第四组元对机械合金化MgNiCu合金贮氢性能的影响

采用机械合金化方法由Ｍｇ，Ｎｉ和Ｃｕ单质粉末以及添加第四组元粉末按选定比例合成ＭｇＮｉＣｕ和ＭｇＮｉＣｕ－Ｍ５％贮氢材料，着重研究了分别添加不同的第四组元Ａｌ，Ｍｎ，Ｔｉ元素对不同球磨时间后ＭｇＮｉＣｕ合金贮氢性能的影响。结果表明，添加第四组元都不同程度地改善了ＭｇＮｉＣｕ俣金的初始活化条件；添加Ｍｎ能降低ＭｇＮｉＣｕ合金的吸放氢平台，显著改善其吸放氢动力学性质；添加Ｔｉ提高了ＭｇＮｉＣｕ合金的最     

Fe—Mn—Si形状记忆合金中元素对材料耐蚀性的影响

研究了Ｆｅ－Ｍｎ－Ｓｉ形状记忆合金中元素对材料耐腐蚀性能及形状记忆性能的影响。结果表明：在Ｆｅ－Ｍｎ－Ｓｉ合金中，随着Ｍｎ，Ｓｉ含量的增加，其耐腐蚀性能略有提高，但Ｍｎ含量过高会导致合金形状记忆性能下降。而在Ｆｅ－Ｍｎ－Ｓｉ合金中加入适量的Ｃｒ，可明显提高该合金的耐腐蚀性能，并使之具有良好的形状记忆性能。     

Fe－Mn－Si形状记忆合金中元素对材料耐蚀性的影响

研究了Ｆｅ－Ｍｎ－Ｓｉ形状记忆合金中元素对材料耐腐蚀性能及形状记忆性能的影响。结果表明：在Ｆｅ－Ｍｎ－Ｓｉ合金中，随着Ｍｎ、Ｓｉ含量的增加，其耐腐蚀性能略有提高，但Ｍｎ含量过高会导致合金形状记忆性能下降。而在Ｆｅ－Ｍｎ－Ｓｉ合金中加入适量的Ｃｒ，可明显提高该合金的耐腐蚀性能，并使之具有良好的形状记忆性能。     

FeMnSiCrNi形状记忆合金研究

研究了ＦｅＭｎＳｉＣｒＮｉ合金的化学成分、蠕变性能及腐蚀特性。结果表明，Ｆｅ－１４Ｍｎ－６Ｓｉ－９Ｃｒ－５Ｎｉ合金具有较好的形状记忆效应。经训练后，合金绝对应变回复率可达６．２％，并具有较好的抗蠕变性能、抗碱性腐蚀性能和抗晶间腐蚀性能。     

时效温度对Fe-Mn-Si-Cr-Ni-C合金形状记忆效应的影响

研究了时效温度对Ｆｅ－１４Ｍｎ－５Ｓｉ－４Ｎｉ－０．２Ｃ记忆合金形状记忆效应,力学性能和显微组织的影响。结果表明：合金的形状回复率随时效温度的升高而增加,在１２２３Ｋ时达到最大值,比固溶态提高了６８％;随后形状回复率随时效温度的进一步升高而急剧下降。时效温度对合金硬度的影响与其对形状回复率得一致的。能谱和波谱分析表明时效析出的第二相是富铬,富锰和富硅的（Ｆｅ,Ｍｎ,Ｓｉ,Ｃｒ）３Ｃ合金渗渗碳体,且     

快速凝固高阻尼Al—Zn—Mg—Cu系合金的研究

本文研究了利用快速凝固粉末冶金工艺制备高阻尼Ａｌ－Ｚｎ－Ｍｇ－Ｃｕ系合金。通过拉伸性能与阻尼性能的测试，以及显微组织分析，探讨了纯铝及石墨对合金拉伸性能及阻尼性能的影响。结果表明：Ａｌ－Ｚｎ－Ｍｇ－Ｃｕ／１５ｗｔ％Ａｌ合金的室温拉伸性能已达到ＬＣ９ＣＧＳ１的水平，阻尼性能为Ｑ＝６．０×１０＾－３；在室温至３００℃温度范围内，随着温度的升高，合金的阻尼能力提高；合金的阻尼机制属复合型机制。     

Cu－Zn－Al－Mn合金高温时效时相变机制的研究

用示差扫描量热法（ＤＳＣ）、电阻测量和透射电子显微镜对Ｃｕ－Ｚｎ－Ａｌ－Ｍｎ合金高温时效的贝氏体相变进行了研究。结果表明，合金经高温时效，溶质原子首先析出，有利于降低层错能，随后由于切变引起在（１１１）面上形成大量层错，从而促进了贝氏体相变。     

