湿法烟气脱硫塔能效特性研究

针对湿法烟气脱硫能效规律欠缺问题,以150 MW超低排放机组湿法脱硫塔为研究对象,基于脱硫设备的主要能耗和脱硫效率构建了脱硫能效指标——脱硫能效值,并采用数值模拟和理论分析相结合的方法,探究了液气比、入口烟气量、烟气流速、入口SO₂质量浓度、烟气温度等参数以及不同喷淋层组合方式对脱硫能效特性的影响规律。结果表明：脱硫能效值为0.22~0.96 kg/（kW·h）,并随入口SO₂质量浓度增加呈正比例变化,随喷淋层组合数、液气比和入口烟气温度增加呈反比例变化,随入口烟气量和塔内烟气流速增加先上升后下降。研究结果可为脱硫技术评价和脱硫系统节能运行提供参考。     

喷雾半干法脱硫塔内射流卷吸特性的数值模拟

喷雾半干法烟气脱硫塔内射流卷吸特性对塔内烟气与吸收剂的混合以及流场分布均匀有着重要影响。该文通过数值模拟的方法,分析双流体雾化喷嘴的射流卷吸混合特性,得到喷雾半干法烟气脱硫塔内射流流场分布。结果表明：双流体雾化喷嘴在塔内流场呈现中间大两边小的对称分布,并且在靠近塔壁的两侧产生了回流;射流流体与周围气体发生动量交换,对周围气体有明显的卷吸作用,沿着射流轴线方向,射流卷吸量逐渐增加,随着伴随风量的增加,射流卷吸量也逐渐增加。     

气-液膜接触器结构优化及其传质性能研究

以海水作为吸收剂,采用模拟烟气,对气-液膜接触器进行传质性能评价试验,考察其工艺结构参数、气液介质流动速率及方式、气液压差、烟气SO2浓度等因素对传质系数、脱硫率及膜效用的影响.试验表明,在气相压力较低情况下,气液流速、气液压差对总气相传质系数影响明显,而烟气SO2浓度的影响可忽略不计.适当提高膜接触器的填充密度,增加膜吸收级数,采用错流模式的气液流动方式,均可改善烟气流场分布,增大有效传质面积,提高膜效用.与传统吸收塔相比,新型膜气体吸收装置的气液两相独立控制,可灵活应对烟气浓度变化对脱硫稳定性的影响,同时具有低气阻、耐污染、规模可线性放大等优点,工业化应用前景广阔.     

The effect of hydrogen peroxide solution on SO2 removal in the semidry flue gas desulfurization process

The present study attempts to use hydrogen peroxide solution to humidify Ca(OH)₂ particles to enhance the absorption of SO₂ to achieve higher removal efficiency and to solve the valuable reuse of the reaction product in the semidry flue gas desulfurization (FGD) process. Experiments were carried out to examine the effect of various operating parameters including hydrogen peroxide solution concentration, Ca/S molar ratio and approach to adiabatic saturation temperature on SO₂ removal efficiency in a laboratory scale spray reactor. The product samples were analyzed to obtain semi-quantitative measures of mineralogical composition by X-ray diffraction (XRD) with reference intensity ratio (RIR) method and the morphology of the samples was examined by scanning electron microscope (SEM). Compared with spraying water to humidify Ca(OH)₂, SO₂ removal efficiency was improved significantly by spraying hydrogen peroxide solution of 1–3 wt.% to humidify Ca(OH)₂ because hydrogen peroxide solution enhanced the dissolution and absorption rate of SO₂. Moreover, XRD and SEM analyses show that the desulfurization products contain less amount of unreacted Ca(OH)₂ and more amount of stable calcium sulfate with increasing hydrogen peroxide solution concentration. Thus, the process mechanism of the enhanced absorption of SO₂ by spraying hydrogen peroxide solution to humidify Ca(OH)₂ was elucidated on the basis of the experimental results.     

