Hydrogeochemistry and geothermometry of Changal thermal springs,Zagros region,Iran

This study addresses the hydrogeochemistry of thermal springs that emerge from the Asmari limestone in a gorge at Changal Anticline in the vicinity of the Salman-Farsi dam. The Changal thermal springs vary in temperature between 28 and 40 °C. Chemical and isotopic compositions of the thermal waters suggest two distinct hydrogeological systems: a deep, moderate-temperature (∼40 °C) geothermal system recharged by deeply circulating meteoric waters, and a shallow cold aquifer system related to local groundwater. The source geothermal fluid temperature was calculated using different geothermometers and mineral saturation indexes. Based on chemical and isotopic data, it is hypothesized that: (1) mixing occurs between the ascending geothermal water and shallow cold water; (2) the resulting thermal waters reaching surface are a mixture of 80% local, shallow meteoric water and 20% geothermal water; and (3) the circulation depth of the meteoric water is about 1500 m. The thermal reservoir temperature is estimated to be between 70 and 80 °C according to calculations using different geothermometers and computation of saturation indices for different solid phases.     

A helium isotope perspective on the Dixie Valley,Nevada, hydrothermal system

Fluids from springs, fumaroles, and wells throughout Dixie Valley, NV were analyzed for noble gas abundances and isotopic compositions. The helium isotopic compositions of fluids produced from the Dixie Valley geothermal field range from 0.70 to 0.76 Ra, are among the highest values in the valley, and indicate that ∼7.5% of the total helium is derived from the mantle. A lack of recent volcanics or other potential sources requires flow of mantle-derived helium up along the valley bounding Stillwater Range Front Fault, from which the geothermal fluids are produced. Using a one-dimensional flow model, a lower limit fluid flow rate up through the fault of 7 mm/yr is estimated, corresponding to a mantle ³He flux of ∼10⁴ atoms m⁻² s⁻¹.A comparison between the fluids from Dixie Valley springs, fumaroles, and wells and the fluids produced from the geothermal field reveals a mixing trend between the geothermal fluid and younger, cooler groundwaters. The exceptions are those features that either emanate directly from the Stillwater fault or wells that penetrate and extract fluids from the fault zone, all of which have helium isotopic compositions that are indistinguishable from the geothermal production fluids. The results of our study indicate that the Stillwater Range Front Fault system must act as a permeable conduit that can sustain high vertical fluid flow rates from deep within the crust and crust-mantle boundary and that high permeability may exist along most of its length. This suggests that the geothermal potential of the Stillwater fault may be significantly greater than the 6–8 km long system presently under production. Since all the numerous springs, wells, and fumaroles in the valley also contain a fluid component that is indistinguishable from the geothermal/Stillwater fault fluid, the potential for an additional deeper and more pervasive geothermal system also exists and should be further evaluated. Furthermore, we suggest that elevated helium isotope compositions in regions with little or no recent magmatism are an indicator of the deep crustal permeability that is required to drive and sustain extensional geothermal systems.     

Geology of the tengchong geothermal field and surrounding area, West Yunnan, China

This paper describes the regional tectonics, active structures and thermal springs of the Tengchong geothermal field and surrounding area. Regional tectonic evidence shows that Tengchong and the surrounding area was a microcontinent between the Gondwanaland and Eurasian plates. The distribution of the thermal springs is controlled by active faults in the “arched” and circular structures. The majority of the thermal areas have a deep circulation within the fault system. Only a few high-temperature hydrothermal systems issuing sodium chloride may be heated by a local magmatic source.     

