A novel hybrid absorption–compression refrigeration cycle

When used in traditional pool-boiling type refrigeration cycles, non-azeotropic mixed refrigerants tend to result in a reduced efficiency compared to pure refrigerants. This results from the composition shift effect, which distributes the mixture components: concentrating the more volatile component in the high pressure part of the cycle, and the less volatile component in the low pressure part. The obvious effect of this is to increase the compression ratio relative to a single component. This article investigates a way of manipulating the composition change of a refrigerant mixture, using two components of similar volatility, in order to reduce the compression ratio. Counter-current vapour–liquid contact is used in a “refrigeration column”, which is combined with a distillation column. The cycle is able to exploit heat sources below 100°C as input to the distillation column and the designer is able to optimise the consumption of compressor power and distillation heat input.     

A combined-cycle refrigeration system using ejector-cooling cycle as the bottom cycle

A combined-cycle refrigeration system (CCRS) that comprises a conventional refrigeration and air-conditioning system using mechanical compressor (RAC/MC) and an ejector-cooling cycle (EJC) is proposed and studied. The EJC is driven by the waste heat from the RAC/MC and acts as the bottom cycle of the RAC/MC. A system analysis shows that the COP of a CCRS is significantly higher than a single-stage refrigeration system. Improvement in COP can be as high as 18.4% for evaporating temperature of the RAC/MC T_e at −5°C. A prototype of the CCRS was built and tested in the present study. Experimental results show that at T_e=−4.5°C, COP is improved by 14% for a CCRS. For T_e at 5°C, COP can be improved by 24% for a CCRS with higher condensing temperature of the RAC/MC. The present study shows that the CCRS using the ejector-cooling cycle as the bottom cycle of the RAC/MC is viable. Further improvement in COP is possible since the prototype is not designed and operated at an optimal condition.     

The impact of work input to sorption cyclesImpact de l'apport en énergie sur les cycles à sorption

In recent years the interest in cooling machines or heat pumps combining the principles of compression and sorption technology is increasing. The reason is that both technologies have specific drawbacks which can be overcome by the combination. Our discussion is centred around absorption cycles which use a compressor, and, consequently, an input of a significant amount of mechanical work in addition to heat. In most publications cycles of this kind are discussed in terms of one single COP as usual in the refrigeration industry. This, however, is wrong from a thermodynamic, and misleading from a technical and economical point of view. In order to highlight the need for a strict thermodynamic approach, a fundamental difference between distinct kinds of work input, namely “recoverable work”, “dissipative work” and “heat transformation work” is discussed in the first part of the paper. In the second part it is shown how the input of both work and heat into a energy conversion system has to be handled with both mechanical and thermal COP. The method is thermodynamically sound and straightforward, technically feasible and easy to apply, and most quickly transferred into economical terms. In the third part, a practical example of a compression–absorption hybrid is investigated.     

A general thermodynamic framework for understanding the behaviour of absorption chillersCadre thermodynamique facilitant la compréhension du comportement des refroidisseurs à absorption

In this article, a general definition of the process average temperature has been developed, and the impact of the various dissipative mechanisms on 1/COP of the chiller evaluated. The present component-by-component black box analysis removes the assumptions regarding the generator outlet temperature(s) and the component effective thermal conductances. Mass transfer resistance is also incorporated into the absorber analysis to arrive at a more realistic upper limit to the cooling capacity. Finally, the theoretical foundation for the absorption chiller T–s diagram is derived. This diagrammatic approach only requires the inlet and outlet conditions of the chiller components and can be employed as a practical tool for system analysis and comparison.     

Numerical optimisation of a two-stage ejector refrigeration plant

Jet-refrigeration cycles seem to provide an interesting solution to the increasing interest in environment protection and the need for energy saving due to their low plant costs, reliability and possibility to use water as operating fluid. A steam/steam ejector cycle refrigerator is investigated introducing a two-stage ejector with annular primary at the second stage. The steady_state refrigerator, exchanging heat with the water streams at inlet fixed temperatures at the three shell and tube heat exchangers, evaporator, condenser and generator, is considered as an open system. Heat transfer irreversibilities in the heat exchangers and external friction losses in the water streams are considered, ignoring the internal pressure drop of the vapor. A simulation program numerically searches the maximum COP at given external inlet fluid temperatures as a function of mass flows, dimensions and temperature differences in the heat exchangers. The code gives the ejector and heat exchangers design parameters.     

