FRM用先进陶瓷纤维及其拉伸强度

陶瓷,其耐热性、耐腐蚀性、功能性等引起人们重视,作为一种新材料而得到开发,其有用性得到了公认。所谓新材料,或明显提高原料纯度,或使其形状极端微细化、微粉化或者薄膜化,或使原料组合、制成合金,从而使材料性能得到空前的发挥。碳化硅(SiC)、硼(B)、氧化铝(Al₂O₃)等陶瓷也可使其形状变成又细又长的纤维状,从而使拉伸强度提高,使陶瓷的使用变得容易起来。本稿将就最近开发的轻质高强陶瓷纤维的性能加以介绍。      

有限宽度和椭圆孔形状对缺口层合板强度预测的影响

本文采用有限元方法对正交各向异性材料含有不同椭圆孔形状的有限宽度板作了分析,给出了有限宽度和椭圆孔形状对应力集中因子K₁和孔边应力分布σ_y(x,0)的影响公式。数值结果表明:正交各向异性板的有限宽度和椭圆孔形状对K_r和σ_y(x,0)的影响均与各向同性材料不同,所以有限宽度和椭圆孔形状将对缺口层合板强度的预测产生影响。      

复合材料加筋板的动力分析

本文构造了九自由度三角形拟协调罚函数复合材料板单元与六自由度复合材料梁单元,考虑了剪切变形与转动惯量的影响。用这两种单元对复合材料加筋板的自由振动、阻尼特性和瞬态响应问题进行了研究,给出一些有益结果。      

Microstructure and mechanical properties of CoCrNi-Mo medium entropy alloys:Experiments and first-principle calculations

The effect of Mo additions on the microstructures and mechanical properties of CoCrNi alloys was investigated,meanwhile,ab initio calculations are performed to quantitatively evaluate the lattice distortion and stacking fault energy(SFE).The yield strength,ultimate tensile strength,and elongation of(CoCrNi)₉₇Mo₃alloy are 475 MPa,983 MPa and 69%,respectively.The yield strength is increased by~30%and high ductility is maintained,in comparison with CoCrNi alloy.Besides the nano-twins and dislocations,the higher density of stacking faults is induced during the tensile deformation for(CoCrNi)₉₇Mo₃alloy.Ab initio calculation results indicate the mean square atomic displacement(MSAD)and SFE value of(CoCrNi)₉₇Mo₃alloy is 42.6 pm²and-40.4 mJ/m²at 0 K,respectively.The relationship between mechanical properties and MSAD,SFE for various multiple principal element alloys is discussed.     

冷轧薄宽带钢局部型中浪瓢曲变形行为研究

针对薄宽带钢冷轧过程中易发多发的局部型中浪瓢曲缺陷,引入非均匀载荷宽度、弹性约束系数及平均张应力建立了屈曲变形的解析计算模型。应用能量最低原理对屈曲变形区域进行搜索求解,得到了局部型中浪屈曲临界条件(包括临界应力、屈曲波长和屈曲波宽),获得了其与非均匀载荷宽度、弹性约束系数、平均张应力的关系,并发现平均张应力是产生局部型中浪的重要影响因素。应用样条有限元方法对局部型中浪进行数值仿真分析,验证了屈曲解析计算方法的正确性。在实验轧机上进行了轧制研究,通过轧制获得了局部型中浪屈曲模态,对实验结果分析得到了相对应的屈曲临界条件,与解析法和样条有限元法结果基本吻合,证明了样条有限元计算方法与解析计算方法的正确性及其工程应用价值。     

涂料的前世与今生

<正>2014年3月24日,应国家主席习近平夫人彭丽媛邀请,美国总统奥巴马夫人米歇尔·奥巴马以及米歇尔的母亲和两个女儿抵达西安参观访问。中午1时,米歇尔一行的车队抵达秦陵博物院,在进入一号俑坑的一刹那,米歇尔露出非常惊讶的表情。既惊讶于兵马俑规模的宏大,也好奇于兵马俑彩绘的绚烂。当她来到一件正在清理的陶俑旁边时,陶俑身上的彩绘吸引了米歇尔的目光。米歇尔好奇地询问这些颜色是不是原始的颜色。考古人员告诉她,这是刚刚发现的。米歇尔随后表示,希望能把文物保护     

F16-4型放映机激励灯的调整和固定

激励灯的灯头上有一大一小两个卡片,在灯座上对应的有两个槽,把激励灯装上去应当稳定不动.但由于槽的缝隙较宽,或固定灯泡的弹簧片疲劳使弹力减弱,致使灯泡受震动后容易前(指的是靠镜头一面)后幌动,这样会导致激励光刃变宽或不均匀,使还音含糊不清、失真.     

