Paramagnetic resonance in a “dirty” spin-glass

For a spin-glass with nonmagnetic defects (n _m ^1/3l 1, where n _m is the magnetic impurity concentration and l is the mean free path) an absorption function () is derived. Three ranges of temperature and external magnetic field are considered. In the vicinity of the transition the value of () d is estimated as a function of temperature and field.     

Analysis of the effect of the decomposition of char-forming heat-insulating materials on the free discharge of a gas mixture

The article presents results of a numerical solution of a nonsteady problem on the free discharge of a mixture of gases from a hemispherical volume with allowance for thermal decomposition of heat-insulating materials.Notation V volume - S area - t - P p - T - u v - Q q, dimensional and dimensionless time, pressure, temperature, TIM decomposition rate, and heat flux - adiabatic exponent - R gas constant - density - H specific enthalpy - c specific heat - thermal conductivity - , , _s dimensionless complexes - coefficient expressing the radiative properties of the gas medium and the heat-transfer surface - Stefan-Boltzmann constant Indices 0 initial state and scale factors - s surface - coke - M TIM material - P pyrolysis front - A ablation front - v volatile degradation products - adiabatic conditions - c completion of discharge Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 54, No. 5, pp. 787–793, May, 1988.     

A finite volume technique to simulate the flow of a viscoelastic fluid

Hydrodynamically developing flow of Oldroyd B fluid in the planar die entrance region has been investigated numerically using SIMPLER algorithm in a non-uniform staggered grid system. It has been shown that for constant values of the Reynolds number, the entrance length increases as the Weissenberg number increases. For small Reynolds number flows the center line velocity distribution exhibit overshoot near the inlet, which seems to be related to the occurrence of numerical breakdown at small values of the limiting Weissenberg number than those for large Reynolds number flows. The distributions of the first normal stress difference display clearly the development of the flow characteristics from extensional flow to shear flow.List of symbols D rate of strain tensor - L slit halfheight - P pressure, indeterminate part of the Cauchy stress tensor - R the Reynolds number - t time - U average velocity in the slit - u velocity vector - u,v velocity components - W the Weissenberg number based on the difference between stress relaxation time and retardation time - W ₁ the Weissenberg number based on stress relaxation time - x,y rectangular Cartesian coordinates - ratio of retardation time to stress relaxation time - zero-shear-rate viscosity, ₁ + ₂ - ₁ non-Newtonian contribution to - ₂ Newtonian contribution to - ₁ stress relaxation time - ₂ retardation time - density - (, , ) xx, yy and xy components of ₁, respectively - determinate part of the Cauchy stress tensor - ₁ non-Newtonian contribution to - ₂ Newtonian contribution to      

1 : 2 Long-range ordering and defect mechanism of WO3-doped perovskite Ba(Mg1/3Ta2/3)O3

The nature of the B-site cation ordering and the associated defect process necessary to stabilize the ordered domains were investigated using the WO₃-doped BaMg_1/3Ta_2/3O₃ BMT system as a typical example of BaB_1/3B_2/3O₃-type complex perovskites. It was shown that only the 1 : 2 long-range ordering of the B-site cation existed in both undoped and WO₃-doped BMT perovskites. The atomic defect mechanism associated with the stoichiometric 1 : 2 long-range ordering was systematically investigated. It is concluded that the substitution of W⁶⁺ for Ta⁵⁺ in the WO₃-doped BMT enhances the degree of the 1 : 2 long-range ordering and produces the positively charged W _Ta sites with a concomitant generation of tantalum vacancies V_Ta and mobile oxygen vacancies V _O for the ionic charge compensation.     