Numerical simulation of semi-dry flue gas desulfurization process in the powder-particle spouted bed

Computational fluid dynamics (CFD) combined with the two-fluid model (TFM) was used for simulation of water vaporization and semi-dry flue gas desulfurization process in a two dimensional powder-particle spouted bed (PPSB), on the basis of gas-solid two-phase flow, the mathematical and physical models of water vaporization process and flue gas desulfurization reaction process have been established through reasonable hypothesis and simplification of the system. The numerical method was used to simulate the desulfurization reaction process and the heat and mass transfer in the powder-particle spouted bed. Simulation results indicate that water vaporization rate was high in spout and annular regions. The main area where flue gas desulfurization reaction occurs was annular area, as a result, the maximum value of desulfurization product rate appears in the annulus. Under the same condition, the desulfurization efficiency of simulation value is 75.75% when the value of slurry water content equals 40 kg-H₂O/kg-dry_sorbent, which is close to but greater than the experimental value (75.03%). The desulfurization efficiency of spouted bed increases first and then decreases with the increase of water content of desulfurization slurry, and the optimum slurry water content for desulfurization process in powder-particle spouted bed was obtained by numerical simulation, which was 40 kg-H₂O/kg-dry_sorbent.     

脱硫塔除雾器安装高度对烟气携液量影响的模拟研究

某电厂运行过程中存在周期性的除雾器阻力上升和结垢现象,造成除雾器局部坍塌。为解决这一问题,通过数值模拟方法对脱硫塔内部气液两相流场进行模拟,研究除雾器距离喷淋层高度(2.0~3.5 m)和喷淋雾化粒径(1500~2500μm)等因素下,除雾器最下沿烟气携带喷淋液滴的情况。计算结果表明:随着除雾器距离喷淋层高度的增加,脱硫塔内部流场更趋均匀化,喷淋液滴到达除雾器的质量浓度相应降低。通过数值模拟得出了量化数据,从而为存在除雾器堵塞坍塌等类似现象的国内燃煤电厂提供诊断思路和优化依据。     

Removal of sulfur dioxide from a continuously operated binary fluidized bed reactor using inert solids and hydrated lime

Sulfur dioxide pollutant was treated in the laboratory with hydrated lime particles having a mean diameter of 9.1 microm in a continuously operating binary fluidized bed reactor also containing inert sand particles with sizes varying from 500 to 590 microm. The influence of temperature (500, 600, 700 and 800 degrees C) on the reaction medium, of the superficial velocity of the gas (0.8, 1.0 and 1.2 m/s), and of the Ca/S molar ratio (1, 2 and 3) on the SO2 removal efficiency were investigated for an inflow gas concentration of 1000 ppm and an initially static bed height of 10.0 cm. The pollutant removal efficiency proved to depend on the temperature and the velocity of the gaseous flow and was strongly influenced by the Ca/S molar ratio. The maximum efficiency of 97.7% was achieved at a temperature of 700 degrees C, a Ca/S ratio of 3 and a velocity of 0.8 m/s. The lime particles' mean residence time was determined by an indirect method, which consisted of integrating the gas concentration curves normalized with respect to time. Based on a calculation of the critical transition velocities, it was concluded that the reactor operated in a bubbling regime under each condition investigated here.     

中温干法烟气脱硫反应器中脱硫剂颗粒磨耗过程的数值模拟

针对循环流化床中温干法烟气脱硫技术中存在的由于脱硫剂颗粒磨耗而引起钙利用率偏低的问题,在多流体模型的基础上,采用能够描述颗粒尺度分布变化过程的直接积分矩方法,对脱硫剂颗粒在中温干法烟气脱硫反应器内的流动扩散以及磨耗情况进行数值模拟,获得颗粒尺度分布随时间的变化过程。结果表明,直接积分矩法-多流体模型能够有效地模拟脱硫剂颗粒在反应器内的流动扩散以及磨耗破碎过程,对于循环流化床中温干法烟气脱硫技术的完善具有重要的意义。     