真空技术在射线源注油中的应用

本设备可对注油机的储油箱、拉模箱、溢油箱提供真空环境并对射线源抽真空和注油,注油过程中对各储油室中的绝缘油进行真空脱气、脱水,以确保注油前的性能指标,使油品达到军标、国标、国际标准.使真空技术在射线源注油技术中得到了很好的应用.通过理论计算合理配置真空系统,通过不断的探索和实践在真空系统中加装了氟里昂挡油装置,氟里昂挡油装置的设置从根本上解决了液体绝缘油在进行真空脱气、脱水过程中的一系列难题.     

Tailoring polysulfide trapping and kinetics by engineering hollow carbon bubble nanoreactors for high-energy Li-S pouch cells

Despite great progress of lithium-sulfur(Li-S)battery performance at the laboratory-level,both key parameters and challenges at cell scales to achieve practical high energy density require high-sulfur-loading cathodes and lean electrolytes.Herein,a novel carbon foam integrated by hollow carbon bubble nanoreactors with ultrahigh pore volume of 6.9 cm3·g?1 is meticulously designed for ultrahigh sulfur content up to 96 wt.%.Tailoring polysulfide trapping and ion/electron transport kinetics during the charge-discharge process can be achieved by adjusting the wall thickness of hollow carbon bubbles.And a further in-depth understanding of electrochemical reaction mechanism for the cathode is impelled by the in-situ Raman spectroscopy.As a result,the as-prepared cathode delivers high specific capacitances of 1,269 and 695 mAh·g?1 at 0.1 and 5 C,respectively.Furthermore,Li-S pouch cells with high areal sulfur loading of 6.9 mg·cm?2 yield exceptional practical energy density of 382 Wh·kg?1 under lean electrolyte of 3.5μL·mg?1,which demonstrates the great potential for realistic high-energy Li-S batteries.     

Efficient hexane isomers separation in isoreticular bipyrazolate metal-organic frameworks: The role of pore functionalization

Hydrocarbons separation in petrochemical industries is a key,energy-consuming stage in the manufacture of high-quality added-value products—hence the need for more efficient materials and environmentally friendly methodologies to improve this process.In this context,we have studied the effect of metal-organic frameworks(MOFs)pore functionalization in hexane isomers separation,isolating the robust isoreticular zinc(ll)bipyrazolates Zn(BPZ),showing no pore decoration,Zn(Me₂BPZ),the pores of which are decorated with apolar methyl groups,and Zn(BPZ(NH₂)₂),the spacers of which possess polar Lewis-basic functions(H₂BPZ=1H,1'H-4,4'-bipyrazole;H₂Me₂BPZ=3,3'-dimethyl-1H,1'H-4,4'-bipyrazole;H₂BPZ(NH₂)₂=3,5-diamino-1H,1'H-4,4'-bipyrazole;DMF=dimethylformamide).After characterizing Zn(BPZ(NH₂)₂)as per its crystal structure and thermal behaviour,and all the three MOFs as per their textural properties,we investigated,from the experimental and computational points of view,the impact of the square one-dimensional channels decoration on the separation of the hexane isomers,demonstrating the relevance of pore constrictions in the resolution of the title alkanes mixture.     

Shrinkage compensation approach proposed for ABS material in FDM process

Dimensional accuracy of parts manufactured by Fused Deposition Modelling (FDM) greatly suffers from the shrinkage problems of the available polymer materials. This paper proposes a constructive idea for resolving the shrinkage issues and explains how shrinkage could be managed by interior geometry of the artifacts fabricated on desktop 3D printers. The main principle for preventing the deterioration on dimensional accuracy of the holes/slots is to utilize the auxiliary lines located from the hole’s perimeter to the outer boundaries of the artifact. Thus, the shrinkage of these auxiliary line segments simply helps to pull the original hole backward, acting against the predicted contraction. In this paper, the proposed approach will be examined using a finite element analysis tool to predict the shrinkage behavior of the fabricated samples along with necessary measurements taken on the Coordinate Measuring Machine. Additionally, an analytical framework for modeling the shrinkage behavior of ABS is to be elaborated. The coherence of the simulations and the measurements are to be analyzed regarding the effect of the geometry and material color on the shrinkage behavior. The discussion involves the improvement on the dimensional accuracy of 3D printed features.     