Dislocation structures in Zr3Al-based alloys

Transmission electron microscopy has been used to investigate dislocation structures in deformed binary and ternary Zr₃Al-based alloys. In the binary alloy deformed at temperatures between 293 and 673 K the dislocations in the Zr₃Al phase consisted of a/31 1 2-type partial dislocations bounding superlattice intrinsic stacking fault on {1 1 1} planes. The {111} a/31 1 ¯2 stacking fault energy was approximately 2mJ m^–2 at 673 K. In binary specimens deformed between 873 and 1073 K cube slip predominated. Dislocations consisted mainly of a/2 1 1 0 pairs separated by antiphase boundary. For this temperature range the {1 0 0} a/201 1 antiphase boundary energy was between 30 and 45 mJ m^–2. Alloying with niobium or titanium was found to increase the {111} a/31 1¯2 stacking fault energy and thus increase the propensity for antiphase boundary-type dissociation.     

Effect of the elastic factor on the hydrodynamic stability of a structurally viscous medium

The effect of relaxation phenomena on the hydrodynamic stability of the plane gradient flow of a structurally viscous medium is investigated using linear theory.Notation _ij stress tensor deviator - U_i components of the velocity vector - x_i coordinates - t time - P pressure - =₀L/^*V plasticity parameter - _o limiting shear stress - andc dimensionless wave number and the perturbation frequency - Re=VL/* Reynolds number - density - F_ij deformation rate tensor Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 35, No. 5, pp. 868–871, November, 1978.     

Asymptotic expansions for constant-composition dew-bubble curves near the critical locus

Explicit functional representations are developed for constant-composition dew and bubble curves near critical according to the modified Leung-Griffiths theory. The pressure and temperature incrementsP=P–P _c andT= T–T _c, where c denotes critical, are linearly transformed to new variablesP andT. In the transformed space, the coexistence curves are no longer double-valued and can be expressed as a nonanalytic expansion, where the coefficients are functions of the critical properties and their derivatives. A similar asymptotic expansion is developed forT in terms of the density increment=– _c. In the approximation that the critical exponents=0 and=1/3, the critical point in temperature-density space is shown to be a point of maximum concave upward curvature, rather than an inflection point as previously conjectured.Paper presented at the Tenth Symposium on Thermophysical Properties, June 20–23, 1988, Gaithersburg, Maryland, U.S.A.Formerly National Bureau of Standards     

Thermal transport properties in the normal phase of dilute3He-4He mixtures

We present steady-state measurements of the thermal diffusion ratiok _T and of the heat conductivity for three dilute mixtures of³He in⁴He with concentrations 9×10^–3X(³He)5×10^–2 at saturated vapor pressure in the normal phase close to the superfluid transition. The data are compared with predictions by Dohm and Folk from the renormalization group (RG) theory. From auxiliary determinations of thermodynamic derivatives for these mixtures, we obtain the separation factor =–(k _T /T)×(/X) _T,P /(/T) _X,P above T over the range wherek _T is positive. Here is the mass density. From the transients of X(t) as a function of time, we obtain an estimation for the mass diffusion coefficientD and compare the results with predictions by Dohm and Folk and with results from other experiments.     

Morphological and crystallographic features of γ-γ′ Ni-Al and Ni-Al-Ti two-phase bicrystals

Several- Ni-Al and Ni-Al-Ti two-phase bicrystals were made by the solid-state diffusion couple method. Each couple consisted of a-phase single crystal and a pure-Ni polycrystal, and was annealed at 1473 K in an Ar gas atmosphere. Single crystal layers of-phase with uniform thickness always grow into the parent-phase single crystals. The resultant/ interface has no voids or facets regardless of the orientation of interface and the chemical composition of the-phase. Porosity formation due to the Kirkendall effect is observed in the diffused region. Concentration profiles exhibit nearly constant gradients in-phase. The orientation relationship between both phases is found to be 001//001, that is, the-phase grows epitaxially along the crystal orientation of-phase.     