Geochemistry of thermal waters on the island of Ischia (Campania, Italy)

The stratigraphic and structural situation on the island of Ischia (southern Italy), the recent volcanic activity and the presence of hot springs and fumaroles, suggest the existence of a geothermal field. The chemical and isotopic compositions of the waters from several springs and wells were examined to obtain information on deep temperatures and to formulate a geothermal model of the island. δD values range from −33.60 to −12.50‰ and δ¹⁸O from −7.10 to −1.71‰, relative to SMOW. These variations have mainly been attributed to the presence of seawater, as confirmed by the general shift to more positive values with the increase of Cl content. Water-rock reactions, evaporation and subsurface boiling also contribute to the δ¹⁸O−δD trend. The chemical analyses reveal the presence of alkaline sulphate chloride water (seawater), bicarbonate waters and waters interpreted as the result of mixing. The chemical and isotopic composition of the latter are dependent on water-rock interactions, water circulation rates and eventual evaporation and condensation phenomena. The silica geothermometer, which seems to be the most suitable for determining the deep temperatures of these waters, gave values of about 200°C, even for mixing models. Our data suggest the following geothermal model: the heat flow heats up a deep reservoir, causing steam to rise through faults and fractures and transfer heat to a shallower aquifer. The temperatures of 200°C obtained by the geothermometers are not the maximum reservoir temperatures, but are probably water-rock equilibrium temperatures for the shallower aquifers. The high boron contents and the isotopic data confirm the presence of steam in the system.     

Geochemical study of fluids on Lesbos island, Greece

Sixty-five water samples and seven associated gas samples have been collected on Lesbos island. The lithology and structural setting have resulted in two main types of hydrological circulation: a shallow circulation hosting low-salinity cold waters and a deeper one, hosting high-salinity hot waters that often emerge in thermal springs near the coast. The cold waters are characterized by Ca(Mg)-HCO₃(SO₄) composition, while the thermal waters generally have an Na-Cl composition. The chemical features of the former can be explained by their circulation in the ophiolite-bearing phyllitic basement and volcanic rocks. Waters circulating in the ultramafic layers of the basement are richer in Mg than the waters whose circulation is mainly within marble levels or volcanic rocks. The Na-Cl thermal waters are characterized by salinities ranging from 1910 to 35,700 mg/kg. As indicated by previous hydrogeochemical and isotopic studies, the Na-Cl composition of the thermal waters on Lesbos is the result of mixing between shallow meteoric waters and marine waters. While interacting with the minerals of the geothermal reservoir, the saline waters retain the Na/Cl sea water ratio but become enriched in Ca²⁺ and depleted in Mg²⁺ with respect to sea water.Processes of hydrothermal alteration at depth are activated by a gas phase enriched in CO₂, which reaches the geothermal reservoir by rising along the deep fractures of the basement. Thermodynamic calculations based on hydrothermal alteration processes occurring at the estimated temperatures of the geothermal reservoir (about 120 °C) indicate that the thermal waters of Lesbos are in equilibrium with talc and dolomite.     

Hydrogeochemical exploration of geothermal prospects in the Tecuamburro Volcano region, Guatemala

Chemical and isotopic analyses of thermal and nonthermal waters and of gases from springs and fumaroles are used to evaluate the geothermal potential of the Tecuamburro Volcano region, Guatemala. Chemically distinct geothermal surface manifestations generally occur in separate hydrogeologic areas within this 400 km² region: low-pressure fumaroles with temperatures near local boiling occur at 1470 m elevation in a sulfur mine near the summit of Tecuamburro Volcano; non-boiling acid-sulfate hot springs and mud pots are restricted to the Laguna Ixpaco area, about 5 km NNW of the sulfur mine and 350–400 m lower in elevation; steam-heated and thermal-meteoric waters are found on the flanks of Tecuamburro Volcano and several kilometers to the north in the andesitic highland, where the Infernitos fumarole (97°C at 1180 m) is the primary feature; neutral-chloride hot springs discharge along Rio Los Esclavos, principally near Colmenares at 490 m elevation, about 8–10 km SE of Infernitos. Maximum geothermometer temperatures calculated from Colmenares neutral-chloride spring compositions are 180°C, whereas maximum subsurface temperatures based on Laguna Ixpaco gas compositions are 310°C. An exploration core hole drilled to a depth of 808 m about 0.3 km south of Laguna Ixpaco had a bottom-hole temperature of 238°C but did not produce sufficient fluids to confirm or chemically characterize a geothermal reservoir. Hydrogeochemical data combined with regional geologic interpretations indicate that there are probably two hydrothermal-convection systems, which are separated by a major NW-trending structural boundary, the Ixpaco fault. One system with reservoir temperatures near 300°C lies beneath Tecuamburro Volcano and consists of a large vapor zone that feeds steam to the Laguna Ixpaco area, with underlying hot water that flows laterally to feed a small group of warm, chloriderich springs SE of Tecuamburro Volcano. The other system is located beneath the Infernitos area in the andesitic highland and consists of a lower-temperature (150–190°C) reservoir with a large natural discharge that feeds the Colmenares hot springs.     

