Estimation of chlorophyll‐a concentration in Lake Tai,China using in situ hyperspectral data

Reflectance spectra of water in Lake Tai of East China were measured at 28 monitoring stations with an ASD FieldSpec spectroradiometer at an interval of 1.58 nm over five days in each month from June to August of 2004. Water samples collected at these stations were analyzed in the laboratory to determine chlorophyll‐a (chl‐a) concentration. Twenty‐eight spectral reflectance curves were standardized and correlated with chl‐a concentration. Examination of these curves reveals a peak reflectance at 719 nm. Chl‐a concentration level in the Lake was most closely correlated with the reflectance near 700 nm. If regressed against the reflectance at the wavelength of 667 nm (R ₆₆₇), chl‐a concentration was not accurately estimated at R ² = 0.494. Accuracy of estimation was improved to R ² = 0.817 using the maximum reflectance. A higher accuracy of 0.837 was achieved using the peak reflectance at 719 nm (R ₇₁₉) because it does not drift with the level of chl‐a concentration. The highest accuracy of estimation was achieved at R ² = 0.868 using R ₇₁₉/R ₆₆₇.     

Towards a practical remote-sensing model of suspended sediment concentrations in turbid waters using MERIS measurements

A new empirical index, termed the normalized suspended sediment index (NSSI), is proposed to predict total suspended sediment (TSS) concentrations in inland turbid waters using Medium Resolution Imaging Spectrometer (MERIS) full-resolution (FR) 300 m data. The algorithm is based on the normalized difference between two MERIS spectral bands, 560 and 760 nm. NSSI shows its potential in application to our study region – Poyang Lake – the largest freshwater lake in China. An exponential function (R² = 0.90, p < 0.01) accurately explained the variance in the in situ data and showed better performance for the TSS range 10–524 mg l^?1. The algorithm was then validated with TSS estimates using an atmospheric-corrected MERIS FR image. The validation showed that the NSSI algorithm was a more robust TSS algorithm than the band-ratio algorithms. Findings of this research imply that NSSI can be successfully used on MERIS images to obtain TSS in Poyang Lake. This work provided a practical remote-sensing approach to estimate TSS in the optically and hydrologically complex Poyang Lake and the method can be easily extended to other similar waters.     

A new method to generate a high-resolution global distribution map of lake chlorophyll

A new method was developed, evaluated, and applied to generate a global dataset of growing-season chlorophyll-a (chl) concentrations in 2011 for freshwater lakes. Chl observations from freshwater lakes are valuable for estimating lake productivity as well as assessing the role that these lakes play in carbon budgets. The standard 4 km NASA OceanColor L3 chlorophyll concentration products generated from MODIS and MERIS sensor data are not sufficiently representative of global chl values because these can only resolve larger lakes, which generally have lower chl concentrations than lakes of smaller surface area. Our new methodology utilizes the 300 m-resolution MERIS full-resolution full-swath (FRS) global dataset as input and does not rely on the land mask used to generate standard NASA products, which masks many lakes that are otherwise resolvable in MERIS imagery. The new method produced chl concentration values for 78,938 and 1,074 lakes in the northern and southern hemispheres, respectively. The mean chl for lakes visible in the MERIS composite was 19.2 ± 19.2, the median was 13.3, and the interquartile range was 3.90–28.6 mg m^?3. The accuracy of the MERIS-derived values was assessed by comparison with temporally near-coincident and globally distributed in situ measurements from the literature (n = 185, RMSE = 9.39, R² = 0.72). This represents the first global-scale dataset of satellite-derived chl estimates for medium to large lakes.     

Quantifying suspended sediment concentration in subglacial sediment plumes discharging from two Svalbard tidewater glaciers using Landsat-8 and in situ measurements

