SrO—SrCl2渣系热力学性质的测定与计算

采用Ｍｏ│Ｍｏ＋ＭｏＯ２│ＺｒＯ２（ＭｇＯ）│Ｆｅ＋（ＦｅｘＯ）＋Ａｇ│Ｆｅ固体电池测定ＳｒＯ－ＳｒＣｌ２渣系中ＦｅｘＯ的活度，进而做出该渣系在１６２３Ｋ的等温相图，计算出中ＳｒＯ的活度，探讨了温度对渣中ＦｒｘＯ活度的影响规律。     

Interactions of Titanium and Phosphorus with Tungsten

XRD has been applied to the component interaction in the Ti – W – P system, and an isothermal section at 1070 K has been constructed for the phase diagram in the range 0-0.67 mole fraction of P. A substitutional solid solution based on the phosphide Ti₃P is formed: Ti_3.0-2.4W_0-0.6P, a = 0.9953(2)-0.9934(3) nm, c = 0.4994(2)-0.4943(2) nm. It is confirmed that the ternary phosphide Ti_0.5W_0.5P is present of NbAs structure type. Interactions in the titanium – VIa metal – phosphorus systems are analyzed.     

基于相图和组织控制的先进材料开发

Recent progress on research activities of phase diagrams in our laboratory has been presented. Experimental studies and thermodynamic calculations based on CALPHAD (Calculation of Phase Diagrams) method have been conducted in the following alloy systems. 1. Database on microalloying steels including carbide, nitride and sulfide is now being constructed. 2. ADAMIS (Alloy Database for Micro-Solders) containing 8 elements of Ag, Bi, Cu, In, Sb, Sn, Zn and Pb hasbeen constructed, which can handle all combinations of these elements and all composition ranges. 3. A thermodynamic database of Cu-base alloys including Cu-X binary system and Cu-Fe, Cu-Ni, Cu-Cr base ternarysystems has been constructed. 4. Experimental and thermodynamic calculations on Fe, Ni, Co and Ti aluminides have been conducted. 5. Experimental and thermodynamic calculations on Co base magnetic recording media have been conducted. 6. Thermodynamic analysis of interaction between magnetic and chemical orderings has been performed. By utilizing the information on phase diagrams, the following advanced materials have been developed. (A) New type of high speed steel with high hardness about Hv≈1000 by carbide dispersion carburizing method, (B) New Pb-free machinable stainless steel using titanium carbosulphide. (C) New Pb-free solder for Die-attaching use. (D) Shape memory alloys; Cu-base, Ferromagnetic Ni-base and Fe-base. (E) Invar alloys. (F) Egg-type powder. Typical examples of phase diagrams, phase stability, database and its application for the development of advanced materials will be presented.     

Al-Zn(Cu)合金的相变和Al-Zn-Cu系相图

Al-Zn-Cusystemistheimportantbasisfor practicalAlalloysandZnalloys[1].Amiscibility gapofthefccphaseexistsabove277℃inthe Al Znsystem[2].Thealloywhosecompositionis atthetopofthemiscibilitygapiscalledsym metricalalloyAlZn.Thisalloyhasmanytypical properties.Theimportantoneisthatthespi nodaldecompositioneasilytakesplaceinit.In ordertoavoidthedecomposition,Cuhasbeen added,whichiseffective.Additionof2%Cu molefractioncoulddelaythespinodaldecompo sitionfortwogrades[3,4].AlZn 2Cuisanalloy which…     

高炉环形砌砖计算图

根据高炉环形砌砖内,砖量计算式为直线方程的原理,设计并绘制了高炉环形砖计算图,该图具有实用价值。     

Phase Diagram of the Ni ― Os System

Metallography, DTA, x-ray, and electron-probe microanalysis methods have been applied to alloys with four compositions in the cast and annealed states. A phase diagram has been constructed for the entire concentration range on the basis of these data together with published ones. The diagram is of peritectic type, and the peritectic temperature is 1500°C. The mutual solubilities of the components at that temperature are 13.3 at.% osmium in nickel and 13 at. % nickel in osmium. The solubility of osmium in nickel falls to 9.2 at. % when the temperature is reduced to 1200°C.     

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Dilatometry is a powerful technique for phase transformation analysis of solid state in iron and steel by measuring linear strain as a function of time and temperature during thermal cycle. The basic fundamentals, equipment and experimental analysis method of dilatometric analysis were introduced. Several practical examples and applications of dilatometry in iron and steel research were briefly described, with an emphasis on continuous heating transformation (CHT) and kinetic model, continuous cooling transformation (CCT) diagram and time temperature transformation (TTT) diagram.     

镁的合金化与合金相图

论文分析了镁基合金二元和多元相图的研究现状；指出了镁合金在合金化中存在的问题。在此基础上探讨了在镁合金的设计与研究过程中如何进行相图的研究。指出由6－10个元素组成镁合金集团进行合金相图的实验测定和热力学计算的方案是可行的。     

Effect of Si,C and Mn on the formation of bainite in ferrite-bainite steel

High-strength steels have been widely applied to automotive chassis parts.In order to form complex shapes,high hole expansion rates and high formability are required.Dual phase (DP) steel has a good formability,but a poor hole expansion rate.In this circumstance,another kind of steel which has a microstructure of ferrite-bainite,rather than ferrite-martensite,has been found to be an alternative solution.It is called FB steel.This steel with Si,C and Mn additions are applied in this study.A two-step cooling process is used to get the desired F+ B microstructures.Continuous cooling transformation (CCT) diagrams are made with deformation and without deformation,and starting times and temperatures of the phase transformations of interest are obtained.It is shown that Si,C and Mn contents in the steel strongly affect the shapes and positions of the CCT diagrams,as well as the final microstructures of FB steel.An increase of the Si content can promote the formation of ferrite and move the CCT diagram toward the left.However,when Si content is too high,when comparing to carbon and manganese contents,the formation of bainite will be retarded because of the formation of more ferrite.It increases the amount of C in a solid solution in the untransformed austenite and promotes the formation of pearlite.C and Mn can inhibit the formation of ferrite and retard the accumulation of C in austenite.Therefore,the appropriate balance of C,Si and Mn contents in steels will be able to help in obtaining the desired microstructure.     

M-Si-B合金非晶形成能力的CALPHAD模式评估

Evaluation of the amorphous-forming ability of M-Si-B ternary alloys using CALPHAD approach@長谷部光弘$日本九州工业大学 @OHTANI Hiroshi$Department of Materials Science and Engineering, Kyushu Institute of Technology @HASEBE Mitsuhiro$Department of Materials Science and Engineering, Kyushu Institute of Technology…