共查询到16条相似文献,搜索用时 156 毫秒
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失水甘油基三甲基氯化铵(GTMAC)有高反应活性的醚键,可用于有机合成和作为接枝改性剂。以环氧氯丙烷(EPIC)与三甲胺(TMA)反应水法合成GTMAC,实验得出GTMAC的最佳合成条件为:n(TMA)∶n(EPIC)为0.3,反应时间6.5 h,反应温度20℃,最佳溶剂为EPIC,GTMAC的收率为92.5%,测定其熔点为137~139℃。并对产物的环氧值、吸湿性进行了测试,通过IR对产品进行了表征。 相似文献
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甲苯二异氰酸酯和硼砂交联改性聚乙烯醇胶水的研究 总被引:6,自引:0,他引:6
探讨了硼砂和甲苯二异氰酸酯 ( TDI)对聚乙稀醇 ( PVA)胶水进行交联改性。采用正交实验法研究硼砂和 TDI的加入量对 PVA粘合剂的耐水性能和剥离强度的影响。利用硼砂、TDI与 PVA反应产物的水不溶性判断该交联反应的进程。研究结果表明 ,少量硼砂和 TDI能较大程度地提高 PVA胶水的耐水性能和粘结性能 相似文献
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以麦糟(RSG)为基材,氯乙酸为醚化剂,NaOH为催化剂,制备了醚化改性麦糟(MSG),研究了MSG对亚甲基蓝(MB)的吸附性能.考察了改性条件对MB吸附效果的影响.结果表明,在固液比1:50(g:mL)、n(NaOH):n(ClCH2COOH)=1.25:1.0、醚化温度为75℃、醚化时间为2.5 h的条件下,制得的MSG对MB吸附效果最好,吸附量达到201.20 mg/g.采用SEM、N2吸附-脱附、FTIR、XPS和零电荷点技术对改性前后麦糟的外观形貌、比表面积和孔径分布、表面性质等进行了表征.Langmuir方程和拟二级动力学方程可很好地描述MSG吸附MB的过程,化学吸附为其主要吸附方式. 相似文献
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以葡萄糖衍生物、碱金属氢氧化物、氯化苄为原料,以正辛烷为带水剂,经Williamson醚化反应合成了3个苄醚化葡萄糖衍生物。考察了带水剂、碱、苄醚化试剂及投料比对反应的影响,得到优化的反应条件为:n(底物羟基)∶n(氢氧化钾或氢氧化钠)∶n(氯化苄)=1.00∶(1.10~1.15)∶(1.10~1.15),正辛烷为带水剂,125~130℃保温回流脱水反应4 h,在该条件下产物产率为96.8%~98.2%。产物结构经FTIR、UPLC-MASS、1HNMR确证。 相似文献
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我国聚乙烯醇改性技术进展 总被引:3,自引:0,他引:3
综述了国内聚乙烯醇改性技术的进展情况.改性方法包括:共聚、共混和聚合物后反应(涉及醚化、醇化、缩醛化、交联、降解及表面改性等)三大类.较为详细地介绍了聚乙烯醇纤维的改性.并对我国聚乙烯醇工业的发展进行了展望. 相似文献
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Conditions for the preparation of etherified hemicelluloses from sugarcane bagasse with 2, 3‐epoxypropyltrimethylammonium chloride (ETA) using sodium hydroxide as a catalyst in aqueous solution were studied comparatively. The extent of the etherification was measured by yield percentage and degree of substitution. The effects of reaction time of 3–7 h, reaction temperature of 50–80°C, temperature of alkaline activation of 30–60°C, and time of alkaline activation of 0–60 min on the reaction yield and degree of substitution were investigated in detail. The overall yield and degree of substitution were varied from 35.2 to 41.9% and from 0.14 to 0.33, respectively, by changing the reaction temperature and duration as well as time and temperature of alkaline activation. The new materials were characterized by FT‐IR and 13C NMR spectroscopy, thermal analysis as well as GPC. It was found that the thermal stability of the hemicellulosic ethers decreased after chemical modification, and the molecular weights of the etherified hemicelluloses were lower than those of the native hemicelluloses. 13C NMR spectra gave the evidence for etherification reaction and the quaternization of hemicelluloses occurred mainly at C‐3 position. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
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聚乙烯醇缩醛型胶粘剂可通过聚乙烯醇(PVA)与醛类缩合而得,其性质取决于原料PVA的结构、水解程度、醛类的化学结构和缩醛化程度等。将PVA与乙醛酸(无毒、无味和不挥发)进行缩醛化反应,可制备出一种安全环保型聚乙烯醇缩乙醛酸树脂(PVGa)胶粘剂。以n(乙醛酸)∶n(PVA中-OH基)比例、反应时间、反应温度和PVA水溶液浓度为试验因素,缩醛度为衡量指标,采用正交试验法优选出制备PVGa的最适宜工艺条件。结果表明:当反应温度为80℃、PVA水溶液浓度为15%、n(乙醛酸)∶n(PVA中-OH基)=1∶5和反应时间为40min时,PVGa的缩醛度为39.85%;PVGa的吸湿性能比PVA高4~6倍,PVGa的力学性能优于PVA,两者的热失重情况基本相似。 相似文献
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This work deals with the incorporation of reactive isocyanate groups into polymer additives, which could be potentially used to modify the rheological properties of lubricating greases by reinforcing the role of traditional thickening agents. Thus, a batch of partially protected poly(vinylalcohol) (PVA) copolymers was successfully synthesized. Some of their OH groups were blocked as tetrahydropyranyl (THP) ethers (PVA–THP), while the spare hydroxyl groups were further functionalized with NCO pendant groups by reaction with 1,6-hexamethylene diisocyanate, leading to several isocyanate-functionalized PVA-based polymers (PVA–THP–NCO), which were tested as rheology modifiers of lithium lubricating greases. The highest protection degree of hydroxyl groups achieved as THP-ether was 58.5% and the recovered polymers were isolated with excellent yields (close to 90% in most cases). NCO-functionalized PVA-based polymers (PVA–THP–NCO) exerted a significant rheological modification in lithium 12-hydroxystearate lubricating greases, increasing the values of the linear viscoelastic functions. The influence of the degree of protection and later functionalization of PVA on the rheological properties of PVA–THP–NCO-additivated lubricating greases is discussed. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
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The crosslinking reaction of poly(vinyl alcohol) (PVA) by esterification using poly(acrylic acid) (PAA) as a crosslinking reagent was investigated to obtain highly insoluble PVA materials. Blend films of PVA and PAA (PVA/PAA = 8/2) were prepared to examine the effect of degree of neutralization (DN) in PAA and heat‐treatment conditions on the degree of crosslinking reaction. The degree of crosslinking reaction varied significantly when the DN of PAA changed. The optimum DN for the crosslinking reaction was in the range of 5 to 10 mol %. In the case of unneutralized PAA, the degree of crosslinking reaction was at most 15 mol % by heat treatment for 20 min at 200°C. Applying partially neutralized PAA (DN = 10 mol %) raised the degree to about 40 mol % under the same heat‐treatment conditions. FTIR analysis revealed that the hydroxyl group of PVA in the film blended with unneutralized PAA was degraded to a greater degree than that with partially neutralized PAA as a result of heat treatment. It was found that heat treatment at a low pH condition enhances the degradation of the hydroxyl group of PVA, resulting in a decrease of the number of crosslinking sites by esterification. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2420–2427, 2003 相似文献