Mixed convection flow of micropolar fluid over an isothermal plate with variable spin gradient viscosity

Summary A steady two-dimensional mixed convection flow of viscous incompressible micropolar fluid past an isothermal horizotal heated plate with uniform free stream and variable spin-gradient viscosity is considered. With appropriate transformations the boundary layer equations are transformed into nonsimilar equations appropriate for three distinct regimes, namely, the forced convection regime, the free convection regime and the mixed convection regime. Solutions of the governing equations for these regimes are obtained by an implicit finite difference scheme developed for the present problem. Results are obtained for the pertinent parameters, such as the buoyancy parameter, in the range of 0 to 10 and the vortex viscosity parameters, =0.0, 1.0, 3.0, 5.0 and 10.0 for fluid with Prandtl number Pr=0.7 and are presented in terms of local shear-stress and the local rate of heat transfer. Effects of these parameters are also shown graphically on the velocity, temperature and the couple stress distributions. From the present analysis, it is observed that both the momentum boundary layer and the thermal boundary layer increase due to an increase in the vortex viscosity of the fluid.List of symbols f, F, dimensionless stream function for forced convection free convection and mixed convection, respectively - g acceleration due to gravity - Gr_x local Grashof number - j micro-inertia density - m ₂₃ distribution of couple stress - N microrotation component normal to (x, y)-plane - p pressure of the fluid - q dimensionless rate of heat transfer - Re_x local Reynolds number - T temperature of the fluid in the boundary layer - T temperature of the ambient fluid - T temperature at the surface - u, v thex andy-components of the velocity field - U free stream velocity - x, y axis in direction along and normal to the plate Greek thermal diffusivity - coefficient of volume expansion - vortex viscosity parameter - stream function - , , nondimensional similarity variables - buoyancy parameter (=Gr _x Re _x ^/5/2 ) - vortex viscosity - density of the fluid - v kinematic coefficient of viscosity - spin-gradient viscosity - stream function - dimensionless skin-friction - fluid viscosity     

Temperature coefficients of capacitance of solids

An earlier treatment of temperature coefficient of capacitance, _c [1] has been extended to include most solids. Materials are divided into those with given ranges of permittivity, , and temperature coefficient of polarisability. It appears that, for low dielectric loss, high permittivity glasses, like simple ionic compounds, always have a positive _c, whereas paraelectrics and polymers have negative _c. Ferroelectrics can have any value of _c. Limitations in _c and for given classes of solid are discussed.     

The thermal conductivity of AISI 304L stainless steel

A compilation and critical analysis of the thermal conductivity () of AISI 304 stainless steel (SS) between 100 and 1707 K has been given in the literature. The author represented his recommended values of by an inflection in the A versus temperature relationship between 300 and 500 K. Because a physical mechanism had not been identified that would produce such a temperature dependence in of 304 SS, interest was generated in the possible existence of an as yet undiscovered phenomenon that might cause such an inflection. Consequently, experimental verification of the inflection was sought. The present paper presents recent measurements of , the electrical resistivity, and the absolute Seebeck coefficient of 304L SS from 300 to 1000 K and of the thermal diffusivity () from 297 to 423 K. The values computed from the a measurements were within ± 1.6% of the directly measured An inflection was not observed in the temperature dependence of between 300 and 500 K. After careful evaluation and because a physical mechanism still has not been identified which would produce such an inflection, the authors conclude that the inflection in the vs T relationship reported in the literature was caused by the data analysis technique.     

Hydrodynamic reaction to accelerated onedimensional motion of gas bubbles of variable volume in an unbounded liquid

A solution is given for the problem of the hydrodynamic reaction of an ellipsoidal gas bubble of variable volume to accelerated motion and the relation between the value of the apparent mass and the eccentricity of the bubble.Notation (,) velocity potential - V velocity of motion of the bubble with respect to the liquid - (, ) velocity potential of the near field - T₂ kinetic energy of the liquid due to the variation in bubble volume - F_r reaction force of the liquid - B₁ momentum of the liquid - _e apparent mass of the ellipsoid - density of the liquid - V_e volume of the ellipsoidal bubble Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 1, pp. 47–50, July, 1980.     