Oxygen and hydrogen isotopes in deep thermal waters from the south meager creek geothermal area, british columbia, canada

Deuterium and oxygen-18 (¹⁸O) have been measured in deep thermal, shallow thermal and non-thermal water samples collected at various times between 1982 and 1989 from the Meager Creek area, with the aim of assessing the origin of the thermal waters. The isotopic composition of the reservoir waters (δ¹⁸O = −13‰ and δD = −114.8‰) was calculated from data on post-flash deep thermal waters, using a two-stage steam loss model. The reservoir composition shows an oxygen shift of 2.4‰ relative to the local meteoric water line. The composition of the recharge, obtained by removing the oxygen shift, is isotopically heavier than the average local meteoric waters, suggesting that the recharge may be from an area to the west of Mt Meager where isotopically heavier ground-waters are likely to be found. The small δ¹⁸O shift of the deep high-temperature waters is indicative of dominance of fracture-related permeability in the reservoir. Analysis of the chemistry and the temperature of the waters from hot springs and shallow thermal wells suggests that these waters have evolved from the deep geothermal waters through dilution by meteoric waters and about 40°C adiabatic cooling (steam loss).     

Application of chemical geothermometers to thermal springs of the Maghreb,North Africa

In order to assess the geothermal potential in the Maghrebian region, several studies have been undertaken in the three countries concerned, Morocco, Algeria and Tunisia, during the past decade. Research programmes have considered the surface evidence (thermal springs) and underground thermal information from deep and shallow wells. The main chemical characteristics of the sampled thermal springs and the results of the application of geothermometers as result from these studies are presented. Of the 238 inventoried thermal springs, 169 have been selected, on the basis of complete water analyses and acceptable ionic balances. Measured temperatures range from 22.5 to 98°C, thermal indexes from 0.5 to 78°C and salinities from 0.13 to 52.5 g/L. Most studied springs are sodium-chloride type waters. These basic data allow identification of the main thermal anomalies in the Maghrebian zone, which are located in regions of the Libyan-Tunisian, Algerian-Moroccan and Algerian-Tunisian frontiers, of northern Tunisia, the Eastern Rif and the northern part of the Saharan Atlas.Several chemical geothermometers have been applied to selected springs: NaK, NaKCa, NaKCaMg, Na/Li, Mg/Li, K²/Mg, quarts, chalcedony (Fournier) and chalcedony (Arnorsson). The NaK, NaKCa, NaKCaMg, Na/Li and Mg/Li geothermometers seem to give unreliable results, while K²/Mg and silica temperatures are apparently reasonable. However, dissolved silica seems to be governed by quartz solubility for some thermal springs and by chalcedony solubility for others. The results are tentatively compared with known geothermal gradients and geological features.     