Empirical correlation for ejector designCorrélation empirique pour la conception des éjecteurs

In the present study, two empirical correlations from the test results of 15 ejectors are derived for the performance prediction of ejectors using R141b as the working fluid. The ratio of the hypothetical throat area of the entrained flow to the nozzle throat area A_e/A_t, the geometric design parameter of the ejector A₃/A_t, and the pressure ratios P_g/P_e and P_c*/P_e are used to correlate the performance of the ejector. The prediction of the entrainment ratio ω using the correlations is within ±10% error. A method of calculation for the ejector design using the correlations is also developed. R141b is shown in the present study to be a good working fluid for an ejector. The measured ω for the ejectors used in the present study can reach as high as 0.54 at P_g=0.465 MPa (84°C), P_c^*=0.087 MPa (28°C) and P_e=0.040 MPa (8°C). For P_g=0.538 MPa (90°C), P_c^*=0.101 MPa (32°C) and P_e=0.040 MPa (8°C), ω reaches 0.45.

Résumé

Dans cette étude, on a établi deux corrélations empiriques à partir des résultats expérimentaux obtenus utilisant 15 éjecteurs; ces corrélations ont été utilisées ensuite pour prédire la performance d'éjecteurs utilisant le R141b comme fluide frigorigène. Les rapports A_e/A_t (section de passage du fluide entraîné rapporté à la section théorique du col de l'éjecteur), et A₃/A_t (section de sortie de l'éjecteur rapporté à la section théorique du col de l'éjecteur) et les relations entre pressions P_g/P_e et P_c*/P_e sont utilisés pour trouver la corrélation de la performance de l'éjecteur. La prévision du taux d'entraînement à partir des corrélations est précise à la hauteur de ±10%. Les auteurs ont également développé une méthode de calcul permettant de concevoir des éjecteurs à partir des corrélations. On a montré dans cette étude que le R141b s'avère être un fluide actif efficace pour cette utilisation. Le ω mesuré des éjecteurs utilisés dans cette étude peuvent atteindre 0.54 à P_g=0.465 MPa (84°C), P_c^*=0.087 MPa (28°C) et P_e=0.040 MPa (8°C). Pour P_g=0.538 MPa (90°C), P_c^*=0.101 MPa (32°C) et P_e=0.040 MPa (8°C), ω atteint 0.45.     

A 1-D analysis of ejector performanceAnalyse unidimensionnelle de la performance d'un éjecteur

A 1-D analysis for the prediction of ejector performance at critical-mode operation is carried out in the present study. Constant-pressure mixing is assumed to occur inside the constant-area section of the ejector and the entrained flow at choking condition is analyzed. We also carried out an experiment using 11 ejectors and R141b as the working fluid to verify the analytical results. The test results are used to determine the coefficients, η_p, η_s, φ_p and φ_m defined in the 1-D model by matching the test data with the analytical results. It is shown that the1-D analysis using the empirical coefficients can accurately predict the performance of the ejectors.     

Simulation of ternary ammonia–water–salt absorption refrigeration cyclesSimulation des cycles frigorifiques à absorption à ammoniac / eau / sel

This paper proposes a new working fluid for refrigeration cycles utilizing low temperature heat sources. The proposed working fluid consists of the ammonia–water working fluid mixture and a salt. The salt is used to aid the removal of ammonia from the liquid solution. This effect is a manifestation of the well known “salting-out” effect. While the addition of salt improves the generator performance, it also has a detrimental effect on the absorber. The overall effects on the performance of three absorption cycles using the NH₃–H₂O–NaOH working fluid have been investigated using computer simulations. The results indicated that salting out can lower the generator operating temperature while simultaneously improving the cycle performance. Furthermore, limiting the salt to the generator suggests potential for further improvement in cycle performance.     