Numerical simulation on gas-droplet flow characteristics and spray evaporation process in CFB-FGD tower

Nozzle arrangement in the nozzle spray system has a significant impact on the gas-droplet flow characteristics and the temperature distribution within the circulating fluidized bed flue gas desulphurization (CFB-FGD) tower, which is critical to the SO₂ removal efficiency. The effects of spray direction, nozzle number and nozzle spray angle on gas-droplet distribution and temperature distribution inside the FGD tower are investigated with numerical simulation based on a Eulerian-Lagrangian mathematical model. An optimal nozzle arrangement scheme is proposed to improve the contact between gas and water droplets and the flue gas temperature distribution. Results show that upward spray direction is beneficial to the interaction between water droplets, improving gas-droplet flow characteristics and spray evaporation process, and water droplets number trapped by tower wall could be reduced in the water droplets evaporation. With the increase in nozzle number, it is conducive to the contact between flue gas and water droplets to increase the evaporation efficiency of water droplets, as well as the uniformity of temperature distribution inside the tower. With nozzle spray angle increases from 30° to 120°, flue gas velocity decreases, water droplets number trapped by the tower wall increases. The temperature distribution at different cross-section is the most uniform when the nozzle spray angle is 60°.     

海水烟气脱硫膜吸收单元及工艺研究

以海水作为吸收剂,采用自行研制的中空纤维管式膜接触器作为吸收单元,进行膜吸收法海水烟气脱硫过程模拟试验研究.考察膜接触器结构、膜填充密度、膜吸收单元工艺方式、模拟烟气SO2浓度、温度、气液流量等因素对脱硫效率的影响.结果表明,提高烟气温度、海水流量、膜接触器内气液分布均匀程度、气液相有效接触面积、增加膜吸收级数,均有利于提高脱硫率;烟气流量及SO2浓度的增大不利于SO2的脱除;烟气流经管程的气液流程方式利于提高脱硫率,但是气阻大,进气压力高,工程化应用难以实现.提高膜材料传质特性和优化设计膜接触器结构是提高膜吸收法烟气脱硫效率的根本途径.     

Numerical simulation of gas-droplets mixing and spray evaporation in rotary spray desulfurization tower

Motion and evaporation of droplets significantly affect the semidry flue gas desulfurization efficiency and long-term operation. Both the flow field distribution and the heat and mass transfer in the spray towers are studied by numerical simulation, and the process of droplet motion and evaporation is analyzed in detail. Then, two indices, mixing variance and droplet mass-weighted life, are provided to quantify gas droplet mixing and the droplet group evaporation time. The simulation results show that the radial penetration distance of the droplets is longer with the diameter increase, and the appropriate swirl number improves the mixing between the flue gas and droplets. With the increase of droplet diameter and velocity, the droplet distribution in the tower is more widely, obtaining the optimum mixing variance. The droplet mass-weighted life is promoted linearly with the increase of average droplet diameter and the decrease of flue gas temperature. With flue gas temperature increase from 458 k to 488 K, the droplet mass-weighted life decreases linearly by 31%. In comparison, the initial droplet velocity and spray angle have a slight effect on the droplet mass-weighted life.     

脱硫吸收塔废水坑浆液溢流原因分析及控制对策

某燃煤电厂脱硫系统中，#1吸收塔出现废水坑大量浆液溢流、石膏含水量过高和除雾器堵塞等现象。通过分析，发现主要原因为吸收塔负荷较大，导致空塔流速过快、亚硫酸钙氧化不充分、吸收塔内浆液密度过高、脱硫吸收浆液雾化颗粒量不足；结合其脱硫系统的超低排放改造，进行了增设喷淋层和改用单向双头式喷嘴、增设不锈钢托盘、设置增效环、改用三级屋脊高效除雾器、增加备用旋流子等设备改扩建。同时，提出了控制吸收塔pH值和密度、添加脱硫增效剂、增加氧化风机运行台数和提高除雾器清洗频率等改进措施。     

