共查询到18条相似文献,搜索用时 171 毫秒
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以蒽醌作催化剂,水热加氢还原从Ni(OH)2水浆制备了超细镍粉.研究了催化剂量、温度、时间、氢分压、浓度和pH等因素对还原速度和粉末粒度的影响,还原率通过X-射线衍射分析本被还原的镍来确定.用扫描电镜观察分析了粉末的粒度与形貌.研究表明,在温度高于200℃的条件下,蒽醌对Ni(OH)2浆料还原成金属镍粉是一种良好的催化剂.所得的粉末是平均粒径约为300nm的球状超细镍粉. 相似文献
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以六水合氯化镍为镍源,水合肼为还原剂,在SiC的表面,采用原位化学沉淀法制得包裹均匀的Ni/SiC复合粉体.采用扫描电子显微镜(SEM)、X射线衍射仪(XRD)、傅立叶红外光谱仪(FT-IR)等测试表征手段研究了工艺条件对原位沉积反应的影响.研究发现不同络合反应时间形成的镍肼络合物前驱体和镀镍反应温度可以影响反应速率,从而控制Ni颗粒的沉积速率和包裹效果.对比结果表明:络合反应时间为5 min形成的镍肼络合物前驱体在50℃水浴温度下和络合反应时间为2h得到的镍肼络合物前驱体在60℃水浴温度下得到的复合粉体包裹效果最佳. 相似文献
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表面活性剂对氢氧化镍制备的影响 总被引:7,自引:0,他引:7
近年来,在Ni(OH)2的制备中使用表面活性剂主要是制备纳米Ni(OH)2或超微粉末[1-4]。但由于纳米级或超微粉末Ni(OH)2不适合于目前以泡沫镍为基体的Ni-MH电池的生产,所以本实验制备Ni(OH)2晶体时,加入适量表面活性剂对颗粒表面进行改性,控制颗粒的生长和团聚,制备微米级Ni(OH)2。1实验部分以氨作配合剂利用化学沉淀法将硫酸镍溶液、氢氧化钠溶液、表面活性剂溶液、氨水以一定的比例并流加入反应器,连续搅拌,控制反应温度在50~60℃,pH值10~12之间。反应14~16 h后停止加料,陈化约8 h后,固液分离,洗涤沉淀,烘干得到氢氧化镍产品。在制备过… 相似文献
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以NiSO4.6H2O、NaOH和H2为原料,采用低温固相法制备了分布均匀、平均粒径为20~35 nm的纳米镍粉,并采用X射线衍射(XRD)、透射电子显微镜(TEM)、扫描电子显微镜(SEM)和X射线光电子能谱分析(XPS)等微观分析手段对产物表面结构和价态进行了表征。研究了纳米镍粉加氢还原硝基苯制备苯胺体系中温度、氢压力、催化剂用量等因素对转化率的影响,并与Raney Ni的活性做了比较。结果表明,纳米镍粉催化加氢活性高于RaneyNi,是同条件下Raney Ni的9倍左右;催化剂用量4wt%~6wt%(质量含量,下同),温度为120℃为还原的最佳条件;同时发现氢压力对转化率也有着较大影响,当压力达到0.8 MPa,硝基苯转化为苯胺的转化率高达76.42%。 相似文献
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以水合肼为还原剂,用偶合物合成了2-(2'-羟基-5'-甲基苯基)苯并三唑-N-氧化物.考察了原料比,氢氧化钠用量及浓度等因素对产品收率的影响.得到了适宜的反应条件偶合物、水合肼与氢氧化钠的摩尔比为10.535.3,氢氧化钠溶液的浓度为18%,反应温度80~82℃,收率达95%以上,纯度为99%. 相似文献
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Xian Jian Zuowan Zhou Sixin Wu Lei Chen Qing Zeng Chao Wang 《Nanoscale research letters》2014,9(1):370
The mass preparation of high-purity coiled carbon fibers (CCFs) remains challenging due to the high complexity and low controllability of reaction. In this work, a controllable growth of Ni particles was fulfilled by liquid phase reduction of nickel sulfate with hydrazine hydrate. The impacts of the reaction temperature, NaOH concentration, and reaction time on the particle size and purity were investigated. The as-deposited Ni particles were characterized by scanning electron microscopy and X-ray diffraction. In addition, these Ni particles were also applied in preparing high-purity CCFs both on graphite and ceramic substrates. The diameter of the as-grown carbon microcoil was about 500 nm, and the related growth mechanism was discussed. 相似文献
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Synthesis of nickel nanopowders from aqueous solution using hydrothermal reduction method with hydrazine hydrate as a reducing agent and Cetyl trimethyl ammonium bromide (CTAB) as a surfactant was investigated. Statistical design was used to study the effects of reaction time, concentration of nickel chloride, and concentration of surfactant on the nickel particles size. Formed nickel particles were characterized using XRD and SEM. The formation of nickel single phase was revealed from XRD patterns. On the other hand, SEM showed that the nickel particles are in nanosized ranges from 55 nm to 250 nm. The analysis of the results indicated that the reaction time and surfactant addition were the controlling factors. The reduction of nanocrystalline nickel hydroxide Ni(OH)2 into Ni is the possible formation mechanism. 相似文献
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Precipitation and Calcination Processes for Yttrium Aluminum Garnet Precursors Synthesized by the Urea Method 总被引:5,自引:0,他引:5
Naoya Matsushita Noriyoshi Tsuchiya Katsuto Nakatsuka Takakimi Yanagitani 《Journal of the American Ceramic Society》1999,82(8):1977-1984
Yttrium aluminum garnet (YAG) precursors for transparent ceramics were synthesized by the urea method under various [urea]/[metal ions] ([U]/[M]) conditions. Monophase YAG was obtained from solutions with a high [U]/[M] ratio after calcination at a temperature of 1200°C. The condition of the precipitates seemed to indicate that the yttrium compounds had precipitated onto the aluminum compounds. The surface morphology and size of the particles were controlled by the [U]/[M] ratio. The different reaction sequences of YAG crystallization for low- and high-ratio samples were dependent on morphology, size, and the quantity of chemical species that was precipitated as carbonate and/or sulfate compounds. 相似文献
