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1.
为调查Al2O3对烧结矿的还原少高温性能的影响,对不同Al2O3含量的烧结矿进行加热还原。调查了高铝烧结矿的初始软化温度和压损。同时用X射线观察了还原过程,用EPMA和SEM分析了冷却后的试样,发现高铝烧结矿在还原初始阶段存在大量的FeO-2CaO·SiO2·Al2O3共晶相。高铝烧结矿在较低温度下会产生大量的富Al2O3熔融相。  相似文献   

2.
为了阐明钢在凝固过程中氧化物和硫之间的反应,观察分析了连铸钢氧化物成分对它的影响,结果如下:在低Al含量钢中(Al=0.005%)观察到CaO-SiO2-Al2O3和CaO-SiO2氧化物,在高Al含量钢中(Al=0.031%)看到CaO-Al2O3氧化物。CaO-SiO2_Al2O3和CaO-Al2O3氧化物比CaO-SiO2氧化物具有较高的硫含量。氧化物中的S含量随钢在凝固温度下的液相率和硫容  相似文献   

3.
对用高温结构陶瓷替代传统的高纯金属铜,制备高炉风嘴的可能性进行了研究,用SFM、X射线衍射和动态模拟实验法分析了氧化铝瓷烧结过程。结果表明,在实验条件下添加2.5%CaO、3.5%SiO_2的制品,烧结性能与力学性能最佳。制品中形成的CaO·6Al_2O_3和CaO·Al_2O_3·2SiO_2复相促进了烧结,并使高温相接触紧密,改善了力学性能。  相似文献   

4.
氧化锰在锰铁渣中的热力学活度及金属与渣相间锰的分布   总被引:1,自引:0,他引:1  
研究了埋弧炉锰铁生产中由MnO-CaO-MgO-SiO2-Al2O3组成的标准炉渣。渣中Al2O3含量固定在5%。本研究目标集中在1500℃时锰铁渣中MnO的热力学活度上。为了达到校准的目的,在1300、1400和1500℃时重新测定了Mn在Pt-Mn合金中的热力学活度。在1500℃CO气氛下研究了碳饱和的Mn-Si-Fe-C合金与MnO-CaO-MgO-SiO2-Al2O3渣之间的平衡。在试验中发现,aMnO值随着MnO的增加而增大,趋向于随CaO/MgO比的增大而增大。aMnO值也随着碱度的增大而增大。在渣-金属平衡试验中,金属相中碳和硅的含量为反比关系。当硅含量一定时,由于Mn/Fe比增加,碳在金相中的溶解度增加。金属中含硅量随着渣中SiO2含量的增加而增加.以及当MgO代替渣中的CaO时,金属中含硅量增加。增大渣碱度使金属相含硅量降低。  相似文献   

5.
选用Si3N4,AlN,Al2O3和Sn2O3(或Nd2O3)粉末为原料,在1800~1950℃的温度范围内,1.0~3.0MPa氮气压力下烧吉(GPS),制备了性能优良的Re-α/β-Sialon(Re=Nd,Sm)陶瓷材料,利用XRD,EDS,TEM和EREM手段研究了材料的相组成,显微结构特性与其性能的关系。结果表明,其主晶相为长柱状的β-Silaon和近似等轴的Re-α-Sialon,晶界  相似文献   

6.
钢中夹杂物含量及其形态对钢力学性能的影响   总被引:9,自引:0,他引:9  
在实验室16kg真空感应炉上对铝镇静钢水用CaO-CaF2-Al和CaO-CaF2-Al-Ca进行精炼处理,降低了钢中硫含量和总氧含量,研究了钢中氧化物和硫化物夹杂的含理及其形态对钢力学性能,尤其是冲击韧性的影响。钢水经钙处理后,钢中硫含量和总氧含量都可降低到10ppm以下,且钢中Al2O3和MnS夹杂物能完全转变成硫化钙和铝酸钙,钢的转变温度低于-60℃,而且钢的各向异性消失。  相似文献   

7.
弹簧钢夹杂物形态控制   总被引:11,自引:1,他引:10  
李正邦  薛正良  张家雯 《钢铁》1999,34(4):20-23
分析了高应力条件下弹簧疲劳断裂的主要原因以及用稀土控制弹簧钢夹杂物形态的局限性。指出了MnO-Al2O3-SiO2或CaO-Al2O3-SiO2三元塑性夹杂物的成分范围,并以60Si2CrVA为例确定之与相平衡的钢液脱氧条件,提出了相应的工艺措施。  相似文献   