Sulfation and attrition of calcium sorbent in a bubbling fluidized bed

A bubbling fluidized bed reactor was used as a desulfurization apparatus in this study. The height of the bed was 2.5 m, and the inner diameter was 9 cm. The bed materials were calcium sorbent and silica sand. The effects of the operating parameters of the flue gas desulfurization including relative humidity, temperature, superficial gas velocity, and the particle size of calcium sorbent on SO₂ removal efficiency and calcium sorbent conversion and attrition rate in the fluidized bed were investigated. It was found that the temperature effect in our system was negligible from 40 to 65°C. A higher relative humidity had a higher calcium conversion and a higher sulfur dioxide removal efficiency. Moreover, a smaller particle size of calcium sorbent had a lower calcium conversion in the cyclone but a higher sulfur dioxide removal efficiency. A lower superficial gas velocity resulted in a higher sulfur dioxide removal efficiency and a higher calcium conversion, thus, the total volume of the flue gas treated was maximum near the minimum fluidization velocity. Finally, an attrition rate model proposed in this study could predict the elutriation rate satisfactorily.     

昆明市南窑火毁建筑物的控制爆破拆除

介绍了地处闹市区的大面积火毁钢筋混凝土框架结构建筑物拆除爆破的设计与施工工艺 ,并对爆破方案的确定、参数的选择以及所采取的安全措施进行了论述。     

燃煤烟气中Hg迁移转化特性研究

研究了300 MW煤粉锅炉系统选择性催化还原（selective catalytic reduction,SCR）、低低温电除尘器、海水脱硫、湿式电除尘器等超低排放设施在不同工况、不同煤种情况下的Hg迁移特性和脱除能力。结果表明：各工况下总汞排放浓度为1.16~2.90 μg/m³。最终排入大气中的汞主要以单质汞存在,还有少量氧化态汞,颗粒态汞被全部脱除;汞主要是在海水法烟气脱硫中被去除的,低低温电除尘器、海水脱硫、湿式电除尘器对总汞平均脱除率分别为25%、62%、37%;Hg²⁺占比是影响烟气中汞脱除效率的关键,气相中较高的Hg²⁺份额有利于在电除尘器和海水脱硫装置中获得较高的脱除效率;在该配备SCR脱硝、低低温电除尘器、海水脱硫、湿式电除尘器等超低排放设施的300 MW煤粉锅炉电厂中,总汞平均脱除率约为83%,能够实现较大程度的汞脱除。     

Structure optimization of granular bed filter for industrial flue gas filtration containing coagulative particles: An experimental and numerical study

A numerical model for the flow and filtration characteristics of industrial flue gas in granular bed filter (GBF) was established and the local filtration efficiency for different granule layers was investigated. Numerical validation results show that the GBF structure with large size granules at the inlet region and small size granules at the outlet region can effectively improve the filtration performance of GBF and the underlying mechanism was revealed. Then an experimental system was built to validate the suitability of the optimized GBF structure for the filtration of industrial flue gas with coagulative particles. The experimental results show that the optimized GBF structure is also suitable and its superiority is more significant with the increase of filtration time. The results show that the pressure drop and filtration efficiency of the experimental system increase with the increase of dust particles concentration. The existing of coagulative particles is conducive to the growth of smaller size dust particles, the pressure drop and filtration efficiency increase significantly. In addition, the pressure drop and filtration efficiency decrease with the increase of cooling rate. The results of this study are expected to be useful for the design and optimization of industrial flue gas purification and waste heat recovery.     