Marine-terminating outlet glaciers discharge mass through iceberg calving, submarine melting, and meltwater run-off. While calving can be quantified by in situ and remote-sensing observations, meltwater run-off, the subglacial transport of meltwater, and submarine melting are not well constrained due to inherent difficulties observing the subglacial and proglacial environments at tidewater glaciers. Remote-sensing and in situ measurements of surface sediment plumes, and their suspended sediment concentration (SSC), have been used as a proxy for glacier meltwater run-off. However, this relationship between satellite reflectance and SSC has predominantly been established using land-terminating glaciers. Here, we use two Svalbard tidewater glaciers to establish a well-constrained relationship between Landsat-8 surface reflecance and SSC and argue that it can be used to measure relative meltwater run-off at tidewater glaciers throughout a summer melt season. We find the highest correlation between SSCs and Landsat-8 surface reflectance by using the red + NIR band combination (r² = 0.76). The highest correlation between SSCs and in situ field spectrometer measurements is in the 740–800 nm wavelength range (r² = 0.85), a spectral range not currently measured by Landsat. Additionally, we find that in situ and Landsat-8 measurements for surface reflectance of SSCs are not interchangeable and therefore establish a relationship for each detection method. We then use the Landsat-8 relationship to calculate total surface sediment load, finding a strong correlation between total surface sediment load and a proxy for meltwater run-off (r² ≥ 0.89). Our results establish a new metric to calculate SSCs from Landsat-8 surface reflectance and demonstrate how the SSC of subglacial sediment plumes can be used to monitor relative seasonal meltwater discharge at tidewater glaciers.     

Mapping inland lake water quality across the Lower Peninsula of Michigan using Landsat TM imagery

The number, size, and distribution of inland freshwater lakes present a challenge for traditional water-quality assessment due to the time, cost, and logistical constraints of field sampling and laboratory analyses. To overcome this challenge, Landsat imagery has been used as an effective tool to assess basic water-quality indicators, such as Secchi depth (SD), over a large region or to map more advanced lake attributes, such as cyanobacteria, for a single waterbody. The overarching objective of this research application was to evaluate Landsat Thematic Mapper (TM) for mapping nine water-quality metrics over a large region and to identify hot spots of potential risk. The second objective was to evaluate the addition of landscape pattern metrics to test potential improvements in mapping lake attributes and to understand drivers of lake water quality in this region. Field-level in situ water-quality measurements were collected across diverse lakes (n = 42) within the Lower Peninsula of Michigan. A multicriteria statistical approach was executed to map lake water quality that considered variable importance, model complexity, and uncertainty. Overall, band ratio radiance models performed well (R² = 0.65–0.81) for mapping SD, chlorophyll-a, green biovolume, total phosphorus (TP), and total nitrogen (TN) with weaker (R² = 0.37) ability to map total suspended solids (TSS) and cyanobacteria levels. In this application, Landsat TM and pattern metrics showed poor ability to accurately map non-purgable organic carbon (NPOC) and diatom biovolume, likely due to a combination of gaps in temporal overpass and field sampling and lack of signal sensitivity within broad spectral channels of Landsat TM. The composition and configuration of croplands, urban, and wetland patches across the landscape were found to be moderate predictors of lake water quality that can complement lake remote-sensing data. Of the 4071 lakes, over 4 ha in the Lower Peninsula, approximately two-thirds, were identified as mesotrophic (n = 2715). This application highlights how an operational tool might support lake decision-making or assessment protocols to identify hot spots of potential risk.     

Using hyperspectral remote sensing to estimate chlorophyll‐a and phycocyanin in a mesotrophic reservoir

This research estimates phytoplankton pigment concentrations (chlorophyll‐a (chl‐a) and phycocyanin (PC)) from hyperspectral Airborne Imaging Spectrometer for Applications (AISA) imagery. AISA images were acquired for a meso‐eutrophic reservoir in Central Indiana, USA. Concurrent with the airborne image acquisition, in situ water samples and reflectances were collected. The water samples were subsequently analysed for pigment concentrations, and in situ measured reflectance spectra were used for calibrating the AISA images. Spectral indices, derived from the AISA reflectance spectra, were regressed against the measured pigment concentrations to derive algorithms for estimating chl‐a and PC. The relationship between the pigment concentrations and the spectral indices were analysed and evaluated. The results indicate that the highest correlation occurred between chl‐a and a near‐infrared to red ratio (coefficient of determination R ²?=?0.78) and between PC and the reflectance trough at 628 nm (R ²?=?0.80). The relationship between PC and the reflectance at 628 nm provides an approach to the estimation of cyanobacteria concentration from hyperspectral imagery, which facilitates water‐quality authorities or management agencies in making well‐informed management decisions.     

