internal reaction, the solution is very difficult to get; for conventional numerical methods such as finite difference method, discrete treatment of both time and space may cause calculation errors. Considering that, the state-space method widely used in modern automation control field and the heat transfer field is applied to simulate VOC emissions from building materials. It assumes that a slab of building material is composed of a number of finite layers, in each of which the instantaneous VOC concentration is homogenous during the entire process of emission, while the time is kept continuous. Based on this assumption we can predict both the VOC emissions rate and the concentrations of VOCs in the air of a chamber or room. The method is generally applied to simulate VOC emissions from arbitrary layers of building materials, and the solution is explicit and simple. What's more, the method can be applied to the cases where a reaction producing/removing VOC in building materials exists. For some specific cases the method is validated using the experimental data and the analytical solutions in the literature. The method provides a simple but powerful tool for simulating VOC emissions from building materials, which is especially useful in developing indoor air quality (IAQ) simulation software.     

Indoor air quality for chemical and ultrafine particle contaminants from printers

There are various emission sources of chemical contaminants, such as volatile organic compounds (VOCs) and ozone and particulate matter. This report is a study into the indoor air of a room containing either a laser printer/ink-jet printer, and the air contaminations were monitored for VOCs, ozone and ultrafine particle. The result confirmed an increase in the concentration of ozone and ultrafine particle numbers in the printing processes of the printer. The emission of VOCs and ozone were measured by the use of a test chamber. The chamber concentrations of styrene, xylenes and ozone were increased in printing process of the laser printer, and pentanol was detected from the ink-jet printer. The results suggest that an office or residential printer may be a source of indoor air contamination. It is necessary for emission from printers to monitor not only VOCs and particle but also ultrafine particles and other contaminants in indoor air.     

Development of a new photocatalytic oxidation air filter for aircraft cabin

A new photocatalytic oxidation air filter (PCO unit) has been designed for aircraft cabin applications. The PCO unit is designed as a regenerable VOC removal system in order to improve the quality of the recirculated air entering the aircraft cabin. The PCO was designed to be a modular unit, with four UV lamps sandwiched between two interchangeable titanium dioxide coated panels. Performances of the PCO unit has been measured in a single pass mode test rig in order to show the ability of the unit to decrease the amount of VOCs (toluene, ethanol, and acetone) entering it (VOCs are fed separately), and in a multipass mode test rig in order to measure the ability of the unit to clean the air of an experimental room polluted with the same VOCs (fed separately). Triangular cell panels have been chosen instead of the wire mesh panels because they have higher efficiency. The efficiency of the PCO unit depends on the type of VOCs that challenges it, toluene being the most difficult one to oxidise. The efficiency of the PCO unit decreases when the air flow rate increases. The multipass mode test results show that the VOCs are oxidized but additional testing time would be necessary in order to show if they can be fully oxidized. The intermediate reaction products are mainly acetaldehyde and formaldehyde whose amount depends on the challenge VOC. The intermediate reaction products are also oxidized and additional testing time would be necessary in order to show if they can be fully oxidized. The development of this new photocatalytic air filter is still going on. PRACTICAL IMPLICATIONS: The VOC/odor removing adsorbers are available for only a small proportion of aircraft currently in service. The photocatalytic oxidation (PCO) technique has appeared to be a promising solution to odors problems met in aircraft. This article reports the test results of a new photocatalytic oxidation air filter (PCO unit) designed for aircraft cabin applications. The overall efficiency of the PCO unit is function of the compound (toluene, ethanol, and acetone) that challenges the unit and toluene appears to be the most difficult compound to oxidize. Test results have shown the influence of the design of the PCO unit, the air flow rate and the type of UV on the efficiency of the PCO unit. The results obtained in this study represent a first attempt on the way to design a filter for VOC removal in cabin aircraft applications. The PCO technique used by the tested prototype unit is able to partially oxidized the challenge VOCs but one has to be aware that some harmful intermediate reaction products (mainly formaldehyde and acetaldehyde) are produced during the oxidation process before being partially oxidized too.     

Selective permeation of moisture and VOCs through polymer membranes used in total heat exchangers for indoor air ventilation

Fresh air ventilation is central to indoor environmental control. Total heat exchangers can be key equipment for energy conservation in ventilation. Membranes have been used for total heat exchangers for more than a decade. Much effort has been spent to achieve water vapor permeability of various membranes; however, relatively little attention has been paid to the selectivity of moisture compared with volatile organic compounds (VOCs) through such membranes. In this investigation, the most commonly used membranes, both hydrophilic and hydrophobic ones, are tested for their permeability for moisture and five VOCs (acetic acid, formaldehyde, acetaldehyde, toluene, and ethane). The selectivity of moisture vs. VOCs in these membranes is then evaluated. With a solution-diffusion model, the solubility and diffusivity of moisture and VOCs in these membranes are calculated. The resulting data could provide some reference for future material selection. PRACTICAL IMPLICATIONS: Total heat exchangers are important equipment for fresh air ventilation with energy conservation. However, their implications for indoor air quality in terms of volatile organic compound permeation have not been known. The data in this article help us to clarify the impacts on indoor VOC levels of membrane-based heat exchangers. Guidelines for material selection can be obtained for future use total heat exchangers for building ventilation.     

Volatile Organic Compounds,Indoor Air Quality and Health

This publication summarizes field investigations and controlled experiments on the relation between low levels of indoor air pollution with volatile organic compounds (VOC) and human health and comfort. The Henle-Kock criteria from epidemiology are revised for the dose-response relation between VOC's and health as comfort effects and existing evidence for each criterion are discussed. A biological model for human responses is suggested, based on three mechanisms: sensory perception of the environment, weak inflammatory reactions, and environmental stress reactions. Further, the TVOC-indicator concept for exposure is discussed. The conclusion is that no experimental or field data contradict the proposed causality. On the contrary, evidence supports the suggested causality. The biological model, however, is not yet based on acceptable measures of the variables for exposures, co-variables or health effects. A tentative guideline for VOC's in non-industrial indoor environments is suggested. The no-effect level seems to be about 0.2 mg/m³. A multi-factorial exposure range may exist between 0.2 and 3 mg/m³. Above 3 mg/m³ discomfort is expected.