A theoretical study on a novel combined power and ejector refrigeration cycle

A new combined power and refrigeration cycle is proposed for the cogeneration, which combines the Rankine cycle and the ejector refrigeration cycle by adding an extraction turbine between heat recovery vapor generator (HRVG) and ejector. This combined cycle could produce both power output and refrigeration output simultaneously, and could be driven by the flue gas from gas turbine or engine, solar energy, geothermal energy and industrial waste heats. Parametric analysis and exergy analysis are conducted to examine the effects of thermodynamic parameters on the performance and exergy destruction in each component for the combined cycle. The results show that the condenser temperature, the evaporator temperature, the turbine inlet pressure, the turbine extraction pressure and extraction ratio have significant effects on the turbine power output, refrigeration output, exergy efficiency and exergy destruction in each component in the combined cycle. It is also shown that the biggest exergy destruction occurs in the heat recovery vapor generator, followed by the ejector and turbine.     

CFD analysis of ejector in a combined ejector cooling system

One-dimensional ejector analyses often use coefficients derived from experimental data for a set of operating conditions with limited functionality. In this study, several ejector designs were modelled using finite volume CFD techniques to resolve the flow dynamics in the ejectors. The CFD results were validated with available experimental data. Flow field analyses and predictions of ejector performance outside the experimental range were also carried out. During validation, data from CFD predicted the entrainment ratios with greater accuracy on definite area ratios, although no shock was recorded in the ejector. Predictions outside the experimental range—at operating conditions in a combined ejector–vapour compression system—and flow conditions resulting from ejector geometry variations are discussed. It is found that the maximum entrainment ratio happens in the ejector just before a shock occurs and that the position of the nozzle is an important ejector design parameter.     

A theoretical study of a novel regenerative ejector refrigeration cycle

There has been a demand for developments of the ejector refrigeration systems using low grade thermal energy, such as solar energy and waste heat. In this paper, a novel regenerative ejector refrigeration cycle was described, which uses an auxiliary jet pump and a conventional regenerator to enhance the performance of the novel cycle. The theoretical analysis on the performance characteristics was carried out for the novel cycle with the refrigerant R141b. Compared with the conventional cycle, the simulation results show that the coefficient of performance (COP) of the novel cycle increases, respectively, by from 9.3 to 12.1% when generating temperature is in a range of 80–160 °C, the condensing temperature is in a range of 35–45 °C and the evaporating temperature is fixed at 10 °C. Especially due to the enhanced regeneration with increasing the pump outlet pressure, the improvement of COP of the novel cycle is approached to 17.8% compared with that in the conventional cycle under the operating condition that generating temperature is 100 °C, condensing temperature is 40 °C and evaporating temperature is 10 °C. Therefore, the characteristics of the novel cycle performance show its promise in using low grade thermal energy for the ejector refrigeration system.     

Development of a slug flow absorber working with ammonia-water mixture: part I—flow characterization and experimental investigation

This study deals with an experimental investigation for a counter-current slug flow absorber, working with ammonia–water mixture, for significantly low solution flow rate conditions that are required for operating as the GAX (generator absorber heat exchanger) cycle. It is confirmed that the slug flow absorber operates well at the low solution flow rate conditions. From visualization results of the flow pattern, frost flow just after the gas inlet, followed by slug flow with well-shaped Taylor bubble, is observed, while dry patch on the tube wall are not observed. The liquid film at the slug flow region has smooth gas–liquid interface structure without apparent wavy motion. The local heat transfer rate is measured by varying main parameters, namely, ammonia gas flow rate, solution flow rate, ammonia concentration of inlet solution and coolant inlet conditions. The heat transfer rate while absorption is taking place is higher than that after absorption has ended. The absorption length is greatly influenced by varying main parameters, due to flow conditions and thermal conditions.     