8.
RECl3与NH4HCO3的沉淀反应及伴生杂质的共沉淀行为   总被引:10,自引:3,他引:10  
本文通过对沉淀过程的pH值变化特征研究和沉淀物的组成分析,确定了NH4HCO3与RECl3的沉淀反应。研究了伴生金属离子Al3+、Fe2+、Mn2+、Ca2+、Mg2+随稀土的共沉淀行为,讨论了杂质离子对产品纯度的影响。  相似文献   

9.
二茂铁甲酸稀土配合物的合成与表征   总被引:1,自引:0,他引:1  
本文用稀土高氯酸盐RE(ClO_4)_3·nH_2O(n=8或9)与二茂铁甲酸钠盐NaL在无水乙醇中反应,合成了四种新的稀土配合物。通过元素分析、红外光谱、TG-DTA分析和x射线粉末衍射分析等手段研究了配合物的性质,确定这些配合物的组成为[REL_3(H_2O)_2]·nH_2O(式中RE为Pr、Nd、Sm、Y、n=2或),配体羧基以双齿配位。RE的配位数为8。  相似文献   

10.
利用渣-钢热力学平衡研究了CaO-Mgo-SiO2-Al2O3-FetO-MnO-P2O5渣系对钢水二次氧化的行为。得到了渣中FetO活度的近似表达式。在固定FetO摩尔分数的条件下,FetO的活度系数在炉渣碱度(NCaO+NMgO+NMnO)/(NSiO2+NAl2O3+Np2O5)达到2.5左右时出事最大值;而MnO的活度系数则随碱度的增加逐渐增大。γFetO(L)在NFetO固定时,随渣中(  相似文献   

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13.
<正>Minmetals Resources acquired the world’s largest copper mine under construction for USD5.85 billion.One after another,listed companies Jien Nickle,China Molybdenum and Chihong Zinc and Germanium raised money to get involved in overseas mining projects…SOEs and private enterprises are engaged in a frenzy of overseas mine purchasing.A reporter with Economic  相似文献   

14.
正Judging from China’s copper consumption field,the biggest consumption unit is electric power,which accounts for 47%of total consumption;it is followed by light industry sector,including household electrical appliance,machinery,durable goods and hardware etc,which accounts for 22%of total consumption;followed by transportation field,  相似文献   

15.
正In 2013,the Central Geological Prospecting Fund(CGPF)Project newly discovered 15 ore fields,including 3 large above ore fields,and 5medium sized ore fields.The reporter learned from the recently published"Annual Report of Central Geological Prospecting Fund Project(2013)"that,from 2006 to 2013 the CGPF  相似文献   

16.
正This year,the investment growth rate of real estate industry continued to slow down,sold area of commercial housing also dropped significantly,which brought huge pressure to the domestic air conditioning manufactures.In the first half of the year,by relying on high growth in national financial expenditure,along with investment in public infrastructure  相似文献   

17.
正Kang Yi,Honorary Chairman of China Nonferrous Metals Industry Association,said recently at the Forum on Development of the Non-ferrous Metals Industry in Central and Western China held in Zhengzhou that,as more and more electrolytic aluminum factories in Xinjiang came into operation,the electrolytic aluminum output of Xinjiang had reached2,275,000 tons in the first 7 months this year,  相似文献   

18.
正"Xinjiang project has been completed according to schedule,but total completion and total start of production are two different concepts,after completion it still needs a gradual process of reaching production target."On the morning of November 3,Shenhuo Coal Industry and Electricity Power told investors the above statement on the investor interaction platform.  相似文献   

19.
正The reporter learned from Guangdong Province Precious Metal Transaction Center that in 2013the Center maintained healthy development momentum,and had become the second largest precious metal transaction platform in China in terms of market size;currently Guangdong is quickening steps of financial innovation for the Center,aiming to build a transaction center with international core competitiveness.  相似文献   

20.
正On May 22,Baotou Rare Earth Industry Cooperation Consultation MeetingProject Agreement-signing Ceremony was held in Ningbo,nearly 40 enterprises from Ningbo,Guangdong,Hunan,and Shanxi participated in project consultation.After multi-lateral communication,agreements were signed for a total of 7 rare earth projects successfully.  相似文献   

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