Reflectance spectroscopy for the assessment of soil salt content in soils of the Yellow River Delta of China

There has been growing interest in the use of reflectance spectroscopy as a rapid and inexpensive tool for soil characterization. In this study, we collected 95 soil samples from the Yellow River Delta of China to investigate the level of soil salinity in relation to soil spectra. Sample plots were selected based on a field investigation and the corresponding soil salinity classification map to maximize variations of saline characteristics in the soil. Spectral reflectances of air‐dried soil samples were measured using an Analytical Spectral Device (ASD) spectrometer (350–2500 nm) with an artificial light source. In the Yellow River Delta, the dominant chemical in the saline soil was NaCl and MgCl₂. Soil spectra were analysed using two‐thirds of the available samples, with the remaining one‐third withheld for validation purposes. The analysis indicated that with some preprocessing, the reflectance at 1931–2123 nm and 2153–2254 nm was highly correlated with soil salt content (S _SC). In the spectral region of 1931–2123 nm, the correlation R ranged from ?0.80 to ?0.87. In the region of 2153–2254 nm, the S _SC was positively correlated with preprocessed reflectance (0.79–0.88). The preprocessing was done by fitting a convex hull to the reflectance curve and dividing the spectral reflectance by the value of the corresponding convex hull band by band. This process is called continuum removal, and the resulting ratio is called continuum removed reflectance (CR reflectance). However, the S _SC did not have a high correlation with the unprocessed reflectance, and the correlation was always negative in the entire spectrum (350–2500 nm) with the strongest negative correlation at 1981 nm (R = ?0.63). Moreover, we found a strong correlation (R = 0.91) between a soil salinity index (S _SI: constructed using CR reflectance at 2052 nm and 2203 nm) and S _SC. We estimated S _SC as a function of S _SI and S _SI′ (S _SI′: constructed using unprocessed reflectance at 2052 nm and 2203 nm) using univariate regression. Validation of the estimation of S _SC was conducted by comparing the estimated S _SC with the holdout sample points. The comparison produced an estimated root mean squared error (RMSE) of 0.986 (S _SC ranging from 0.06 to 12.30 g kg^?1) and R ² of 0.873 for S _SC with S _SI as independent variable and RMSE of 1.248 and R ² of 0.8 for S _SC with S _SI′ as independent variable. This study showed that a soil salinity index developed for CR reflectance at 2052 nm and 2203 nm on the basis of spectral absorption features of saline soil can be used as a quick and inexpensive method for soil salt‐content estimation.     

Detection of mosaic virus disease in cassava plants by sunlight-induced fluorescence imaging: a pilot study for proximal sensing

Cassava mosaic disease (CMD) is a prominent virus infection that causes considerable crop damage and yield reduction. Early detection of crop damage by remote sensing could be a useful tool for initiating remedial measures to reduce further crop damage. This article presents a non-destructive method for detection and classification of CMD infection, based on the red:far-red chlorophyll (chl) fluorescence image ratio. This pilot study was carried out in 14 varieties of potted cassava plants (Manihot esculenta Crantz) with a multispectral imaging system (MSIS) consisting of an electron multiplying charge coupled device (EMCCD) camera. Sunlight-induced chl fluorescence (SICF) images of plant leaves were recorded using the MSIS at the Fraunhofer lines of O₂-B at 687 nm and O₂-A at 759.5 nm and their off-lines at 684 and 757.5 nm. The recorded images were analysed using the Fraunhofer line discrimination (FLD) technique to extract the SICF from the solar reflectance in the recorded images. The chl fluorescence image ratio (red:far-red, F₆₈₇:F₇₆₀) was computed and correlated with the laser-induced chl fluorescence (LICF) ratio (F₆₈₅:F₇₃₅) determined by point monitoring, chl content variation, and the net photosynthetic rate (P_n). The scatter plot of the F₆₈₇:F₇₆₀ image ratio showed good discrimination between different levels of CMD infection as evidenced by the high sensitivity and specificity values. It is observed that the fluorescence image ratio (F₆₈₇:F₇₆₀) has a good correlation with P_n (coefficient of determination (R²) = 0.85), chl content (R² = 0.82), and the LICF ratio (F₆₈₅:F₇₃₅) (R² = 0.80), thereby highlighting the potential of the SICF image ratio in the discrimination of CMD infection. The results clearly indicate that changes in the red:far-red fluorescence image ratio due to CMD stress can easily be detected at an early stage and the technique has great potential for monitoring the health of crops and vegetation from proximal sensing platforms.     