Distillation column configurations in ammonia–water absorption refrigeration systems

In ammonia–water absorption refrigeration systems a purification process to reduce the water content in the vapour leaving the generator is required. During this process the water content in the vapour must be reduced to a minimum, otherwise it tends to accumulate in the evaporator and strongly deteriorates the efficiency of the system. The vapour purification can be carried out by partial condensation, by establishing a liquid–vapour counter flow or by combining both methods. In systems with partial condensation, the distillation column can be composed of one or more rectifiers using different cooling mediums, and the rectifying and stripping sections. In complete condensation systems only the rectifying and stripping sections can be used. Therefore different distillation column arrangements should be considered. This paper presents a study of several distillation column configurations for single stage ammonia–water absorption refrigeration systems with partial and complete condensation. In order to evaluate and compare the different configurations, a parameter that indicates the ratio of the ammonia vapour concentration increase in each part of the column to the total ammonia purification has been defined. The analysis has been based on the system COP. Finally the efficiency in each part of the column has been calculated to estimate its design requirements.     

A phenomenological theory of polycomponent interactions in non-ideal mixtures. Application to NH3/H2O and other working pairsInteractions entre les composants de mélanges non-idéaux : théorie et application au fluide actif NH3 / H2O et à d'autres fluides actifs

The paper proposes an original linear phenomenological theory (Ph T) of evolution physical mono-, bi- and particular polycomponent gas–liquid interactions with non-ideal mixture. The expressions of the phenomenological factors (entropy source, force, coefficient and coupled heat and mass transfer currents) are deduced. The theory is particularized to the NH₃/H₂O and other gas–liquid systems used in the thermal absorption technology. The work's conclusions are listed next. The paper raises the problem of ammonia bubble absorption which is difficult to answer with current theory of interface mass transfer and absorption as a surface phenomenon. The heat and mass transfer at the gas–liquid interface is governed by the thermodynamic force, which applies also to solid–liquid, solid–gas, or liquid–liquid, gas–gas type interactions and continuous or discontinuous media. The paper mentions a postulate referring to the force behavior approaching an ideal point, previously formulated by the author. According to its consequence, the mass and heat currents suffer an ideal point approaching (i.p.a.) effect, not mentioned so far in the specialized literature, consisting in a continuous increase of their absolute value by several percent (for a pure component), to several hundred times (for a binary system) when the interacting system approaches an ideal state, as compared to the values of states which are far from the same ideal point. In this way, “far from equilibrium” becomes synonymous to “low interaction”. The classic assessment of the interface mass transfer by analogy with heat transfer lacks basic physics. The (Ph T) satisfactorily explains the problem of ammonia bubble absorption. Absorption is a mass phenomenon, not a surface one. An intensive way of improving absorption is emphasized, which seeks to promote the i.p.a. effect appearance rather than the extensive way currently used, based on increasing gas–liquid interaction area. To this extent, the bubble absorber is hereby proposed for efficient absorption. The i.p.a. effect existence offers an additional chance for a satisfactory explanation of the Marangoni effect.     

Performance of compression/absorption hybrid refrigeration cycle with propane/mineral oil combination

This paper discusses the feasibility of a vapor compression/absorption hybrid refrigeration cycle for energy saving and utilization of waste heat. The cycle employs propane as a natural refrigerant and a refrigeration oil as an absorbent. A prototype of the cycle is constructed, in which a compressor and an absorption unit are combined in series. The performance of the cycle is examined both theoretically and experimentally. Although the solubility of the propane with the oil is not enough as a working pair in the absorption unit, the theoretical calculation shows that the hybrid cycle has a potential to achieve a higher performance in comparison with a simple vapor compression cycle by using the waste heat. In the experiment, the prototype cycle is operated successfully and it is found that an improvement of an absorber is necessary to achieve the good performance close to the theoretical one. The application of an AHE (absorber heat exchanger) can reduce the heat input to a generator. Further examinations on some other combinations of refrigerant/refrigeration oil and additives are desirable.     