The Interplay of Electronic and Nuclear Magnetism in PtFe x at Milli-, Micro-, and Nanokelvin Temperatures

We have measured ac susceptibility, nuclear magnetic resonance, and nuclear heat capacity of two PtFe _x samples with concentrations of magnetic impurities x = 11 ppm and 41 ppm at magnetic fields (0 ± 0.05) mTB248 mT. The susceptibility data have been measured at temperatures of 0.3 KT100 mK, no hint for nuclear magnetic ordering could be detected to a temperature of 0.3 K. The nuclear heat capacity data taken at 1.4 KT10 mK show enhanced values which scale with x at low polarization. This effect is described by a model assuming an internal magnetic field caused by the impurities. No indication for nuclear magnetic ordering could be detected to 1.4 K. The nuclear magnetic resonance experiments have been performed on these samples at 0.8 KT0.5 mK and 2.5 mTB22.8 mT as well as on three other samples with x = 5, 10, 31 ppm in a different setup at 40 KT0.5 mK and at 5.4 mTB200 mT. Spin-lattice and effective spin-spin relaxation times ₁and ₂ ^* of ¹⁹⁵ Pt strongly depend on x and on the external magnetic field. No temperature dependence of ₁and ₂ ^* could be detected and the NMR data, too, give no hint for nuclear magnetic ordering to 0.8 K.     

Microstructure and mechanical properties of rapidly quenched L20 and L20+L12 alloys in Ni-Al-Fe and Ni-Al-Co systems

Ductile L2₀-type wires and+L1₂-type duplex wires with high strengths and large elongation in the Ni-Al-Fe and Ni-Al-Co ternary systems have been manufactured directly from the liquid state by an in-rotating-water spinning method. The wire diameter was in the range 80 to 180m and the average grain size was 2 to 4m for the wires and 0.2 to 1.0m for the+ wires. _y, _f and _p of the wires were found to be about 360 to 760 MPa, 560 to 960 MPa, and 0.2 to 5.5%, respectively, for the Ni-Al-Fe system, those of the+ wires were about 395 to 660 MPa, 670 to 1285 MPa, and 3.5 to 17%, respectively, for the Ni-Al-Fe system, and about 260 to 365 MPa, 600 to 870 MPa, and 4.0 to 7.0%, respectively, for the Ni-Al-Co system. Cold-drawing caused a significant increase in _y and _f and the values attained were about 1850 and 2500 MPa, respectively, for Ni-20Al-30Fe and Ni-25Al-30Co wires drawn to about 90% reduction in area. The high strengths, large elongation and good cold-workability of the melt-quenched and+ compound wires have been inferred to be due to the structural change into a low-degree ordered state containing a high density of phase boundaries, suppression of grain-boundary segregation and refinement of grain size.     

Ultrasonic study of the elastic and nonlinear acoustic properties of ceramic aluminum nitride

Pulse-echo-overlap measurements of ultrasonic wave velocity have been used to determine the elastic stiffness moduli and related elastic properties of aluminum nitride (AlN) ceramic samples as functions of temperature in the range 100–295 K and hydrostatic pressure up to 0.2 GPa at room temperature. Aluminum nitride is an elastically stiff but light ceramic: at 295 K, the longitudinal stiffness (C _L), shear stiffness (), adiabatic bulk modulus (B ^S), Young's modulus (E) and Poisson's ratio () are 373 GPa, 130 GPa, 200 GPa, 320 GPa and 0.234, respectively. The temperature dependences of C _L and B ^S show normal behaviour and can be approximated by the conventional model for vibrational anharmonicity. The results of measurements of the effects of hydrostatic pressure on the ultrasonic wave velocity have been used to determine the hydrostatic-pressure derivatives of elastic stiffnesses and the acoustic-mode Grüneisen parameters. The values determined at 295 K for the hydrostatic-pressure derivatives (C _L/P) _P=0, (/P) _P=0 and (B ^S/P) _P=0 are 4.7 ± 0.1, 0.22 ± 0.03 and 4.4 ± 0.15, respectively. The adiabatic bulk modulus B ^S and its hydrostatic-pressure derivative (B ^S/P) _P=0 are in good agreement with the results of recent high pressure X-ray diffraction measurements and theoretical calculations. The longitudinal (_L), shear (_S), and mean (^el) acoustic-mode Grüneisen parameters of AlN are positive: the zone-centre acoustic phonons stiffen under pressure. The shear _S (=0.006) is much smaller than the longitudinal _L (=1.09) accounting for the low thermal Gr¨neisen parameter ^th (=0.65) obtained for this ceramic: since the acoustic Debye temperature _D (=980 ± 5 K) is so high, the shear modes play an important role in acoustic phonon population at room temperature. Hence knowledge of the elastic and nonlinear acoustic properties sheds light on the thermal properties of ceramic AlN.     