Hydrogeological and geochemical studies of the Efteni and Derdin geothermal areas,Turkey

The Efteni and Derdin geothermal areas are located in northwestern Turkey. Relatively low-temperature springs emerge from the Duzce Fault, a normal-component-dominated fault segment of the North Anatolian Fault System. The thermal waters of the Efteni and Derdin Springs show distinct geochemical and isotopic characteristics since they originate from different geothermal reservoirs and reflect the effects of different water–rock interaction processes. Geothermometry revealed higher reservoir temperatures for the Efteni system, however a strong δ¹⁸O shift, interpreted as being the result of isotopic exchange at high temperatures, was observed in the Derdin system. Hydrogeological and geochemical techniques are applied to identify recharge mechanisms, water–rock interaction processes and to construct conceptual models of these geothermal systems.     

Temperature and chemical changes in the fluids of the Obama geothermal field (SW Japan) in response to field utilization

Thermal waters from Quaternary volcanic rocks (predominantly andesites) discharge along faults in the Obama geothermal field of southwestern Japan. The chemistry of more than 100 thermal and ground water samples collected between 1936 and 2005 indicate that the Na–Cl hot spring waters are a mixture of “andesitic” magmatic, sea and meteoric waters. Mixing models and silica and cation geothermometry were used to estimate the SiO₂ and Cl composition and the temperature (∼200 °C) of the reservoir fluids deep in the geothermal system. The isotopic data (¹⁸O and D) are consistent with a mixed origin interpretation of the waters feeding the Obama hot springs, i.e. a large proportion of meteoric and sea waters, and a small magmatic component. Temperatures and chemical concentrations of the thermal waters were affected by the 1944–1959 salt production operations, but have recovered after closure of the salt factories; now they are similar to their pre-1940 values. In the future, the Obama geothermal field may be suitable for electric power generation, although heat and fluid extraction will require careful management to prevent or minimize reservoir cooling.     

Magmatic fluid input to the Kuju-Iwoyama hydrothermal system prior to the 1995 eruption of the Kuju volcano (Kyushu, Japan)

A schematic model showing the sources of hot waters being discharged at the surface in the Kuju-Iwoyama of the Kuju volcano has been developed. Based on the isotopic characteristics of these fluids it is inferred that deep magmatic fluid mixes with thermal waters derived from rainwater in a shallow geothermal reservoir, and with local groundwaters in a deeper reservoir. These thermal waters feed hot springs that discharge waters with Cl/SO₄ ratios that differ from that of the fumaroles on Kuju-Iwoyama, due to the addition of SO₄²⁻ ions produced by the decomposition of native sulfur and mixing with magmatic fluid of high Cl content.     

Fluid geochemistry of the San Vicente geothermal field (El Salvador)

The volcano Chichontepeque (San Vicente) is one of the nine recent volcanoes making up the El Salvador sector of the WNW-ESE-trending active Central American volcanic belt. Thermal activity is at present reduced to a few thermal springs and fumaroles. The most important manifestations (Agua Agria and Los Infernillos Ciegos) are boiling springs and fumaroles located on the northern slope of the volcano (850 m a.s.l.) along two radial faults. The chloride acid waters of the Los Infernillos area are partly fed by a deep hydrothermal aquifer (crossed at 1100–1300 m by a geothermal exploration well), which finds a preferential path to the surface through the radial fault system. C0₂ is the most important gas (>90%) of the Los Infernillos Ciegos and Agua Agria fumaroles. Part of the Los Infernillos gases may also come from a deeper, hotter source, given their high HCl/S_tot. ratio and their more reducing conditions. The application of geothermometric and geobarometric methods to the gases and thermal waters suggests that both thermal areas are linked to the identified 1100–1300 m reservoir, whose temperature (250°C), lateral extension and chemical composition, as resulting from this study, are of interest for industrial development.     