The thermodynamic performance of a new solution cycle in double absorption heat transformer using water/lithium bromide as the working fluids

In this paper, a new solution cycle in the double absorption heat transformer is presented and the thermodynamic performance of this new cycle is simulated based on the thermodynamic properties of aqueous solution of lithium bromide. The results show that this new cycle is superior to the cycle being studied by some researchers. This new solution cycle has a wider range of operation in which the system maintains the high value of COP and has larger temperature lifts and operation stability. The relationship between the absorber and the absorbing evaporator is more independent and this makes the operation and control of the system more easier.     

Application of an ejector in autocascade refrigeration cycle for the performance improvement

This paper presented a novel autocascade refrigeration cycle (NARC) with an ejector. In the NARC, the ejector is used to recover some available work to increase the compressor suction pressure. The NARC enables the compressor to operate at lower pressure ratio, which in turn improves the cycle performance. Theoretical computation model based on the constant pressure-mixing model for the ejector is used to perform a thermodynamic cycle analysis for the NARC with the refrigerant mixture of R23/R134a. The effects of some main parameters on cycle performance were investigated. The results show the NARC has an outstanding merit in decreasing the pressure ratio of compressor as well as increasing the COP. For NARC operated at the condenser outlet temperature of 40 °C, the evaporator inlet temperature of −40.3 °C, and the mass fraction of R23 is 0.15, the pressure ratio of the ejector reaches to 1.35, the pressure ratio of compressor is reduced by 25.8% and the COP is improved by 19.1% over the conventional autocascade refrigeration cycle.     

Maximum mass flow ratio due to secondary flow choking in an ejector refrigeration system

The occurrence of flow choking in an ejector of an ejector refrigeration system (ERS) was analysed and a model for predicting the maximum flow ratio of the ejector was developed. The multi-parameter equation to calculate the mass flow ratio takes into account the performance of the primary nozzle, the flow entrainment and mixing relating to ejector geometry and operating conditions. We validated the model using the reported experimental data of refrigerant R113, R141b and steam ERS. The present model was shown to provide better accuracy compared with results obtained by applying the existing 1-D ejector theory. We discussed the application of the model and highlighted the significance of the parameters for future work.     

Carnot-COP for sorption heat pumps working between four temperature levels

The theoretical efficiency limits of heat driven heat pumps operating between three and four temperatures are derived from the fundamental thermodynamical laws, i.e. the energy balance and the entropy balance. While in the three temperatures case the system is fully determined by specification of the three temperatures and the cooling capacity, a four temperature heat pump needs, in addition to the four temperatures and the cooling capacity, specification of an additional operating parameter. This can be, for example, the ratio of the two heat flows which are released at the two different intermediate temperatures. Various assumptions regarding this proportion are discussed with respect to their relevance for both the combination power cycle/vapor compression cycle as well as for single-effect sorption cycles. The present analysis shows that a single-effect sorption heat pump is principally not able to operate reversibly in an environment of four externally specified temperatures unless the four temperatures follow, incidentally, a correlation that is given by the equilibrium properties of the employed working fluids. Therefore, in endo-reversible models for four-temperature sorption cycles only three rather than four operating temperatures may be specified independently.     

Supersonic two-phase flow of CO2 through converging–diverging nozzles for the ejector refrigeration cycle

CO₂ is environmentally friendly, safe and more suitable to ejector refrigeration cycle than to vapor compression cycle. Supersonic two-phase flow of CO₂ in the diverging sections of rectangular converging–diverging nozzles was investigated. The divergence angles with significant variation of decompression were 0.076°, 0.153°, 0.306° and 0.612°. This paper presents experimental decompression phenomena which can be used in designing nozzles and an assessment of Isentropic Homogeneous Equilibrium (IHE). Inlet conditions around 6–9 MPa, 20–37 °C were used to resemble ejector nozzles of coolers and heat pumps. For inlet temperature around 37 °C, throat decompression boiling from the saturated liquid line, supersonic decompression and IHE solution were obtained for the two large divergence angles. For divergence angles larger than 0.306°, decompression curves for inlet temperature above 35 °C approached IHE curves. For divergence angles smaller than 0.306° or for nozzles with inlet temperature below 35 °C, IHE had no solution.