Ice formation process by cooling water–oil emulsion with stirring in a vessel

An emulsion, which was a mixture of silanol-aqueous solution and silicone oil, was investigated as a heat storage material for a dynamic type ice storage system. The emulsion was poured into a vessel, which was immersed into a constant temperature bath at a low temperature, and frozen with stirring. Using stainless steel vessels coated with PFA resin and PTFE vessels with different thickness, the experiments were carried out under various conditions of temperature. Measuring the temperature history in the vessel, overall heat transfer coefficients before the start of freezing and during the ice formation were obtained. The effects of the material of the cooling surface and the thermal resistance of the wall on the ice formation process were clarified. If the heat flux of the wall was less than a critical value, slurry ice was formed without adhesion to the cooling surface. The results obtained under the same condition of the thermal resistance proved that it was effective against ice adhesion to coat PFA resin inside the vessel. It was found by the experiments in which the PTFE vessels were used that the critical value of the heat flux was nearly constant regardless of the thermal resistance.     

Tribologische Kennwerte für Reibwerkstoffe

Tribology parameters for friction materials The tribology parameters of the friction materials are currently the coefficient of friction and the wear coefficient. They are determined depending on the material, the surface pressure and the frictional speed. These two parameters are not sufficient for an evaluation of the friction materials on the basis of a wear theory. Their validity is therefore limited. It is proposed to evaluate the friction materials on the basis of the energetic wear theory. The parameters are then the wear energy density, the shear stress of friction and the linear wear intensity. These values can be shown in a diagram and allow for the direct comparison of widely varying friction materials. The reference coefficient of friction is being introduced as a new wear parameter. The determination of the proposed parameters is made on a flywheel test rig, combined with the laser‐optical online measurement of the wear particles. It was possible to demonstrate that the parameters correctly describe the practice‐relevant requirements using two proven friction materials.     

Parametric optimization of a new combined refrigeration cycle – active thermal potentiostatting system

The active thermal potentiostatting system proposed by Martinovskii and Tsirlin is directly generalized to a more practical case, in which one intermediate chamber, besides a thermal potentiostatting chamber, and two irreversible refrigeration cycles are included and the influence of the thermal resistance between the working fluid and the reservoirs, the heat leakages from the environment to the intermediate chamber and from the intermediate chamber to the potentiostatting chamber are taken into account. Expressions for the main parameters of the system are derived. By using the optimal control theory, the minimum total power input of the system with non-zero cooling rates is calculated and the temperatures of the working fluid in the isothermal processes of the refrigeration cycles are optimized. The optimal allocation of the heat-transfer areas of the heat-exchangers in the refrigeration cycles is discussed in detail. The results obtained here are more general and useful than the relevant results in literature and can provide some valuable guidance for the optimal design and operation of real active thermal potentiostatting systems.     

Verbesserung des Eigenspannungszustands beim Kaltfließpressen durch den aktiven Einsatz eines gesteuerten Gegenstempels

By using an active counter punch during cold extrusion, the residual stress of the component can significantly be improved, which can increase its fatigue strength. In general, the workpieces produced through full‐forward extrusion are characterized by a strongly unfavourable stress state: The resulting high axial tensile residual stresses on the surface as well as the steep stress gradient accelerate the formation and the growth of cracks during cyclic loading. A system developed by the authors, consisting of a counter punch actively employed during the forming process allows improving the residual stress state of the final product. This result is obtained through a homogenization of the deformations in the samples during the cold extrusion. Therefore, a finite element simulation of the process was developed in Simufact Forming®. The simulation was experimentally validated by using the two austenitic steels 1.4307 and 1.4404. Another focus is the development of suitable measuring strategies for the X‐ray residual stress analysis with the sin²Ψ‐method to ensure the quality of the measurement results despite coarse‐grained and anisotropic microstructures. The results of the simulations and the experiments show that his technique has a considerable potential to increase the product quality without modifying the process time.     