Thermal regime, groundwater flow and petroleum occurrences in the Cap Bon region, northeastern Tunisia

The Cap Bon region of northeastern Tunisia is part of a young continental margin that presents a thick column of sediments deposited mainly during Cretaceous and Miocene extended tectonic episodes. This sedimentary package is characterised by broad synclines alternating with NE–SW trending anticlines, and is affected by numerous NE–SW, NW–SE and E–W striking faults. Oligo-Miocene sandstones constitute the most important potential reservoir rocks in the region.The distribution of subsurface temperatures in the Cap Bon basin reflects local groundwater circulation patterns and correlates with the location of known oil and gas fields. The results of geothermal studies could therefore prove useful in the search for new hydrocarbon resources in the region. Subsurface temperatures were measured in deep oil exploration and shallow water wells. Local geothermal gradients range from 25 to 35 °C/km, showing higher values in the Korbous and Zennia areas, which correspond to zones of groundwater discharge and convergence in the Oligo-Miocene aquifer system, respectively.Analysis of thermo-hydraulic and geochemical data relative to the thermal springs in the Korbous region along the Mediterranean coast has made a useful contribution to geothermal prospecting for potential deep reservoirs. Positive geothermal gradient anomalies correspond to areas of ascending thermal waters (i.e. discharge areas), whereas negative anomalies indicate areas of infiltrating colder meteoric waters (i.e. recharge areas). The zones of convergence of upward-moving water and groundwater may be associated with petroleum occurrences.     

Geothermal resources in Algeria and their possible use

A map of geothermal resources in Algeria is now being compiled. An inventory of hot springs has already been prepared. The groups of springs, of different chemical characteristics can mostly be found in the NE and NW of Algeria, with the most interesting ones in the NE. Huge reserves of hot waters (50–56°C) are present in the sedimentary basin of the low Sahara. Hammam Meskhoutine (Guelma) in the NE and Hammam Righa in the NW are of particular interest. The geothermal potential of both areas will be in heating applications.     

Hydrogeochemistry and geothermal characteristics of the White Lake basin, South-central British Columbia, Canada

Hydrogeochemistry and geothermal characteristics of the Tertiary White Lake basin are described in order to provide constraints on the hydrogeology and thermal regime of the basin. The basin can be divided into three flow subsystems on the basis of chemical and isotopic variations. The groundwaters evolve chemically from young Ca–Mg–HCO₃ type waters in the shallow surficial sediments to Na-dominated waters in the deeper intermediate system. Surface waters and shallow groundwaters collected from wells completed in overburden have undergone extensive evaporation as evidenced by their enriched δ¹⁸O and δ²H composition. Minor evaporation identified in the isotope composition of groundwater from domestic wells completed in bedrock, as well as from springs, suggests a local to intermediate origin for these waters, and perhaps mixing with shallow evaporative waters. In contrast, the uniform isotope signatures of deep basin waters measured both spatially and vertically suggest recharge at higher elevations, and a much deeper circulation system that is essentially isolated from the shallow subsurface. Chemical geothermometry indicates that spring waters and bedrock well waters have equilibrated at temperatures of less than 20 and 60°C, respectively. Groundwaters encountered by deep diamond drill holes, with equilibration temperatures of less than 80°C, are representative of intermediate flow systems, and may serve to modify the heat flow regime in the basin. Regional groundwater flow within the basin is complex due to numerous faults that exert a strong influence on fluid circulation patterns. Transport of heat in the subsurface, which has resulted in variations in the measured thermal gradients across the basin, occurs either at depths greater than those investigated in this study or has been significantly influenced by the circulation of cooler groundwater in the central part of the basin.     

Modelling of the chemical composition of alkaline hot waters

The computer program MEQTP, which calculates the composition of a geothermal water and follows the evolution of the composition during temperature and pressure changes, has been applied to some springs from the south of France. This represents a first attempt at taking pressure changes into account in calculating pressure as well as temperature of the deep reservoirs supplying the thermal springs. The calculated temperature corresponds well with the values obtained by means of classical geothermometers and from previous calculations, in which pressure variations are neglected. Calculation of pressure requires a better understanding of the mechanism (read the mineral) controlling the Mg²⁺ concentration in the geothermal waters.     