First principles study of effect of lattice misfit on the bonding strength of Ni/Ni3Al interface

By using a discrete variational X (DV-X) method, the electronic structures and bonding strengths of Ni/Ni₃Al (or /) interface with different lattice misfits () were calculated in the framework of the nonrelativistic first-principles theory. In order to describe the effect of on the interfacial binding strength and the structural stability of coherent / interface, we calculated the interfacial binding covalent bond density (CBD) and the local environmental total bond overlap population (LTBOP). Very obvious effects of lattice misfits on the electronic structures of coherent / interface were found. On one hand, less than –0.6% negative lattice misfit can increase the binding strength of the /' interface. On the other hand, the local environmental total bonding strength of the /' interface decreases with increasing magnitude of . Therefore, the magnitude and sign of lattice misfit must be carefully controlled to balance the high-temperature creep strength of Ni-base single crystal superalloy and the structural stability of the /' interface when one designs new alloys.     

Structural Changes in the Surface Layers of PdHx Alloys Caused by the Hydride Phase Decomposition

By the method of optical microscopy, we perform the in-situ investigation of the plane polished surfaces of PdH _x alloys (with video recording of the processes of transformation) in the case of their rapid cooling at a rate of 11–20°C·sec^–1 from T _c = 292°C ( = 1.97MPa) with simultaneous lowering of the pressure of hydrogen within the temperature range 100–160°C. In the course of decomposition of the PdH_0.24 alloy according to a scheme ₀ + , the formation of nuclei of the - and -phases and their growth were not detected. However, we observe a simultaneous coherent transformation of the entire surface accompanied by the formation of a surface topography similar to the modulated structures formed as a result of the spinodal decomposition. We discuss the possibility of realization of spinodal decomposition under the described experimental conditions.     

The Ni3Al-Ni3Cr-Ni3Ru section of the Ni-Cr-Al-Ru system

An investigation is reported of the 75 at% nickel section of the Ni-Cr-Al-Ru system at 1523 and 1273 K. Constitutional data obtained by electron probe microanalysis, X-ray diffraction and microscopical examination are presented as partial isothermal sections. At 1523 K, the major part of the section consists of phase, while the aluminium-rich region contains a and+ region; the extent of the solid solution of chromium and ruthenium in totals ~ 4 at%. The ruthenium-rich corner of the section shows a two-phase region consisting of + ruthenium-rich solid solution. At 1273 K the,+ and + ruthenium regions increase in extent. The/ mismatch values in the equilibrated alloys studied lie in the range ~ –0.08 to –0.39%. Constitutional features of as-cast alloys are also reported.     

Self-Charging of Quench Condensed Tritium Films

Self-charging of a solid tritium film (T₂) has been discovered by chance in a precision spectroscopy experiment on tritium decay as a shift of the endpoint energy by several eV. The effect was then investigated systematically as a function of film thickness and time by measuring the energy shift of monochromatic conversion electrons from ^{83 m} Kr evaporated onto T₂ films. The steady state is characterized by a practically constant, critical electric field strength E _c 62 MV/m (20 mV/monolayer) over the film, at which the residual positive charges attain sufficient mobility to penetrate the film towards the conducting substrate. This kind of breakthrough behaviour is analyzed in terms of a thermal hopping model, where a trapping potential of ₀175 k _BK is lowered in direction of the electric force by a factor of 3 in order to facilitate hopping at a film temperature of about 1.9 K.