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针对混合C9芳烃原料中沸点接近、分离困难的连三甲苯-茚满物系,以环丁砜为萃取剂进行了萃取精馏分离提纯实验,并采用Aspen Plus化工流程模拟软件对萃取精馏工艺过程进行了模拟研究,萃取精馏实验数据与模拟结果吻合较好,相对偏差小于5%。结合萃取精馏实验和流程模拟考察了萃取精馏塔的理论塔板数、溶剂比(萃取剂与原料的质量比)、回流比以及原料和萃取剂的进料位置等因素对分离效果的影响规律。结果表明,环丁砜萃取精馏提纯连三甲苯较适宜的工艺条件是:萃取精馏塔的理论塔板数为60~65、溶剂比为5~7、回流比为3~4、原料的进料位置为第34~36块板、萃取剂的进料位置为第8~10块板,在此条件下,塔顶可获得高纯度的连三甲苯产品,其质量分数可达99%以上,回收率可达93%以上。 相似文献
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萃取精馏萃取剂的一种实验筛选方法 总被引:1,自引:0,他引:1
介绍了萃取精馏萃取剂的一种实验筛选方法,汽液平衡仪直接法。并对水一醋酸体系进行了实验,实验结果证明该方法是可行的,可以有效地对萃取精馏的萃取剂进行实验筛选。 相似文献
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低浓度醋酸水溶液的回收 总被引:7,自引:0,他引:7
通过三脂肪胺-煤油-正癸醇体系萃取低浓醋酸水溶液的实验,比较了萃取剂三种成分的不同酸比以及温度对分配系数的影响,确定了萃取操作的最佳萃取剂配比及适宜操作温度。通过静态混合器对萃取过程的强化及减压精馏回收萃取剂实验,验证了三脂肪胺-煤油-正癸醇体系萃取低浓醋酸的工业可行性。 相似文献
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萃取精馏中用脱溶剂方法计算萃取剂用量十分繁杂,计算误差大。主要原因是:萃取剂的挥发度小,用数值小的数据关联数值较大的萃取剂用量,可能产生计算误差;在计算过程中脱溶剂的数据与不脱溶剂的数据混用;脱溶剂计算方法没有考虑液气比对分离效果的影响。建立了萃取精馏在三角相图中的几何意义,用浓度杠杆规则可以计算萃取剂的用量。计算结果合理,且符合精馏的各种规律。 相似文献
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本文采用3种不同方法,分别以乙醇、丙酮、水作为提取溶剂对黄连小檗碱进行提取.以盐酸小檗碱作为对照,用标准曲线法测定各种溶剂及方法提取液中黄连小檗碱的提取率.实验结果表明:采用回流提取法,提取溶剂为乙醇,黄连小檗碱的提取率达到81%以上,标准偏差为0.0005,相对标准偏差为0.06% 相似文献
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Craig M. Ruecker Michael A. Mensik Aydin Akgerman 《Chemical Engineering Communications》1986,41(1):279-289
Analysis of trickle-bed reactor data is almost always done by assuming that the catalyst particles are completely covered by a liquid film. The effect on reactor performance from violations of this assumption is demonstrated. The hydrodesulfurization of benzothiophene was simulated with the feed consisting of 10%, by weight, benzothiophene and 90% decalin. The temperature and pressure were held constant at 630 K and 68 atm. The results show that the exit conversion is strongly affected by the wetting efficiency. 相似文献
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Mohsen Adhami Movahedirad Salman Mohammad Amin Sobati Amir Hossein Khalili-Garakani 《加拿大化工杂志》2023,101(11):6315-6327
The desulphurization of hydrocarbon fuels with high sulphur content and a wide variety of sulphur-containing compounds brings significant challenges. In the present work, the non-catalytic desulphurization of vacuum gas oil (VGO) and natural gas condensate mixed fuel has been investigated. In this regard, ozone was employed as the oxidant in a bubble column gas–liquid contactor, and an extraction step was further incorporated. The effects of the oxidation reactor scheme, ozonation time, and extraction with different solvents, applying pre- and post-extraction strategies (i.e., ozonation/extraction/extraction and extraction/ozonation/extraction), have been studied. It was found that pre-extraction of mixed fuel increases the oxidative desulphurization (ODS) efficiency due to the removal of light sulphur-containing compounds (SCCs). N-methyl-2-pyrrolidone (NMP) has been found to be the most effective extraction agent, removing 44% of sulphur by pure extraction and 77.4% by ozonation + extraction. However, in terms of fuel loss, dimethylformamide (DMF) performs better than NMP, and it has been shown to be the most appropriate solvent for achieving a 90% desulphurization ratio. Finally, it was found that the applied procedure could effectively remove the wide range of SCCs, especially refractive components such as benzothiophene (BT) and dibenzothiophene (DBT). 相似文献
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CRAIG M. RUECKER MICHAEL A. MENSIK AYDIN AKGERMAN 《Chemical Engineering Communications》2013,200(1-6):279-289
Analysis of trickle-bed reactor data is almost always done by assuming that the catalyst particles are completely covered by a liquid film. The effect on reactor performance from violations of this assumption is demonstrated. The hydrodesulfurization of benzothiophene was simulated with the feed consisting of 10%, by weight, benzothiophene and 90% decalin. The temperature and pressure were held constant at 630?K and 68?atm. The results show that the exit conversion is strongly affected by the wetting efficiency. 相似文献
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针对甲基异丁基甲酮(MIBK)和异丙醚(DIPE)两种萃取剂以及在不同剂溶比时萃取苯酚羟化液的萃取效果进行了比较;并进一步采用磷酸三丁酯(TBP)为配合剂、甲基异丁基甲酮(MIBK)为稀释剂研究了苯酚羟化液的配合萃取.结果表明:MIBK的萃取效果优于DIPE,MIBK为萃取剂时的最优剂溶比为1:3,此时苯酚羟化液的三级错流萃取率可达99%发上.通过MIBK对羟化液的多级错流萃取过程模拟计算进一步验证了此结论.采用TBP络合萃取苯酚羟化液,实验表明,萃取率可达到99.76%. 相似文献
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R A Gómez-Brenes E I Nú?ez R Bressani J E Braham 《Archivos latinoamericanos de nutrición》1983,33(3):503-518
A study was carried out to determine the effect of different solvents on the extraction of protein fractions in beans. Black bean protein was extracted with the following solvents: distilled water, 0.01 M sodium hydroxide, 0.05 M sodium chloride, and 70% ethanol. By using each solvent under different conditions, it was possible to establish the optimum ones for the best extraction and fractionation of proteins from leguminous seeds. These conditions were the following: one hour agitation at room temperature, three successive extractions with the same solvent, and a ratio of solid to solvent of 1:20 W/V. The effect of 24 different sequences of solvents upon the extraction of protein was also investigated. From the extraction point of view, the best sequence of solvents for extracting the protein was that where NaOH constituted the first solvent used; this sequence, however, has the disadvantage of extracting all the protein from the seed, making it impossible to separate other protein fractions by another solvent. If the purpose of the extraction is to separate different protein fractions, the best sequence of solvents is distilled water or sodium chloride in the first place, followed by ethanol and sodium hydroxide. The need for using standardized methodology for the fractionation of protein from seeds in order to obtain comparable data between research laboratories is emphasized. 相似文献