1060 MW燃煤机组烟道流场性能诊断与优化

燃煤机组烟道结构和布置形式不仅决定了烟风系统阻力的大小,而且影响相关设备的运行状态。某2×1060 MW机组引风机至脱硫塔之间的烟道设计不合理,使两台并联引风机中的一台振动严重,致机壳开裂,导致机组长期低负荷运行,影响机组的可靠性和经济性。该文采用流体动力学计算软件对该部分烟道的流场进行数值模拟,分析烟道设计结构中存在的主要问题,结合现场条件提出最优改造方案。改造实施后,该部分烟道的整体阻力降低为300 Pa,并联引风机出口静压偏差低于3%,将引风机振动由4.6 mm/s以上降为2.5 mm/s左右,控制在安全运行允许的范围内。该次优化解决了引风机振动问题并使烟道阻力大幅降低,为电厂创造了经济效益。     

Wet flue gas desulphurization using a new O-element design

Scrubbing by liquid sprayingis one of the most effective processes used for removal of fine particles and soluble gas pollutants (such as SO₂, HCl, HF) from the flue gas. The primary function of venturi scrubber, which represents the first stage of the wet flue gas cleaning processes, such as in waste incineration plants, is to capture fine particles as well as remove HCl, HF or SO₂ as a result of the decrease in the flue gas temperature before entering the absorption column. In this paper, a newly developed four-branch O-element is proposed as a replacement for venturi scrubber. By means of this device, sulphur dioxide (SO₂) removal efficiency and pressure loss and temperature drop were experimentally calculated. The dependence of these variables on liquid–gas ratio was monitored. The simulated flue gas was prepared by the combustion of the carbon disulphide solution in toluene (1:1 vol.) in the presence of the flame in the reactor. Such prepared flue gas with temperature around 150 °C was processed in the laboratory-designed O-element scrubber. Water was used as an absorbent liquid. The maximal efficiency of SO₂ removal achieved by this process was up to 70 %, which is far better in comparison with the commonly used venturi scrubbers. The pressure drop of our proposed newly designed wet scrubber is similar to that of the commonly used venturi scrubbers; nevertheless, the influence of the amount of the liquid on pressure drop is not so significant. In parallel, a mathematical model describing the mass transfer, enthalpy balance and pH change of the absorbing solution was also developed. Enthalpy balance was calculated by numerical iteration to determine the unknown outlet liquid temperature. Mass transfer calculation was used for the determination of complete Henry constant from all the subsequent SO₂ absorption reactions.     

Effect of the inlet angle on the performance of a cyclone separator using CFD-DEM

Hydrodynamic characteristics in a cyclone separator are simulated by means of DEM-CFD. Reynolds stress turbulence model (RSM) is used to capture gas turbulence. By changing the inlet angle, the distributions of pressure drop, tangential and axial velocity of gas phase are obtained within the cyclone. Simulated results indicate that the flow pattern consists of two regions: loss-free vortex region and forced vortex region. The negative inlet angle brings about a larger pressure drop comparing to positive inlet angle. The separation efficiency and trajectory of particles from simulation are obtained. The effects of inlet angle and particle size on separation efficiency are quantified. The separation efficiency is increased with an increase of particle size, while the separation efficiency firstly increases and then declined as inlet angle changes from negative to positive. An agreement between the numerical simulation and experimental results has been achieved in a cyclone separator.     

Modeling the operation of a three-stage fluidized bed reactor for removing CO2 from flue gases

A bubbling counter-current multistage fluidized bed reactor for the sorption of carbon dioxide (CO(2)) by hydrated lime particles was simulated employing a two-phase model, with the bubble phase assumed to be in plug flow, and the emulsion phase in plug flow and perfectly mixed flow conditions. To meet prescribed permissible limit to emit carbon dioxide from industrial flue gases, dry scrubbing of CO(2) was realized. For the evaluation, a pilot plant was built, on which also the removal efficiency of CO(2) was verified at different solids flow rates. The model results were compared with experimental data in terms of percentage removal efficiency of carbon dioxide. The comparison showed that the EGPF model agreed well with the experimental data satisfactorily. The removal efficiency was observed to be mainly influenced by flow rates of adsorbent and CO(2) concentration.