Geophysical investigations of the Seferihisar geothermal area, Western Anatolia, Turkey

Self-potential (SP), magnetic and very low frequency electromagnetic (EM-VLF) surveys were carried out in the Seferihisar geothermal area to identify major and minor fault zones and characterize the geothermal system. The SP study provided useful information on the local faults and subsurface fluid flow. The main SP anomalies appear mostly along and near active fault zones in the area of the Cumalı, Tuzla and Doğanbey hot springs. Two of these anomalies near the Tuzla hot springs were further evaluated by SP modelling. Total magnetic field values increase from the Doğanbey to the Cumalı hot springs. Modelling performed on the magnetic data indicates that between these two spring areas are four different regions or units that can be distinguished on the basis of their magnetic susceptibility values. Fraser filtering of EM-VLF data also indicates that there are three significant conductive zones in the regions around the Cumalı, Tuzla and Doğanbey hot springs, and that they lie between important fault systems. The EM-VLF and total (stacked) SP data show that the conductive tilt anomalies obtained by Fraser filtering generally coincide with negative SP areas.According to our geophysical investigations, new exploratory wells should be drilled into the conductive zones located between the Cumalı and Tuzla hot springs. We further recommend that resistivity and magnetotelluric methods be carried out in the area to obtain additional information on the Seferihisar geothermal system.     

Geochemistry of the thermal waters of Salbardi and Tatapani, India

Geochemical studies have been carried out on water samples collected from Tatapani and Salbardi hot springs. The waters of these hot springs are classified as NaHCO₃ type. Waters in deep aquifers are associated with quartz, shale and clay terrains. Activity studies of the minerals and the waters present in the aquifers suggest that the thermal waters are within equilibrium with montmorillonite, kaolinite and quartz at about 150°C. The geochemical thermometers also estimate 150 ± 10°C as aquifer temperatures for Tatapani and Salbardi.     

Geothermal resources in Algeria

The geothermal resources in Algeria are of low-enthalpy type. Most of these geothermal resources are located in the northeastern of the country. There are more than 240 thermal springs in Algeria. Three geothermal zones have been delineated according to some geological and thermal considerations: (1) The Tlemcenian dolomites in the northwestern part of Algeria, (2) carbonate formations in the northeastern part of Algeria and (3) the sandstone Albian reservoir in the Sahara (south of Algeria). The northeastern part of Algeria is geothermally very interesting. Two conceptual geothermal models are presented, concerning the northern and southern part of Algeria. Application of gas geothermometry to northeastern Algerian gases suggests that the reservoir temperature is around 198 °C. The quartz geothermometer when applied to thermal springs gave reservoir temperature estimates of about 120 °C. The thermal waters are currently used in balneology and in a few experimental direct uses (greenhouses and space heating). The total heat discharge from the main springs and existing wells is approximately 642 MW. The total installed capacity from producing wells and thermal springs is around 900 MW.     

Gas geochemistry of the Cordón Caulle geothermal system,Southern Chile

The Cordón Caulle geothermal system is located in a NW-trending volcano-tectonic depression of the Southern Andean Volcanic Zone of Chile. Outflows of low chloride water were previously interpreted as the surface expression of a shallow steam-heated aquifer, with subsurface temperatures of 150–170 °C. Gas data from fumaroles and hot springs have been used to assess the nature and temperature of the deeper, underlying geothermal reservoir. Fumaroles at the northeastern border of Cordón Caulle have ³He/⁴He ratios typical of subduction margins (6–7 R_A) and N₂/Ar ratios of about 40, indicating deep convection of air-saturated groundwater. Fumaroles at the southwestern border have N₂/Ar ratios >300, suggesting the presence of a deep volcanic component. Gas ratios of fumarole discharges yield equilibration temperatures >300 °C, whereas those of hot spring waters suggest temperatures of about 160 °C. Based on these data, and comparisons with well documented liquid and vapor-dominated geothermal systems, a model is proposed of a boiling liquid-dominated geothermal system overlain by a secondary steam-heated aquifer.