Measurement of water colour using AVIRIS imagery to assess the potential for an operational monitoring capability in the Pamlico Sound Estuary,USA

The monitoring of water colour parameters can provide an important diagnostic tool for the assessment of aquatic ecosystem condition. Remote sensing has long been used to effectively monitor chlorophyll concentrations in open ocean systems; however, operational monitoring in coastal and estuarine areas has been limited because of the inherent complexities of coastal systems, and the coarse spectral and spatial resolutions of available satellite systems. Data were collected using the National Aeronautics and Space Administration (NASA) Advanced Visible–Infrared Imaging Spectrometer (AVIRIS) flown at an altitude of approximately 20 000 m to provide hyperspectral imagery and simulate both MEdium Resolution Imaging Spectrometer (MERIS) and Moderate Resolution Imaging Spectrometer (MODIS) data. AVIRIS data were atmospherically corrected using a radiative transfer modelling approach and analysed using band ratio and linear regression models. Regression analysis was performed with simultaneous field measurements data in the Neuse River Estuary (NRE) and Pamlico Sound on 15 May 2002. Chlorophyll a (Chl a) concentrations were optimally estimated using AVIRIS bands (9.5 nm) centred at 673.6 and 692.7 nm, resulting in a coefficient of determination (R ²) of 0.98. Concentrations of Chromophoric Dissolved Organic Matter (CDOM), Total Suspended Solids (TSS) and Fixed Suspended Solids (FSS) were also estimated, resulting in coefficients of determination of R ² = 0.90, 0.59 and 0.64, respectively. Ratios of AVIRIS bands centred at or near those corresponding to the MERIS and MODIS sensors indicated that relatively good satellite‐based estimates could potentially be derived for water colour constituents at a spatial resolution of 300 and 500 m, respectively.     

Estimation of chlorophyll-a concentration in coastal waters with HJ-1A HSI data using a three-band bio-optical model and validation

Accurate assessment of phytoplankton chlorophyll-a (chl-a) concentration in turbid waters by means of remote sensing is challenging because of the optical complexity of case 2 waters. We applied a bio-optical model of the form [R^–1(λ₁) – R^–1(λ₂)](λ₃), where R(λ_i) is the remote-sensing reflectance at wavelength λ_i, to estimate chl-a concentration in coastal waters. The objectives of this article are (1) to validate the three-band bio-optical model using a data set collected in coastal waters, (2) to evaluate the extent to which the three-band bio-optical model could be applied to the spectral radiometer (SR) ISI921VF-512T data and the hyperspectral imager (HSI) data on board the Chinese HJ-1A satellite, (3) to evaluate the application prospects of HJ-1A HSI data in case 2 waters chl-a concentration mapping. The three-band model was calibrated using three SR spectral bands (λ₁ = 664.9 nm, λ₂ = 706.54 nm, and λ₃ = 737.33 nm) and three HJ-1A HSI spectral bands (λ₁ = 637.725 nm, λ₂ = 711.495 nm, and λ₃ = 753.750 nm). We assessed the accuracy of chl-a prediction with 21 in situ sample plots. Chl-a predicted by SR data was strongly correlated with observed chl-a (R² = 0.93, root mean square error (RMSE) = 0.48 mg m^–3, coefficient of variation (CV) (RMSE/mean(chl-a_mea)) = 3.72%). Chl-a predicted by HJ-1A HSI data was also closely correlated with observed chl-a (R² = 0.78, RMSE = 0.45 mg m^–3, CV (RMSE/mean(chl-a_mea)) = 7.51%). These findings demonstrate that the HJ-1A HSI data are promising for quantitative monitoring of chl-a in coastal case-2 waters.     