快速凝固高阻尼Al－Zn－Mg－Cu系合会的研究

本文研究了利用快速凝固粉末冶金工艺制备高阻尼Ａｌ－Ｚｎ－Ｍｇ－Ｃｕ系合金。通过拉伸性能与阻尼性能的测试，以及显微组织分析，探讨了纯铝及石墨对合金拉伸性能及阻尼性能的影响。结果表明：Ａｌ－Ｚｎ－Ｍｇ－Ｃｕ／１５ｗｔ％Ａｌ合金的室温拉伸性能已达到ＬＣ９ＣＧＳＩ的水平，阻尼性能为Ｑ＝６．０×１０￣３；在室温至３００℃温度范围内，随着温度的升高，合金的阻尼能力提高；合金的阻尼机制属复合型机制。     

γ—FeMnAlCr反铁磁合金电阻应变性能的探索

研究了γＦｅＭｎＡｌＣｒ合金的电阻应变性能。实验结果说明，γＦｅＭｎＡｌＣｒ合金丝的室温电阻应变灵敏系数为４．０～４．２，制成的应变片灵敏系数平均为３．７，远高于目前常用的应变电阻合金。合金发生反铁磁→顺磁转变时灵敏系数将急剧下降，说明γＦｅＭｎＡｌＣｒ合金的高灵敏系数来源于合金的反铁磁自旋有序结构。此外，γＦｅＭｎＡｌＣｒ合金具有较小的机械滞后，但蠕变和电阻温度系数较大，因此它适合于室温的动态应变测量。     

Cu—Zn—Al—Mn合金高温时效时相变机制的研究

用示差扫描量热法、电阻测量和透射电子显微镜对Ｃｕ－Ｚｎ－Ａｌ－Ｍｎ合金高温时效的贝氏体相变进行了研究。结果表明，合金经高温时效，溶质原子首先析出，有利于降低层错能，随后由于切变引起在（１１１）面上形成大量层错，从而促进了贝氏体相变。     

Structural studies on the alloying behaviour of γ-Mn and the development of a high damping capacity in Mn-Cu alloys

Quenched Mn-Cu alloys undergo an unusual type of phase transformation and form metastable structures. A miscibility gap exists in these alloys, and the stability of the alloy phases is associated with the allotropic form of elemental Mn-atoms beyond the equi-atomic compositions. Quenched Mn-33.4 at% Cu alloy, which corresponds to the centre of the miscibility gap, upon ageing gives rise to a high damping capacity. The internal lattice strain which is the cause of the high damping capacity is thought to be due to interfacial misfit of the MnCu phase and elemental Mn in the proposed metastable structure of the alloy.     

Remarkable improvement of damping capacity in FeMn-based alloys by a long annealing

ABSTRACT

Effects of a long annealing up to 10?h were investigated on damping capacity and phase evolutions in FeMn-based alloys. The damping capacity in the Fe17.5Mn alloy rose with the annealing time. A highest damping capacity was obtained in the Fe16.5Mn10.5Cr alloy after 2?h annealing. The highest damping capacity was comparable in Fe17.5Mn and Fe16.5Mn10.5Cr alloys. A positive relationship between the damping capacity and the stacking faults existed in both the Fe17.5Mn and Fe16.5Mn10.5Cr alloys annealed for above 2?h. To reduce the amount of α′-martensites was favourable to the further improvement of damping capacity. The α′-martensites clustered locally in the Fe17.5Mn alloy, but they distributed inside the ?-martensite bands in the Fe16.5Mn10.5Cr alloy.     

Application of damping mechanism model and stacking fault probability in Fe–Mn alloy

In this paper, the damping mechanism model of Fe–Mn alloy was analyzed using dislocation theory. Moreover, as an important parameter in Fe–Mn based alloy, the effect of stacking fault probability on the damping capacity of Fe–19.35Mn alloy after deep-cooling or tensile deformation was also studied. The damping capacity was measured using reversal torsion pendulum. The stacking fault probability of γ-austenite and ε-martensite was determined by means of X-ray diffraction (XRD) profile analysis. The microstructure was observed using scanning electronic microscope (SEM). The results indicated that with the strain amplitude increasing above a critical value, the damping capacity of Fe–19.35Mn alloy increased rapidly which could be explained using the breakaway model of Shockley partial dislocations. Deep-cooling and suitable tensile deformation could improve the damping capacity owning to the increasing of stacking fault probability of Fe–19.35Mn alloy.     