An experimental study on minimizing frost deposition on a cold surface under natural convection conditions by use of a novel anti-frosting paint. Part II. Long-term performance, frost layer observation and mechanism analysis

In this part of study, the comparative observations of the structure and the surface temperature of the frost layer of both the coated and uncoated surfaces ware carried out and a preliminary analysis was presented. A series of the repeated cycling tests were completed that lasted for more than 2 months, and the influences of the coating thickness were also investigated. The results show that the frost layer deposited on the coating surface has a very fragile structure and can be removed easily by external force. The coating thickness has an important effect on the anti-frosting performance of the paint. The results also show that the coating of the paint on the copper surface is durable and presents a very good repeated cycling performance.     

Two-phase split of refrigerants at a T-junction

The present study experimentally investigated the two-phase flow split of refrigerants at a T-junction. As geometric parameters, the direction of the inlet or branch tube and the tube diameter ratio of branch to inlet tube were chosen. As inlet flow parameters, the inlet mass flux and quality were varied from 100 to 700 kg m⁻² s⁻¹ and from 0.1 to 0.9, respectively, for the condition of distribution header of a multi-pass evaporator in the general refrigeration system. All experiments were performed for R-22, R-134a, and R-410A. The measured data were compared with the values predicted by the models developed for air–water or steam–water mixture in the literature. We propose a modified model for application to the reduced T-junction and vertical orientation of tubes. Among the geometric parameters, the branch tube direction showed the largest sensitivity to the mass flow rate ratio for the gas phase, while the inlet quality showed the largest sensitivity to the mass flow rate ratio among the inlet flow parameters.     

Numerical Analysis of Powder Properties in Low Power Plasma Torch

A mathematical model was presented to describe the particle trajectory, velocity and temperature properties in the low power plasma spraying torch (3.6 kW)in which powder particles were directly injected into the region between the cathode and anode. The results show that the characteristics of the particles by low power plasma spraying are similar to that by traditional APS( Atmosphere plasma spraying) in 40 kW. The velocities of the particles increase with the increase of inlet gas flow rate, current and percentage of nitrogen and hydrogen, while the temperature of the powder increase with the decrease of the gas flow rate and with the increase of current and percentage of nitrogen and hydrogen.     

Unified damage description and risk assessment of buildings under extreme natural hazards

Internationally different classification schemes are available for the assessment of structural damage due to the different natural hazards. Due to their heterogeneity, these classification schemes are insufficiently suited for the consideration of damage in the sense of a multi hazard approach. A unified system is necessary for the evaluation of the building vulnerability and the damage prognosis due the different natural hazards. The unified system transfers repeatedly observed damage patterns into a scheme of damage grades. With this instrument, the structural damage can be uniformly evaluated and the relationship to the input parameters can be established. Following the concept of the European Macroseismic Scale 1998 (EMS‐98) for earthquake damage, it is distinguished between structural and non‐structural damage to which characteristic damage patterns can be assigned in the form of damage grades. A general classification scheme for building damage is presented, which enables a comparison of the damage due to the individual natural hazards. On the basis of real observed damage cases, the typical damage patterns for the natural hazards flood, tsunami and wind are highlighted and converted into harmonized classification schemes for damage grades. For the first time, a harmonized set of instruments is available for evaluation of damage cases on a building stock as a result of different natural hazards according to criteria standardized in engineering terms. The outlook refers to the damage prognosis due to the different natural hazards and their possible sequences.     

Capturing Nitrosamines in Environment by Zeolite

To meet the requirement of environment protection, the adsorption of volatile nitrosamines, which are carcinogenic compounds in tobacco smoke, by zeolite is investigated in this article, along with the temperature programmed surface reaction of nitrosamines on zeolite to assess the catalytic capability of the porous material on the decomposition of the carcinogens. The actual function of zeolite to reduce the level of nitrosamines in cigarette smoke is also studied. The influences of zeolite pore's structure and the surface acid-basic properties of the adsorbent on the adsorption are explored in terms of geometric matching content and adsorbent-adsorbate interaction. Moreover, the role played by the cation of zeolite in the adsorption of volatile nitrosamines is discussed and the possible attracting range of the sodium cation in basic zeolite to pull the nitrosamine molecule is tentatively calculated. Owing to the specific ability of capturing nitrosamines, zeolite is proven to be the most effective additive encased within a cigarette as the functional additive for lowering the nitrosamines content of smoke to protect the environment and public health. Other porous oxides such as amorphous silica and alumina are also utilized in these experiments, and their actual functions to trap nitrosamines as well as their potential application as the candidates for cigarette additives are discussed and prospected, too.