Detecting marine intrusion into rivers using EO-1 ALI satellite imagery: Modaomen Waterway,Pearl River Estuary,China

Because of increasing marine intrusion into the Pearl River Estuary (PRE) in China, salinity has become one of the important and necessary hydrological and water quality monitoring parameters. In this research, we examined the relationships between the reflectance from Earth Observing-1 (EO-1) Advanced Land Imager (ALI) satellite imagery and total suspended solids (TSS) based on the synchronous in situ spectra analysis of the river water, in an attempt to detect salinity using remote sensing technique. The study site was the Modaomen Waterway in the PRE, Guangdong Province, China. We found a strong negative linear relationship between in situ reflectance at 549 nm and TSS concentrations (R ²?=?0.91, p < 0.001) when the salinity of the river was less than 1.46‰. It indicates that the TSS near Pinggang and Nanzhen in Modaomen Waterway of PRE tends to be dominated by organic mater carried by the particles and this is one major reason for the inverse relation between reflectance and TSS. Meanwhile, a strong correlation was observed between salinity and TSS (R ²?=?0.70, p < 0.001). The salinity-TSS model accounted for 70% of variation in salinity and allowed the estimation of salinity with a root mean square error (RMSE) of less than 0.036‰ when the TSS concentrations were between 7.4 and 28 mg l^?1. Therefore, we were able to develop a new method of detecting surface salinity of the river estuary from the calibrated EO-1 ALI reflectance data. The EO-1 ALI derived surface salinity and TSS concentrations were validated using in situ data that were collected on 18 December 2005, synchronous with EO-1 ALI satellite imagery acquisition. The results showed that the semi-empirical relationships are capable of deducing the TSS concentrations and then salinity from EO-1 ALI imagery in the PRE under low salinity. The methodology of detecting salinity from ALI imagery provides potential to monitor coastal saltwater intrusion and provides the water supply and conservancy authorities with useful spatial information to spatially understand and manage the marine intrusion.     

Estimation of chlorophyll‐a concentration and trophic states for inland lakes in Northeast China from Landsat TM data and field spectral measurements

Landsat TM data and field spectral measurements were used to evaluate chlorophyll‐a (Chl‐a) concentration levels and trophic states for three inland lakes in Northeast China. Chl‐a levels were estimated applying regression analysis in the study. The results obtained from the field reflectance spectra indicate that the ratio between the reflectance peak at 700 nm and the reflectance minimum at 670 nm provides a relatively stable correlation with Chl‐a concentration. Their determination of coefficients R ² is 0.69 for three lakes in the area. From Landsat TM data, the results show that the most successful Chl‐a was estimated from TM3/TM2 with R ² = 0.63 for the two lakes on 26 July 2004, from TM4/TM3 with R ² = 0.89 for the two lakes on 14 October 2004, and from the average of TM2, TM3 and TM4 with R ² = 0.72 for the three lakes tested on 13 July 2005. These results are applicable to estimate Chl‐a from satellite‐based observations in the area. We also evaluate the trophic states of the three lakes in the region by employing Shu's modified trophic state index (TSI_M) for the Chinese lakes' eutrophication assessment. Our study presents the TSI_M from different TM data with R ² more than 0.73. The study shows that satellite observations are effectively applied to estimate Chl‐a levels and trophic states for inland lakes in the area.     

Developing a two-step retrieval method for estimating total suspended solid concentration in Chinese turbid inland lakes using Geostationary Ocean Colour Imager (GOCI) imagery

Total suspended solid (TSS) concentration is an important water quality parameter. Mapping its varying distribution using satellite images with high temporal resolution is valuable for studying suspended sediment transportation and diffusion patterns in inland lakes. A total of 255 sites were used to make remote-sensing reflectance measurements and surface water sampling at four Chinese inland lakes, i.e. Taihu Lake, Chaohu Lake, Dianchi Lake, and the Three Gorges Reservoir, at different seasons. A two-step retrieval method was then developed to estimate TSS concentration for contrasting Chinese inland lakes, which is described in this article. In the first step, a cluster method was applied for water classification using eight Geostationary Ocean Colour Imager (GOCI) channel reflectance spectra simulated by spectral reflectance measured by an Analytical Spectral Devices (ASD) Inc. spectrometer. This led to the classification of the water into three classes (1, 2, and 3), each with distinct optical characteristics. Based on the water quality, spectral absorption, and reflectance, the optical features in Class 1 were dominated by TSS, while Class 3 was dominated by chl-a and the optical characteristics of Class 2 were dominated jointly by TSS and chl-a. In the second step, class-specific TSS concentration retrieval algorithms were built. We found that the band ratio Band 8/Band 4 was suitable for Class 1, while the band ratio of Band 7/Band 4 was suitable for both Class 2 and Class 3. A comprehensive determination value, combining the spectral angle mapper and Euclidean distance, was adopted to identify the classes of image pixels when the method was applied to a GOCI image. Then, based on the pixel’s class, the class-specific retrieval algorithm was selected for each pixel. The accuracy analysis showed that the performance of this two-step method was improved significantly compared to the unclassed method: the mean absolute percentage error decreased from 38.9% to 24.3% and the root mean square error decreased from 22.1 to 16.5 mg l^–1. Finally, the GOCI image acquired on 13 May 2013 was used as a demonstration to map the TSS concentration in Taihu Lake with a reasonably good accuracy and highly resolved spatial structure pattern.     