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Present work involves synthesis of NiO nanoparticles using chemical homogeneous precipitation (CHP) method as a facile procedure. Ammonia as a complex agent was used in this method. Effects of different types of complexation-precipitation methods on the crystallinity and morphology of nanoparticles were investigated. NiO particles were prepared by direct precipitation method from NiSO4 solution to compare crystallinity and morphology of NiO particles with particles obtained via complexation-precipitation methods. Our major intent was to investigate the effect of complex agent on the crystallization and growth of NiO nanoparticles. Results showed that the best condition for synthesizing spherical NiO shape was using NaOH as decomposing agent, of which the consequence was more uniformity and spherical nanoparticles with a diameter in the range of 40–60 nm. The size of the nickel oxide and nickel hydroxide nanoparticles was estimated by X-ray powder diffraction (XRD) pattern. The chemical structure information of the particles was studied by Fourier transform infrared (FT-IR) spectroscopy. Spherical, elliptical, sheet or flowerlike shapes were detected by field emission scanning electron microscopy (FESEM) analysis. Results showed that by the use of ammonia as complex agent, crystalline state and particles size distribution of NiO nanoparticles improved. 相似文献
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《Ceramics International》2017,43(18):16593-16599
In the present study, nickel-doped zinc oxide thin films (ZnO:Ni) at different percentages (0–10%) were deposited on glass substrates by using a chemical spray technique. The effect of Ni concentration on the structural and optical properties of the ZnO:Ni thin films was investigated. The effect of Ni contents on the crystalline structure and optical properties of the films was systematically investigated by X-ray diffraction (XRD), scanning electronic microscopy (SEM), UV–vis, Photoluminescence spectra PL, and Raman spectrometry. The XRD analysis showed that both the undoped and Ni-doped ZnO films were crystallized in the hexagonal structure with a preferred orientation of the crystallites along the [002] direction perpendicular to the substrate. The XRD analysis also showed that the films were well crystallized in würtzite phase with the crystallites preferentially oriented towards (002) direction parallel to the c-axis. SEM study reveals the surface of NiZnO to be made of nanocrystalline particles. The SEM images showed a relatively dense surface structure composed of crystallites in the spherical form whose average size decreases when the [Ni]/[Zn] ratio increases. The optical study showed that all the films were highly transparent. The band gap decreased up to the 7 at% Ni doping level, but the band gap increased after 10 at% Ni doping level. All thin films exhibited approximately 80% and above transmittance in the visible region. PL spectra of undoped and Ni-doped ZnO thin films showed some marked peaks at 376, 389, 494, and 515 nm. The obtained results revealed that the structures and optical properties of the films were greatly affected by doping levels. These films are useful as conducting layers in electro chromic and photovoltaic devices. Finally, all results were discussed in terms of the nickel doping concentration. 相似文献
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化学法制备电极用超细铜粉 总被引:1,自引:0,他引:1
以CuSO4溶液为原料,采用NaOH沉淀-葡萄糖预还原-水合肼还原工艺(简称两步液相还原法)制得了粒度均匀可控、分散性好、适用于陶瓷电容器电极的球形超细铜粉。实验研究了葡萄糖预还原、水合肼的添加方式以及添加剂聚乙烯吡咯烷酮(PVP)和NH4Cl对超细铜粉粒度和形貌的影响。结果表明,葡萄糖预还原和水合肼的分步添加均有利于超细铜粒子的均匀生长,适量PVP的加入有助于超细铜粉粒径均匀并使其形貌趋于一致,NH4Cl可使铜粉的粒径变小,当Cu与NH4Cl的摩尔比为1∶1时铜粉的形貌会由类球形向正多面体转变。 相似文献
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以高浓度NaOH溶液为亚熔盐介质分解钾长石矿精粉,考察了矿物粒径、NaOH溶液浓度、搅拌速度、反应时间、反应温度、液固比对K+溶出率的影响,并对分解过程动力学进行分析. 结果表明,100 mm粒径钾长石矿精粉的最佳反应条件为:NaOH初始浓度60%(w)、反应温度约160℃、搅拌速度400 r/min、液固质量比4:1、反应140 min,该条件下K+溶出率大于98%. 钾长石的分解符合粒径恒定的缩核模型,反应初期固相产物层内扩散为速控步骤. 80~140℃下,反应的表观活化能为110.42 kJ/mol. 相似文献