形状记忆合金内耗行为的研究进展

综述了形状记忆合金内耗特性的构成和产生机理，研制了利用Cu-Al-Ni-Mn-Ti记忆合金与铍青铜复合，研制成功了一种新型的弹性、减震、导电复合材料，并对其内耗性能进行了研究。     

铸态Cu20Ni35Mn合金的直接时效强化研究

制备成分为Cu20Ni35Mn的合金试样,对铸态锰白铜合金直接进行时效处理,研究了不同的时效工艺对锰白铜合金的强化效果,分析了时效强化机理.实验结果表明,锰白铜合金在铸态下可以直接进行时效处理,最佳时效工艺为:时效温度400～470℃,时效时间为60～72h,硬度可达到HV400以上.并发现MnNi相的析出是合金时效强化的主要原因.     

A study of the effect of antimony content on damping capacity of ZA84 magnesium alloy

The effects of antimony content on damping capacity of as cast Mg–8Zn–4A1–0.3Mn magnesium alloy were investigated by using optical microscopy and dynamic mechanical analyzer, etc. The results indicated that the damping capacity of Mg–8Zn–4A1–0.3Mn magnesium alloy was reduced at the low temperatures (<80 °C) after adding antimony, but its damping capacity was improved at the higher temperatures (>80 °C). There exists a damping peak in both modified and unmodified alloys with different temperature, adding antimony postpones the emergence temperature of damping peak. The damping capacities of the modified alloys were decreased gradually with the increase of antimony content. In the present work, the best damping capacity was obtained from the modified alloy containing 0.1 wt.% antimony at the high temperatures.     

Effect of Cu content on microstructure and properties of Fe-16Cr-2.5Mo damping alloy

Five Fe-16 Cr-2.5 Mo damping alloys with different Cu contents(0%,0.25%,0.5%,1.0% and 2.0%) were prepared.The microstructure was observed by scanning transmission electron microscopy(STEM) and the damping behavior was measured by using a dynamic mechanical analyzer(DMA).The results show that the grain size of experimental alloy with(0.25–1.0%) Cu was refined compared with the 0 Cu alloy.The Cu element is fully dissolved in the matrix and there are no Cu precipitates and carbides observed.Although the internal stress increases because of Cu addition,the damping capacity of the 0.5 Cu and1.0 Cu alloys has been significantly improved.The reason of damping improvement is that the magnetic domain structure is strongly modified.Meanwhile,the strength was improved gradually due to the Cu solid solution strengthening and grain refining.In the 2.0 Cu alloy,lots of Cu-riched particles appeared in the matrix.These Cu precipitates with 10–15 nm in size are spherical and homogeneously distributed,which strongly induce strength improvement through precipitation strengthening.On the contrary,the elongation and impact energy of the 2.0 Cu alloy decrease sharply.In addition,lots of Cu precipitates will significantly decrease the damping capacity by hindering the mobility of domain walls.     

铸态MnCu合金的非线性内耗

测量了Mn60Cu40铸态合金不同振幅及不同频率下的内耗,观察到较强的非线性内耗和非线性共振现象,分析了它们的来源,提出了一个衡量材料非线性共振的参数(P参数)。并对其高阻尼的机理进行了探讨。     

Preparation and properties of Mg-Cu-Mn-Zn-Y damping magnesium alloy

This paper presents the successful preparation of a high-damping, high-strength Mg-Cu-Mn-Zn-Y alloy by alloying and extrusion. The damping capacity of the as-cast Mg-3Cu-1Mn alloy (alloy 1) displayed evident variations with changes in Y and Zn content. The as-cast Mg-3Cu-1Mn-2Zn-1Y alloy (alloy 2) exhibited excellent damping capacity and unusual damping growth in the high-strain amplitude stage; the damping capacity of alloy 2 exceeded that of alloy 1 and even approached that of pure Mg when the strain amplitude exceeded 5 × 10⁻⁴. This observation is believed to be related to the formation of long and parallel dislocation configurations and the interactions between these dislocations and plastic second-phase particles. The study also showed a remarkable improvement in the mechanical properties of as-extruded Mg-Cu-Mn-Zn-Y alloys. We attribute this finding to dynamic recrystallization, dispersion strengthening, and work hardening during hot extrusion.     

RE对Mg-8Zn-4Al-0.3Mn镁合金阻尼性能的影响

研究了 RE对Mg-8Zn-4Al-0.3Mn镁合金阻尼性能的影响.研究表明,加入RE后降低了合金低温下的阻尼性能,但明显提高了其在高温下(≥120℃)的阻尼性能.高温下,加入1.0%RE的合金表现出了最高的阻尼性能.由于高温下合金中相界面的软化及粘性滑动,四种合金在高温下均存在一个温度内耗峰,只是出现的温度不同.RE的加入推迟了温度内耗峰出现的温度.分析认为,加入RE后合金的阻尼机制主要是位错机制和界面机制.可动位错密度越高,晶粒越细,晶界和相界越多,阻尼性能越好.