Simultaneous determination of aerosol optical thickness and surface reflectance using ASTER visible to near-infrared data over land

An innovative method for the determination of aerosol optical thickness (AOT) and surface reflectance for operational use of Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) visible to near-infrared data is presented. This method is designed to obtain the atmospheric parameters needed in the correction of the image. This method is based on a simplified radiative transfer equation describing the relation between the ground surface reflectance, AOT and top-of-atmosphere reflectance. By exploiting the ASTER dual-angle view capabilities in band 3N (Nadir) and band 3B (Backwards), surface reflectance and AOT can be retrieved synchronously. Thus, it solves the problem of separating atmospheric radiance from the transmitted radiance of the surface to some extent. After applying this new atmospheric correction method to three areas of ASTER images, Beijing urban city, the Heihe River Basin and Hong Kong of China, ASTER surface reflectance products (AST07) were obtained. AOT values from in situ measurements of CIMEL Electronique 318 Sun Photometers or AERONET (AErosol RObotic NETwork) and surface reflectance in situ measured using an Analytical Spectral Device (ASD) Field Spec spectral radiometer are used for validation. AOT derived from the new method is consistent with in situ station measurements from CIMEL Electronique 318 Sun Photometer and level 2.0 data from AERONET, with correlation coefficient (R ²) of 0.98 and root mean square error of 0.05, whereas Multi-angle Imaging Spectroradiometer AOT products underestimate AERONET AOT and Moderate-Resolution Imaging Spectroradiometer AOT products overestimate AERONET AOT in these regions. More encouraging is the comparison between the corrected surface reflectance, AST07 and ASD measurements. Root mean square error of AST07 and retrieved surface reflectance are as follows: band 1 (556 nm) = 0.04 and 0.05; band 2 (661 nm) = 0.036 and 0.035; band 3 (807 nm) = 0.056 and 0.038, which suggests that compared with AST07 in bands 2 and 3, retrieved surface reflectance has better agreement with measured reflectance from ASD.     

Development of a MODIS data based algorithm for retrieving nearshore sea surface salinity along the northern Gulf of Mexico coast

Remote sensing algorithms for retrieval of Sea Surface Salinity (SSS) were generally developed for deep ocean waters while practical applications of SSS are commonly involved in coastal (particularly nearshore) waters. To fill the gap, this paper presents a new SSS algorithm, called Nearshore SSS Algorithm, developed using the Artificial Neural Networks toolbox in the MATLAB Program and 7 years of cloud-free Moderate Resolution Imaging Spectroradiometer (MODIS) Aqua data as well as in situ data collected from United States Geological Survey (USGS) stations along the Northern Gulf of Mexico coast. The independent input variables involved in the new algorithm include the water-leaving reflectance at 412 nm, 443 nm, 488 nm, 555 nm, 678 nm, and 645 nm of MODIS Aqua sensor. Results of sensitivity analysis indicate that SSS in nearshore waters is most sensitive to reflectance at 412 nm and 488 nm, followed by the reflectance at 555 nm and 645 nm. While reflectance at 678 nm is also important, reflectance at 443 nm is the least important to SSS in nearshore waters, providing new insights into SSS in coastal waters. MODIS data collected from January 2012 to September 2014 were used for validation of the nearshore SSS algorithm. The linear correlation coefficient of this algorithm for Louisiana coast was 0.7256 and 0.6985 for the development and validation, respectively. A unique feature of this paper is that while the new algorithm is particularly useful to the retrieval of SSS in nearshore waters, it is also expanded to further offshore waters, providing reliable SSS data for various applications of coastal environment and resources management particularly along the northern Gulf of Mexico coast.     

Bio‐optical properties and estimation of the optically active substances in Lake Tianmuhu in summer

Bio‐optical properties in an optically complex and biologically productive region of Lake Tianmuhu were determined in three cruises from June to August 2006. The concentrations of three optically active substances, tripton C _Tripton (calculated from total suspended matter and chlorophyll‐a (Chla) and phaeophytin‐a (Pa)), phytoplankton pigment C _Chla+Pa , and chromophoric dissolved organic matter (CDOM) a _CDOM(440), were predicted from the estimated irradiance reflectance based on in situ measurements and laboratory analyses. The total relative contributions of phytoplankton, tripton, CDOM and pure water over the range of photosynthetically active radiation (PAR) (400–700 nm) were 36.1%, 24.2%, 15.9% and 23.8%, respectively. The dominant contribution of phytoplankton to the total absorption was due to high phytoplankton pigment concentration. The range and variation in irradiance reflectance and diffuse attenuation coefficient derived from a bio‐optical model, based on inherent optical properties, compared well with the measured variability. A reasonably strong relationship (R² = 0.92) was observed between irradiance reflectance at 780 nm R(780) and C _Tripton. For our data set, the best algorithm for C _Chla+Pa used the three‐band reflectance model [R ^?1(688)?R ^?1(717)]×R(747). The a _CDOM(440) could be estimated using the ratio of irradiance reflectance R(682)/R(555). The retrieval accuracy (R²) of tripton, phytoplankton pigment and CDOM was 0.92, 0.87 and 0.91, respectively, while the rms. error was 0.90 mg l^?1 (18.2%), 3.27 µg l^?1 (14.8%) and 0.073 m^?1 (15.3%), respectively. Estimation of the concentrations of the three optically active substances was reasonably accurate based on inherent optical properties measurement.     

Potential signatures of heavy metal complexes in lichen reflectance spectra

Lichens are sensitive to atmospheric pollutants emitted from anthropogenic activities and are thus effective biomonitors. A variety of heavy metals, such as nickel (Ni), iron (Fe), lead (Pb), copper (Cu), and cadmium (Cd), can be emitted by metal smelters. The purpose of this study was twofold: (1) to measure the spectral reflectance properties (350–2500 nm) of expected heavy metal complexes in lichens (oxalates and sulphides); and (2) to determine whether these complexes contribute features to reflectance spectra of lichens from the vicinity of a heavy metal smelter. Some metal oxalate spectra are characterized by crystal field transition absorption bands in the 500–1300 nm region, which are specific to the particular metal cation they contain and its oxidation state. The 1900–2500 nm region exhibits multiple absorption bands attributable to the oxalate molecule. The metal sulphide reflectance spectra are characterized by generally low reflectance and few if any strong or diagnostic spectral features; those that are found can be related to a specific cation and its oxidation state. These spectra were used to determine whether reflectance spectra of a diverse suite of lichens collected downwind of a smelter showed spectral evidence indicative of heavy metal oxalates or sulphides. The lichen spectra, coupled with the oxalate and sulphide spectra and independently determined heavy metal concentration, failed to reveal spectral features that could be unambiguously related to heavy metal complexes. This was likely due to a number of causes: lichen reflectance spectra have absorption bands that overlap those of oxalates; oxalate and sulphide concentrations may have been too low to allow for their unambiguous identification, and lichen spectra are naturally diverse in the region below 1300 nm. There were no strong or significant linear trends between metal concentrations and distance from the smelter (coefficient of determination (R²) values <0.05), or between absorption band depths in the lichen spectra and distance from the smelter (R² values <0.06). This was likely due to the inclusion of multiple lichen species in the analysis, which may interact with airborne pollutants in different ways, and microenvironmental effects.     

Determination of seasonal variations in solar energy utilization by the leaves of Washington navel orange trees (Citrus sinensis L. Osbeck)

Definition of both quality and quantity of energy consumption of crops by recently developed remote sensing methods has been an important factor in the control of sustainable bioenergy production in terms of food security. This study was conducted to find the critical physiological stages of orange trees from their energy supply and energy balances using remote sensing methods. The relationships between absorbed photosynthetically active radiation (APAR) and chlorophyll content (chl) of the leaves at different growth stages were investigated. Canopy reflectance by hand‐held spectroradiometer and total chl analysis at the laboratory were measured simultaneously from the random samples taken from four different parts of orange trees in orchards, each orchard being at a different age group. Reflectance measurements were conducted between 450?nm and 900?nm wavelength at four different bands (three visible bands and one near‐infrared band) at the four basic physiological periods of orange trees. Reflectance values measured in the field were converted to APAR (W?m^?2) and the chl values were determined in mg?ml^?1. According to the statistical analysis, there was a strong relationship between APAR at the bands of 450–520?nm (blue) and 630–690?nm (red) and the chlorophyll content (?p?0.01; R ²?=?0.750 at blue wavelength and R²?=?0.770 at red wavelength) in June (fruit setting stage). These results showed that the relationships between chl and APAR values were very strong despite low levels of APAR at this stage, in comparison to the other ones. Amongst all the stages, APAR values were the highest in November. Another important result was that Washington navel trees unexpectedly had the highest APAR during the dormancy stage. These results suggested that the relationships between PAR utilization and chlorophyll content were important for tree health and indirect yield of per annum plants such as citrus. The values obtained from the leaves of orange trees at different physiological periods were more important than those relationships for the trees of different ages.     

Satellite survey of seasonal trophic status and occasional anoxic ‘malaïgue’ crises in the Thau lagoon using MERIS images

The Thau lagoon, located in southern France, suffers episodically from anoxic crises locally known as ‘malaïgue’. Such crises mostly occur under warm conditions, low winds leading to a strong eutrophication of the lagoon. The development of a sulphur bacterium sometimes gives locally to the waters a ‘milky turquoise’ appearance and leads to shellfish mortality. One of the indicators of the eutrophication status of the lagoon can be surveyed by the chlorophyll product provided by remote sensing images such as Medium Resolution Imaging Spectrometer (MERIS). In this paper we compare chl2 (or algal2) estimations provided by MERIS level 2 products and the ground measurements of chlorophyll a concentrations in water and we propose a linear correction of the chl2 MERIS product. The corrected chl2 estimations obtained over four years are analysed to understand the seasonal evolution of the trophic status of the Thau lagoon. We also study the influence of the anoxic crises of summers 2003 and 2006 on the chl2 estimations and we find a strong correlation between chl2 and the oxygen percentage at 1 m depth (0.70 for measurements in summers 2003 and 2006).     

Absorption characteristics of ocean water in the Arabian Sea during winter bloom from in situ measurements and Oceansat 2 OCM and MODIS data

In the northern Arabian Sea, blooms usually occur during the northeast monsoon (November–January) and inter-monsoon (February–April) periods. After death, these phytoplankton blooms produce massive subsurface zones of low dissolved oxygen levels that have a major impact on the ocean water ecosystem. Many studies have been done to identify the bloom in this region, but those on the optical properties of bloom water are scarce. The present study emphasizes the optical properties (inherent) of the bloom water in the study region using in situ and satellite data. The total absorption coefficient of ocean water was measured from in situ radiance data collected in the northern Arabian Sea from the Sagar Sampada cruise (SS-286) during March 2011. The same data were also derived from the top-of-atmosphere radiance and remote sensing reflectance of the Oceansat 2 Ocean Colour Monitor (OCM-2) and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) sensors, respectively. A comparison between measured (in situ) and retrieved total absorption coefficients from OCM-2 was made. The measured and retrieved absorption coefficients are in good agreement. Root mean square errors between measured and retrieved absorption coefficients are 0.018 m^?1, 0.026 m^?1, and 0.034 m^?1 for 490 nm, 510 nm, and 555 nm, respectively. An inter-comparison of total absorption properties retrieved from OCM-2 and MODIS data in the region of one degree radius around the stations was also made. A fairly good match was observed on 10, 14, and 16 March 2011 (coefficient of determination, R² = 0.75, 0.87, and 0.62, respectively) for the blue band (490 nm) and (R² = 0.77, 0.79, and 0.71, respectively) the green band (555 nm). The study demonstrates the potential of using remote-sensing optical data for identifying bloom waters.